KR100549139B1 - 비수 전해질 이차 전지 - Google Patents
비수 전해질 이차 전지 Download PDFInfo
- Publication number
- KR100549139B1 KR100549139B1 KR1020020030271A KR20020030271A KR100549139B1 KR 100549139 B1 KR100549139 B1 KR 100549139B1 KR 1020020030271 A KR1020020030271 A KR 1020020030271A KR 20020030271 A KR20020030271 A KR 20020030271A KR 100549139 B1 KR100549139 B1 KR 100549139B1
- Authority
- KR
- South Korea
- Prior art keywords
- positive electrode
- active material
- electrode active
- lithium
- limn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011255 nonaqueous electrolyte Substances 0.000 title claims abstract description 29
- 239000007774 positive electrode material Substances 0.000 claims abstract description 159
- 239000013078 crystal Substances 0.000 claims abstract description 40
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 27
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 27
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 26
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 25
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 25
- 229910052718 tin Inorganic materials 0.000 claims abstract description 22
- 239000002131 composite material Substances 0.000 claims abstract description 17
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910001416 lithium ion Inorganic materials 0.000 claims abstract description 14
- 239000007773 negative electrode material Substances 0.000 claims abstract description 7
- 238000003780 insertion Methods 0.000 claims abstract description 4
- 230000037431 insertion Effects 0.000 claims abstract description 4
- 238000009830 intercalation Methods 0.000 claims description 2
- 238000009831 deintercalation Methods 0.000 claims 1
- 229910052726 zirconium Inorganic materials 0.000 abstract description 19
- 239000006182 cathode active material Substances 0.000 abstract description 10
- 239000000463 material Substances 0.000 abstract description 9
- CKFRRHLHAJZIIN-UHFFFAOYSA-N cobalt lithium Chemical compound [Li].[Co] CKFRRHLHAJZIIN-UHFFFAOYSA-N 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 7
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 69
- 239000011777 magnesium Substances 0.000 description 36
- 239000010936 titanium Substances 0.000 description 36
- 229910015645 LiMn Inorganic materials 0.000 description 30
- 239000000203 mixture Substances 0.000 description 29
- 230000000052 comparative effect Effects 0.000 description 27
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 27
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 23
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 21
- 229910000625 lithium cobalt oxide Inorganic materials 0.000 description 21
- 239000011135 tin Substances 0.000 description 20
- 229910002102 lithium manganese oxide Inorganic materials 0.000 description 19
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 18
- 230000014759 maintenance of location Effects 0.000 description 16
- 239000011259 mixed solution Substances 0.000 description 16
- 238000007600 charging Methods 0.000 description 15
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 11
- 238000002441 X-ray diffraction Methods 0.000 description 11
- ASKVAEGIVYSGNY-UHFFFAOYSA-L cobalt(ii) hydroxide Chemical compound [OH-].[OH-].[Co+2] ASKVAEGIVYSGNY-UHFFFAOYSA-L 0.000 description 11
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 11
- 238000006467 substitution reaction Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 8
- 238000011084 recovery Methods 0.000 description 8
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 7
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 7
- 229910021314 NaFeO 2 Inorganic materials 0.000 description 6
- 239000011149 active material Substances 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 5
- 125000005842 heteroatom Chemical group 0.000 description 5
- 239000011572 manganese Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 4
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 4
- 229910015555 LiMn0.50Co0.50Ti0.01O2 Inorganic materials 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910000428 cobalt oxide Inorganic materials 0.000 description 4
- 238000007599 discharging Methods 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000008151 electrolyte solution Substances 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000005486 organic electrolyte Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- 229910012752 LiNi0.5Mn0.5O2 Inorganic materials 0.000 description 3
- 229910013870 LiPF 6 Inorganic materials 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- KLARSDUHONHPRF-UHFFFAOYSA-N [Li].[Mn] Chemical compound [Li].[Mn] KLARSDUHONHPRF-UHFFFAOYSA-N 0.000 description 3
- 239000006183 anode active material Substances 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 229910017052 cobalt Inorganic materials 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000003795 desorption Methods 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 150000004679 hydroxides Chemical class 0.000 description 3
- 239000000395 magnesium oxide Substances 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 3
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000007784 solid electrolyte Substances 0.000 description 3
- 239000011029 spinel Substances 0.000 description 3
- 229910052596 spinel Inorganic materials 0.000 description 3
- 229910015531 LiMn0.49Co0.49Al0.02O2 Inorganic materials 0.000 description 2
- 229910015528 LiMn0.49Co0.49Mg0.02O2 Inorganic materials 0.000 description 2
- 229910015525 LiMn0.49Co0.49Sn0.02O2 Inorganic materials 0.000 description 2
- 229910015542 LiMn0.49Co0.49Ti0.02O2 Inorganic materials 0.000 description 2
- 229910015545 LiMn0.49Co0.49Zr0.02O2 Inorganic materials 0.000 description 2
- 229910015558 LiMn0.50Co0.50O2 Inorganic materials 0.000 description 2
- 229910015571 LiMn0.50Ni0.50O2 Inorganic materials 0.000 description 2
- 229910014689 LiMnO Inorganic materials 0.000 description 2
- 229910013290 LiNiO 2 Inorganic materials 0.000 description 2
- 239000002033 PVDF binder Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- ZYXUQEDFWHDILZ-UHFFFAOYSA-N [Ni].[Mn].[Li] Chemical compound [Ni].[Mn].[Li] ZYXUQEDFWHDILZ-UHFFFAOYSA-N 0.000 description 2
- 125000002015 acyclic group Chemical group 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000006258 conductive agent Substances 0.000 description 2
- 238000010281 constant-current constant-voltage charging Methods 0.000 description 2
- 150000005676 cyclic carbonates Chemical class 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- IIPYXGDZVMZOAP-UHFFFAOYSA-N lithium nitrate Chemical compound [Li+].[O-][N+]([O-])=O IIPYXGDZVMZOAP-UHFFFAOYSA-N 0.000 description 2
- BFZPBUKRYWOWDV-UHFFFAOYSA-N lithium;oxido(oxo)cobalt Chemical compound [Li+].[O-][Co]=O BFZPBUKRYWOWDV-UHFFFAOYSA-N 0.000 description 2
- ZAUUZASCMSWKGX-UHFFFAOYSA-N manganese nickel Chemical compound [Mn].[Ni] ZAUUZASCMSWKGX-UHFFFAOYSA-N 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 2
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 230000001629 suppression Effects 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229910013063 LiBF 4 Inorganic materials 0.000 description 1
- 229910013684 LiClO 4 Inorganic materials 0.000 description 1
- 229910013733 LiCo Inorganic materials 0.000 description 1
- 229910013275 LiMPO Inorganic materials 0.000 description 1
- 229910015753 LiMn0.40Co0.60Al0.01O2 Inorganic materials 0.000 description 1
- 229910015751 LiMn0.40Co0.60Mg0.01O2 Inorganic materials 0.000 description 1
- 229910015748 LiMn0.40Co0.60O2 Inorganic materials 0.000 description 1
- 229910015745 LiMn0.40Co0.60Ti0.01O2 Inorganic materials 0.000 description 1
- 229910015759 LiMn0.45Co0.55Al0.01O2 Inorganic materials 0.000 description 1
- 229910015758 LiMn0.45Co0.55Mg0.01O2 Inorganic materials 0.000 description 1
- 229910015511 LiMn0.45Co0.55O2 Inorganic materials 0.000 description 1
- 229910015538 LiMn0.475Co0.525Al0.01O2 Inorganic materials 0.000 description 1
- 229910015534 LiMn0.475Co0.525Ti0.01O2 Inorganic materials 0.000 description 1
- 229910015569 LiMn0.525Co0.475Al0.01O2 Inorganic materials 0.000 description 1
- 229910015567 LiMn0.525Co0.475Mg0.01O2 Inorganic materials 0.000 description 1
- 229910015587 LiMn0.525Co0.475O2 Inorganic materials 0.000 description 1
- 229910015586 LiMn0.55Co0.45Al0.01O2 Inorganic materials 0.000 description 1
- 229910015584 LiMn0.55Co0.45O2 Inorganic materials 0.000 description 1
- 229910015582 LiMn0.55Co0.45Ti0.01O2 Inorganic materials 0.000 description 1
- 229910015812 LiMn0.60Co0.40Al0.01O2 Inorganic materials 0.000 description 1
- 229910015843 LiMn0.60Co0.40Mg0.01O2 Inorganic materials 0.000 description 1
- 229910015842 LiMn0.60Co0.40O2 Inorganic materials 0.000 description 1
- 229910015841 LiMn0.60Co0.40Ti0.01O2 Inorganic materials 0.000 description 1
- 229910013528 LiN(SO2 CF3)2 Inorganic materials 0.000 description 1
- 229910013385 LiN(SO2C2F5)2 Inorganic materials 0.000 description 1
- 229910002099 LiNi0.5Mn1.5O4 Inorganic materials 0.000 description 1
- 229910006378 Li—Mn—Ni Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- NXPZICSHDHGMGT-UHFFFAOYSA-N [Co].[Mn].[Li] Chemical compound [Co].[Mn].[Li] NXPZICSHDHGMGT-UHFFFAOYSA-N 0.000 description 1
- RTBHLGSMKCPLCQ-UHFFFAOYSA-N [Mn].OOO Chemical compound [Mn].OOO RTBHLGSMKCPLCQ-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 230000010261 cell growth Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- 150000001869 cobalt compounds Chemical class 0.000 description 1
- 229940044175 cobalt sulfate Drugs 0.000 description 1
- 229910000361 cobalt sulfate Inorganic materials 0.000 description 1
- KTVIXTQDYHMGHF-UHFFFAOYSA-L cobalt(2+) sulfate Chemical compound [Co+2].[O-]S([O-])(=O)=O KTVIXTQDYHMGHF-UHFFFAOYSA-L 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000010280 constant potential charging Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 229910021397 glassy carbon Inorganic materials 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 1
- 229910052808 lithium carbonate Inorganic materials 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- IEYPVFIAXMWHSZ-UHFFFAOYSA-N lithium nickel(2+) trinitrate Chemical compound [Li+].[Ni++].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O IEYPVFIAXMWHSZ-UHFFFAOYSA-N 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 1
- 239000011656 manganese carbonate Substances 0.000 description 1
- 235000006748 manganese carbonate Nutrition 0.000 description 1
- 229940093474 manganese carbonate Drugs 0.000 description 1
- 150000002697 manganese compounds Chemical class 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- 229910000016 manganese(II) carbonate Inorganic materials 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- VSZWPYCFIRKVQL-UHFFFAOYSA-N selanylidenegallium;selenium Chemical compound [Se].[Se]=[Ga].[Se]=[Ga] VSZWPYCFIRKVQL-UHFFFAOYSA-N 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JPJP-P-2001-00164728 | 2001-05-31 | ||
JP2001164728A JP3588338B2 (ja) | 2001-05-31 | 2001-05-31 | 非水電解質二次電池 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR20020092213A KR20020092213A (ko) | 2002-12-11 |
KR100549139B1 true KR100549139B1 (ko) | 2006-02-03 |
Family
ID=19007511
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1020020030271A Expired - Fee Related KR100549139B1 (ko) | 2001-05-31 | 2002-05-30 | 비수 전해질 이차 전지 |
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US (1) | US7056622B2 (ja) |
JP (1) | JP3588338B2 (ja) |
KR (1) | KR100549139B1 (ja) |
CN (1) | CN1207802C (ja) |
TW (1) | TWI230482B (ja) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20010031399A1 (en) * | 2000-02-14 | 2001-10-18 | Hyun-Sook Jung | Positive active material for rechargeable lithium battery and method of preparing same |
CN100429811C (zh) * | 2003-04-28 | 2008-10-29 | 深圳市振华新材料股份有限公司 | 锂离子电池正极材料的制备方法 |
CN100364153C (zh) * | 2005-05-24 | 2008-01-23 | 中国科学院成都有机化学有限公司 | 一种尖晶石LiMn2O4表面包覆Li4Ti5O12电极材料及其制备方法 |
JP5019892B2 (ja) * | 2007-01-23 | 2012-09-05 | 三洋電機株式会社 | 非水電解質二次電池 |
JP5436898B2 (ja) * | 2009-03-23 | 2014-03-05 | 三洋電機株式会社 | 非水電解質二次電池及びその製造方法 |
JP5397436B2 (ja) * | 2010-11-18 | 2014-01-22 | 日産自動車株式会社 | 二次電池 |
EP2751030B1 (en) * | 2011-08-31 | 2017-04-26 | 3M Innovative Properties Company | High capacity positive electrodes for use in lithium-ion electrochemical cells and methods of making the same |
EP2973802B1 (en) | 2013-03-12 | 2023-08-30 | Apple Inc. | High voltage, high volumetric energy density li-ion battery using advanced cathode materials |
US10297821B2 (en) | 2015-09-30 | 2019-05-21 | Apple Inc. | Cathode-active materials, their precursors, and methods of forming |
CN114583154A (zh) | 2016-03-14 | 2022-06-03 | 苹果公司 | 用于锂离子电池的阴极活性材料 |
WO2018057584A1 (en) | 2016-09-20 | 2018-03-29 | Apple Inc. | Cathode active materials having improved particle morphologies |
WO2018057621A1 (en) | 2016-09-21 | 2018-03-29 | Apple Inc. | Surface stabilized cathode material for lithium ion batteries and synthesizing method of the same |
US11695108B2 (en) | 2018-08-02 | 2023-07-04 | Apple Inc. | Oxide mixture and complex oxide coatings for cathode materials |
US11749799B2 (en) | 2018-08-17 | 2023-09-05 | Apple Inc. | Coatings for cathode active materials |
US11757096B2 (en) | 2019-08-21 | 2023-09-12 | Apple Inc. | Aluminum-doped lithium cobalt manganese oxide batteries |
US12206100B2 (en) | 2019-08-21 | 2025-01-21 | Apple Inc. | Mono-grain cathode materials |
US12074321B2 (en) | 2019-08-21 | 2024-08-27 | Apple Inc. | Cathode active materials for lithium ion batteries |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
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FR2751135A1 (fr) * | 1996-07-12 | 1998-01-16 | Accumulateurs Fixes | Electrode de generateur electrochimique rechargeable au lithium |
JP4318002B2 (ja) | 1999-04-09 | 2009-08-19 | Agcセイミケミカル株式会社 | 非水電解液二次電池用正極活物質の製造方法 |
JP2000294241A (ja) * | 1999-04-09 | 2000-10-20 | Mitsui Mining & Smelting Co Ltd | 非水電解液二次電池正極材料及びそれを用いた非水電解液二次電池 |
JP4318270B2 (ja) | 1999-07-06 | 2009-08-19 | Agcセイミケミカル株式会社 | リチウム二次電池の製造方法 |
JP2001319652A (ja) * | 2000-05-11 | 2001-11-16 | Sony Corp | 正極活物質及び非水電解質電池、並びにそれらの製造方法 |
EP1211741A3 (en) * | 2000-11-29 | 2004-01-02 | Toda Kogyo Corporation | Cathode active material for non-aqueous electrolyte secondary cell and process for producing the same |
TW533612B (en) * | 2000-12-28 | 2003-05-21 | Sony Corp | Positive-electrode active material and non-aqueous electrolyte secondary battery |
JP3631166B2 (ja) * | 2001-05-31 | 2005-03-23 | 三洋電機株式会社 | 非水電解質二次電池 |
GB0117235D0 (en) * | 2001-07-14 | 2001-09-05 | Univ St Andrews | Improvements in or relating to electrochemical cells |
JP3844733B2 (ja) * | 2002-12-26 | 2006-11-15 | 松下電器産業株式会社 | 非水電解質二次電池 |
JP4274801B2 (ja) * | 2003-01-09 | 2009-06-10 | パナソニック株式会社 | 非水電解質二次電池用正極活物質の製造法 |
JP4271448B2 (ja) * | 2003-01-16 | 2009-06-03 | パナソニック株式会社 | 非水電解質二次電池用正極活物質 |
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2001
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2002
- 2002-05-30 TW TW091111516A patent/TWI230482B/zh active
- 2002-05-30 KR KR1020020030271A patent/KR100549139B1/ko not_active Expired - Fee Related
- 2002-05-31 US US10/158,019 patent/US7056622B2/en not_active Expired - Fee Related
- 2002-05-31 CN CNB021216827A patent/CN1207802C/zh not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
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CN1389944A (zh) | 2003-01-08 |
TWI230482B (en) | 2005-04-01 |
CN1207802C (zh) | 2005-06-22 |
US7056622B2 (en) | 2006-06-06 |
US20020182504A1 (en) | 2002-12-05 |
JP2002358961A (ja) | 2002-12-13 |
JP3588338B2 (ja) | 2004-11-10 |
KR20020092213A (ko) | 2002-12-11 |
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