BR9908977A - Sistema de catalisador para uso na polimerização e copolimerização de etileno e processo para preparar o referido sistema - Google Patents
Sistema de catalisador para uso na polimerização e copolimerização de etileno e processo para preparar o referido sistemaInfo
- Publication number
- BR9908977A BR9908977A BR9908977-7A BR9908977A BR9908977A BR 9908977 A BR9908977 A BR 9908977A BR 9908977 A BR9908977 A BR 9908977A BR 9908977 A BR9908977 A BR 9908977A
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst system
- polymerization
- ethylene
- halide
- organic
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
''SISTEMA DE CATALISADOR PARA USO NA POLIMERIZAçãO E COPOLIMERIZAçãO DE ETILENO E PROCESSO PARA PREPARAR O REFERIDO SISTEMA'', sendo que o sistema de catalisador é obtido dissolvendo-se um ativador doador de elétrons e, opcionalmente, um agente de ajuste de haleto de metal em uma solução de haleto de magnésio em um sistema de solvente consistindo essencialmente de compostos de epoxi orgânico e compostos de fósforo orgânicos para formar uma solução homogênea, e então misturar com pelo menos um coprecipitador e um haleto de titânio de metal de transição, ou seu derivado, para formar um componente sólido, sendo a seguir realizada a incorporação em combinação com um componente de alumínio orgânico, antes do uso em polimerizações. Quando usado na polimerização de etileno, o sistema de catalisador exibe uma atividade de polimerização muito elevada, e as partículas de polímero resultantes exibem melhor morfologia de partícula e maior densidade aparente.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN98101108A CN1086191C (zh) | 1998-03-17 | 1998-03-17 | 用于乙烯聚合或共聚合的催化剂及其制法 |
PCT/CN1999/000037 WO1999047568A1 (fr) | 1998-03-17 | 1999-03-16 | Systeme catalyseur a utiliser dans la polymerisation et copolymerisation d'ethylene et son procede de preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
BR9908977A true BR9908977A (pt) | 2000-11-14 |
BR9908977B1 BR9908977B1 (pt) | 2009-05-05 |
Family
ID=5216470
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI9908977-7A BR9908977B1 (pt) | 1998-03-17 | 1999-03-16 | sistema de catalisador para uso na polimerização ou copolimerização de etileno, processo para preparar uma composição de catalisador e uso do sistema de catalisador. |
Country Status (7)
Country | Link |
---|---|
US (1) | US6617278B1 (pt) |
EP (1) | EP1083187B1 (pt) |
JP (1) | JP4394280B2 (pt) |
KR (1) | KR100512605B1 (pt) |
CN (1) | CN1086191C (pt) |
BR (1) | BR9908977B1 (pt) |
WO (1) | WO1999047568A1 (pt) |
Families Citing this family (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1137155C (zh) * | 1999-12-06 | 2004-02-04 | 中国石油化工集团公司 | 用于烯烃聚合或共聚合的催化剂体系 |
SG95635A1 (en) * | 2000-03-30 | 2003-04-23 | Sumitomo Chemical Co | Process for producing catalyst for ethylene polymerization and process for producing ehtylene polymer |
WO2002094755A1 (en) * | 2001-05-22 | 2002-11-28 | Firmenich Sa | Catalytic system for aldol reactions |
KR100828287B1 (ko) * | 2001-12-26 | 2008-05-07 | 삼성토탈 주식회사 | 에틸렌 중합 및 공중합용 고체착물 티타늄 촉매의제조방법 및 그로부터 제조되는 촉매 |
CN1194993C (zh) * | 2002-06-06 | 2005-03-30 | 中国石油化工股份有限公司 | 用于乙烯聚合的固体催化剂组分及其催化剂 |
ATE514484T1 (de) | 2002-12-18 | 2011-07-15 | Basell Poliolefine Srl | Addukte basierend auf magnesium dichlorid und damit hergestellte bestandteile |
US6767857B1 (en) | 2003-05-29 | 2004-07-27 | Fina Technology, Inc. | Process for forming a Ziegler-Natta catalyst system having a controlled morphology |
CN1229400C (zh) * | 2003-09-18 | 2005-11-30 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其催化剂 |
KR20050095133A (ko) * | 2004-03-25 | 2005-09-29 | 차이나 페트로리움 앤드 케미컬 코포레이션 | 에틸렌 중합용 촉매, 및 그의 제조방법과 용도 |
CN1297575C (zh) * | 2004-04-12 | 2007-01-31 | 中国石油化工股份有限公司 | 用于乙烯聚合或共聚合的催化剂组分及其催化剂 |
US7351778B2 (en) * | 2004-04-30 | 2008-04-01 | China Petroleum & Chemical Corporation | Catalyst component for olefin polymerization and catalyst comprising the same |
CN1310968C (zh) * | 2004-07-05 | 2007-04-18 | 中国石油化工股份有限公司 | 一种用于烯烃聚合或共聚合的催化剂、制备方法及其应用 |
CN1931885B (zh) * | 2005-09-16 | 2010-05-05 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂及其制法 |
EP1947123B1 (en) * | 2005-10-31 | 2016-03-09 | China Petroleum & Chemical Corporation | Catalyst component for ethylene polymerization, preparation thereof and catalyst containing the same |
WO2007076639A1 (fr) | 2006-01-04 | 2007-07-12 | China Petroleum & Chemical Corporation | Composant de catalyseur pour la polymerisation ou la copolymerisation d'olefines, son procede de preparation, catalyseur contenant ledit composant de catalyseur et son utilisation |
CN101173014B (zh) * | 2006-10-31 | 2011-05-04 | 中国石油化工股份有限公司 | 一种用于乙烯聚合或共聚合的催化剂、制法和应用 |
CN101125898A (zh) * | 2007-07-19 | 2008-02-20 | 中国科学院长春应用化学研究所 | 一种用于合成宽分子量分布聚丙烯的催化剂 |
US8344079B2 (en) * | 2007-12-31 | 2013-01-01 | Basf Corporation | Molar ratio modifications to larger polyolefin catalysts |
CN101724106B (zh) * | 2008-10-31 | 2012-05-30 | 中国石油化工股份有限公司 | 用于乙烯聚合反应的催化剂组分及其催化剂 |
RU2567391C2 (ru) | 2009-08-21 | 2015-11-10 | Чайна Петролеум Энд Кемикал Корпорейшн | Компонент катализатора для полимеризации этилена, приготовление такового и катализатор, включающий компонент катализатора |
SA3686B1 (ar) | 2009-10-16 | 2014-10-22 | China Petroleum& Chemical Corp | مكون حفاز لبلمرة الأولفين وحفاز يشتمل عليه |
WO2011081460A2 (ko) | 2009-12-31 | 2011-07-07 | 주식회사 효성 | 올레핀 중합용 지글러-나타 촉매 |
CN102286117B (zh) * | 2010-06-18 | 2013-07-03 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的含钛的固体催化剂组分及催化剂 |
CN102286118B (zh) * | 2010-06-18 | 2013-02-27 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的含钛的固体催化剂组分及催化剂 |
CN102295716B (zh) * | 2010-06-25 | 2013-03-27 | 中国石油化工股份有限公司 | 一种用于乙烯聚合的催化剂、制法和应用 |
CN102399329B (zh) * | 2010-09-16 | 2013-08-14 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及催化剂 |
CN102399327B (zh) * | 2010-09-16 | 2013-06-05 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分及其催化剂 |
CN102453162B (zh) * | 2010-10-22 | 2013-07-03 | 中国石油化工股份有限公司 | 一种聚丙烯催化剂组分及其催化剂 |
CN103772536B (zh) * | 2012-10-18 | 2016-05-25 | 中国石油化工股份有限公司 | 一种用于乙烯聚合或共聚合的催化剂组分及其催化剂 |
CN103772543B (zh) * | 2012-10-19 | 2016-08-17 | 中国石油化工股份有限公司 | 一种乙烯聚合用催化剂及其制法 |
CN103772552B (zh) * | 2012-10-23 | 2016-07-06 | 中国石油化工股份有限公司 | 一种用于乙烯聚合或共聚合的催化剂组分及催化剂 |
CN103772546B (zh) * | 2012-10-23 | 2016-09-21 | 中国石油化工股份有限公司 | 一种乙烯聚合用催化剂组分及其催化剂 |
CN103772549B (zh) * | 2012-10-23 | 2016-07-06 | 中国石油化工股份有限公司 | 一种用于乙烯聚合或共聚合的催化剂组分及催化剂 |
CN103772553B (zh) * | 2012-10-24 | 2016-08-17 | 中国石油化工股份有限公司 | 一种用于乙烯聚合的催化剂及其制备方法 |
US9593182B2 (en) | 2012-11-08 | 2017-03-14 | W.R.Grace & Co.-Conn. | Process of polymerization catalyst production with controlled catalyst properties and use of same in olefin polymerizations |
RU2668082C2 (ru) | 2013-10-18 | 2018-09-27 | Чайна Петролеум Энд Кемикал Корпорейшн | Сферические носители для катализатора полимеризации олефинов, компоненты катализатора, катализатор и методы их получения |
CN104558282B (zh) | 2013-10-18 | 2017-02-15 | 中国石油化工股份有限公司 | 用于烯烃聚合的催化剂组分及其制备方法和用于烯烃聚合的催化剂与应用 |
ES2974931T3 (es) * | 2014-03-14 | 2024-07-02 | Basell Poliolefine Italia Srl | Componentes catalizadores para la polimerización de olefinas |
CN104974279B (zh) * | 2014-04-11 | 2017-08-25 | 中国石油化工股份有限公司 | 用于乙烯聚合反应的催化剂组分及其催化剂和制备方法 |
CN104974282B (zh) * | 2014-04-11 | 2017-06-30 | 中国石油化工股份有限公司 | 一种用于乙烯聚合反应的催化剂组分、制备方法及催化剂 |
CN105085742B (zh) * | 2014-04-29 | 2018-06-12 | 中国石油化工股份有限公司 | 一种用于烯烃聚合的催化剂组分的制备方法 |
WO2015169831A1 (en) | 2014-05-06 | 2015-11-12 | Basell Poliolefine Italia S.R.L. | Random propylene-ethylene copolymers and process for their preparation |
CN105330770B (zh) * | 2014-06-18 | 2018-11-30 | 中国石油化工股份有限公司 | 一种用于乙烯淤浆聚合的催化剂及其应用 |
CN105175587A (zh) * | 2014-06-18 | 2015-12-23 | 中国石油化工股份有限公司 | 一种用于乙烯聚合的催化剂及其应用 |
CN105732855B (zh) * | 2014-12-11 | 2019-04-05 | 中国石油天然气股份有限公司 | 用于烯烃聚合的主催化剂组分和催化剂 |
US10576720B2 (en) | 2015-08-06 | 2020-03-03 | Basell Poliolefine Italia S.R.L. | Film comprising propylene-ethylene-1-butene terpolymers |
JP6633184B2 (ja) * | 2015-09-11 | 2020-01-22 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | オレフィン重合用触媒成分の製造方法 |
CN109400763B (zh) * | 2017-08-18 | 2021-03-16 | 中国石油化工股份有限公司 | 烯烃聚合催化剂载体及其制备方法和应用 |
CN111072804B (zh) * | 2018-10-19 | 2022-07-12 | 中国石油化工股份有限公司 | 烯烃聚合催化剂组分及其应用和烯烃聚合催化剂及烯烃聚合方法 |
CN111234069B (zh) * | 2018-11-29 | 2022-10-21 | 中国石油化工股份有限公司 | 含镁/钛的固体催化剂组分及其制备方法和烯烃聚合催化剂及其应用 |
CN112724284B (zh) * | 2019-10-28 | 2023-05-12 | 中国石油化工股份有限公司 | 固体催化剂组分及制备方法与烯烃聚合催化剂和应用 |
CN112724287A (zh) * | 2019-10-28 | 2021-04-30 | 中国石油化工股份有限公司 | 一种用于乙烯聚合的催化剂组分及其制备方法和应用 |
US11124586B1 (en) | 2020-11-09 | 2021-09-21 | Chevron Phillips Chemical Company Lp | Particle size control of metallocene catalyst systems in loop slurry polymerization reactors |
CA3204719A1 (en) | 2020-12-08 | 2022-06-16 | Chevron Phillips Chemical Company Lp | Particle size control of supported chromium catalysts in loop slurry polymerization reactors |
CN117980344A (zh) | 2021-09-13 | 2024-05-03 | 切弗朗菲利浦化学公司 | 水力旋流器对用于烯烃聚合的催化剂体系组分的修改 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5032270B2 (pt) * | 1972-09-14 | 1975-10-18 | ||
JPS58183708A (ja) | 1982-04-20 | 1983-10-27 | Mitsubishi Petrochem Co Ltd | α−オレフイン重合用固体触媒成分 |
CN1006071B (zh) * | 1985-04-01 | 1989-12-13 | 中国石油化工总公司 | 用于烯烃聚合和共聚合的催化剂体系 |
DE69330044T2 (de) * | 1992-10-28 | 2001-07-19 | Mitsubishi Chemical Corp., Tokio/Tokyo | Katalysatorbestandteil für Olefinpolymerisation |
US5604170A (en) * | 1993-02-23 | 1997-02-18 | Nippon Oil Company, Limited | Solid catalyst components for olefin polemerization and use thereof |
US6635734B2 (en) * | 1994-04-26 | 2003-10-21 | Fina Technology, Inc. | Catalyst system to produce highly crystalline polypropylene |
ZA974798B (en) * | 1996-05-31 | 1998-11-30 | Sastech Pty Ltd | Termpolymerization |
-
1998
- 1998-03-17 CN CN98101108A patent/CN1086191C/zh not_active Expired - Lifetime
-
1999
- 1999-03-16 WO PCT/CN1999/000037 patent/WO1999047568A1/zh active IP Right Grant
- 1999-03-16 JP JP2000536759A patent/JP4394280B2/ja not_active Expired - Lifetime
- 1999-03-16 EP EP99908737A patent/EP1083187B1/en not_active Expired - Lifetime
- 1999-03-16 BR BRPI9908977-7A patent/BR9908977B1/pt not_active IP Right Cessation
- 1999-03-16 US US09/268,826 patent/US6617278B1/en not_active Expired - Lifetime
- 1999-03-16 KR KR10-2000-7010248A patent/KR100512605B1/ko not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JP4394280B2 (ja) | 2010-01-06 |
US6617278B1 (en) | 2003-09-09 |
KR20010041937A (ko) | 2001-05-25 |
WO1999047568A1 (fr) | 1999-09-23 |
CN1086191C (zh) | 2002-06-12 |
EP1083187B1 (en) | 2006-10-25 |
KR100512605B1 (ko) | 2005-09-05 |
EP1083187A1 (en) | 2001-03-14 |
CN1229092A (zh) | 1999-09-22 |
EP1083187A4 (en) | 2004-05-19 |
BR9908977B1 (pt) | 2009-05-05 |
JP2002506893A (ja) | 2002-03-05 |
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