SK128597A3 - Process for activating polysaccharides, polysaccharides produced by this process, and use thereof - Google Patents

Process for activating polysaccharides, polysaccharides produced by this process, and use thereof Download PDF

Info

Publication number: SK128597A3
Authority: SK; Slovakia
Prior art keywords: cellulose; polysaccharide; ammonia; pressure; liquid ammonia
Prior art date: 1995-03-25

Application number

SK1285-97A

Other languages

English (en)

Slovak (sk)

Inventor

Ties Karstens

Hans Steinmeier

Original Assignee

Rhodia Ag Rhone Poulenc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1995-03-25

Filing date

1996-03-22

Publication date

1998-03-04

1996-03-22 Application filed by Rhodia Ag Rhone Poulenc filed Critical Rhodia Ag Rhone Poulenc

1998-03-04 Publication of SK128597A3 publication Critical patent/SK128597A3/sk

Links

238000000034 method Methods 0.000 title claims abstract description 69
229920001282 polysaccharide Polymers 0.000 title claims abstract description 57
239000005017 polysaccharide Substances 0.000 title claims abstract description 57
230000008569 process Effects 0.000 title claims abstract description 31
230000003213 activating effect Effects 0.000 title claims abstract description 9
150000004676 glycans Chemical class 0.000 title claims abstract 20
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 187
229920002678 cellulose Polymers 0.000 claims abstract description 80
239000001913 cellulose Substances 0.000 claims abstract description 79
229920002907 Guar gum Polymers 0.000 claims abstract description 15
239000000665 guar gum Substances 0.000 claims abstract description 15
235000010417 guar gum Nutrition 0.000 claims abstract description 15
229960002154 guar gum Drugs 0.000 claims abstract description 15
229920002101 Chitin Polymers 0.000 claims abstract description 13
238000006884 silylation reaction Methods 0.000 claims abstract description 9
230000010933 acylation Effects 0.000 claims abstract description 7
238000005917 acylation reaction Methods 0.000 claims abstract description 7
229920002472 Starch Polymers 0.000 claims abstract description 5
230000029936 alkylation Effects 0.000 claims abstract description 5
238000005804 alkylation reaction Methods 0.000 claims abstract description 5
239000008107 starch Substances 0.000 claims abstract description 5
235000019698 starch Nutrition 0.000 claims abstract description 5
229910021529 ammonia Inorganic materials 0.000 claims description 74
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 43
239000000463 material Substances 0.000 claims description 39
239000002360 explosive Substances 0.000 claims description 18
239000000126 substance Substances 0.000 claims description 12
238000010438 heat treatment Methods 0.000 claims description 7
229920001131 Pulp (paper) Polymers 0.000 claims description 5
238000002441 X-ray diffraction Methods 0.000 claims description 5
238000004519 manufacturing process Methods 0.000 claims description 4
229920000926 Galactomannan Polymers 0.000 claims description 3
108090000623 proteins and genes Proteins 0.000 claims description 3
102000004169 proteins and genes Human genes 0.000 claims description 3
230000009467 reduction Effects 0.000 claims description 3
230000021235 carbamoylation Effects 0.000 claims description 2
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OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 claims 2
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QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
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238000004220 aggregation Methods 0.000 description 6
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ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 5
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238000001035 drying Methods 0.000 description 5
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125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 4
FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 4
239000000178 monomer Substances 0.000 description 4
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QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
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JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 2
OURXRFYZEOUCRM-UHFFFAOYSA-N 4-hydroxymorpholine Chemical compound ON1CCOCC1 OURXRFYZEOUCRM-UHFFFAOYSA-N 0.000 description 1
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229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
244000007835 Cyamopsis tetragonoloba Species 0.000 description 1
239000004593 Epoxy Chemical class 0.000 description 1
PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
229920001202 Inulin Polymers 0.000 description 1
238000006845 Michael addition reaction Methods 0.000 description 1
239000005662 Paraffin oil Substances 0.000 description 1
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240000008042 Zea mays Species 0.000 description 1
235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
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238000005299 abrasion Methods 0.000 description 1
125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 1
239000012345 acetylating agent Substances 0.000 description 1
238000005903 acid hydrolysis reaction Methods 0.000 description 1
239000000783 alginic acid Substances 0.000 description 1
235000010443 alginic acid Nutrition 0.000 description 1
229920000615 alginic acid Polymers 0.000 description 1
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150000004781 alginic acids Chemical class 0.000 description 1
150000008044 alkali metal hydroxides Chemical class 0.000 description 1
230000003113 alkalizing effect Effects 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
235000011114 ammonium hydroxide Nutrition 0.000 description 1
150000003863 ammonium salts Chemical class 0.000 description 1
238000005280 amorphization Methods 0.000 description 1
239000012298 atmosphere Substances 0.000 description 1
230000005540 biological transmission Effects 0.000 description 1
229920001222 biopolymer Polymers 0.000 description 1
150000004657 carbamic acid derivatives Chemical class 0.000 description 1
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125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
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238000004090 dissolution Methods 0.000 description 1
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238000005485 electric heating Methods 0.000 description 1
230000032050 esterification Effects 0.000 description 1
238000005886 esterification reaction Methods 0.000 description 1
238000011156 evaluation Methods 0.000 description 1
238000001704 evaporation Methods 0.000 description 1
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239000004744 fabric Substances 0.000 description 1
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239000002657 fibrous material Substances 0.000 description 1
239000003574 free electron Substances 0.000 description 1
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230000003301 hydrolyzing effect Effects 0.000 description 1
238000010348 incorporation Methods 0.000 description 1
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JYJIGFIDKWBXDU-MNNPPOADSA-N inulin Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)OC[C@]1(OC[C@]2(OC[C@]3(OC[C@]4(OC[C@]5(OC[C@]6(OC[C@]7(OC[C@]8(OC[C@]9(OC[C@]%10(OC[C@]%11(OC[C@]%12(OC[C@]%13(OC[C@]%14(OC[C@]%15(OC[C@]%16(OC[C@]%17(OC[C@]%18(OC[C@]%19(OC[C@]%20(OC[C@]%21(OC[C@]%22(OC[C@]%23(OC[C@]%24(OC[C@]%25(OC[C@]%26(OC[C@]%27(OC[C@]%28(OC[C@]%29(OC[C@]%30(OC[C@]%31(OC[C@]%32(OC[C@]%33(OC[C@]%34(OC[C@]%35(OC[C@]%36(O[C@@H]%37[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O%37)O)[C@H]([C@H](O)[C@@H](CO)O%36)O)[C@H]([C@H](O)[C@@H](CO)O%35)O)[C@H]([C@H](O)[C@@H](CO)O%34)O)[C@H]([C@H](O)[C@@H](CO)O%33)O)[C@H]([C@H](O)[C@@H](CO)O%32)O)[C@H]([C@H](O)[C@@H](CO)O%31)O)[C@H]([C@H](O)[C@@H](CO)O%30)O)[C@H]([C@H](O)[C@@H](CO)O%29)O)[C@H]([C@H](O)[C@@H](CO)O%28)O)[C@H]([C@H](O)[C@@H](CO)O%27)O)[C@H]([C@H](O)[C@@H](CO)O%26)O)[C@H]([C@H](O)[C@@H](CO)O%25)O)[C@H]([C@H](O)[C@@H](CO)O%24)O)[C@H]([C@H](O)[C@@H](CO)O%23)O)[C@H]([C@H](O)[C@@H](CO)O%22)O)[C@H]([C@H](O)[C@@H](CO)O%21)O)[C@H]([C@H](O)[C@@H](CO)O%20)O)[C@H]([C@H](O)[C@@H](CO)O%19)O)[C@H]([C@H](O)[C@@H](CO)O%18)O)[C@H]([C@H](O)[C@@H](CO)O%17)O)[C@H]([C@H](O)[C@@H](CO)O%16)O)[C@H]([C@H](O)[C@@H](CO)O%15)O)[C@H]([C@H](O)[C@@H](CO)O%14)O)[C@H]([C@H](O)[C@@H](CO)O%13)O)[C@H]([C@H](O)[C@@H](CO)O%12)O)[C@H]([C@H](O)[C@@H](CO)O%11)O)[C@H]([C@H](O)[C@@H](CO)O%10)O)[C@H]([C@H](O)[C@@H](CO)O9)O)[C@H]([C@H](O)[C@@H](CO)O8)O)[C@H]([C@H](O)[C@@H](CO)O7)O)[C@H]([C@H](O)[C@@H](CO)O6)O)[C@H]([C@H](O)[C@@H](CO)O5)O)[C@H]([C@H](O)[C@@H](CO)O4)O)[C@H]([C@H](O)[C@@H](CO)O3)O)[C@H]([C@H](O)[C@@H](CO)O2)O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JYJIGFIDKWBXDU-MNNPPOADSA-N 0.000 description 1
229940029339 inulin Drugs 0.000 description 1
239000010410 layer Substances 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
238000002844 melting Methods 0.000 description 1
230000008018 melting Effects 0.000 description 1
230000004660 morphological change Effects 0.000 description 1
239000005445 natural material Substances 0.000 description 1
229910052758 niobium Inorganic materials 0.000 description 1
239000010955 niobium Substances 0.000 description 1
GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
239000012299 nitrogen atmosphere Substances 0.000 description 1
125000004433 nitrogen atom Chemical group N* 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
230000010355 oscillation Effects 0.000 description 1
238000004806 packaging method and process Methods 0.000 description 1
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238000002360 preparation method Methods 0.000 description 1
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230000005855 radiation Effects 0.000 description 1
239000002994 raw material Substances 0.000 description 1
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229920005989 resin Polymers 0.000 description 1
238000007788 roughening Methods 0.000 description 1
238000005201 scrubbing Methods 0.000 description 1
238000007086 side reaction Methods 0.000 description 1
FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 description 1
239000007787 solid Substances 0.000 description 1
238000004611 spectroscopical analysis Methods 0.000 description 1
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239000007921 spray Substances 0.000 description 1
239000010959 steel Substances 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
125000001424 substituent group Chemical group 0.000 description 1
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
238000009834 vaporization Methods 0.000 description 1
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Classifications

- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/02—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from solutions of cellulose in acids, bases or salts
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B1/00—Preparatory treatment of cellulose for making derivatives thereof, e.g. pre-treatment, pre-soaking, activation
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B1/00—Preparatory treatment of cellulose for making derivatives thereof, e.g. pre-treatment, pre-soaking, activation
- C08B1/06—Rendering cellulose suitable for etherification
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0024—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
- C08B37/0027—2-Acetamido-2-deoxy-beta-glucans; Derivatives thereof
- C08B37/003—Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/006—Heteroglycans, i.e. polysaccharides having more than one sugar residue in the main chain in either alternating or less regular sequence; Gellans; Succinoglycans; Arabinogalactans; Tragacanth or gum tragacanth or traganth from Astragalus; Gum Karaya from Sterculia urens; Gum Ghatti from Anogeissus latifolia; Derivatives thereof
- C08B37/0087—Glucomannans or galactomannans; Tara or tara gum, i.e. D-mannose and D-galactose units, e.g. from Cesalpinia spinosa; Tamarind gum, i.e. D-galactose, D-glucose and D-xylose units, e.g. from Tamarindus indica; Gum Arabic, i.e. L-arabinose, L-rhamnose, D-galactose and D-glucuronic acid units, e.g. from Acacia Senegal or Acacia Seyal; Derivatives thereof
- C08B37/0096—Guar, guar gum, guar flour, guaran, i.e. (beta-1,4) linked D-mannose units in the main chain branched with D-galactose units in (alpha-1,6), e.g. from Cyamopsis Tetragonolobus; Derivatives thereof
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives

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Chemical & Material Sciences (AREA)
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Materials Engineering (AREA)
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Polymers & Plastics (AREA)
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General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
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Polysaccharides And Polysaccharide Derivatives (AREA)
Preparation Of Compounds By Using Micro-Organisms (AREA)

SK1285-97A 1995-03-25 1996-03-22 Process for activating polysaccharides, polysaccharides produced by this process, and use thereof SK128597A3 (en)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
DE19511061		1995-03-25
PCT/EP1996/001274 WO1996030411A1 (de)	1995-03-25	1996-03-22	Verfahren zur aktivierung von polysacchariden, danach hergestellte polysaccharide und deren verwendung

Publications (1)

Publication Number	Publication Date
SK128597A3 true SK128597A3 (en)	1998-03-04

Family

ID=7757778

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
SK1285-97A SK128597A3 (en)	1995-03-25	1996-03-22	Process for activating polysaccharides, polysaccharides produced by this process, and use thereof

Country Status (20)

Country	Link
US (1)	US5939544A (es)
EP (1)	EP0817803B1 (es)
JP (2)	JP3390015B2 (es)
KR (1)	KR100254840B1 (es)
CN (1)	CN1083454C (es)
AT (1)	ATE181338T1 (es)
AU (1)	AU695331B2 (es)
BG (1)	BG62778B1 (es)
BR (1)	BR9607992A (es)
CA (1)	CA2214245C (es)
CZ (1)	CZ284387B6 (es)
DE (2)	DE19611416A1 (es)
EA (1)	EA000169B1 (es)
ES (1)	ES2135221T3 (es)
HU (1)	HUP9802337A3 (es)
PL (1)	PL322468A1 (es)
RO (1)	RO115053B1 (es)
SK (1)	SK128597A3 (es)
WO (1)	WO1996030411A1 (es)
ZA (1)	ZA962370B (es)

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1996
- 1996-03-22 ES ES96908120T patent/ES2135221T3/es not_active Expired - Lifetime
- 1996-03-22 PL PL96322468A patent/PL322468A1/xx unknown
- 1996-03-22 DE DE19611416A patent/DE19611416A1/de not_active Withdrawn
- 1996-03-22 CZ CZ973005A patent/CZ284387B6/cs unknown
- 1996-03-22 RO RO97-01782A patent/RO115053B1/ro unknown
- 1996-03-22 BR BR9607992-4A patent/BR9607992A/pt not_active IP Right Cessation
- 1996-03-22 HU HU9802337A patent/HUP9802337A3/hu unknown
- 1996-03-22 CA CA002214245A patent/CA2214245C/en not_active Expired - Fee Related
- 1996-03-22 EP EP96908120A patent/EP0817803B1/de not_active Expired - Lifetime
- 1996-03-22 JP JP52890696A patent/JP3390015B2/ja not_active Expired - Fee Related
- 1996-03-22 EA EA970268A patent/EA000169B1/ru not_active IP Right Cessation
- 1996-03-22 SK SK1285-97A patent/SK128597A3/sk unknown
- 1996-03-22 KR KR1019970706698A patent/KR100254840B1/ko not_active IP Right Cessation
- 1996-03-22 AT AT96908120T patent/ATE181338T1/de not_active IP Right Cessation
- 1996-03-22 DE DE59602248T patent/DE59602248D1/de not_active Expired - Fee Related
- 1996-03-22 AU AU51481/96A patent/AU695331B2/en not_active Ceased
- 1996-03-22 US US08/913,782 patent/US5939544A/en not_active Expired - Fee Related
- 1996-03-22 CN CN96192823A patent/CN1083454C/zh not_active Expired - Fee Related
- 1996-03-22 WO PCT/EP1996/001274 patent/WO1996030411A1/de active IP Right Grant
- 1996-03-25 ZA ZA962370A patent/ZA962370B/xx unknown
1997
- 1997-09-15 BG BG101888A patent/BG62778B1/bg unknown
2001
- 2001-11-08 JP JP2001343847A patent/JP2002161101A/ja active Pending

Also Published As

Publication number	Publication date
CZ284387B6 (cs)	1998-11-11
HUP9802337A3 (en)	1999-03-29
MX9707309A (es)	1997-11-29
WO1996030411A1 (de)	1996-10-03
CA2214245A1 (en)	1996-10-03
HUP9802337A2 (hu)	1999-02-01
AU5148196A (en)	1996-10-16
ES2135221T3 (es)	1999-10-16
CZ300597A3 (en)	1997-12-17
DE19611416A1 (de)	1996-09-26
PL322468A1 (en)	1998-02-02
CN1083454C (zh)	2002-04-24
CA2214245C (en)	2001-10-02
KR100254840B1 (ko)	2000-05-01
BR9607992A (pt)	1999-11-30
JPH10505130A (ja)	1998-05-19
ATE181338T1 (de)	1999-07-15
DE59602248D1 (de)	1999-07-22
BG101888A (en)	1998-04-30
BG62778B1 (bg)	2000-07-31
RO115053B1 (ro)	1999-10-29
CN1179781A (zh)	1998-04-22
AU695331B2 (en)	1998-08-13
US5939544A (en)	1999-08-17
JP3390015B2 (ja)	2003-03-24
EA000169B1 (ru)	1998-10-29
JP2002161101A (ja)	2002-06-04
EP0817803A1 (de)	1998-01-14
EP0817803B1 (de)	1999-06-16
KR19980703294A (ko)	1998-10-15
ZA962370B (en)	1996-10-07
EA199700268A1 (ru)	1998-02-26

Publication	Publication Date	Title
SK128597A3 (en)	1998-03-04	Process for activating polysaccharides, polysaccharides produced by this process, and use thereof
Chowdhury et al.	2016	Preparation and characterization of nanocrystalline cellulose using ultrasonication combined with a microwave-assisted pretreatment process
CN103097447B (zh)	2016-02-17	基于纤维素的复合材料
US4302252A (en)	1981-11-24	Solvent system for cellulose
Ye et al.	2005	Improving accessibility and reactivity of celluloses of annual plants for the synthesis of methylcellulose
US5906926A (en)	1999-05-25	Method for modified manufacture of cellulose carbamate
Sophonputtanaphoca et al.	2019	Potential of Thai rice straw as a raw material for the synthesis of carboxymethylcellulose
de Paula et al.	2008	Sisal cellulose acetates obtained from heterogeneous reactions
CA2260782A1 (en)	1998-01-22	Production of cellulose carbamate
JPS63235599A (ja)	1988-09-30	強化セルロースアミノメタネート
Ibrahim et al.	2015	Synthesis of tosylated and trimethylsilylated methyl cellulose as pH-sensitive carrier matrix
EP0444335B1 (en)	1994-12-07	Methods for producing bleached, mercerized and unmercerized cellulose and for producing cellulose triacetate therefrom
AU699832B2 (en)	1998-12-17	Process for producing cellulose derivatives
Sophonputtanaphoca et al.	2023	Utilization of sugarcane bagasse for synthesis of carboxymethylcellulose and its biodegradable blend films.
Vismara et al.	2009	Alpha cellulose from industrial and agricultural renewable sources like short flax fibres, ears of corn and wheat-straw and its transformation into cellulose acetates
FI129257B (en)	2021-10-15	Method for derivatizing cellulose
JPH0428331B2 (es)	1992-05-14
Rinaudo et al.	2000	Polysaccharide derivatives
MXPA97007309A (es)	1998-07-03	Procedimiento para activar polisacaridos,polisacaridos hechos mediante este procedimiento y su uso
Azeh et al.	2018	Studies on Isolation, Modification, Characterization and Evaluation of Some Physicochemical Parameters of Potato Starch
Ibrahim et al.	2014	Carboxymethyl and carbanilated cellulose modified with tosyl and trimethylsilyl groups: Preparation, characterization, and applications in controlled release of anti-acid drugs
Bakri et al.	2022	Extraction, types, and classification of cellulose
Pinto et al.	2021	Scientific African
Molenveld et al.	0	Groene Cellulose
LATIF et al.	2007	Two-Step Synthesis and Characterization of Carboxymethylcellulose from