US20100330430A1 - Lithium secondary battery with high energy density - Google Patents
Lithium secondary battery with high energy density Download PDFInfo
- Publication number
- US20100330430A1 US20100330430A1 US12/829,116 US82911610A US2010330430A1 US 20100330430 A1 US20100330430 A1 US 20100330430A1 US 82911610 A US82911610 A US 82911610A US 2010330430 A1 US2010330430 A1 US 2010330430A1
- Authority
- US
- United States
- Prior art keywords
- lithium
- secondary battery
- capacity
- electrode
- positive electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 229910052744 lithium Inorganic materials 0.000 title claims abstract description 245
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 title claims abstract description 233
- 229910052751 metal Inorganic materials 0.000 claims abstract description 61
- 239000002184 metal Substances 0.000 claims abstract description 61
- 238000003860 storage Methods 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 26
- 230000002441 reversible effect Effects 0.000 claims abstract description 20
- 229910000314 transition metal oxide Inorganic materials 0.000 claims abstract description 16
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 37
- 230000002427 irreversible effect Effects 0.000 claims description 18
- 239000011149 active material Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 13
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 9
- 238000000151 deposition Methods 0.000 claims description 9
- 239000011888 foil Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 229920000642 polymer Polymers 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- 239000000956 alloy Substances 0.000 claims description 6
- AYTAKQFHWFYBMA-UHFFFAOYSA-N chromium dioxide Chemical compound O=[Cr]=O AYTAKQFHWFYBMA-UHFFFAOYSA-N 0.000 claims description 6
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 claims description 6
- 229910045601 alloy Inorganic materials 0.000 claims description 5
- 238000009831 deintercalation Methods 0.000 claims description 5
- 238000009830 intercalation Methods 0.000 claims description 5
- 239000007772 electrode material Substances 0.000 claims description 4
- 229910052710 silicon Inorganic materials 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- GRUMUEUJTSXQOI-UHFFFAOYSA-N vanadium dioxide Chemical compound O=[V]=O GRUMUEUJTSXQOI-UHFFFAOYSA-N 0.000 claims description 3
- 230000002687 intercalation Effects 0.000 claims description 2
- 229910000733 Li alloy Inorganic materials 0.000 abstract description 6
- 239000001989 lithium alloy Substances 0.000 abstract description 6
- 239000010410 layer Substances 0.000 description 30
- 238000001994 activation Methods 0.000 description 13
- 230000004913 activation Effects 0.000 description 12
- 239000011247 coating layer Substances 0.000 description 9
- 230000008569 process Effects 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000007774 positive electrode material Substances 0.000 description 5
- PDHXHYRJLUNSDZ-UHFFFAOYSA-N [C].C#C Chemical group [C].C#C PDHXHYRJLUNSDZ-UHFFFAOYSA-N 0.000 description 4
- 239000006230 acetylene black Substances 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000003990 capacitor Substances 0.000 description 4
- 210000004027 cell Anatomy 0.000 description 4
- 239000010949 copper Substances 0.000 description 4
- 239000007773 negative electrode material Substances 0.000 description 4
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- 229910002097 Lithium manganese(III,IV) oxide Inorganic materials 0.000 description 3
- 239000003575 carbonaceous material Substances 0.000 description 3
- 230000008021 deposition Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- -1 explosion Chemical compound 0.000 description 3
- 229910001416 lithium ion Inorganic materials 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 206010054949 Metaplasia Diseases 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 210000001787 dendrite Anatomy 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 229910021437 lithium-transition metal oxide Inorganic materials 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 230000015689 metaplastic ossification Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229910003528 Li(Ni,Co,Al)O2 Inorganic materials 0.000 description 1
- 229910003548 Li(Ni,Co,Mn)O2 Inorganic materials 0.000 description 1
- 229910052493 LiFePO4 Inorganic materials 0.000 description 1
- 229910013191 LiMO2 Inorganic materials 0.000 description 1
- 229910003005 LiNiO2 Inorganic materials 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 239000002355 dual-layer Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052609 olivine Inorganic materials 0.000 description 1
- 239000010450 olivine Substances 0.000 description 1
- 239000005486 organic electrolyte Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000011232 storage material Substances 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/42—Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
- H01M10/44—Methods for charging or discharging
- H01M10/446—Initial charging measures
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/134—Electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/362—Composites
- H01M4/366—Composites as layered products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/386—Silicon or alloys based on silicon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/40—Alloys based on alkali metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/46—Alloys based on magnesium or aluminium
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T156/00—Adhesive bonding and miscellaneous chemical manufacture
- Y10T156/10—Methods of surface bonding and/or assembly therefor
Definitions
- the lithium layer is formed using a method of compressing a metal foil on the electrode surface, a method of depositing metal lithium on the electrode surface, or a method of dispersing and coating particles, including an excessive amount of metal lithium, together with a specific binder polymer on the electrode surface.
- the transition metal oxide includes one or more selected from a group comprising MnO 2 , MoO 3 , VO 2 , V 2 O 5 , V 6 O 13 , Cr 3 O 8 , and CrO 2 .
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Composite Materials (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/304,829 US8497040B2 (en) | 2009-05-26 | 2011-11-28 | Lithium secondary battery with high energy density |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2009-0045776 | 2009-05-26 | ||
KR20090045776 | 2009-05-26 | ||
PCT/KR2010/003313 WO2010137862A2 (ko) | 2009-05-26 | 2010-05-26 | 고에너지 밀도 리튬이차전지 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2010/003313 Continuation WO2010137862A2 (ko) | 2009-05-26 | 2010-05-26 | 고에너지 밀도 리튬이차전지 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/304,829 Division US8497040B2 (en) | 2009-05-26 | 2011-11-28 | Lithium secondary battery with high energy density |
Publications (1)
Publication Number | Publication Date |
---|---|
US20100330430A1 true US20100330430A1 (en) | 2010-12-30 |
Family
ID=43223235
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/829,116 Abandoned US20100330430A1 (en) | 2009-05-26 | 2010-07-01 | Lithium secondary battery with high energy density |
US13/304,829 Active US8497040B2 (en) | 2009-05-26 | 2011-11-28 | Lithium secondary battery with high energy density |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/304,829 Active US8497040B2 (en) | 2009-05-26 | 2011-11-28 | Lithium secondary battery with high energy density |
Country Status (7)
Country | Link |
---|---|
US (2) | US20100330430A1 (de) |
EP (1) | EP2437331B1 (de) |
JP (1) | JP5509475B2 (de) |
KR (1) | KR101156608B1 (de) |
CN (1) | CN102449811A (de) |
TW (1) | TWI425703B (de) |
WO (1) | WO2010137862A2 (de) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120227252A1 (en) * | 2011-03-08 | 2012-09-13 | GM Global Technology Operations LLC | Silicate cathode for use in lithium ion batteries |
US9139441B2 (en) | 2012-01-19 | 2015-09-22 | Envia Systems, Inc. | Porous silicon based anode material formed using metal reduction |
US9166222B2 (en) | 2010-11-02 | 2015-10-20 | Envia Systems, Inc. | Lithium ion batteries with supplemental lithium |
US9190694B2 (en) | 2009-11-03 | 2015-11-17 | Envia Systems, Inc. | High capacity anode materials for lithium ion batteries |
US9281515B2 (en) | 2011-03-08 | 2016-03-08 | Gholam-Abbas Nazri | Lithium battery with silicon-based anode and silicate-based cathode |
EP3076416A4 (de) * | 2013-11-29 | 2017-01-18 | Asahi Kasei Kabushiki Kaisha | Lithium-ionen-kondensator |
US9601228B2 (en) | 2011-05-16 | 2017-03-21 | Envia Systems, Inc. | Silicon oxide based high capacity anode materials for lithium ion batteries |
US9761902B2 (en) | 2012-11-12 | 2017-09-12 | Panasonic Intellectual Property Management Co., Ltd. | Method for manufacturing nonaqueous electrolyte battery, and nonaqueous electrolyte battery |
US9780358B2 (en) | 2012-05-04 | 2017-10-03 | Zenlabs Energy, Inc. | Battery designs with high capacity anode materials and cathode materials |
US10062906B2 (en) * | 2014-10-06 | 2018-08-28 | Lg Chem, Ltd. | Electrode having enhanced adhesion for lithium secondary batteries |
US10290871B2 (en) | 2012-05-04 | 2019-05-14 | Zenlabs Energy, Inc. | Battery cell engineering and design to reach high energy |
EP3503262A4 (de) * | 2016-11-21 | 2019-08-21 | LG Chem, Ltd. | Elektrode und lithiumsekundärbatterie damit |
US11094925B2 (en) | 2017-12-22 | 2021-08-17 | Zenlabs Energy, Inc. | Electrodes with silicon oxide active materials for lithium ion cells achieving high capacity, high energy density and long cycle life performance |
US11316156B2 (en) | 2017-08-11 | 2022-04-26 | Lg Energy Solution, Ltd. | Pre-lithiation using lithium metal and inorganic composite layer |
US11322736B2 (en) * | 2017-06-08 | 2022-05-03 | Lg Energy Solution, Ltd. | Negative electrode, secondary battery including the same, and method of preparing the negative electrode |
US11430977B2 (en) * | 2017-10-16 | 2022-08-30 | Lg Energy Solution, Ltd. | Lithium electrode and lithium secondary battery comprising same |
US11476494B2 (en) | 2013-08-16 | 2022-10-18 | Zenlabs Energy, Inc. | Lithium ion batteries with high capacity anode active material and good cycling for consumer electronics |
US11545660B2 (en) | 2017-10-20 | 2023-01-03 | Lg Energy Solutions, Ltd. | Long-life and ultra-high energy density lithium secondary battery |
US11545659B2 (en) | 2017-11-21 | 2023-01-03 | Lg Energy Solution, Ltd. | Negative electrode for lithium secondary battery and manufacturing method thereof |
WO2025035640A1 (zh) * | 2023-08-14 | 2025-02-20 | 天津中能锂业有限公司 | 一种锂电池负极及其制备方法和应用 |
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JP5625848B2 (ja) * | 2010-12-09 | 2014-11-19 | 日本電気株式会社 | リチウムイオン二次電池及びその製造方法 |
KR101386156B1 (ko) * | 2012-05-08 | 2014-04-21 | 한국전기연구원 | 주석계 음극활물질 전극 및 그 제조방법 및 이를 구비한 리튬이차전지 |
US20150000118A1 (en) * | 2013-06-26 | 2015-01-01 | Xin Zhao | Method for manufacturing graphene-incorporated rechargeable li-ion battery |
KR102363963B1 (ko) | 2016-10-19 | 2022-02-17 | 주식회사 엘지에너지솔루션 | 리튬 이차전지 |
WO2018093088A2 (ko) | 2016-11-21 | 2018-05-24 | 주식회사 엘지화학 | 전극 및 이를 포함하는 리튬 이차 전지 |
KR102172070B1 (ko) | 2017-01-09 | 2020-10-30 | 주식회사 엘지화학 | 리튬 메탈 패터닝 및 이를 이용한 전기화학 소자 |
KR102254353B1 (ko) * | 2017-03-10 | 2021-05-21 | 주식회사 엘지화학 | 이차전지의 충전방법 |
KR102140128B1 (ko) * | 2017-06-20 | 2020-07-31 | 주식회사 엘지화학 | 리튬 전극 및 이를 포함하는 리튬 이차전지 |
EP3584860A4 (de) | 2017-07-12 | 2020-04-29 | LG Chem, Ltd. | Negativelektrode für lithiumsekundärbatterie, lithiumsekundärbatterie damit und verfahren zur herstellung davon |
CN111326717B (zh) * | 2018-12-13 | 2021-11-16 | 深圳先进技术研究院 | 铝负极材料、制备方法及二次电池 |
KR102804521B1 (ko) * | 2019-11-22 | 2025-05-07 | 주식회사 엘지에너지솔루션 | 플렉서블 이차전지 |
KR20210112908A (ko) * | 2020-03-06 | 2021-09-15 | 주식회사 엘지에너지솔루션 | 신규한 이차 전지의 제조 방법 |
CN114068871B (zh) * | 2020-07-31 | 2023-04-28 | 天津中能锂业有限公司 | 双面覆超薄锂层复合带及其制备方法 |
Citations (6)
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US5130211A (en) * | 1990-10-24 | 1992-07-14 | Her Majesty The Queen In Right Of The Provence Of British Columbia | Electrolyte solution sequestering agents for electrochemical cells having carbonaceous electrodes |
US6706447B2 (en) * | 2000-12-22 | 2004-03-16 | Fmc Corporation, Lithium Division | Lithium metal dispersion in secondary battery anodes |
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Also Published As
Publication number | Publication date |
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JP5509475B2 (ja) | 2014-06-04 |
EP2437331A4 (de) | 2013-11-27 |
US8497040B2 (en) | 2013-07-30 |
EP2437331B1 (de) | 2016-10-12 |
US20120070742A1 (en) | 2012-03-22 |
TW201106521A (en) | 2011-02-16 |
WO2010137862A3 (ko) | 2011-03-31 |
TWI425703B (zh) | 2014-02-01 |
WO2010137862A2 (ko) | 2010-12-02 |
KR101156608B1 (ko) | 2012-06-15 |
EP2437331A2 (de) | 2012-04-04 |
CN102449811A (zh) | 2012-05-09 |
KR20100127730A (ko) | 2010-12-06 |
JP2012528450A (ja) | 2012-11-12 |
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