Prof. Mrs. R.S.

Amrutkar’s
CHEMISTRY ACADEMY
XI-XII/JEE/NEET/MHT-CET
Cuboid, 401,402, 4th Floor, Krushi nagar lane,
Near Don Bosco school, College road, Nashik- 422005
Mob: 9403276008, 9423121555, Website: amrutkarschemistryacademy.com

DATE 10.01.25 Chemical Equilibrium MARKS 50

TEST ID MHT-CET TEST (SET - B) TIME 1.30 hrs

1. In the given reaction N2 + O2 2NO , equilibrium 1) Kc = [H2][N2]/[NH3] 2) Kc = [H2]2[N2]/[NH3]

means that 3) Kc = [H2]3[N2]/[NH3] 4) Kc = [H2]3[N2]/[NH3]2

(1) Concentration of reactant is changing where as 5. Active mass concentration of 96 g of O2(g) contained

concentration of products is constant in a 2 L vessel is -

(2) Concentration of all substances is constant (1) 16 mol/L (2) 1.5 mol/L
(3) Concentration of reactants is constant where as (3) 4 mol/L (4) 24 mol/L
concentration of products is changing 6. In a reaction A(g) + B(g) C(g) + D(g) the rate
(4) Concentration of all substances is changing constant of forward & backward reactions are k1 and
2. Rate of reaction curve for equilibrium can be like : [rf k2 respectively then the equilibrium constant (K) for
= forward rate , rb = backward rate] reaction is expressed as –
k2 k1
(1) K = (2) K =
k1 k2
(1) (2) (3) K = k1 x k2 (4) K = k1 + k2

7. Which of the following is an example of

heterogeneous equilibrium?
(3) (4) All of these 1) Formation of N2O4(s)
2) Dissociation of NH4HS
3. At equilibrium which of the following statement is 3) Decomposition of lime stone
correct? 4) All of the above
1) Concentration of reactants is only constant 8. Write the equilibrium expression for the
2) Products concentration is only constant decomposition of lime stone in a closed vessel.
3) Time is constant CaO [CO 2 ] [CO ]
1) Kc = [CaCO 3 ]
2) Kc = [CaCO2
3]
4) r1=r2
CaO [CO 2 ]
4. The Correct equilibrium constant for the following 3) Kc = [CO 2−
4) Kc = [CO2]
3 ]

reaction 9. N2 + O2 2NO. For this reaction Kp = 100, then

2NH3 ⇋ N2 + 3H2 Kp for reaction, 2NO N2 + O2 will be :
 (1) 0.01 (2) ) 0.1 14. For a reaction N2 + 3H2 2NH3, the value of KC
(3) 10 (4) 100 depends upon :
10. At a certain temperature, the following reactions (1) Initial concentration of the reactants
have the equilibrium constant as shown below : (2) Pressure
S(s) + O2 (g) SO2 (g); Kc1 = 5 × 1052 (3) Temperature
(4) catalyst
2S(s) + 3O2 (g) 2SO3(g); Kc2=1029  
15. The equilibrium constant of a reaction at 298 K
 What is the equilibrium constant Kc for the reaction
and 308 K are 1.0 × 10–2 and 2 × 10–2
at the same temperature ?
Respectively, the reaction is
2SO2(g) + O2 (g) 2SO3(g)
1) exothermic
(1) 2.5 × 1076 (2) 4 × 1023 2) endothermic

(3) 4 × 10–77 (4) None of these 3) May be endothermic or exothermic

4) Cannot be predicted
11. If Kc value for the formation of ammonia is 100.
16. The equilibrium constant of the reaction
Find the Kc value for the reverse process…..
(Kc)2SO2(g) + O2 (g) ⇔ 2SO3 (g) when the
1) 100 2) 200
reaction is conducted in a litre vessel was found to
3) 0.1 4) 0.01
be 2.5 × 10–3. If the reaction is conducted at the
12. For the reaction : Cu(s) + 2Ag+(aq) ⇔ Cu2+(aq) +
temperature in a 2 litre vessel then the value of Kc
2Ag(s), the equilibrium constant is given by
Cu 2+ Ag 2 Cu 2+ Ag + 2
is
1) 2)
Cu Ag + 2 Cu Ag 2 1) 6.25 × 10–4 2) 1.25 × 10–3
Cu 2+ Ag + 2
3) 4) 3) 2.5 × 10–3 4) 5 × 10–3
Ag + 2 Cu 2+
17. When Kc >> 1 for a chemical reaction,
13. Equilibrium constant of some reaction are given as
under ; (1) the equilibrium would be achieved rapidly
(2) the equilibrium would be achieved slowly
(a) x y K = 10–1
(3) product concentrations would be much greater
(b) y z K = 2 × 10–2
than reactant concentrations at equilibrium
(c) P Q K = 3 × 10–4
(4) reactant concentrations would be much greater
(d) R S K = 2 × 10–3 then product concentrations at equilibrium.
Initial concentration of the reactants for each 18. For the following gases equilibrium, N2O4 (g)
reaction was taken be equal :
2NO2 (g), Kp is found to be equal to Kc. This is
Review the above reaction and indicate the reactions
attained when :
in which the reactants and products respectively
(1) 0oC (2) 273 K
were of highest concentration : -
(3) 1 K (4) 12.19 K
(1) d, c (2) c, a
19. In a reversible reaction H2(g) + I2(g) ⇔ 2HI(g), if
(3) a, d (4) b, c
the concentration of H2 and I2 are increased, the
value of Kc
 1) Decreases concentration of B. What is the concentration of D at
2) Increases equilibrium?
3) Remains the same (1) n/2 (2) (3n – 1/2)
4) Changes exponentially (3) (n – n/3) (4) n
20. For the homogeneous reaction : 4NH3(g) + 5O2(g) 26. A certain quantity of PCl5 was heated in a 10 litre
⇔ 4NO(g) + 6H2O(g) the equilibrium constant Kc
vessel at 250ºC. At equilibrium the vessel contains
has the unit of
0.1 mole of PCl5 0.20 mole of PCl3 and 0.2 mole of
1) (Conc)–1 2) Conc.
Cl2; The equilibrium constant of the reaction PCl5(g)
3) (Conc)+10 4) It is dimensionless
21. For which reaction is Kp = KC : PCl3(g) + Cl2(g) is :

(1) 2 NOCl(g) 2NO(g) + Cl2(g) (1) 0.02 (2) 0.05

(3) 0.04 (4) 0.025
(2) N2(g) + 3H2(g) 2NH3(g)
27. For the reaction N2 (g) + O2 (g) ⇔ 2NO (g); △H =
(3) H2(g) + Cl2(g) 2HCl(g)
180 kJ mol-1. Which of the following is not true?
(4) 2SO2(g) + O2(g) 2SO3(g)
1) Change in pressure at constant volume does not
22. For hypothetical equilibrium, 4A(g) + 5B(g) effect the equilibrium
4X(g) +6Y(g) 2) △n = 0
The unit of KC will be : 3) The formation of NO is increased at higher
temperature
(1) litre mole–1 (2) mole litre–1
4) The formation of NO is decreased at higher
(3) litre mole–2 (4) mole2 litre–2
temperature
23. For which of the reversible reaction Kp = Kc.
28. In the equilibrium 4H2O (g) + 3Fe (s) ⇔ Fe3O4 (s)
1) N2(g) + 3H2(g) ⇔ 2NH3 (g)
+ 4H2 (g) the yield of H2 can be increased by
2) 2SO2(g) + O2(g) ⇔ 2SO3 (g)
1) Increasing the pressure
3) PCl3(g) + Cl2(g) ⇔ PCl5 (g)
2) Passing more steam
4) N2(g) + O2(g) ⇔ 2NO (g)
3) Increasing the mass of iron
24. For the reaction H2 (g) + I2 (g) ⇔ 2HI (g) at 721 K,
4) Decreasing the pressure
the value of equilibrium constant is 50. The value
29. 4 moles of A are mixed with 4 moles of B, when 2
of Kp under the same conditions will be
moles of C are formed at equilibrium, according to
1) 0.02 2) 0.2
the reaction, A + B C + D. The equilibrium
3) 50 4) 50/RT
constant is :
25. The reaction A(g) + B(g) C(g) + D(g) is studied
(1) 4 (2) 1
in a one litre vessel at 250°C. The initial
(3) (4)
concentration of A was 3n and that of B was n. When
30. In the reaction 2P(g) + Q(g) 3R(g) + S(g). If 2
equilibrium was attained, equilibrium concentration
moles each of P and Q taken initially in a 1 litre flask.
of C was found to the equal to the equilibrium
At equilibrium which is true :
(1) [P] < [Q] (2) [P] = [Q]
 (3) [Q] = [R] (4) None of these ρ2 α2ρ
3) Kp = 1− α 2 4) Kp = 1− α 2
31. For the reaction C(s) + CO2(s) ⇌ 2CO(g), the
37. 28 g of N2 and 6 g of H2 were kept at 400ºC in 1 litre
partial pressure of CO2 and CO is 2.0 and 4.0 atm.
vessel, the equilibrium mixture contained 17g of
Respectively, at equilibrium. The Kp of the reaction
NH3. The value of KC for the reaction N2 + 3H2
is
1) 0.5 2) 5.0 2NH3 is :

3) 30.0 4) 8.0 (1) 7.5 (2) 0.5

32. 2 mol of N2 is mixed with 6 mol of H2 in closed (3) 0.6 (4) 100
vessel of one litre capacity. If 50% N2 is 38. A mixture of 0.3 mole of H2 and 0.3 mole of I2 is
concentrated into NH3 at equilibrium, the value of allowed to react in a 10 litre evacuated flask at
Kc for the reaction N2(g) + 3H2(g) ⇌ 2NH2(g)
500ºC. Equilibrium constant for the reaction H2 + I2
1) 4/27 2) 27/4
2HI , is found to be 64. The amount of
3) 2/27 4) 20
unreacted I2 at equilibrium is :
33. 1 mole of N2 and 2 moles of H2 are allowed to react
(1) 0.15 mole (2) 0.06 mole
in a 1 dm3 vessel. At equilibrium, 0.8 mole of NH3 is
(3) 0.03 mole (4) 0.2 mole
formed. The concentration of H2 in the vessel is : 39. A reaction mixture containing H2, N2 and NH3 has
(1) 0.6 mol/L (2) 0.8 mol/L partial pressure 2 atm, 1 atm and 3 atm respectively
(3) 0.2 mol/L (4) 0.4 mol/L at 725 K. If the value of KP for the reaction, N2 + 3H2
34. An equilibrium mixture for the reaction
2NH3 is 4.28  10–5 atm–2 at 725 K, in which
2H2S 2H2(g) + S2(g)
direction the net reaction will go :
had 1 mol of H2S, 0.2 mol of H2 and 0.8 mol of S2 in
(1) Forward
a 2 litre flask. The value of KC in mol lit–1 is : (2) Backward
(1) 0.08 (2) 0.016 (3) No net reaction
(3) 0.004 (4) 0.160 (4) Direction of reaction cannot be predicted
35. The equilibrium constant for the reaction N2(g) + 40. For the reaction,
O2(g) ⇌ 2NO(g) at temperature T is 4×10-4. The 2A + B 3C at 298 K, KC = 49
value of Kc for the reaction NO(g) ⇌ ½ N2(g) + ½
A 3L vessel contains 2, 1 and 3 moles of A, B and C
O2 (g) at the same temperature is
respectively. The reaction at the same temperature
1) 25 × 102 2) 50
(1) must proceed in forward direction
3) 4 × 10-4 4) 10.00
(2) must proceed in backward direction
36. In this dissociation of PCI5 as PCI5(g) ⇌ PCI3(g) +
(3) must be equilibrium
CI2(g) if the degree of dissociation is α at
(4) can not be predicted
equilibrium constant for the reaction is
α2 α2ρ2
1) Kp = 1+ α 2 ρ 2) Kp = 1+ α 2
41. 4 moles of PCl5 are heated at constant temperature 47. 0.5 mole of H2(g) and 1.0 mole of HI(g) are added

in closed container. If degree of dissociation for PCl5 to a 1.0 L vessel and allowed to reach equilibrium
according to the following reaction: H2 + I2 ⇌
is 0.5 calculate total number of moles at equilibrium:
2H(g). If x is the equilibrium concentration of
(1) 4.5 (2) 6
I2(g), the correct equilibrium constant expression
(3) 3 (4) 4
is
42. The dissociation of CO2 can be expressed as 2CO2
𝑥(0.5 − 𝑥) (2 − 𝑥) 2 )
1) 2)
2CO + O2. If the 2 moles of CO2 is taken initially (1 + 2𝑥) 2 (0.5 + 𝑥) 2

𝑥(2 − 𝑥) 2 (1 − 𝑥) 2
and 40% of the CO2 is dissociated equilibrium then 3) (0.5 − 𝑥) 2 4) (0.5 + 𝑥)𝑥

total number of moles at equilibrium : 48. Manufacture of ammonia by Haber’s process

(1) 2.4 (2) 2.0 involves the reaction N2 + 3H2 ⇔ 2NH3; △H = -

(3) 1.2 (4) 5 22.4K. cals. The effect of increase of temperature

43. A chemical reaction is at equilibrium when on the equilibrium is

1) Equilibrium is shifted to the right
(1) Reactants are completely transformed into
2) Equilibrium is unaffected
products
3) Equilibrium is shifted to the left
(2) The rates of forward and backward reactions are
4) Equilibrium is shifted first to right then to left
equal
49. For the equilibrium N2 + 3H2 2NH3 Kc at
(3) Formation of products is minimised
(4) Equal amounts of reactants and products are 1000K is 2.37 × 10–3 . If the equilibrium

present concentration of N2 and H2 are 2M and 3M

44. The correct relation between Kc, Kf and Kb…… respectively, then [NH3] at equilibrium is :
1) Kc = Kf x Kb 2) Kc = Kf/Kb (1) 0.00358 M (2) 0.0358 M
3) Kc = Kb/Kf 4) Kc = Kb2/Kf (3) 0.358 M (4) 3.58 M
45. The unit of equilibrium constant for the formation 50. Kc = 9 for the reaction, A + B C + D, If A and B
of HI from its elements?
are taken in equal amounts, then ratio of C to A at
1) moles/litre 2) moles/litre2
equilibrium is :
3) moles2/litre2 4) No unit
(1) 1 (2) 0.25
46. For the reaction A B ; KC = 2
(3) 0.75 (4) None of these
B C ; KC = 4, C D ; KC = 6

KC for the reaction A D

(1) 12 (2) 4/3

(3) 24 (4) 48