4.
Consider the following reversible chemical
CHEMICAL EQUILIBRIUM reactions :
1.
In a chemical reaction, A + 2B
K
2C + D,
A2(g) + Br2(g)
K1
2AB(g) .....(1)
the initial concentration of B was 1.5 times of
K
6AB(g) 3A2(g) + 3B2(g) .....(2)
2
the concentration of A, but the equilibrium
The relation between K1 and K2 is :
concentrations of A and B were found to be
(1) K2 = K13 (2) K2 = K1–3
equal. The equilibrium constant(K) for the
1
aforesaid chemical reaction is : (3) K1K2 = 3 (4) K1K2 =
3
(1) 16 (2) 4
5. 5.1g NH4SH is introduced in 3.0 L evacuated
1 flask at 327°C. 30% of the solid NH4SH
(3) 1 (4)
4 decomposed to NH3 and H2S as gases. The Kp
2. Two solids dissociate as follows of the reaction at 327°C is
B(g) + C(g) ; K = x atm2
A(s)
EN p1
C(g) + E(g) ; K = y atm2
D(s) p2
The total pressure when both the solids
dissociate simultaneously is :-
(1) (x + y) atm (2) x2 + y2 atm
(R = 0.082 L atm mol–1K–1, Molar mass of
S = 32 g mol/01, molar mass of N = 14g mol–1)
(1) 1 × 10–4 atm2
(2) 4.9 × 10–3 atm2
(3) 0.242 atm2
(4) 0.242 × 10–4 atm2
(3) 2 ( )
x + y atm (4) x + y atm
LL
6. The value of Kp/KC for the following reactions
3. Consider the reaction, at 300K are, respectively :
N2(g) + 3H2(g) 2NH3(g) (At 300K, RT = 24.62 dm3atm mol–1)
The equilibrium constant of the above reaction 2NO(g)
N2(g) + O2(g)
is KP. If pure ammonia is left to dissociate, the
partial pressure of ammonia at equilibrium is 2NO2(g)
N2O4(g)
given by (Assume that PNH << Ptotal at
A
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equilibrium) 2NH3(g)
N2(g) + 3H2(g)
3
2
1 3
2
1 (1) 1, 24.62 dm3atm mol–1,
(1) 3 K P P (2) 3 K P P
2 2 2 2
606.0 dm6atm2mol–2
4 16
1 1
(2) 1, 4.1 × 10–2 dm–3atm–1 mol–1,
2 2
(3) K P P (4) K P P
2 2
606.0 dm6 atm2 mol–2
16 4 (3) 606.0 dm6atm2mol–2,
1.65 × 10–3 dm3atm–2 mol–1
(4) 1, 24.62 dm3atm mol–1,
1.65 × 10–3 dm–6atm–2 mol2
E
2 Chemical Equilibrium
7. For the following reactions, equilibrium 8. For the reaction,
constants are given : 2SO2(g) + O2(g) 2SO3(g),
S(s) + O2(g) SO2(g); K1 = 1052 DH = –57.2kJ mol–1 and
2S(s) + 3O2(g) 2SO3(g); K2 = 10129 Kc = 1.7 × 1016.
The equilibrium constant for the reaction, Which of the following statement is
2SO2(g) + O2(g) 2SO3(g) is : INCORRECT?
(1) 10181 (2) 10154 (1) The equilibrium constant is large suggestive
(3) 1025 (4) 1077 of reaction going to completion and so no
catalyst is required.
(2) The equilibrium will shift in forward
direction as the pressure increase.
(3) The equilibrium constant decreases as the
temperature increases.
EN 9.
(4) The addition of inert gas at constant volume
will not affect the equilibrium constant.
In which one of the following equilibria,
Kp ¹ Kc ?
(1) NO2(g) + SO2(g) NO(g) + SO3(g)
(2) 2 HI(g) H2(g) + I2(g)
LL
(3) 2NO(g) N2(g) + O2(g)
(4) 2C(s) + O2(g) 2CO(g)
A
1
CHEMICAL EQUILIBRIUM 5. 2SO2(g) + O2(g) 2SO3(g)
1. At 1990 K and 1 atm pressure, there are equal In an equilibrium mixture, the partial pressures
number of Cl2 molecules and Cl atoms in the are PSO3 43 kPa ; PO2 530 Pa and
reaction mixture. The value KP for the reaction
PSO2 45 kPa. The equilibrium constant
Cl2(g) 2Cl(g) under the above conditions is
KP = ______ × 10–2. (Nearest integer)
x × 10–1. The value of x is _______.
2SO2(g) + O2(g) 2SO3(g)
(Rounded off to the nearest integer)
6. Value of KP for the equilibrium reaction
2. The stepwise formation of [Cu(NH3)4]2+ is
N2O4 (g) 2NO2(g) at 288 K is 47.9. The KC for
given below
K1
this reaction at same temperature is _______.
Cu 2 NH3 [Cu(NH 3 )]2
(Nearest integer)
(R = 0.083 L bar K–1 mol–1)
K2
[Cu(NH3 )]2 NH3 [Cu(NH 3 ) 2 ]2
K3
7. For the reaction
[Cu(NH3 )2 ]2 NH3 [Cu(NH3 )3 ]2
A + B 2C
K4
[Cu(NH3 )3 ]2 NH3 [Cu(NH3 ) 4 ]2
the value of equilibrium constant is 100 at
The value of stability constants K1, K2, K3 and 298 K. If the initial concentration of all the
K4 are 104, 1.58 × 103, 5 × 102 and 102 three species is 1 M each, then the equilibrium
respectively. The overall equilibrium constants concentration of C is x × 10–1 M. The value of x
for dissociation of [Cu(NH3)4]2+ is x × 10–12. is ________ .
The value of x is ________. (Rounded off to the (Nearest integer)
nearest integer) 8. Presence of which reagent will affect the
reversibility of the following reaction, and
3. A homogeneous ideal gaseous reaction
change it to a irreversible reaction :
AB2(g) A(g) + 2B(g) is carried out in a 25 litre
hv
CH4 + I2 CH3 – I + HI
flask at 27°C. The initial amount of AB2 was Reversible
1 mole and the equilibrium pressure was 1.9 (1) HOCl
atm. The value of KP is x × 10–2. The value of x (2) dilute HNO2
is______.(Integer answer) (3) Liquid NH3
4. Consider the reaction N2O4(g) 2NO2(g). (4) Concentrated HIO3
The temperature at which KC = 20.4 and 9. PC15 PCl3 + Cl3 ; Kc = 1.844
KP = 600.1, is_____K. (Round off to the 3.0 moles of PCl5 is introduced in a 1 L closed
Nearest Integer). reaction vessel at 380 K. The number of moles
[Assume all gases are ideal and R = 0.0831 L of PCl5 at equilibrium is ___ × 10–3.
bar K–1 mol–1] (Round off to the Nearest Integer)
E
2
10. The equilibrium constant for the reaction 13. The reaction rate for the reaction
1
A(s) M(s) O2 (g) [PtCl4]2– + H2O [Pt(H2O)Cl3]– + Cl–
2
is Kp = 4. At equilibrium, the partial pressure of O2 was measured as a function of concentrations of
is ___ atm. (Round off to the nearest integer) different species. It was observed that
11. The following data was obtained for chemical d PtCl 4
2
= 4.8 × 10–5
PtCl 4 –2.4 ×
2
reaction given below at 975 K. dt
2NO(g) 2H2(g) N2(g) 2H2 O(g)
10–3 Pt(H2 O)Cl3 Cl – .
[NO] [H2] Rate
where square brackets are used to denote molar
mol L–1 mol L–1 mol L–1s–1
concentrations. The equilibrium constant
–5 –5 –9
(A) 8 × 10 8 × 10 7 × 10 Kc=_____. (Nearest integer)
–5 –5 –8
(B) 24 × 10 8 × 10 2.1 × 10 14. When 5.1 g of solid NH4HS is introduced into a
(C) 24 × 10–5 32 × 10–5 8.4 × 10–8 two litre evacuated flask at 27°C, 20% of the
The order of the reaction with respect to NO is solid decomposes into gaseous ammonia and
_______. [Integer answer] hydrogen sulphide. The Kp for the reaction at
12. The equilibrium constant Kc at 298 K for the 27°C is x × 10–2. The value of x is _______.
(Integer answer)
reaction A + B C+D
[Given R = 0.082 L atm K–1 mol–1]
is 100. Starting with an equimolar solution with
concentrations of A, B, C and D all equal to
1M, the equilibrium concentration of D is
_____ × 10–2 M. (Nearest integer)
