NO309571B1 - Alkylfenylbisacyl-fosfinoksyder, fotoinitiatorblandinger og fotopolymeriserbare sammensetninger samt anvendelse herav - Google Patents

Alkylfenylbisacyl-fosfinoksyder, fotoinitiatorblandinger og fotopolymeriserbare sammensetninger samt anvendelse herav Download PDF

Info

Publication number: NO309571B1
Authority: NO; Norway
Prior art keywords: alkyl; formula; hydrogen; methyl; compounds
Prior art date: 1996-03-04

Application number

NO970962A

Other languages

English (en)

Norwegian (no)

Other versions

NO970962D0 (no

NO970962L (no

Inventor

David George Leppard

Manfred Koehler

Andreas Valet

Original Assignee

Ciba Sc Holding Ag

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-03-04

Filing date

1997-03-03

Publication date

2001-02-19

1997-03-03 Application filed by Ciba Sc Holding Ag filed Critical Ciba Sc Holding Ag

1997-03-03 Publication of NO970962D0 publication Critical patent/NO970962D0/no

1997-09-05 Publication of NO970962L publication Critical patent/NO970962L/no

2001-02-19 Publication of NO309571B1 publication Critical patent/NO309571B1/no

Links

239000000203 mixture Substances 0.000 title claims description 146
125000005037 alkyl phenyl group Chemical group 0.000 title 1
150000001875 compounds Chemical class 0.000 claims description 99
-1 methoxy, methylthio, morpholino Chemical group 0.000 claims description 54
239000001257 hydrogen Substances 0.000 claims description 47
229910052739 hydrogen Inorganic materials 0.000 claims description 47
QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 claims description 29
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
125000000217 alkyl group Chemical group 0.000 claims description 25
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 25
238000004519 manufacturing process Methods 0.000 claims description 23
XMLYCEVDHLAQEL-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-phenylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1 XMLYCEVDHLAQEL-UHFFFAOYSA-N 0.000 claims description 22
GUCYFKSBFREPBC-UHFFFAOYSA-N [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=C(C)C=C1C GUCYFKSBFREPBC-UHFFFAOYSA-N 0.000 claims description 20
150000002431 hydrogen Chemical class 0.000 claims description 19
125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 19
239000002966 varnish Substances 0.000 claims description 13
125000004178 (C1-C4) alkyl group Chemical group 0.000 claims description 11
239000000463 material Substances 0.000 claims description 11
238000007639 printing Methods 0.000 claims description 11
125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 9
150000001412 amines Chemical class 0.000 claims description 8
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 8
RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 7
239000012965 benzophenone Substances 0.000 claims description 7
125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 7
125000000229 (C1-C4)alkoxy group Chemical group 0.000 claims description 6
KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 claims description 6
ILPDGPRRWKVEPG-UHFFFAOYSA-N [(2,6-dimethylbenzoyl)-phenylphosphoryl]-(2,6-dimethylphenyl)methanone Chemical compound CC1=CC=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=CC=C1C ILPDGPRRWKVEPG-UHFFFAOYSA-N 0.000 claims description 6
239000006096 absorbing agent Substances 0.000 claims description 6
150000001721 carbon Chemical group 0.000 claims description 6
229910052799 carbon Inorganic materials 0.000 claims description 6
229910052736 halogen Inorganic materials 0.000 claims description 6
125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 6
229920006395 saturated elastomer Polymers 0.000 claims description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
150000002367 halogens Chemical class 0.000 claims description 5
229910052757 nitrogen Inorganic materials 0.000 claims description 5
125000004433 nitrogen atom Chemical group N* 0.000 claims description 5
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 4
239000000976 ink Substances 0.000 claims description 4
RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 claims description 3
ZCILGMFPJBRCNO-UHFFFAOYSA-N 4-phenyl-2H-benzotriazol-5-ol Chemical class OC1=CC=C2NN=NC2=C1C1=CC=CC=C1 ZCILGMFPJBRCNO-UHFFFAOYSA-N 0.000 claims description 3
NJCDRURWJZAMBM-UHFFFAOYSA-N 6-phenyl-1h-1,3,5-triazin-2-one Chemical class OC1=NC=NC(C=2C=CC=CC=2)=N1 NJCDRURWJZAMBM-UHFFFAOYSA-N 0.000 claims description 3
WXPWZZHELZEVPO-UHFFFAOYSA-N (4-methylphenyl)-phenylmethanone Chemical compound C1=CC(C)=CC=C1C(=O)C1=CC=CC=C1 WXPWZZHELZEVPO-UHFFFAOYSA-N 0.000 claims description 2
KNVGEVSDKAHVAH-UHFFFAOYSA-N 2-benzyl-1-(3,4-dimethoxyphenyl)-2-morpholin-4-ylbutan-1-one Chemical group C1COCCN1C(C(=O)C=1C=C(OC)C(OC)=CC=1)(CC)CC1=CC=CC=C1 KNVGEVSDKAHVAH-UHFFFAOYSA-N 0.000 claims description 2
QPXVRLXJHPTCPW-UHFFFAOYSA-N 2-hydroxy-2-methyl-1-(4-propan-2-ylphenyl)propan-1-one Chemical compound CC(C)C1=CC=C(C(=O)C(C)(C)O)C=C1 QPXVRLXJHPTCPW-UHFFFAOYSA-N 0.000 claims description 2
JLZIXYIYQIKFHP-UHFFFAOYSA-N 2-methyl-1-(4-methylphenyl)-2-morpholin-4-ylpropane-1-thione Chemical compound C1=CC(C)=CC=C1C(=S)C(C)(C)N1CCOCC1 JLZIXYIYQIKFHP-UHFFFAOYSA-N 0.000 claims description 2
IPOKLFYTTOXXMG-UHFFFAOYSA-N C(=O)(O)C1=C(C=CC=C1)C1=C(C=CC=C1)C(=O)C1=C(C=CC=C1)C1=C(C=CC=C1)C(=O)O Chemical compound C(=O)(O)C1=C(C=CC=C1)C1=C(C=CC=C1)C(=O)C1=C(C=CC=C1)C1=C(C=CC=C1)C(=O)O IPOKLFYTTOXXMG-UHFFFAOYSA-N 0.000 claims description 2
BWPYBAJTDILQPY-UHFFFAOYSA-N Methoxyphenone Chemical compound C1=C(C)C(OC)=CC=C1C(=O)C1=CC=CC(C)=C1 BWPYBAJTDILQPY-UHFFFAOYSA-N 0.000 claims description 2
NZBALVNWIMUAMP-UHFFFAOYSA-N [[2,6-dimethyl-4-(2-methylpropyl)benzoyl]-phenylphosphoryl]-[2,6-dimethyl-4-(2-methylpropyl)phenyl]methanone Chemical compound CC1=CC(CC(C)C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=C(CC(C)C)C=C1C NZBALVNWIMUAMP-UHFFFAOYSA-N 0.000 claims description 2
SKMUIZHHMAPKIV-UHFFFAOYSA-N bis(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)C1=C(C)C=C(C)C=C1C SKMUIZHHMAPKIV-UHFFFAOYSA-N 0.000 claims description 2
LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims description 2
125000006273 (C1-C3) alkyl group Chemical group 0.000 claims 1
UHFFVFAKEGKNAQ-UHFFFAOYSA-N 2-benzyl-2-(dimethylamino)-1-(4-morpholin-4-ylphenyl)butan-1-one Chemical compound C=1C=C(N2CCOCC2)C=CC=1C(=O)C(CC)(N(C)C)CC1=CC=CC=C1 UHFFVFAKEGKNAQ-UHFFFAOYSA-N 0.000 claims 1
NLQYBGASAMIPJJ-UHFFFAOYSA-N 2-hydroxy-1-[2-(2-hydroxyethoxy)phenyl]-2-methylpropan-1-one Chemical compound CC(C)(O)C(=O)C1=CC=CC=C1OCCO NLQYBGASAMIPJJ-UHFFFAOYSA-N 0.000 claims 1
IZQPOHAUAILGKE-UHFFFAOYSA-N [2-(4-methylphenyl)sulfanylphenyl]-phenylmethanone Chemical compound C1=CC(C)=CC=C1SC1=CC=CC=C1C(=O)C1=CC=CC=C1 IZQPOHAUAILGKE-UHFFFAOYSA-N 0.000 claims 1
239000010410 layer Substances 0.000 description 32
238000000576 coating method Methods 0.000 description 30
238000001723 curing Methods 0.000 description 21
238000000034 method Methods 0.000 description 20
239000011248 coating agent Substances 0.000 description 19
239000000843 powder Substances 0.000 description 19
239000000758 substrate Substances 0.000 description 19
229920001577 copolymer Polymers 0.000 description 17
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
229920000642 polymer Polymers 0.000 description 13
239000002904 solvent Substances 0.000 description 13
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
239000004922 lacquer Substances 0.000 description 12
QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 12
229910052753 mercury Inorganic materials 0.000 description 12
239000000178 monomer Substances 0.000 description 12
229920000728 polyester Polymers 0.000 description 12
GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 11
229920005862 polyol Polymers 0.000 description 11
239000000243 solution Substances 0.000 description 11
239000007788 liquid Substances 0.000 description 10
238000002156 mixing Methods 0.000 description 10
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 9
238000009472 formulation Methods 0.000 description 9
150000003077 polyols Chemical class 0.000 description 9
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 8
150000001252 acrylic acid derivatives Chemical class 0.000 description 8
238000006243 chemical reaction Methods 0.000 description 8
238000005286 illumination Methods 0.000 description 8
229910052751 metal Inorganic materials 0.000 description 8
239000002184 metal Substances 0.000 description 8
238000002360 preparation method Methods 0.000 description 8
TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 7
FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 7
FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 7
XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 7
239000000654 additive Substances 0.000 description 7
239000002131 composite material Substances 0.000 description 7
150000002148 esters Chemical class 0.000 description 7
239000003999 initiator Substances 0.000 description 7
239000000600 sorbitol Substances 0.000 description 7
229940096522 trimethylolpropane triacrylate Drugs 0.000 description 7
239000002023 wood Substances 0.000 description 7
FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 6
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 description 6
QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 6
MTVHMOTUJAWONX-UHFFFAOYSA-N [(2,5-dimethylphenyl)-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC=C(C)C(P(=O)(C(=O)C=2C(=CC(C)=CC=2C)C)C(=O)C=2C(=CC(C)=CC=2C)C)=C1 MTVHMOTUJAWONX-UHFFFAOYSA-N 0.000 description 6
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
239000011230 binding agent Substances 0.000 description 6
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239000003960 organic solvent Substances 0.000 description 6
229920002120 photoresistant polymer Polymers 0.000 description 6
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150000003254 radicals Chemical class 0.000 description 6
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MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 5
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 5
125000003118 aryl group Chemical group 0.000 description 5
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ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 4
QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
239000004952 Polyamide Substances 0.000 description 4
229910052782 aluminium Inorganic materials 0.000 description 4
125000003277 amino group Chemical group 0.000 description 4
239000012964 benzotriazole Substances 0.000 description 4
WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
239000007795 chemical reaction product Substances 0.000 description 4
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JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
SWRNIYAQKATHDJ-UHFFFAOYSA-N dichloro(dichlorophosphanyl)phosphane Chemical compound ClP(Cl)P(Cl)Cl SWRNIYAQKATHDJ-UHFFFAOYSA-N 0.000 description 4
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238000002844 melting Methods 0.000 description 4
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HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 description 4
238000004383 yellowing Methods 0.000 description 4
HUCQPHINKBNKRU-UHFFFAOYSA-N (4-methylphenyl)phosphane Chemical compound CC1=CC=C(P)C=C1 HUCQPHINKBNKRU-UHFFFAOYSA-N 0.000 description 3
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XQAABEDPVQWFPN-UHFFFAOYSA-N octyl 3-[3-(benzotriazol-2-yl)-5-tert-butyl-4-hydroxyphenyl]propanoate Chemical compound CC(C)(C)C1=CC(CCC(=O)OCCCCCCCC)=CC(N2N=C3C=CC=CC3=N2)=C1O XQAABEDPVQWFPN-UHFFFAOYSA-N 0.000 description 1
125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000003921 oil Substances 0.000 description 1
ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
239000013307 optical fiber Substances 0.000 description 1
150000002894 organic compounds Chemical class 0.000 description 1
239000011368 organic material Substances 0.000 description 1
239000012074 organic phase Substances 0.000 description 1
SOWBFZRMHSNYGE-UHFFFAOYSA-N oxamic acid Chemical compound NC(=O)C(O)=O SOWBFZRMHSNYGE-UHFFFAOYSA-N 0.000 description 1
239000007800 oxidant agent Substances 0.000 description 1
230000003647 oxidation Effects 0.000 description 1
238000007254 oxidation reaction Methods 0.000 description 1
MMCOUVMKNAHQOY-UHFFFAOYSA-L oxido carbonate Chemical compound [O-]OC([O-])=O MMCOUVMKNAHQOY-UHFFFAOYSA-L 0.000 description 1
125000004430 oxygen atom Chemical group O* 0.000 description 1
NWVVVBRKAWDGAB-UHFFFAOYSA-N p-methoxyphenol Chemical compound COC1=CC=C(O)C=C1 NWVVVBRKAWDGAB-UHFFFAOYSA-N 0.000 description 1
238000010422 painting Methods 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
FZUGPQWGEGAKET-UHFFFAOYSA-N parbenate Chemical compound CCOC(=O)C1=CC=C(N(C)C)C=C1 FZUGPQWGEGAKET-UHFFFAOYSA-N 0.000 description 1
UWJJYHHHVWZFEP-UHFFFAOYSA-N pentane-1,1-diol Chemical compound CCCCC(O)O UWJJYHHHVWZFEP-UHFFFAOYSA-N 0.000 description 1
125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
125000000864 peroxy group Chemical group O(O*)* 0.000 description 1
239000003208 petroleum Substances 0.000 description 1
239000012071 phase Substances 0.000 description 1
150000002989 phenols Chemical class 0.000 description 1
ZPNJBTBYIHBSIG-UHFFFAOYSA-N phenyl-(2,2,6,6-tetramethylpiperidin-4-yl)methanone Chemical compound C1C(C)(C)NC(C)(C)CC1C(=O)C1=CC=CC=C1 ZPNJBTBYIHBSIG-UHFFFAOYSA-N 0.000 description 1
235000021317 phosphate Nutrition 0.000 description 1
150000004714 phosphonium salts Chemical class 0.000 description 1
XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 description 1
150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
150000003018 phosphorus compounds Chemical class 0.000 description 1
FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 1
239000003504 photosensitizing agent Substances 0.000 description 1
239000006223 plastic coating Substances 0.000 description 1
239000011092 plastic-coated paper Substances 0.000 description 1
239000011120 plywood Substances 0.000 description 1
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
229920000058 polyacrylate Polymers 0.000 description 1
229920000515 polycarbonate Polymers 0.000 description 1
239000004417 polycarbonate Substances 0.000 description 1
229940068886 polyethylene glycol 300 Drugs 0.000 description 1
229920000139 polyethylene terephthalate Polymers 0.000 description 1
239000005020 polyethylene terephthalate Substances 0.000 description 1
239000004848 polyfunctional curative Substances 0.000 description 1
229920001721 polyimide Polymers 0.000 description 1
229920001228 polyisocyanate Polymers 0.000 description 1
239000005056 polyisocyanate Substances 0.000 description 1
229920002959 polymer blend Polymers 0.000 description 1
229920001451 polypropylene glycol Polymers 0.000 description 1
229920001296 polysiloxane Polymers 0.000 description 1
229920002223 polystyrene Polymers 0.000 description 1
229920000909 polytetrahydrofuran Polymers 0.000 description 1
229920000166 polytrimethylene carbonate Polymers 0.000 description 1
229920002689 polyvinyl acetate Polymers 0.000 description 1
239000011118 polyvinyl acetate Substances 0.000 description 1
229920001289 polyvinyl ether Polymers 0.000 description 1
229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
239000001267 polyvinylpyrrolidone Substances 0.000 description 1
235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
150000004032 porphyrins Chemical class 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
230000002028 premature Effects 0.000 description 1
125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
238000012545 processing Methods 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
239000011241 protective layer Substances 0.000 description 1
KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
INCIMLINXXICKS-UHFFFAOYSA-M pyronin Y Chemical compound [Cl-].C1=CC(=[N+](C)C)C=C2OC3=CC(N(C)C)=CC=C3C=C21 INCIMLINXXICKS-UHFFFAOYSA-M 0.000 description 1
150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
238000001953 recrystallisation Methods 0.000 description 1
230000002441 reversible effect Effects 0.000 description 1
PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
238000007761 roller coating Methods 0.000 description 1
239000005060 rubber Substances 0.000 description 1
150000003839 salts Chemical class 0.000 description 1
238000007790 scraping Methods 0.000 description 1
238000007789 sealing Methods 0.000 description 1
238000000926 separation method Methods 0.000 description 1
238000004904 shortening Methods 0.000 description 1
RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
229910052710 silicon Inorganic materials 0.000 description 1
239000010703 silicon Substances 0.000 description 1
235000012239 silicon dioxide Nutrition 0.000 description 1
239000011734 sodium Substances 0.000 description 1
235000017557 sodium bicarbonate Nutrition 0.000 description 1
229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
230000003595 spectral effect Effects 0.000 description 1
239000007921 spray Substances 0.000 description 1
125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
238000003756 stirring Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000002344 surface layer Substances 0.000 description 1
230000008961 swelling Effects 0.000 description 1
239000000454 talc Substances 0.000 description 1
229910052623 talc Inorganic materials 0.000 description 1
MDDUHVRJJAFRAU-YZNNVMRBSA-N tert-butyl-[(1r,3s,5z)-3-[tert-butyl(dimethyl)silyl]oxy-5-(2-diphenylphosphorylethylidene)-4-methylidenecyclohexyl]oxy-dimethylsilane Chemical compound C1[C@@H](O[Si](C)(C)C(C)(C)C)C[C@H](O[Si](C)(C)C(C)(C)C)C(=C)\C1=C/CP(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 MDDUHVRJJAFRAU-YZNNVMRBSA-N 0.000 description 1
150000003512 tertiary amines Chemical class 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
150000005622 tetraalkylammonium hydroxides Chemical class 0.000 description 1
239000004753 textile Substances 0.000 description 1
238000010003 thermal finishing Methods 0.000 description 1
239000002562 thickening agent Substances 0.000 description 1
150000003573 thiols Chemical class 0.000 description 1
YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
125000003944 tolyl group Chemical group 0.000 description 1
LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
238000005809 transesterification reaction Methods 0.000 description 1
238000012546 transfer Methods 0.000 description 1
AYNNSCRYTDRFCP-UHFFFAOYSA-N triazene Chemical compound NN=N AYNNSCRYTDRFCP-UHFFFAOYSA-N 0.000 description 1
KKFOMYPMTJLQGA-UHFFFAOYSA-N tribenzyl phosphite Chemical compound C=1C=CC=CC=1COP(OCC=1C=CC=CC=1)OCC1=CC=CC=C1 KKFOMYPMTJLQGA-UHFFFAOYSA-N 0.000 description 1
TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
CNUJLMSKURPSHE-UHFFFAOYSA-N trioctadecyl phosphite Chemical compound CCCCCCCCCCCCCCCCCCOP(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC CNUJLMSKURPSHE-UHFFFAOYSA-N 0.000 description 1
UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Chemical class OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 description 1
XHGIFBQQEGRTPB-UHFFFAOYSA-N tris(prop-2-enyl) phosphate Chemical compound C=CCOP(=O)(OCC=C)OCC=C XHGIFBQQEGRTPB-UHFFFAOYSA-N 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
229920001567 vinyl ester resin Polymers 0.000 description 1
KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 1
239000011345 viscous material Substances 0.000 description 1
235000012431 wafers Nutrition 0.000 description 1
238000004804 winding Methods 0.000 description 1
239000008096 xylene Substances 0.000 description 1
125000005023 xylyl group Chemical group 0.000 description 1
239000001043 yellow dye Substances 0.000 description 1
229910052725 zinc Inorganic materials 0.000 description 1
239000011701 zinc Substances 0.000 description 1
239000011787 zinc oxide Substances 0.000 description 1

Classifications

- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/029—Inorganic compounds; Onium compounds; Organic compounds having hetero atoms other than oxygen, nitrogen or sulfur
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/50—Organo-phosphines
- C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
- C07F9/5337—Phosphine oxides or thioxides containing the structure -C(=X)-P(=X) or NC-P(=X) (X = O, S, Se)
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
- Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
- Y10S430/1055—Radiation sensitive composition or product or process of making
- Y10S430/114—Initiator containing
- Y10S430/117—Free radical

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Physics & Mathematics (AREA)
Life Sciences & Earth Sciences (AREA)
Biochemistry (AREA)
Materials Engineering (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
General Physics & Mathematics (AREA)
Crystallography & Structural Chemistry (AREA)
Spectroscopy & Molecular Physics (AREA)
Inorganic Chemistry (AREA)
General Health & Medical Sciences (AREA)
Molecular Biology (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Wood Science & Technology (AREA)
Polymerisation Methods In General (AREA)
Paints Or Removers (AREA)
Inks, Pencil-Leads, Or Crayons (AREA)
Adhesives Or Adhesive Processes (AREA)
Medicines Containing Antibodies Or Antigens For Use As Internal Diagnostic Agents (AREA)
Dental Preparations (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Compositions Of Macromolecular Compounds (AREA)

NO970962A 1996-03-04 1997-03-03 Alkylfenylbisacyl-fosfinoksyder, fotoinitiatorblandinger og fotopolymeriserbare sammensetninger samt anvendelse herav NO309571B1 (no)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
CH55896		1996-03-04

Publications (3)

Publication Number	Publication Date
NO970962D0 NO970962D0 (no)	1997-03-03
NO970962L NO970962L (no)	1997-09-05
NO309571B1 true NO309571B1 (no)	2001-02-19

Family

ID=4189800

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
NO970962A NO309571B1 (no)	1996-03-04	1997-03-03	Alkylfenylbisacyl-fosfinoksyder, fotoinitiatorblandinger og fotopolymeriserbare sammensetninger samt anvendelse herav

Country Status (22)

Country	Link
US (2)	US6020528A (da)
JP (1)	JP4168352B2 (da)
KR (1)	KR100474236B1 (da)
CN (1)	CN1092201C (da)
AT (1)	AT404729B (da)
BE (1)	BE1011437A5 (da)
BR (1)	BR9701154A (da)
CA (1)	CA2198803C (da)
CH (1)	CH691970A5 (da)
DE (2)	DE19758946B4 (da)
DK (1)	DK176096B1 (da)
ES (1)	ES2132018B1 (da)
FR (1)	FR2745575B1 (da)
GB (1)	GB2310855B (da)
IT (1)	IT1290006B1 (da)
NL (1)	NL1005424C2 (da)
NO (1)	NO309571B1 (da)
RU (1)	RU2180667C2 (da)
SE (1)	SE520727C2 (da)
SG (1)	SG55281A1 (da)
TW (1)	TW408136B (da)
ZA (1)	ZA971810B (da)

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DE60006210T2 (de)	1999-12-08	2004-07-15	Ciba Specialty Chemicals Holding Inc.	Neues Photoinitiatorsystem aus Phosphinoxidverbindungen und wenig gefärbte härtbare Zusammensetzungen
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GB2365430B (en) *	2000-06-08	2002-08-28	Ciba Sc Holding Ag	Acylphosphine photoinitiators and intermediates
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US6528555B1 (en)	2000-10-12	2003-03-04	3M Innovative Properties Company	Adhesive for use in the oral environment having color-changing capabilities
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US6613812B2 (en)	2001-01-03	2003-09-02	3M Innovative Properties Company	Dental material including fatty acid, dimer thereof, or trimer thereof
TW583299B (en)	2001-04-13	2004-04-11	Fuji Photo Film Co Ltd	Liquid crystal composition, color filter and liquid crystal display device
US7148382B2 (en)	2001-08-21	2006-12-12	Ciba Specialty Chemicals Corporation	Bathochromic mono- and bis-acylphosphine oxides and sulfides and their use as photoinitiators
US6780546B2 (en) *	2001-08-30	2004-08-24	Inphase Technologies, Inc.	Blue-sensitized holographic media
EP1323784B1 (en)	2001-12-26	2005-02-16	Dainippon Ink And Chemicals, Inc.	Resin composition for coating optical fiber and coated optical fiber and optical fiber unit using the same
WO2003063804A1 (en)	2002-01-31	2003-08-07	3M Innovative Properties Company	Dental pastes, dental articles, and methods
ZA200301683B (en) *	2002-03-04	2004-09-06	Ciba Sc Holding Ag	Synergistic combinations of UV absorbers for pigmented polyolefins.
DE60336306D1 (de)	2002-04-03	2011-04-21	Dainippon Ink & Chemicals	Photoinitiator, neue verbindung und photohärtbare zusammensetzung
RU2346016C2 (ru) *	2002-04-19	2009-02-10	Циба Спешиалти Кемикэлз Холдинг Инк.	Отверждение покрытий, индуцированное плазмой
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US7091259B2 (en) *	2002-07-03	2006-08-15	3M Innovative Properties Company	Dental fillers, pastes, and compositions prepared therefrom
US20050288387A1 (en) *	2002-08-21	2005-12-29	Li Feng	Acrylate dental compositions with improved viscosity and storage odor
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JP4777235B2 (ja)	2003-05-06	2011-09-21	チバホールディングインコーポレーテッド	光硬化されかつ安定化されたコーティング
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1997
- 1997-02-21 CH CH00408/97A patent/CH691970A5/de not_active IP Right Cessation
- 1997-02-21 SE SE9700616A patent/SE520727C2/sv not_active IP Right Cessation
- 1997-02-25 GB GB9703896A patent/GB2310855B/en not_active Expired - Lifetime
- 1997-02-26 KR KR1019970006936A patent/KR100474236B1/ko not_active IP Right Cessation
- 1997-02-26 US US08/806,498 patent/US6020528A/en not_active Expired - Lifetime
- 1997-02-27 DK DK199700217A patent/DK176096B1/da not_active IP Right Cessation
- 1997-02-28 DE DE19758946A patent/DE19758946B4/de not_active Expired - Lifetime
- 1997-02-28 BE BE9700178A patent/BE1011437A5/fr active
- 1997-02-28 DE DE19708294A patent/DE19708294B4/de not_active Expired - Lifetime
- 1997-02-28 SG SG1997000624A patent/SG55281A1/en unknown
- 1997-02-28 CA CA002198803A patent/CA2198803C/en not_active Expired - Lifetime
- 1997-03-03 BR BR9701154A patent/BR9701154A/pt not_active IP Right Cessation
- 1997-03-03 IT IT97MI000460A patent/IT1290006B1/it active IP Right Grant
- 1997-03-03 ZA ZA9701810A patent/ZA971810B/xx unknown
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- 1997-03-03 NO NO970962A patent/NO309571B1/no not_active IP Right Cessation
- 1997-03-03 FR FR9702478A patent/FR2745575B1/fr not_active Expired - Lifetime
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- 1997-03-03 TW TW086102489A patent/TW408136B/zh not_active IP Right Cessation
- 1997-03-03 NL NL1005424A patent/NL1005424C2/nl not_active IP Right Cessation
- 1997-03-03 CN CN97102866A patent/CN1092201C/zh not_active Expired - Lifetime
- 1997-03-04 RU RU97103536/04A patent/RU2180667C2/ru active
- 1997-03-04 JP JP06531797A patent/JP4168352B2/ja not_active Expired - Lifetime
1998
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Also Published As

Publication number	Publication date
SE9700616L (sv)	1997-11-04
GB9703896D0 (en)	1997-04-16
SG55281A1 (en)	1998-12-21
US6284813B1 (en)	2001-09-04
CA2198803C (en)	2006-11-07
JP4168352B2 (ja)	2008-10-22
JPH1029997A (ja)	1998-02-03
CA2198803A1 (en)	1997-09-04
DK176096B1 (da)	2006-05-29
CN1160718A (zh)	1997-10-01
DE19758946B4 (de)	2011-12-08
MX9701638A (es)	1997-09-30
NO970962D0 (no)	1997-03-03
CH691970A5 (de)	2001-12-14
NL1005424A1 (nl)	1997-09-05
GB2310855A (en)	1997-09-10
IT1290006B1 (it)	1998-10-19
DE19708294B4 (de)	2011-03-24
SE520727C2 (sv)	2003-08-19
DE19708294A1 (de)	1997-09-11
ATA36297A (de)	1998-06-15
AT404729B (de)	1999-02-25
US6020528A (en)	2000-02-01
SE9700616D0 (sv)	1997-02-21
ITMI970460A1 (it)	1998-09-03
NL1005424C2 (nl)	1999-03-22
TW408136B (en)	2000-10-11
KR100474236B1 (ko)	2005-07-21
NO970962L (no)	1997-09-05
KR970065546A (ko)	1997-10-13
BR9701154A (pt)	1998-12-15
RU2180667C2 (ru)	2002-03-20
FR2745575B1 (fr)	1999-11-19
ES2132018B1 (es)	2000-04-01
ES2132018A1 (es)	1999-08-01
FR2745575A1 (fr)	1997-09-05
DK21797A (da)	1997-09-05
BE1011437A5 (fr)	1999-09-07
GB2310855B (en)	1999-10-27
ZA971810B (en)	1997-09-16
CN1092201C (zh)	2002-10-09

Publication	Publication Date	Title
NO309571B1 (no)	2001-02-19	Alkylfenylbisacyl-fosfinoksyder, fotoinitiatorblandinger og fotopolymeriserbare sammensetninger samt anvendelse herav
AU720186B2 (en)	2000-05-25	Molecular complex compounds as photoinitiators
US5767169A (en)	1998-06-16	Photopolymerizable compositions comprising alkoxyphenyl-substituted bisacylphosphine oxides
US6486228B2 (en)	2002-11-26	Mono-and Bis-acylphosphine oxide photoinitiator combinations
RU2210798C2 (ru)	2003-08-20	Композиция и способ ее отверждения
US5723512A (en)	1998-03-03	Dimeric bisacylphosphines, oxides and sulfides
JP2001270894A (ja)	2001-10-02	有機金属モノアシルアリールホスフィン類
US6361925B1 (en)	2002-03-26	Photoinitiator mixtures and compositions with alkylphenylbisacylphosphine oxides
EP0898202B1 (en)	2000-07-19	Photogeneration of amines from alpha-aminoacetophenones
AU682793B2 (en)	1997-10-16	Novel acylphosphine oxides
KR20000047902A (ko)	2000-07-25	광개시제 혼합물
MXPA01001448A (en)	2002-06-05	Organometallic monoacylarylphosphines
MXPA97001638A (en)	1998-07-03	Oxides of alkylphenilbisacilphosphine and mixtures defotoinicia
MXPA97006542A (en)	1998-11-09	Compounds of molecular complex as photoinicided

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2017-03-13	MK1K	Patent expired