PART-B: CHEMISTRY 4.

In Kp = Kc (RT)∆n , ∆n may have :

(1) +ve values

1. Consider the reaction (2) –ve values
2SO2 (g) + O2 (g)  2SO3 (g)
(3) Integer or fractional values
For which Kc = 278 M–1. 0.001 mole of
(4) Either of the above
each of the reagents SO2(g), O2(g) and
Ans. ()
SO3(g) are mixed in a 1.0 L flask.
Determine the reaction quotient of the
system and the spontaneous direction of 5. At 25°C for the reaction,
the system : PCl5(g),  PCl3(g) + Cl2(g)
(1) QC = 0.001; the equilibrium shifts to
the left KC = 0.414. Calculate KP for the reaction
(2) QC = 0.001; the equilibrium shifts to (1) 10.11 (2) 101.1
the right (3) 1.01 (4) 0.11
(3) QC = 1000; the equilibrium shifts to Ans. ()
the right
(4) QC = 1000; the equilibrium shifts to
the left 6. In which of the following reactions, the
Ans. () increase in volume of the container will
favour the formation of products?
2. For the equilibrium (1) C(s) + H2O(g)  CO(g) + H2 (g)
Kc
SO2Cl 2 ( g)  SO2 + Cl 2 the value of is (2) H2 ( g) + I2 ( g)  2HI(g)
Kp
equal to: (3) 4NH3 (g) + 5O2 (g)  4NO(g) + 6H2O(l)
1 (4) 3O2 ( g)  2O3 ( g)
(1) RT (2)
RT
Ans. ()
(3) 1.0 (4) RT
Ans. ()
7. Naphthalene, a white solid used to make
3. At a certain temperature the following mothballs, has vapour pressure of 0.10
reactions have the equilibrium constants mm Hg at 27°C. Hence, Kp and KC for the
as shown below :
equilibrium are :
S(s) + O2 (g)  SO2 (g);Kc =
5 × 1052
C10H8 (s)  C10H8 (g)
2 S( s) + 3O2 ( g)  2SO3 ( g);Kc =
1029
(1) 1.32 × 10–4, 5.36 × 10–6
What is the equilibrium constant KC for
the reaction at the same temperature ? (2) 5.36 × 10–6, 1.32 × 10–4
2SO2 ( g) + O2 ( g)  2SO3 ( g) (3) 0.10, 0.10
(1) 4 × 10–77 (2) 4 × 1023 (4) 0.10, 4.1 × 10–3
(3) 2.05 × 1076 (4) 4 × 10–70 Ans. ()
Ans. ()

Space for Rough Work

NEET (Pre-Medical) | Growth-3 | Minor Test-6 11

8. The conversion of ozone into oxygen is 12. The equilibrium constant KP for the
exothermic. Under what conditions is reaction;
ozone the most stable ?
PCl 5 ( g)  PCl 3 + Cl 2 ( g) is 16.
2O3 (g)  3O2 (g)
If the volume of the container is reduced
(1) At high pressure and low temperature
(2) At low pressure and high temperature to half of its original volume, the value of
(3) At low pressure and low temperature KP for the reaction at the same
(4) At high pressure and high temperature temperature will be:
Ans. ()
(1) 4 (2) 16
(3) 32 (4) 64
9. Given the reaction
2X(g) + Y(g)  Z(g) + 80kcal Ans. ()
Which combination of pressure and
temperature gives the highest yield of Z 13. Consider the reactions,
at equilibrium ?
1
(1) 1000 atm and 100°C NO2 (g)  N (g) + O2 K 1
2 2
(2) 500 atm and 100°C
N2O4 (g)  2NO2 (g) K2
(3) 1000 atm and 500°C
(4) 500 atm and 500°C Give the equilibrium constant for the
Ans. () formation of N2O4 form N2 and O2 :
1 1 1 1
10. Solubility of a substance which dissolves (1) × (2) +
K 1 K2
2
2K 1 K2
with a decrease in volume and
absorption of heat will be favoured by : 1 K2
(3) (4)
(1) High pressure and high temperature K 1K2 K1
(2) Low pressure and high temperature Ans. ()
(3) Low pressure and low temperature
(4) High pressure and low temperature
14. In the following equilibria,
Ans. ()
I: A + 2B  C; K 1
11. The reaction, II : C + D  3A; K2
C2H4 (g) + H2 (g)  C2H6 (g); ∆H =−32.7kcal
III : 6B + D  2C; K3
is carried out in a vessel. The equilibrium
concentration of C2H4 can be increased hence,
by: (1) 3K 1 × K22 =
K3
(1) Increasing the temperature
(2) K31 × K2 =
K3
(2) Decreasing the pressure
(3) Removing some hydrogen (3) 3K 1 × K2 =
K3
(4) All of the above (4) K31 × K22 =
K3
Ans. ()
Ans. ()

Space for Rough Work

NEET (Pre-Medical) | Growth-3 | Minor Test-6 12

15. Consider the following equilibria at 300 K 18. Which oxide of nitrogen is the most
and 400 K with their equilibrium stable :
constants (1) 2NO2 (g)  N2 (g) + 2O2 (g);
300 K 400 K K 6.7 × 1016 mol litre−1
=
I : A( g)  2B(=
g) Keq 10
= Keq 5 (2) 2NO(g)  N2 (g) + O2 (g);
II : C(g)  D(g)
= Keq 2=Keq 5 K 2.2 × 1030 mol litre−1
=
Thus : (3) 2N2O5 (g)  2N2 (g) + 5O2 (g);
(1) I is endothermic, II is exothermic K 1.2 × 1034 mol litre−5
=
(2) I and II both are exothermic (4) 2N2O(g)  2N2 (g) + O2 (g);
(3) I and II both are endothermic
K 3.5 × 1033 mol litre−1
=
(4) I is exothermic, II is endothermic
Ans. ()
Ans. ()

19. When pressure is applied to the

16. A catalyst is a substance which :
equilibrium system :
(1) Shortens the time to reach
Ice  Water. Which of the following
equilibrium
phenomenon will happen ?
(2) Supplies energy to the reaction
(1) More water will be formed
(3) Increases the equilibrium
(2) Equilibrium will not be formed
concentration of the product
(3) More ice will be formed
(4) Changes the equilibrium constant of
(4) Water will evaporate
the reaction
Ans. ()
Ans. ()

20. Increase in the pressure for the following

17. The equilibrium constant for the reaction
equilibrium
N2(g) + O2(g)  2NO(g) is 4 × 10–4 at 200
H2O(l)  H2O(g)
K. In presence of a catalyst, equilibrium
Result in the
is attained ten times faster. Therefore,
I: formation of more H2O(l)
the equilibrium constant in presence of
II : formation of more H2O(g)
the catalyst at 200 K is :
III : increase in boiling point of H2O(l)
(1) 40 × 10–4 (2) 4 × 10–3
IV : decrease in boiling point of H2O(l)
(3) 4 × 10–4 (4) 4 × 10–2
Hence correct statement are.
Ans. ()
(1) I, II (2) II, III
(3) I, III (4) I, IV
Ans. ()
Space for Rough Work

NEET (Pre-Medical) | Growth-3 | Minor Test-6 13

21. At a certain temperature the equilibrium 25. 2.0 moles of PCl5 were introduced in a 2
constant Ke is 0.25 for the reaction : litre flask and heated at 625 K to
A(g) + B(g)  C(g) + D(g)
establish equilibrium when 60% of PCl5
If we take 1 mole of each of four gases in
was dissociated into PCl3 and Cl2. Find
a 10 litre container, what would be the
equilibrium concentration of A(g) ? the value of equilibrium constant.
(1) 0.331 M (2) 0.133 M (1) 0.9 (2) 0.8
(3) 0.033 M (4) 1.33 M (3) 0.7 (4) 0.6
Ans. ()
Ans. ()

22. The equilibrium :

P4 ( g) + 6Cl 2 ( g)  4PCl 3 ( g) 26. The Kp value for the reaction,

Is attained by mixing equal moles of P4 H2 + I2  2HI

and Cl2 in an evacuated vessel. Then at at 460°C is 49. If the initial pressure of
equilibrium :
H2 and I2 is 0.5 atm respectively,
(1) [P4] > [Cl2] (2) [Cl]2 > [PCl3]
determine the partial pressure of HI at
(3) [Cl]2 > [P4] (4) [PCl3] > [P4]
Ans. () equilibrium.
2 3.5
(1) (2)
23. SO3(g) is heated in a closed vessel. An 9 9
equilibrium : 7 8
(3) (4)
2SO3 ( g)  2SO2 ( g) + O2 ( g) 9 9
is established. The vapour density of the Ans. ()
mixture, in which SO3 is 50% dissociated
is :
27. Which graph will show equilibrium
(1) 42 (2) 35
(3) 32 (4) 55 condition?
Ans. ()

24. For the reaction

I2 ( g)  2I( g),K
= 37.6 × 10−6 (1) (2)
c

at 1000 K. If 1.0 mole of I2 is introduced

into a 1.0 litre flask at 1000 K, at
equilibrium :
(1) [I2] > [I]
(2) [I2] < [I] (3) (4) None of these
(3) [I2] = [I]
(4) unpredictable
Ans. () Ans. ()

Space for Rough Work

NEET (Pre-Medical) | Growth-3 | Minor Test-6 14

28. Match the Column-I with Column-II 29. In the reaction PCl5(g)  PCl3(g) + Cl2(g).
Column-I Column-II Which of the graph is/are correct ?
(Reaction) (Effect on
equilibrium)
(A) N2 (g) + 3H2 (g)  2NH3 ; (p) Forward (i)
∆H =−ve shift by
lowering of
temperature
(B) N2 (g) + O2 (g)  2NO(g); (q) Forward
∆H =+ ve shift by use (ii)
in
temperature
(C) PCl 5 (g)  PCl 3 (g) + Cl 2 (g); (r) No effect of
∆H =+ ve pressure
change
(D) 2SO2 (g) + O2 (g)  2SO3 (g); (s) Forward (iii)
∆H =−ve shift by rise
in pressure

(1) (A)→(p); (B)→(q); (C)→(r); (D)→(s) (1) i, ii (2) i, ii, iii

(2) (A)→(p, q, s); (B)→(q, r); (C)→(q); (3) ii, iii (4) i, iii

(D)→(p, s) Ans. ()

(3) (A)→(p, q, r); (B)→(q, s); (C)→(r, q);

(D)→(s) 30. Consider the reaction

(4) (A)→(p, q); (B)→(q, s); (C)→(r, s); (i) 2CO( g) + 2H2O( g)  2CO2 ( g) + 2H2 ( g); =
K1

(D)→(s) (ii) CH4 ( g) + H2O( g)  CO( g) + 3H2 ( g); =

K2
Ans. () (iii) CH4 ( g) + 2H2O( g)  CO2 ( g) + 4H2 ( g); =
K3

Which of the following relation is correct ?

K1 K21
(1) K3 = (2) K3 =
K2 K22

(3) =
K3 K 1 ⋅ K2 (4) K3 = K 1K2
Ans. ()

Space for Rough Work

NEET (Pre-Medical) | Growth-3 | Minor Test-6 15

31. Suphide ions in alkaline solution react 33. Percentage yield of following reaction is
with solid sulphur to form polyvalent plotted against pressure at a definite
sulphide ions. The equilibrium constant
temperature :
for the formation of S22− and S23− form S
2SO2 (g) + O2 (g)  2SO3 (g)
and S2– ions are 1.7 and 3.4 respectively.
Equilibrium constant for the formation of Which of the following relations is
S23− from S22− and S is: correct ?
(1) 1 (2) 2
(3) 4 (4) 3
Ans. ()

32. Which of the following graphs are

correct for the given reaction ;
H2 ( g) + CO2 ( g)  H2O(g) + CO(g) (1) T1 > T2 > T3
Assume initially only H2 and CO2 are (2) T3 > T2 > T1
present : (3) T1 = T2 = T3
(4) T1 > T2 < T3
(1)
Ans. ()

34. A flask containing 5 atm pressure of

A2(g), some solid AB added into flask
which undergoes dissociation according
(2) to 2AB(s)  A2 (g) + B2 (g), Kp = 6 atm2 . The
total pressure (in atm) at equilibrium is:
(1) 10 (2) 6
(3) 11 (4) 15
Ans. ()
(3)
35. One mole of SO3 was placed in a one
litre vessel at a certain temperature. The
following equilibrium was established in
the vessel
2SO3 ( g)  2SO2 ( g) + O2 ( g)
(4)
the equilibrium mixture reacted with 0.2
mole KMnO4 in acidic medium. Hence, KC
is :
Ans. () (1) 0.25 (2) 0.50
(3) 0.125 (4) 1.0
Ans. ()

Space for Rough Work

NEET (Pre-Medical) | Growth-3 | Minor Test-6 16

36. Assertion (A) : For any chemical reaction
at a particular temperature, the
equilibrium constant is fixed and is a
characteristic property.
Reason (R) : Equilibrium constant is
independent of temperature.
(1) Both A and R are true and R is
correct explanation of A.
(2) Both A and R true and R is not
correct explanation of A.
(3) A is true but R is false.
(4) Both A and R are false.
Ans. ()

Space for Rough Work

NEET (Pre-Medical) | Growth-3 | Minor Test-6 17