DK1123332T3 - Mikrogeler og fremgangsmåde til deres fremstilling - Google Patents
Mikrogeler og fremgangsmåde til deres fremstillingInfo
- Publication number
- DK1123332T3 DK1123332T3 DK99932369T DK99932369T DK1123332T3 DK 1123332 T3 DK1123332 T3 DK 1123332T3 DK 99932369 T DK99932369 T DK 99932369T DK 99932369 T DK99932369 T DK 99932369T DK 1123332 T3 DK1123332 T3 DK 1123332T3
- Authority
- DK
- Denmark
- Prior art keywords
- initiator
- ratio
- olefinic monomer
- olefinic
- mono
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 239000000178 monomer Substances 0.000 abstract 6
- 239000003999 initiator Substances 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/04—Polymers provided for in subclasses C08C or C08F
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/061—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Medicinal Preparation (AREA)
- Steroid Compounds (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9229398P | 1998-07-10 | 1998-07-10 | |
PCT/US1999/015538 WO2000002939A1 (en) | 1998-07-10 | 1999-07-09 | Microgels and process for their preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
DK1123332T3 true DK1123332T3 (da) | 2004-06-07 |
Family
ID=22232549
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DK99932369T DK1123332T3 (da) | 1998-07-10 | 1999-07-09 | Mikrogeler og fremgangsmåde til deres fremstilling |
Country Status (16)
Country | Link |
---|---|
US (5) | US6355718B1 (de) |
EP (1) | EP1123332B1 (de) |
JP (1) | JP2002520432A (de) |
KR (1) | KR100570245B1 (de) |
AT (1) | ATE266687T1 (de) |
AU (1) | AU746495B2 (de) |
BR (1) | BR9912258A (de) |
CA (1) | CA2336960A1 (de) |
DE (1) | DE69917311T2 (de) |
DK (1) | DK1123332T3 (de) |
ES (1) | ES2221401T3 (de) |
IL (1) | IL140139A0 (de) |
MX (1) | MXPA01000263A (de) |
NZ (1) | NZ509746A (de) |
PT (1) | PT1123332E (de) |
WO (1) | WO2000002939A1 (de) |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AUPP337298A0 (en) * | 1998-05-07 | 1998-05-28 | University Of Melbourne, The | Process for microgel preparation |
FR2802209B1 (fr) * | 1999-12-10 | 2002-03-01 | Rhodia Chimie Sa | Latex a chimie de surface modifiee et poudres redispersables , leur obtention et leurs utilisations |
AU5143901A (en) * | 2000-04-07 | 2001-10-23 | Du Pont | Process of microgel synthesis and products produced therefrom |
US7064151B1 (en) | 2000-04-07 | 2006-06-20 | E. I. Du Pont De Nemours And Company | Process of microgel synthesis and products produced therefrom |
AUPQ679400A0 (en) * | 2000-04-07 | 2000-05-11 | Commonwealth Scientific And Industrial Research Organisation | Microgel synthesis |
FR2814170B1 (fr) * | 2000-09-18 | 2005-05-27 | Rhodia Chimie Sa | Nouveau latex a proprietes de surface modifiees par l' ajout d'un copolymere hydrosoluble a caractere amphiphile |
JP4889867B2 (ja) * | 2001-03-13 | 2012-03-07 | 株式会社カネカ | 末端にアルケニル基を有するビニル系重合体の製造方法、ビニル系重合体および硬化性組成物 |
EP1411070A4 (de) * | 2001-07-16 | 2005-06-29 | Kaneka Corp | Blockcopolymer |
WO2003037945A1 (fr) * | 2001-10-29 | 2003-05-08 | Kaneka Corporation | Copolymere sequence a base d'acrylonitrile et compositions de resines thermoplastiques |
KR101000839B1 (ko) * | 2001-12-21 | 2010-12-14 | 유니버시티 오브 시드니 | 중합체 입자의 수성 분산액 |
US7585924B2 (en) * | 2002-07-11 | 2009-09-08 | E. I. Du Pont De Nemours And Company | Pressurized high temperature polymerization process and polymerization system used therein |
FR2843314B1 (fr) | 2002-08-06 | 2004-09-24 | Rhodia Chimie Sa | Synthese de microgels statistiques par polymerisation radicalaire controlee |
FR2846973B1 (fr) | 2002-11-07 | 2004-12-17 | Rhodia Chimie Sa | Composition d'antifroissage comprenant un copolymere a architecture controlee, pour articles en fibres textiles |
AU2002953369A0 (en) * | 2002-11-27 | 2003-01-09 | The University Of Melbourne | Free radical polymerisation process for microgel preparation |
AU2002953359A0 (en) * | 2002-11-27 | 2003-01-09 | The University Of Melbourne | Microgel composition |
FR2848429B1 (fr) * | 2002-12-13 | 2006-06-16 | Oreal | Composition capillaire comprenant un copolymere filmogene a gradient, composition aerosol la comprenant et procedes de traitement |
FR2848417B1 (fr) * | 2002-12-13 | 2006-06-16 | Oreal | Composition cosmetique ou dermatologique comprenant un copolymere a gradient et procede cosmetique de maquillage ou de soin employant ledit copolymere |
FR2848430B1 (fr) * | 2002-12-13 | 2006-06-23 | Composition capillaire comprenant un copolymere filmogene a gradient, composition aerosol la comprenant et procedes de traitement | |
US7959906B2 (en) * | 2002-12-13 | 2011-06-14 | L'oreal S.A. | Hair-cosmetic composition comprising at least one film-forming gradient copolymer, aerosol composition comprising the cosmetic composition and method for treating hair using the composition |
FR2870245B1 (fr) * | 2004-05-14 | 2008-08-22 | Rhodia Chimie Sa | Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee |
US8085875B2 (en) * | 2004-07-16 | 2011-12-27 | Qualcomm Incorporated | Incremental pilot insertion for channnel and interference estimation |
WO2006047398A2 (en) | 2004-10-25 | 2006-05-04 | The Lubrizol Corporation | Star polymers and compositions thereof |
US8513172B2 (en) | 2004-10-25 | 2013-08-20 | The Lubrizol Corporation | Process for preparing polymers and compositions thereof |
US7279446B2 (en) | 2004-11-15 | 2007-10-09 | Rhodia Inc. | Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance |
DE102004062551A1 (de) * | 2004-12-24 | 2006-07-06 | Rhein Chemie Rheinau Gmbh | Mikrogel-enthaltende duroplastische Zusammensetzung |
US7344752B2 (en) * | 2004-12-27 | 2008-03-18 | The Goodyear Tire & Rubber Company | Core-shell particles synthesized through controlled free radical polymerization |
FR2894971B1 (fr) * | 2005-12-20 | 2008-05-16 | Rhodia Recherches & Tech | Composition pour le traitement et/ou la modification de surfaces dures, comprenant un polymere synthetique |
FR2903109B1 (fr) * | 2006-06-30 | 2012-08-03 | Rhodia Recherches & Tech | Polymerisation a partir d'une amine di-allylique et compose comprenant une chaine macromoleculaire comprenant des unites derivant de cette amine |
JP2009215374A (ja) * | 2008-03-07 | 2009-09-24 | Sumitomo Chemical Co Ltd | オレフィン−極性モノマーランダム共重合体、およびその製造方法 |
JP2009215373A (ja) * | 2008-03-07 | 2009-09-24 | Sumitomo Chemical Co Ltd | ブロック共重合体、およびその製造方法 |
FR2965564B1 (fr) * | 2010-09-30 | 2012-10-26 | Rhodia Operations | Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee |
EP2675422B1 (de) * | 2011-02-15 | 2020-09-30 | 3M Innovative Properties Company | Dentale zusammensetzungen mit ethylenisch ungesättigtem additions-fragmentierungsmittel |
FR3034421B1 (fr) * | 2015-03-30 | 2017-04-28 | Total Marketing Services | Copolymere etoile et son utilisation comme ameliorant de viscosite |
EP3453726B1 (de) * | 2016-05-02 | 2021-03-03 | Kyoto University | Verfahren zur herstellung eines mehrfach verzweigten polymers sowie mehrfach verzweigtes polymer |
JP2019099728A (ja) * | 2017-12-06 | 2019-06-24 | 三菱ケミカル株式会社 | 共重合体、レベリング剤、塗料組成物及び塗装物品 |
Family Cites Families (37)
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US4085168A (en) | 1971-02-22 | 1978-04-18 | Cpc International Inc. | Chemically joined, phase separated self-cured hydrophilic thermoplastic graft copolymers and their preparation |
US3928255A (en) | 1971-02-22 | 1975-12-23 | Cpc International Inc | Chemically joined, phase separated self-cured hydrophilic thermoplastic graft copolymers and their preparation |
DE2427957A1 (de) | 1974-06-10 | 1976-01-08 | Basf Ag | Verfahren zur herstellung von netzfoermig aufgebauten polymerisaten |
US4235982A (en) * | 1977-06-03 | 1980-11-25 | Hercules, Incorporated | Organic pigments |
US4196253A (en) * | 1977-09-22 | 1980-04-01 | Hercules Incorporated | Paper coated with binder and organic pigment particles |
KR930000892B1 (ko) | 1983-07-11 | 1993-02-11 | 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 | 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법 |
KR910002473B1 (ko) | 1984-07-05 | 1991-04-23 | 이 아이 듀우판 디 네모아 앤드 캄파니 | 아크릴 별모양 중합체 |
AU583045B2 (en) * | 1984-07-05 | 1989-04-20 | E.I. Du Pont De Nemours And Company | Acrylic star polymers |
DE3608556A1 (de) * | 1986-03-14 | 1987-10-01 | Akzo Gmbh | Telechele polymere |
DE3879275D1 (de) * | 1987-06-04 | 1993-04-22 | Ciba Geigy Ag | Lichtstabilisierte, sternfoermig polymerisierte mikropartikel. |
US4845156A (en) * | 1987-12-21 | 1989-07-04 | E. I. Du Pont De Nemours And Company | Preparation of macromonomers |
US5169914A (en) | 1988-05-03 | 1992-12-08 | Edison Polymer Innovation Corporation | Uniform molecular weight polymers |
JP3245163B2 (ja) * | 1991-08-19 | 2002-01-07 | ミシシッピ ポリマー テクノロジーズ | 反応性末端基を有するマクロモノマー |
DE69312821T2 (de) | 1992-02-10 | 1997-11-27 | Tonen Corp | Endständig modifiziertes polyolefin |
US5322912A (en) | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
JPH06157618A (ja) | 1992-11-27 | 1994-06-07 | Fuji Photo Film Co Ltd | 非水系樹脂分散物の製造方法及び静電写真用液体現像剤 |
US5444135A (en) | 1992-12-17 | 1995-08-22 | Exxon Chemical Patents Inc. | Direct synthesis by living cationic polymerization of nitrogen-containing polymers |
US5310807A (en) * | 1992-12-30 | 1994-05-10 | E. I. Du Pont De Nemours And Company | Star polymers made from macromonomers made by cobalt chain transfer process |
US5344737A (en) | 1993-02-25 | 1994-09-06 | Xerox Corporation | Polywax toner compositions and processes |
US5312871A (en) | 1993-07-27 | 1994-05-17 | Carnegie Mellon University | Free radical polymerization process |
US5395885A (en) * | 1993-12-17 | 1995-03-07 | The University Of Akron | Multi-arm cationic star-polymers |
US5458796A (en) | 1994-03-31 | 1995-10-17 | Shell Oil Company | Synthesis of polyisobutylene star-branched polymers via living carbocationic polymerization |
US5412047A (en) | 1994-05-13 | 1995-05-02 | Xerox Corporation | Homoacrylate polymerization processes with oxonitroxides |
US5530079A (en) | 1995-01-03 | 1996-06-25 | Xerox Corporation | Polymerization processes |
JPH08269107A (ja) | 1995-03-30 | 1996-10-15 | Xerox Corp | フリーラジカル重合方法 |
US5608023A (en) | 1995-03-30 | 1997-03-04 | Xerox Corporation | Rate enhanced polymerization processes |
US5773510A (en) | 1995-03-30 | 1998-06-30 | Xerox Corporation | Processes for the preparation of branched polymers |
US5498679A (en) | 1995-03-30 | 1996-03-12 | Xerox Corporation | Process for producing telechelic, branched and star thermoplastic resin polymers |
US5627248A (en) | 1995-09-26 | 1997-05-06 | The Dow Chemical Company | Difunctional living free radical polymerization initiators |
US5723511A (en) | 1996-06-17 | 1998-03-03 | Xerox Corporation | Processes for preparing telechelic, branched and star thermoplastic resin polymers |
US5789487A (en) * | 1996-07-10 | 1998-08-04 | Carnegie-Mellon University | Preparation of novel homo- and copolymers using atom transfer radical polymerization |
US5728747A (en) | 1996-08-08 | 1998-03-17 | Xerox Corporation | Stable free radical polymerization processes and compositions thereof |
US6075105A (en) | 1996-08-26 | 2000-06-13 | Xerox Corporation | Polymerization processes and resin particles formed thereby |
AU727232B2 (en) * | 1997-01-15 | 2000-12-07 | University Of Melbourne, The | A process for preparing polymeric microgels |
AUPO460797A0 (en) * | 1997-01-15 | 1997-02-06 | University Of Melbourne, The | Polymerisation process |
US6143848A (en) * | 1997-10-23 | 2000-11-07 | The B.F.Goodrich Company | End-functionalized polymers by controlled free-radical polymerization process and polymers made therefrom |
AUPP337298A0 (en) * | 1998-05-07 | 1998-05-28 | University Of Melbourne, The | Process for microgel preparation |
-
1999
- 1999-07-09 AT AT99932369T patent/ATE266687T1/de not_active IP Right Cessation
- 1999-07-09 US US09/350,243 patent/US6355718B1/en not_active Expired - Lifetime
- 1999-07-09 EP EP99932369A patent/EP1123332B1/de not_active Expired - Lifetime
- 1999-07-09 NZ NZ509746A patent/NZ509746A/en not_active Application Discontinuation
- 1999-07-09 BR BR9912258-8A patent/BR9912258A/pt not_active Application Discontinuation
- 1999-07-09 IL IL14013999A patent/IL140139A0/xx unknown
- 1999-07-09 KR KR1020017000355A patent/KR100570245B1/ko not_active IP Right Cessation
- 1999-07-09 CA CA002336960A patent/CA2336960A1/en not_active Abandoned
- 1999-07-09 JP JP2000559168A patent/JP2002520432A/ja active Pending
- 1999-07-09 WO PCT/US1999/015538 patent/WO2000002939A1/en active IP Right Grant
- 1999-07-09 AU AU48686/99A patent/AU746495B2/en not_active Expired
- 1999-07-09 PT PT99932369T patent/PT1123332E/pt unknown
- 1999-07-09 ES ES99932369T patent/ES2221401T3/es not_active Expired - Lifetime
- 1999-07-09 MX MXPA01000263A patent/MXPA01000263A/es not_active IP Right Cessation
- 1999-07-09 DK DK99932369T patent/DK1123332T3/da active
- 1999-07-09 DE DE69917311T patent/DE69917311T2/de not_active Expired - Lifetime
-
2001
- 2001-10-03 US US09/969,672 patent/US6653407B2/en not_active Expired - Lifetime
- 2001-10-03 US US09/969,706 patent/US6646055B2/en not_active Expired - Lifetime
- 2001-10-03 US US09/969,704 patent/US6822056B2/en not_active Expired - Lifetime
- 2001-10-03 US US09/969,710 patent/US6462114B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ATE266687T1 (de) | 2004-05-15 |
US6822056B2 (en) | 2004-11-23 |
US6653407B2 (en) | 2003-11-25 |
KR20010053462A (ko) | 2001-06-25 |
US6646055B2 (en) | 2003-11-11 |
EP1123332A1 (de) | 2001-08-16 |
CA2336960A1 (en) | 2000-01-20 |
JP2002520432A (ja) | 2002-07-09 |
EP1123332B1 (de) | 2004-05-12 |
US20020022683A1 (en) | 2002-02-21 |
MXPA01000263A (es) | 2002-04-24 |
AU4868699A (en) | 2000-02-01 |
US20020022684A1 (en) | 2002-02-21 |
NZ509746A (en) | 2003-09-26 |
KR100570245B1 (ko) | 2006-04-12 |
US6462114B2 (en) | 2002-10-08 |
US20020019476A1 (en) | 2002-02-14 |
AU746495B2 (en) | 2002-05-02 |
DE69917311D1 (de) | 2004-06-17 |
US6355718B1 (en) | 2002-03-12 |
WO2000002939A1 (en) | 2000-01-20 |
IL140139A0 (en) | 2002-02-10 |
ES2221401T3 (es) | 2004-12-16 |
PT1123332E (pt) | 2004-08-31 |
BR9912258A (pt) | 2001-04-17 |
DE69917311T2 (de) | 2004-12-09 |
US20020019475A1 (en) | 2002-02-14 |
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