DE69917311D1 - Mikrogele und verfahren zu deren herstellung - Google Patents
Mikrogele und verfahren zu deren herstellungInfo
- Publication number
- DE69917311D1 DE69917311D1 DE69917311T DE69917311T DE69917311D1 DE 69917311 D1 DE69917311 D1 DE 69917311D1 DE 69917311 T DE69917311 T DE 69917311T DE 69917311 T DE69917311 T DE 69917311T DE 69917311 D1 DE69917311 D1 DE 69917311D1
- Authority
- DE
- Germany
- Prior art keywords
- initiator
- ratio
- olefinic monomer
- olefinic
- mono
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 6
- 239000003999 initiator Substances 0.000 abstract 4
- 239000003054 catalyst Substances 0.000 abstract 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/04—Polymers provided for in subclasses C08C or C08F
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/061—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Medicines That Contain Protein Lipid Enzymes And Other Medicines (AREA)
- Medicinal Preparation (AREA)
- Immobilizing And Processing Of Enzymes And Microorganisms (AREA)
- Steroid Compounds (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US9229398P | 1998-07-10 | 1998-07-10 | |
US92293P | 1998-07-10 | ||
PCT/US1999/015538 WO2000002939A1 (en) | 1998-07-10 | 1999-07-09 | Microgels and process for their preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69917311D1 true DE69917311D1 (de) | 2004-06-17 |
DE69917311T2 DE69917311T2 (de) | 2004-12-09 |
Family
ID=22232549
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69917311T Expired - Lifetime DE69917311T2 (de) | 1998-07-10 | 1999-07-09 | Mikrogele und verfahren zu deren herstellung |
Country Status (16)
Country | Link |
---|---|
US (5) | US6355718B1 (de) |
EP (1) | EP1123332B1 (de) |
JP (1) | JP2002520432A (de) |
KR (1) | KR100570245B1 (de) |
AT (1) | ATE266687T1 (de) |
AU (1) | AU746495B2 (de) |
BR (1) | BR9912258A (de) |
CA (1) | CA2336960A1 (de) |
DE (1) | DE69917311T2 (de) |
DK (1) | DK1123332T3 (de) |
ES (1) | ES2221401T3 (de) |
IL (1) | IL140139A0 (de) |
MX (1) | MXPA01000263A (de) |
NZ (1) | NZ509746A (de) |
PT (1) | PT1123332E (de) |
WO (1) | WO2000002939A1 (de) |
Families Citing this family (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AUPP337298A0 (en) * | 1998-05-07 | 1998-05-28 | University Of Melbourne, The | Process for microgel preparation |
FR2802209B1 (fr) * | 1999-12-10 | 2002-03-01 | Rhodia Chimie Sa | Latex a chimie de surface modifiee et poudres redispersables , leur obtention et leurs utilisations |
AUPQ679400A0 (en) * | 2000-04-07 | 2000-05-11 | Commonwealth Scientific And Industrial Research Organisation | Microgel synthesis |
US7064151B1 (en) | 2000-04-07 | 2006-06-20 | E. I. Du Pont De Nemours And Company | Process of microgel synthesis and products produced therefrom |
AU5143901A (en) * | 2000-04-07 | 2001-10-23 | Du Pont | Process of microgel synthesis and products produced therefrom |
FR2814170B1 (fr) * | 2000-09-18 | 2005-05-27 | Rhodia Chimie Sa | Nouveau latex a proprietes de surface modifiees par l' ajout d'un copolymere hydrosoluble a caractere amphiphile |
JP4889867B2 (ja) * | 2001-03-13 | 2012-03-07 | 株式会社カネカ | 末端にアルケニル基を有するビニル系重合体の製造方法、ビニル系重合体および硬化性組成物 |
US7094833B2 (en) * | 2001-07-16 | 2006-08-22 | Kaneka Corporation | Block copolymer |
JP4199666B2 (ja) * | 2001-10-29 | 2008-12-17 | 株式会社カネカ | アクリロニトリル含有ブロック共重合体及び熱可塑性樹脂組成物 |
EP1463765B1 (de) | 2001-12-21 | 2018-07-18 | University of Sydney | Wässrige dispersionen von polymerteilchen |
US7585924B2 (en) * | 2002-07-11 | 2009-09-08 | E. I. Du Pont De Nemours And Company | Pressurized high temperature polymerization process and polymerization system used therein |
FR2843314B1 (fr) | 2002-08-06 | 2004-09-24 | Rhodia Chimie Sa | Synthese de microgels statistiques par polymerisation radicalaire controlee |
FR2846973B1 (fr) | 2002-11-07 | 2004-12-17 | Rhodia Chimie Sa | Composition d'antifroissage comprenant un copolymere a architecture controlee, pour articles en fibres textiles |
AU2002953359A0 (en) * | 2002-11-27 | 2003-01-09 | The University Of Melbourne | Microgel composition |
AU2002953369A0 (en) * | 2002-11-27 | 2003-01-09 | The University Of Melbourne | Free radical polymerisation process for microgel preparation |
FR2848429B1 (fr) * | 2002-12-13 | 2006-06-16 | Oreal | Composition capillaire comprenant un copolymere filmogene a gradient, composition aerosol la comprenant et procedes de traitement |
FR2848430B1 (fr) * | 2002-12-13 | 2006-06-23 | Composition capillaire comprenant un copolymere filmogene a gradient, composition aerosol la comprenant et procedes de traitement | |
FR2848417B1 (fr) * | 2002-12-13 | 2006-06-16 | Oreal | Composition cosmetique ou dermatologique comprenant un copolymere a gradient et procede cosmetique de maquillage ou de soin employant ledit copolymere |
US7959906B2 (en) * | 2002-12-13 | 2011-06-14 | L'oreal S.A. | Hair-cosmetic composition comprising at least one film-forming gradient copolymer, aerosol composition comprising the cosmetic composition and method for treating hair using the composition |
FR2870245B1 (fr) * | 2004-05-14 | 2008-08-22 | Rhodia Chimie Sa | Synthese de copolymeres en forme d'etoile mikto par polymerisation radicalaire controlee |
US8085875B2 (en) | 2004-07-16 | 2011-12-27 | Qualcomm Incorporated | Incremental pilot insertion for channnel and interference estimation |
CN101087823B (zh) | 2004-10-25 | 2010-08-18 | 卢布里佐尔公司 | 星形聚合物及其组合物 |
EP2292668B1 (de) | 2004-10-25 | 2019-03-20 | The Lubrizol Corporation | Verfahren zur Herstellung von Polymeren und Zusammensetzungen daraus |
US7279446B2 (en) | 2004-11-15 | 2007-10-09 | Rhodia Inc. | Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance |
DE102004062551A1 (de) * | 2004-12-24 | 2006-07-06 | Rhein Chemie Rheinau Gmbh | Mikrogel-enthaltende duroplastische Zusammensetzung |
US7344752B2 (en) * | 2004-12-27 | 2008-03-18 | The Goodyear Tire & Rubber Company | Core-shell particles synthesized through controlled free radical polymerization |
FR2894971B1 (fr) * | 2005-12-20 | 2008-05-16 | Rhodia Recherches & Tech | Composition pour le traitement et/ou la modification de surfaces dures, comprenant un polymere synthetique |
FR2903109B1 (fr) * | 2006-06-30 | 2012-08-03 | Rhodia Recherches & Tech | Polymerisation a partir d'une amine di-allylique et compose comprenant une chaine macromoleculaire comprenant des unites derivant de cette amine |
JP2009215373A (ja) * | 2008-03-07 | 2009-09-24 | Sumitomo Chemical Co Ltd | ブロック共重合体、およびその製造方法 |
JP2009215374A (ja) * | 2008-03-07 | 2009-09-24 | Sumitomo Chemical Co Ltd | オレフィン−極性モノマーランダム共重合体、およびその製造方法 |
FR2965564B1 (fr) * | 2010-09-30 | 2012-10-26 | Rhodia Operations | Preparation de polymeres hydrophiles de haute masse par polymerisation radicalaire controlee |
RU2573997C2 (ru) * | 2011-02-15 | 2016-01-27 | 3М Инновейтив Пропертиз Компани | Стоматологические композиции, содержащие этиленненасыщенный агент присоединения-фрагментации |
FR3034421B1 (fr) * | 2015-03-30 | 2017-04-28 | Total Marketing Services | Copolymere etoile et son utilisation comme ameliorant de viscosite |
CN109071697B (zh) * | 2016-05-02 | 2021-04-23 | 国立大学法人京都大学 | 多支链聚合物的制造方法和多支链聚合物 |
JP2019099728A (ja) * | 2017-12-06 | 2019-06-24 | 三菱ケミカル株式会社 | 共重合体、レベリング剤、塗料組成物及び塗装物品 |
Family Cites Families (37)
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US3928255A (en) | 1971-02-22 | 1975-12-23 | Cpc International Inc | Chemically joined, phase separated self-cured hydrophilic thermoplastic graft copolymers and their preparation |
US4085168A (en) | 1971-02-22 | 1978-04-18 | Cpc International Inc. | Chemically joined, phase separated self-cured hydrophilic thermoplastic graft copolymers and their preparation |
DE2427957A1 (de) | 1974-06-10 | 1976-01-08 | Basf Ag | Verfahren zur herstellung von netzfoermig aufgebauten polymerisaten |
US4235982A (en) * | 1977-06-03 | 1980-11-25 | Hercules, Incorporated | Organic pigments |
US4196253A (en) * | 1977-09-22 | 1980-04-01 | Hercules Incorporated | Paper coated with binder and organic pigment particles |
DE3486145T2 (de) | 1983-07-11 | 1993-09-23 | Commw Scient Ind Res Org | Verfahren zur polymerisation und nach diesem verfahren hergestellte polymere. |
JPH0667969B2 (ja) * | 1984-07-05 | 1994-08-31 | イー・アイ・デュポン・ドゥ・ヌムール・アンド・カンパニー | アクリル系星形ポリマーの製法 |
KR910002473B1 (ko) * | 1984-07-05 | 1991-04-23 | 이 아이 듀우판 디 네모아 앤드 캄파니 | 아크릴 별모양 중합체 |
DE3608556A1 (de) * | 1986-03-14 | 1987-10-01 | Akzo Gmbh | Telechele polymere |
ATE87012T1 (de) * | 1987-06-04 | 1993-04-15 | Ciba Geigy Ag | Lichtstabilisierte, sternfoermig polymerisierte mikropartikel. |
US4845156A (en) * | 1987-12-21 | 1989-07-04 | E. I. Du Pont De Nemours And Company | Preparation of macromonomers |
US5169914A (en) | 1988-05-03 | 1992-12-08 | Edison Polymer Innovation Corporation | Uniform molecular weight polymers |
DE69231754T2 (de) * | 1991-08-19 | 2001-11-15 | Mississippi Polymer Technologies, Inc. | Macromonomere mit reaktiven endgruppen |
WO1993016115A1 (en) | 1992-02-10 | 1993-08-19 | Tonen Corporation | Terminally modified polyolefin |
US5322912A (en) | 1992-11-16 | 1994-06-21 | Xerox Corporation | Polymerization processes and toner compositions therefrom |
JPH06157618A (ja) | 1992-11-27 | 1994-06-07 | Fuji Photo Film Co Ltd | 非水系樹脂分散物の製造方法及び静電写真用液体現像剤 |
US5444135A (en) | 1992-12-17 | 1995-08-22 | Exxon Chemical Patents Inc. | Direct synthesis by living cationic polymerization of nitrogen-containing polymers |
US5310807A (en) * | 1992-12-30 | 1994-05-10 | E. I. Du Pont De Nemours And Company | Star polymers made from macromonomers made by cobalt chain transfer process |
US5344737A (en) | 1993-02-25 | 1994-09-06 | Xerox Corporation | Polywax toner compositions and processes |
US5312871A (en) | 1993-07-27 | 1994-05-17 | Carnegie Mellon University | Free radical polymerization process |
US5395885A (en) * | 1993-12-17 | 1995-03-07 | The University Of Akron | Multi-arm cationic star-polymers |
US5458796A (en) | 1994-03-31 | 1995-10-17 | Shell Oil Company | Synthesis of polyisobutylene star-branched polymers via living carbocationic polymerization |
US5412047A (en) | 1994-05-13 | 1995-05-02 | Xerox Corporation | Homoacrylate polymerization processes with oxonitroxides |
US5530079A (en) | 1995-01-03 | 1996-06-25 | Xerox Corporation | Polymerization processes |
US5608023A (en) | 1995-03-30 | 1997-03-04 | Xerox Corporation | Rate enhanced polymerization processes |
JPH08269107A (ja) | 1995-03-30 | 1996-10-15 | Xerox Corp | フリーラジカル重合方法 |
US5773510A (en) | 1995-03-30 | 1998-06-30 | Xerox Corporation | Processes for the preparation of branched polymers |
US5498679A (en) | 1995-03-30 | 1996-03-12 | Xerox Corporation | Process for producing telechelic, branched and star thermoplastic resin polymers |
US5627248A (en) | 1995-09-26 | 1997-05-06 | The Dow Chemical Company | Difunctional living free radical polymerization initiators |
US5723511A (en) | 1996-06-17 | 1998-03-03 | Xerox Corporation | Processes for preparing telechelic, branched and star thermoplastic resin polymers |
US5789487A (en) * | 1996-07-10 | 1998-08-04 | Carnegie-Mellon University | Preparation of novel homo- and copolymers using atom transfer radical polymerization |
US5728747A (en) | 1996-08-08 | 1998-03-17 | Xerox Corporation | Stable free radical polymerization processes and compositions thereof |
US6075105A (en) | 1996-08-26 | 2000-06-13 | Xerox Corporation | Polymerization processes and resin particles formed thereby |
AU727232B2 (en) * | 1997-01-15 | 2000-12-07 | University Of Melbourne, The | A process for preparing polymeric microgels |
AUPO460797A0 (en) * | 1997-01-15 | 1997-02-06 | University Of Melbourne, The | Polymerisation process |
US6143848A (en) * | 1997-10-23 | 2000-11-07 | The B.F.Goodrich Company | End-functionalized polymers by controlled free-radical polymerization process and polymers made therefrom |
AUPP337298A0 (en) * | 1998-05-07 | 1998-05-28 | University Of Melbourne, The | Process for microgel preparation |
-
1999
- 1999-07-09 DE DE69917311T patent/DE69917311T2/de not_active Expired - Lifetime
- 1999-07-09 WO PCT/US1999/015538 patent/WO2000002939A1/en active IP Right Grant
- 1999-07-09 US US09/350,243 patent/US6355718B1/en not_active Expired - Lifetime
- 1999-07-09 PT PT99932369T patent/PT1123332E/pt unknown
- 1999-07-09 AT AT99932369T patent/ATE266687T1/de not_active IP Right Cessation
- 1999-07-09 EP EP99932369A patent/EP1123332B1/de not_active Expired - Lifetime
- 1999-07-09 ES ES99932369T patent/ES2221401T3/es not_active Expired - Lifetime
- 1999-07-09 MX MXPA01000263A patent/MXPA01000263A/es not_active IP Right Cessation
- 1999-07-09 NZ NZ509746A patent/NZ509746A/en not_active Application Discontinuation
- 1999-07-09 CA CA002336960A patent/CA2336960A1/en not_active Abandoned
- 1999-07-09 JP JP2000559168A patent/JP2002520432A/ja active Pending
- 1999-07-09 BR BR9912258-8A patent/BR9912258A/pt not_active Application Discontinuation
- 1999-07-09 AU AU48686/99A patent/AU746495B2/en not_active Expired
- 1999-07-09 DK DK99932369T patent/DK1123332T3/da active
- 1999-07-09 KR KR1020017000355A patent/KR100570245B1/ko not_active IP Right Cessation
- 1999-07-09 IL IL14013999A patent/IL140139A0/xx unknown
-
2001
- 2001-10-03 US US09/969,672 patent/US6653407B2/en not_active Expired - Lifetime
- 2001-10-03 US US09/969,704 patent/US6822056B2/en not_active Expired - Lifetime
- 2001-10-03 US US09/969,710 patent/US6462114B2/en not_active Expired - Lifetime
- 2001-10-03 US US09/969,706 patent/US6646055B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
PT1123332E (pt) | 2004-08-31 |
JP2002520432A (ja) | 2002-07-09 |
US20020022683A1 (en) | 2002-02-21 |
ATE266687T1 (de) | 2004-05-15 |
US6462114B2 (en) | 2002-10-08 |
EP1123332A1 (de) | 2001-08-16 |
US6822056B2 (en) | 2004-11-23 |
NZ509746A (en) | 2003-09-26 |
ES2221401T3 (es) | 2004-12-16 |
BR9912258A (pt) | 2001-04-17 |
MXPA01000263A (es) | 2002-04-24 |
AU4868699A (en) | 2000-02-01 |
US6653407B2 (en) | 2003-11-25 |
EP1123332B1 (de) | 2004-05-12 |
KR20010053462A (ko) | 2001-06-25 |
US6355718B1 (en) | 2002-03-12 |
WO2000002939A1 (en) | 2000-01-20 |
IL140139A0 (en) | 2002-02-10 |
US20020022684A1 (en) | 2002-02-21 |
US20020019475A1 (en) | 2002-02-14 |
KR100570245B1 (ko) | 2006-04-12 |
DE69917311T2 (de) | 2004-12-09 |
DK1123332T3 (da) | 2004-06-07 |
CA2336960A1 (en) | 2000-01-20 |
US20020019476A1 (en) | 2002-02-14 |
AU746495B2 (en) | 2002-05-02 |
US6646055B2 (en) | 2003-11-11 |
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