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AR087516A1 - Compuestos de n-tio-antranilamida y sus usos como plaguicidas - Google Patents

Compuestos de n-tio-antranilamida y sus usos como plaguicidas

Info

Publication number
AR087516A1
AR087516A1 ARP120102940A ARP120102940A AR087516A1 AR 087516 A1 AR087516 A1 AR 087516A1 AR P120102940 A ARP120102940 A AR P120102940A AR P120102940 A ARP120102940 A AR P120102940A AR 087516 A1 AR087516 A1 AR 087516A1
Authority
AR
Argentina
Prior art keywords
alkyl
alkoxy
group
radicals
partially
Prior art date
Application number
ARP120102940A
Other languages
English (en)
Original Assignee
Basf Se
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se filed Critical Basf Se
Publication of AR087516A1 publication Critical patent/AR087516A1/es

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61P—SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS
    • A61P33/00—Antiparasitic agents
    • A61P33/02—Antiprotozoals, e.g. for leishmaniasis, trichomoniasis, toxoplasmosis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
    • C07D409/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing three or more hetero rings

Landscapes

  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • Environmental Sciences (AREA)
  • Zoology (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Pest Control & Pesticides (AREA)
  • Agronomy & Crop Science (AREA)
  • Veterinary Medicine (AREA)
  • General Chemical & Material Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Tropical Medicine & Parasitology (AREA)
  • Public Health (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Medicinal Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pyridine Compounds (AREA)

Abstract

También un método para combatir o controlar plagas de invertebrados, un método para proteger el material de propagación vegetal y/o las plantas que crecen de este, al material de propagación vegetal que comprende al menos un compuesto de acuerdo con la presente, un método para tratar o proteger un animal de la infestación o infección por parásitos, a un proceso para la preparación de una composición para tratar animales infestados o infectados y/o para proteger animales de la infestación o infección por parásitos, y un compuesto de acuerdo con la presente para usar como medicamento.Reivindicación 1: Un compuesto caracterizado porque tiene la fórmula general (1) en donde R1 se selecciona del grupo que consiste en halógeno y halometilo; R2 se selecciona del grupo que consiste en hidrógeno, halógeno, halometilo y ciano; R3 se selecciona de hidrógeno, alquilo C1-6, haloalquilo C1-6, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6, haloalquinilo C2-6, cicloalquilo C3-8, halocicloalquilo C3-8, alcoxi C1-4-alquilo C1-4, haloalcoxi C1-4-alquilo C1-4, C(=O)Ra, C(=O)ORb y C(O)NRCRd; R4 es halógeno; R5, R6 se seleccionan independientemente entre sí del grupo que consiste en hidrógeno, alquilo C1-10, cicloalquilo C3-8, alquenilo C2-10, alquinilo C2-10, en donde los radicales alifáticos y cicloalifáticos antes mencionados se pueden sustituir con 1 a 10 sustituyentes Re, y fenilo, que no se sustituye o tiene de 1 a 5 sustituyentes Rf; o R5 y R6, en forma conjunta, representan una cadena de alquileno C2-7, alquenileno C2-7 o alquinileno C6-9 y forman, junto con el átomo de azufre al que están unidos, un anillo saturado, parcialmente insaturado o totalmente insaturado de 3, 4, 5, 6, 7, 8, 9 ó 10 miembros, en donde de 1 a 4 de los grupos CH2 en la cadena de alquileno C2-7, de 1 a 4 de cualquiera de los grupos CH2 o CH en la cadena de alquenileno C2-7 o de 1 a 4 de cualquiera de los grupos CH2 en la cadena de alquinileno C6-9 se pueden reemplazar por 1 a 4 grupos seleccionados independientemente del grupo que consiste en C=O, C=S, O, S, N, NO, SO, SO2 y NH, y en donde los átomos de carbono y/o nitrógeno en la cadena de alquileno C2-7, alquenileno C2-7 o alquinileno C6-9 se pueden sustituir con 1 a 5 sustituyentes seleccionados independientemente del grupo que consiste en halógeno, ciano, alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, alquiltio C1-6, haloalquiltio C1-6, cicloalquilo C3-8, halocicloalquilo C3-8, alquenilo C2-6, haloalquenilo C2-6, alquinilo C2-6 y haloalquinilo C2-6; dichos sustituyentes pueden ser idénticos o diferentes entre sí si hay más de un sustituyente; Ra se selecciona del grupo que consiste en alquilo C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C3-8, alcoxi C1-6, alquiltio C1-6, alquilsulfinilo C1-6, alquilsulfonilo C1-6, en donde uno o más grupos CH2 de los radicales antes mencionados se pueden reemplazar por un grupo C=O, y/o las porciones alifáticas y cicloalifáticas de los radicales antes mencionados pueden ser no sustituidas, parcial o totalmente halogenadas y/o pueden tener 1 ó 2 sustituyentes seleccionados de alcoxi C1-4; fenilo, bencilo, piridilo y fenoxi, en donde los cuatro últimos radicales pueden ser no sustituidos, parcial o totalmente halogenados y/o pueden tener 1, 2 ó 3 sustituyentes seleccionados de alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6, (alcoxi C1-6)carbonilo, alquilamino C1-6 y di-(alquil C1-6)amino; Rb se selecciona del grupo que consiste en alquilo C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C3-8, alcoxi C1-6, alquiltio C1-6, alquilsulfinilo C1-6, alquilsulfonilo C1-6, en donde uno o más grupos CH2 de los radicales antes mencionados se pueden reemplazar por un grupo C=O, y/o las porciones alifáticas y cicloalifáticas de los radicales antes mencionados pueden ser no sustituidas, parcial o totalmente halogenadas y/o pueden tener 1 ó 2 sustituyentes seleccionados de alcoxi C1-4; fenilo, bencilo, piridilo y fenoxi, en donde los cuatro últimos radicales pueden ser no sustituidos, parcial o totalmente halogenados y/o pueden tener 1, 2 ó 3 sustituyentes seleccionados de alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6 y (alcoxi C1-6)carbonilo; Rc, Rd se seleccionan, independientemente entre sí e independientemente de cada caso, del grupo que consiste en hidrógeno, ciano, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C3-8, en donde uno o más grupos CH2 de los radicales antes mencionados se pueden reemplazar por un grupo C=O, y/o las porciones alifáticas y cicloalifáticas de los radicales antes mencionados pueden ser no sustituidas, parcial o totalmente halogenadas y/o pueden tener 1 ó 2 radicales seleccionados de alcoxi C1-4; alcoxi C1-6, haloalcoxi C1-6, alquiltio C1-6, alquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquiltio C1-6, fenilo, bencilo, piridilo y fenoxi, en donde los cuatro últimos radicales mencionados pueden ser no sustituidos, parcial o totalmente halogenados y/o pueden tener 1, 2 ó 3 sustituyentes seleccionados de alquilo C1-6, haloalquilo C1-6, alcoxi C1-6, haloalcoxi C1-6 y (alcoxi C1-6)carbonilo; o Rc y Rd, junto con el átomo de nitrógeno al que están unidos, pueden formar un anillo heterocíclico saturado, parcialmente insaturado o totalmente insaturado de 3, 4, 5, 6 ó 7 miembros, que también puede contener 1 ó 2 heteroátomos más o grupos de heteroátomos seleccionados de N, O, S, NO, SO y SO2, como miembros del anillo, en donde el anillo heterocíclico se puede sustituir opcionalmente con halógeno, haloalquilo C1-4, alcoxi C1-4 o haloalcoxi C1-4; Re se selecciona, independientemente, del grupo que consiste en halógeno, ciano, nitro, -OH, -SH, -SCN, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C3-8, en donde uno o más grupos CH2 de los radicales antes mencionados se pueden reemplazar por un grupo C=O, y/o las porciones alifáticas y cicloalifáticas de los radicales antes mencionados pueden ser no sustituidas, parcial o totalmente halogenadas y/o pueden tener 1 ó 2 radicales seleccionados de alcoxi C1-4; alcoxi C1-6, haloalcoxi C1-6, alquiltio C1-6, alquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquiltio C1-6, -ORa, -NRcRd, -S(O)nRa, S(O)nNRcRd, -C(=O)Ra, -C(=O)NRcRd, -C(=O)ORb, -C(=S)Ra, -C(=S)NRcRd, -C(=S)ORb, -C(=S)SRb, -C(=NRc)Rb, -C(=NRc)NRcRd, fenilo, bencilo, piridilo y fenoxi, en donde los cuatro últimos radicales pueden ser no sustituidos, parcial o totalmente halogenados y/o pueden tener 1, 2 ó 3 sustituyentes seleccionados de alquilo C1-6, haloalquilo C1-6, alcoxi C1-6 y haloalcoxi C1-6; o dos radicales Re vecinos forman juntos un grupo =O, =CH(alquilo C1-4), =C(alquil C1-4)alquilo C1-4, =N(alquilo C1-6) o =NO(alquilo C1-6); Rf se selecciona, independientemente, del grupo que consiste en halógeno, ciano, nitro, -OH, -SH, -SCN, alquilo C1-6, alquenilo C2-6, alquinilo C2-6, cicloalquilo C3-8, en donde uno o más grupos CH2 de los radicales antes mencionados se pueden reemplazar por un grupo C=O, y/o las porciones alifáticas y cicloalifáticas de los radicales antes mencionados pueden ser no sustituidas, parcial o totalmente halogenadas y/o pueden tener 1 ó 2 radicales seleccionados de alcoxi C1-4; alcoxi C1-6, haloalcoxi C1-6, alquiltio C1-6, alquilsulfinilo C1-6, alquilsulfonilo C1-6, haloalquiltio C1-6, -ORa, -NRcRd, -S(O)nRa, S(O)nNRcRd, -C(=O)Ra, -C(=O)NRcRd, -C(=O)ORb, -C(=S)Ra, -C(=S)NRcRd, -C(=S)ORb, -C(=S)SRb, -C(=NRc)Rb y -C(=NRc)NRcRd; k es 0 ó 1; n es 0, 1 ó 2; o un estereoisómero, una sal, un tautómero o un N-óxido de aquel.
ARP120102940A 2011-08-12 2012-08-10 Compuestos de n-tio-antranilamida y sus usos como plaguicidas AR087516A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201161522721P 2011-08-12 2011-08-12

Publications (1)

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AR087516A1 true AR087516A1 (es) 2014-03-26

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Country Status (18)

Country Link
US (1) US9044016B2 (es)
EP (1) EP2742037B1 (es)
JP (1) JP2014522875A (es)
KR (1) KR20140051402A (es)
CN (1) CN103857666B (es)
AR (1) AR087516A1 (es)
AU (1) AU2012297004A1 (es)
BR (1) BR112014003217A2 (es)
CA (1) CA2842858A1 (es)
CO (1) CO6880072A2 (es)
CR (1) CR20140045A (es)
EA (1) EA201400212A1 (es)
ES (1) ES2558166T3 (es)
IL (1) IL230596A0 (es)
IN (1) IN2014CN00979A (es)
MX (1) MX2014001609A (es)
WO (1) WO2013024009A1 (es)
ZA (1) ZA201401723B (es)

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