JP2023525984A - 高品質コークス製品 - Google Patents
高品質コークス製品 Download PDFInfo
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- JP2023525984A JP2023525984A JP2022567031A JP2022567031A JP2023525984A JP 2023525984 A JP2023525984 A JP 2023525984A JP 2022567031 A JP2022567031 A JP 2022567031A JP 2022567031 A JP2022567031 A JP 2022567031A JP 2023525984 A JP2023525984 A JP 2023525984A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/04—Raw material of mineral origin to be used; Pretreatment thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/34—Other details of the shaped fuels, e.g. briquettes
- C10L5/36—Shape
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21B—MANUFACTURE OF IRON OR STEEL
- C21B5/00—Making pig-iron in the blast furnace
- C21B5/007—Conditions of the cokes or characterised by the cokes used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
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- Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
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- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Coke Industry (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
5%と12%との間、10%未満、9.5%未満、9%未満、8%未満、7.5%未満、または7%未満の灰分含有量;
1%未満、0.9%未満、0.8%未満、0.7%未満、0.6%未満、または0.5%未満の硫黄含有量;
2%未満、1%未満、0.4%と1%との間、約0.5%、または約0.3%の揮発性物質(VM)含有量;
15%未満、10%未満、9%未満、8%未満、7%未満、6%未満、5%未満、4%未満、3%未満、2%未満、1%未満、または1%と10%の間の水分含有量;および
少なくとも80%、少なくとも85%、少なくとも90%または少なくとも95%の固定炭素量。
この例では、単純化された2次元ランダム充填モデルによるキュポラ充填のシミュレーションを示す。均一な寸法のコークスと比較して、炉に投入される際に、広い粒度分布を有するコークスは、より大きいかさ密度、より大きな表面積、より低いベッド気孔率を有することが期待される。
(1) コークス片の長さおよび幅の変動を、ユーザーが定義した最大値と最小値の間で許容し、各片は、正方形の小端を有すること(すなわちL×W×W)とする、および
(2) コークス片を傾けて、片のより小さい「角」が許容される空間にフィットできるようにする
ことである。傾きの全範囲を許容した場合、シミュレーションは、コークス片が小端上に起立することを優先した。よって、恣意的に、最大傾斜角度を30度に制限した。
測定されたサイズ分布、底部スクリーンカット推定値、ならびに、前述の式を用いるかさ密度に基づいて、Excelのモデルを使用して鋳物用コークスの水力半径を計算した。
Claims (27)
- 細長い形状を有するコークスであって、該コークスの長さ:幅の比が、少なくとも1.1、少なくとも1.5、少なくとも2.0、少なくとも2.5、少なくとも3.0、少なくとも3.5、少なくとも4.0、少なくとも4.5、少なくとも5.0、少なくとも5.5、少なくとも6.0、少なくとも6.5、少なくとも7.0、少なくとも7.5、少なくとも8.0、少なくとも8.5、少なくとも9.0、少なくとも9.5、または、少なくとも10.0であることを特徴とするコークス。
- 長さ:幅の比が、少なくとも2.0、少なくとも2.5、少なくとも3.0、少なくとも3.5、少なくとも4.0、少なくとも4.5、少なくとも5.0、少なくとも5.5、または少なくとも6.0であることを特徴とする請求項1記載のコークス。
- 長さ:幅の比が少なくとも2.0であることを特徴とする、請求項1または2に記載のコークス。
- 長さ:幅の比が少なくとも3.0であることを特徴とする、請求項1から3のいずれかに記載のコークス。
- 長さ:幅の比が少なくとも4.0である、請求項1~4のいずれかに記載のコークス。
- 長さが、2インチと36インチとの間、3インチと15インチとの間、4インチと12インチとの間、または4インチと10インチとの間であり、幅が、1.5インチと12インチとの間、2インチと8インチとの間、3インチと7インチとの間、2インチと4インチとの間、または4インチと6インチとの間であることを特徴とする、請求項1から5のいずれかに記載のコークス。
- 長さが、少なくとも2インチ、少なくとも3インチ、少なくとも4インチ、少なくとも5インチ、少なくとも6インチ、少なくとも7インチ、少なくとも8インチ、少なくとも9インチ、少なくとも10インチ、少なくとも11インチ、少なくとも12インチ、少なくとも13インチ、少なくとも14インチ、少なくとも15インチ、少なくとも16インチ、少なくとも17インチ、少なくとも18インチ、少なくとも19インチ、at20インチ、少なくとも21インチ、少なくとも22インチ、少なくとも23インチ、少なくとも24インチ、少なくとも25インチ、少なくとも26インチ、少なくとも27インチ、少なくとも28インチ、少なくとも29インチ、少なくとも30インチ、少なくとも31インチ、少なくとも32インチ、少なくとも33インチ、少なくとも34インチ、少なくとも35インチ、または、少なくとも36インチであることを特徴とする、請求項1から6のいずれかに記載のコークス。
- 幅が、少なくとも1.5インチ、少なくとも2インチ、少なくとも3インチ、少なくとも4インチ、少なくとも5インチ、少なくとも6インチ、少なくとも7インチ、少なくとも8インチ、少なくとも9インチ、少なくとも10インチ、少なくとも11インチ、少なくとも12インチ、少なくとも13インチ、少なくとも14インチ、少なくとも15インチ、少なくとも16インチ、少なくとも17インチ、少なくとも18インチであることを特徴とする、請求項1から7のいずれかに記載のコークス。
- 単一の製造工程または単一の炉から製造されるコークス製品の集団であって、
少なくとも30%、少なくとも35%、少なくとも40%、少なくとも45%、少なくとも50%、少なくとも55%、少なくとも60%、少なくとも65%、少なくとも70%、少なくとも75%、少なくとも80%、少なくとも80%、少なくとも80%のコークス製品が細長い形状を有し、前記細長い形状は、
2インチと36インチとの間、3インチと15インチとの間、4インチと12インチとの間、または4インチと10インチとの間の長さ、ならびに、1.5インチと12インチの間、2インチと8インチの間、3インチと7インチの間、2インチと4インチの間、または4インチと6インチの間の幅、または、
少なくとも1.1、少なくとも1.5、少なくとも2.0、少なくとも2.5、少なくとも3.0、少なくとも3.5、少なくとも4.0、少なくとも4.5、少なくとも5.0、少なくとも5.5、少なくとも6.0、少なくとも6.5、少なくとも7.0、少なくとも7.5、少なくとも8.0、少なくとも8.5、少なくとも9.0、少なくとも9.5、または、少なくとも10.0である長さ:幅の比
を有することを特徴とするコークス製品の集団。 - コークス製品が水平炉によって製造されることを特徴とする、請求項9に記載のコークス製品の集団。
- 単一の製造工程または単一の炉から製造されるコークス製品の集団であって、
少なくとも40%、少なくとも45%、少なくとも50%、少なくとも55%、少なくとも60%、少なくとも65%、少なくとも70%、少なくとも75%、少なくとも80%、少なくとも85%、少なくとも90%、少なくとも95%、少なくとも98%、または少なくとも99%のコークス製品が細長い形状を有し、前記細長い形状は、
2インチと36インチとの間、3インチと15インチとの間、4インチと12インチとの間、または4インチと10インチとの間の長さ、ならびに、1.5インチと12インチとの間、2インチと8インチとの間、3インチと7インチとの間、2インチと4インチとの間、または4インチと6インチとの間の幅、または、
少なくとも1.1、少なくとも1.5、少なくとも2.0、少なくとも2.5、少なくとも3.5、少なくとも3.0、少なくとも3.5、少なくとも4.0、少なくとも4.5、少なくとも5.0、少なくとも5.5、少なくとも6.0、少なくとも6.5、少なくとも7.0、少なくとも7.5、少なくとも8.0、少なくとも8.5、少なくとも9.0、少なくとも9.5または少なくとも10.0である長さ:幅の比
を有することを特徴とするコークス製品の集団。 - コークスの実直径よりも大きな水力直径(Dh)を有するコークスであって、前記コークスは、20%と45%との間の反応性指数(CRI)、および5%と60%との間の反応後のコークス強度(CSR)を有することを特徴とする、コークス。
- Dhが、少なくとも2インチ、少なくとも2.5インチ、少なくとも3インチ、少なくとも3.5インチ、少なくとも4インチ、少なくとも4.5インチ、少なくとも5インチ、少なくとも5.5インチ、少なくとも6インチ、少なくとも6.5インチ、少なくとも7インチ、少なくとも7.5インチ、少なくとも8インチ、少なくとも8.5インチ、少なくとも9インチ、少なくとも9.5インチ、少なくとも10インチ、少なくとも10.5インチ、少なくとも11インチ、少なくとも11.5インチ、少なくとも12インチ、少なくとも12.5インチ、少なくとも13インチ、少なくとも13.5インチ、少なくとも14インチ、少なくとも14.5インチ、少なくとも15インチ、少なくとも15.5インチ、少なくとも16インチ、少なくとも16.5インチ、少なくとも17インチ、少なくとも17.5インチ、または、少なくとも18インチであることを特徴とする請求項12に記載のコークス。
- CRIが、40%未満、25%と40%との間、または31%と37%との間であることを特徴とする、請求項12または13に記載のコークス。
- CSRが、5%と50%との間、または15%と40%との間であることを特徴とする、請求項12から14のいずれかに記載のコークス。
- CRIが25%と40%との間であり、CSRが15%と50%との間であることを特徴とする、請求項12から15のいずれかに記載のコークス。
- 落下粉砕試験において少なくとも4インチの寸法を有する出発材料を使用した場合に、処理済みコークスは、少なくとも60%、少なくとも65%、少なくとも70%、少なくとも75%、少なくとも80%、少なくとも85%、または少なくとも90%の4インチ落下粉砕度を有することを特徴とする、請求項12から16のいずれかに記載のコークス。
- 落下粉砕試験において少なくとも4インチの寸法を有する出発材料を使用した場合に、処理済みコークスが、少なくとも80%、少なくとも85%、少なくとも90%、または少なくとも95%の2インチ落下粉砕度を有することを特徴とする、請求項12から17のいずれかに記載のコークス。
- 落下粉砕試験において少なくとも4インチの寸法を有する出発材料を使用した場合に、前処理済みコークスが、少なくとも30%、少なくとも35%、少なくとも40%、少なくとも45%、少なくとも50%、少なくとも55%、少なくとも60%、少なくとも65%、少なくとも70%、少なくとも75%、少なくとも80%、少なくとも85%、または少なくとも90%の4インチ落下粉砕度を有することを特徴とする、請求項12から18のいずれかに記載のコークス。
- 落下粉砕試験において少なくとも4インチの寸法を有する出発材料を使用した場合に、前処理済みコークスが、少なくとも40%、少なくとも45%、少なくとも50%、少なくとも55%、少なくとも60%、少なくとも65%、少なくとも70%、少なくとも75%、少なくとも80%、少なくとも85%、少なくとも90%、または少なくとも95%の2インチ落下粉砕度を有することを特徴とする、請求項12から19のいずれかに記載のコークス。
- 少なくとも80%、少なくとも85%、少なくとも90%、または少なくとも95%の固定炭素量を有することを特徴とする、請求項12から20のいずれかに記載のコークス。
- 5%と12%との間、10%未満、9.5%未満、8%未満、7.5%未満、または7%未満の灰分、ならびに、1%未満、0.9%未満、0.8%未満、0.7%未満、0.6%未満、または0.5%の硫黄含有量を有することを特徴とする、請求項12から21のいずれかに記載のコークス。
- 1%未満、0.9%未満、0.8%未満、0.7%未満、0.6%未満、または0.5%未満の硫黄含有量を有することを特徴とする、請求項12から22のいずれかに記載のコークス。
- 2%未満、1%未満、または0.4%と1%との間、または0.5%と0.3%との間の揮発性物質(VM)含有量を有することを特徴とする、請求項12から23のいずれかに記載のコークス。
- 15%未満、10%未満、9%未満、8%未満、7%未満、6%未満、5%未満、4%未満、3%未満、2%未満、1%未満、または1%と10%との間の水分含有量を有することを特徴とする、請求項12から24のいずれかに記載のコークス。
- 灰色または淡灰色を有することを特徴とする、請求項12から25のいずれかに記載のコークス。
- コークスが水平炉で製造される、請求項12から26のいずれかに記載のコークス。
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US202063019405P | 2020-05-03 | 2020-05-03 | |
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PCT/US2021/030520 WO2021225988A1 (en) | 2020-05-03 | 2021-05-03 | High-quality coke products |
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US11767482B2 (en) | 2023-09-26 |
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