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AR095356A1 - Mezclas plaguicidas que comprenden un compuesto de pirazol - Google Patents

Mezclas plaguicidas que comprenden un compuesto de pirazol

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Publication number
AR095356A1
AR095356A1 ARP130102191A ARP130102191A AR095356A1 AR 095356 A1 AR095356 A1 AR 095356A1 AR P130102191 A ARP130102191 A AR P130102191A AR P130102191 A ARP130102191 A AR P130102191A AR 095356 A1 AR095356 A1 AR 095356A1
Authority
AR
Argentina
Prior art keywords
methyl
chloro
group
bromo
phenyl
Prior art date
Application number
ARP130102191A
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English (en)
Original Assignee
Basf Se
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Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=48607274&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=AR095356(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basf Se filed Critical Basf Se
Publication of AR095356A1 publication Critical patent/AR095356A1/es

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/58—1,2-Diazines; Hydrogenated 1,2-diazines
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
    • A01N37/46—N-acyl derivatives
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
    • A01N43/36—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom five-membered rings
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
    • A01N43/78—1,3-Thiazoles; Hydrogenated 1,3-thiazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/88—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with three ring hetero atoms
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D403/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00
    • C07D403/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings
    • C07D403/12—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, not provided for by group C07D401/00 containing two hetero rings linked by a chain containing hetero atoms as chain links

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  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Environmental Sciences (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Pest Control & Pesticides (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
  • Agronomy & Crop Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)

Abstract

Reivindicación 1: Mezcla plaguicida caracterizada porque comprende como compuestos activos: 1) al menos un compuesto de pirazol A seleccionado de los compuestos de la fórmula (1) en donde R¹ es H, alquilo C₁₋₂ o alcoxi C₁₋₂-alquilo C₁₋₂; R² es CH₃, CH₂F, CHF₂ o CF₃; R³ es alquilo C₂₋₆, un radical R³ᵃ o un radical R³ᵇ; R⁴ es alquilo C₁₋₄ o un grupo mencionado para R³ᵃ; R⁵ es H, halógeno o un grupo mencionado para R⁴; R³ y R⁴, junto con el átomo de carbono al que están unidos, pueden formar un carbociclo o heterociclo monocíclico de 3 a 6 miembros, que pueden contener 1 ó 2 porciones de heteroátomos seleccionadas de N-Rᶜ, O y S(O)ₖ, en donde k es 0, 1 ó 2, y en donde el carbociclo o heterociclo es no sustituido o se puede sustituir con 1, 2, 3 ó 4 radicales Rᵃ³; R³ y R⁴, junto con el átomo de carbono al que están unidos, también pueden formar un carbociclo o heterociclo monospiro o dispiro de 5 a 10 miembros, que puede contener 1 ó 2 porciones de heteroátomos seleccionadas de N-Rᶜ, O y S(O)ᵏ, en donde k es 0, 1 ó 2, y en donde el carbociclo o heterociclo es no sustituido o se puede sustituir con 1, 2, 3 ó 4 radicales Rᵃ³; R³ᵃ se selecciona del grupo que consiste en CN, NO₂, S(O)ₙRᵇ, haloalquilo C₁₋₄, alquilo C₁₋₄ que es parcial o totalmente sustituido con Rᵃ¹, alquenilo C₂₋₆, alquinilo C₂₋₆, alcoxi C₁₆, en donde los átomos C en los tres últimos radicales mencionados pueden ser no sustituidos, o parcial o totalmente sustituidos con Rᵃ², cicloalquilo C₃₋₆ y cicloalquenilo C₅₋₆, en donde los átomos C en los dos últimos radicales mencionados pueden ser no sustituidos, o parcial o totalmente sustituidos con Rᵃ³; R³ᵇ es un carbociclo o heterociclo monospiro o dispiro de 5 a 10 miembros, que puede contener 1 ó 2 porciones de heteroátomos seleccionadas de N-Rᶜ, O y S(O)ₖ, en donde k es 0, 1 ó 2, y en donde el carbociclo o heterociclo monospiro o dispiro de 5 a 10 miembros es no sustituido o se puede sustituir con 1, 2, 3 ó 4 radicales Rᵃ³; Rᵃ¹ es CN, NO₂, C(O)NH₂, C(S)NH₂, alquil C₁₋₂carboniloxi, alcoxi C₁₋₄, haloalcoxi C₁₋₂, alquil C₁₋₂oxicarbonilo, o S(O)ₙRᵇ; Rᵃ² es halógeno o un grupo mencionado para Rᵃ¹; Rᵃ³ es halógeno, alquilo C₁₋₂, haloalquilo C₁₋₂, alcoxi C₁₋₂-alquilo C₁₋₂, alquilideno C₁₋₂, =O, =S, =NRᵇ, =NORᵇ, =NSRᵇ o un grupo mencionado para Rᵃ¹; n es 0, 1 ó 2; Rᵇ se selecciona del grupo que consiste en hidrógeno, alquilo C₁₋₂, haloalquilo C₁₋₂, cicloalquilo C₃₋₆ y alcoxi C₁₋₄; Rᶜ es hidrógeno, alquilo C₁₋₂, haloalquilo C₁₋₂, alquil C₁₋₂carbonilo y alcoxi C₁₋₂carbonilo; los estereoisómeros, las sales, los tautómeros y los N-óxidos de estos; y 2) al menos un compuesto B adicional seleccionado de los compuestos de los siguientes grupos A.1, A.2, A.3, A.4, A.5, A.6, A.7, A.8, A.9, A.10, A.11, A.12, A.13, A.14, A.15, A.16, A.17, F.1, F.2, F.3, F.4, F.5, F.6, F.7, F.8, F.9, F.10 y F.11: A.1) Compuestos de carbamato seleccionados del grupo que consiste en methiocarb y thiodicarb; A.2) Compuestos piretroides seleccionados del grupo que consiste en acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cylclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, b-cyfluthrin, cyhalothrin, l-cyhalothrin, g-cyhalothrin, cypermethrin, a-cypermethrin, b-cypermethrin, q-cypermethrin, z-cypermethrin, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, t-fluvalinate, halfenprox, imiprothrin, meperfluthrin, metofluthrin, permethrin, phenothrin, prallethrin, profluthrin, pyrethrin (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethylfluthrin, tetramethrin, tralomethrin y transfluthrin; A.3) Compuestos agonistas / antagonistas del receptor nicotínico seleccionados del grupo que consiste en acetamiprid, bensultap, cartap clorhidrato, clothianidin, dinotefuran, imidacloprid, thiamethoxam, nitenpyram, spinosad (agonista alostérico), spinetoram (agonista alostérico), thiacloprid, thiocyclam y thiosultap-sodium; A.4) Compuestos antagonistas del canal de cloruro regulado por GABA, seleccionados del grupo que consiste en acetoprole, ethiprole y fipronil; A.5) Activadores del canal de cloruro seleccionados del grupo que consiste en abamectin, emamectin benzoate, milbemectin y lepimectin; A.6) Desacopladores de la fosforilación oxidativa, tales como chlorfenapyr; A.7) Sinergistas, tales como butóxido de piperonilo; A.8) Bloqueadores selectivos de la alimentación, seleccionados del grupo que consiste en pymetrozine y flonicamid; A.9) Inhibidores de la síntesis de quitina, seleccionados del grupo que consiste en teflubenzuron y novaluron; A.10) Inhibidores de la biosíntesis de los lípidos, seleccionados del grupo que consiste en spirodiclofen, spiromesifen y spirotetramat; A.11) Moduladores receptores de rianodína tipo diamida - ftalamidas, seleccionadas del grupo que consiste en flubendiamide y (R)-, (S)-3-cloro-N1-{2-metil-4-[1,2,2,2-tetrafluoro-1-(trifluorometil)etil]fenil}-N2-(1-metil-2-metilsulfoniletil)ftalamida (A11.1); A.12) Compuestos de isoxazolina seleccionados del grupo que consiste en 4-[5-(3,5-diclorofenil)-5-trifluorometil-4,5-dihidro-isoxazol-3-iI]-2-metil-N-piridin-2-ilmetil-benzamida (A12.1), 4-[5-(3,5-dicloro-fenil)-5-trifluorometil-4,5-dihidro-isoxazol-3-il]-2metil-N-(2,2,2-trifluoroetil)-benzamida (A12.2), 4-[5-(3,5-dicloro-fenil)-5-trifluorometil-4,5-dihidroisoxazol-3-il]-2-metil-N-[(2,2,2-trifluoro-etilcarbamoil)-metil]-benzamida (A12.3), [(2,2,2-trifluoro-etilcarbamoil)-metil]-amida del ácido 4-[5-(3,5-dicloro-fenil)-5-trifluorometil-4,5-dihidro-isoxazol-3-il]-naftalen-1-carboxílico (A12.4); 4-[5-(3-cloro-5-trifluorometil-fenil)-5-trifluorometil-4,5-dihidro-isoxazol-3-il]-2-metil-N-[(2,2,2-trifluoro-etilcarbamoil)-metil]-benzamida (A12.5), [(2,2,2-trifluoroetilcarbamoil)-metil]-amida del ácido 4-[5-(3-cloro-5-trifluorometilfenil)-5-trifluorometil-4,5-dihidro-isoxazol-3-il]-naftalen-1-carboxílico (A12.6), 5-[5-(3,5-dicloro-4-fluorofenil)-5-trifluorometil-4,5-dihidro-isoxazol-3-il]-2-[1,2,4]triazol-1-il-benzonitrilo (A12.7) y 5-[5-(3,5-dicloro-fenil)-5-trifluorometil-4,5-dihidro-isoxazol-3-iI]-2-[1,2,4]triazol-1-il-benzonitrilo (A12.8); A.13) Moduladores receptores de rianodina tipo diamida - Compuestos de antralinamida seleccionados del grupo que consiste en chloranthraniliprole, cyantraniliprole, [4-ciano-2-(1-ciclopropiletilcarbamoil)-6-metil-fenil]-amida del ácido 5-bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carboxílico (A13.1), [2-cloro-4-ciano-6-(1-ciclopropil-etilcarbamoil)-fenil]-amida del ácido 5-bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carboxílico (A13.2), [2-bromo-4-ciano-6-(1-ciclopropil-etilcarbamoil)-fenil]-amida del ácido 5-bromo-2-(3-cloropiridin-2-il)-2H-pirazol-3-carboxílico (A13.3), [2-bromo-4-cloro-6-(1-ciclopropil-etilcarbamoil)-fenil]-amida del ácido 5-bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carboxílico (A13.4), [2,4-dicloro-6-(1-ciclopropil-etilcarbamoil)-fenil]-amida del ácido 5-bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carboxílico (A13.5), [4-cloro-2-(1-ciclopropil-etilcarbamoil)-6-metil-fenil]-amida del ácido 5-bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carboxílico (A13.6), metiléster del ácido N-(2-{[5-bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carbonil]-amino}-5-cloro-3-metil-benzoil)-hidrazincarboxílico (A13.7), metiléster del ácido N-(2-{[5-bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carbonil]-amino}-5-cloro-3-metil-benzoil)-N-metil-hidrazincarboxílico (A13.8), metiléster del ácido N-(2-{[5-bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carbonil]-amino}-5-cloro-3-metil-benzoil)N,N-dimetilhidrazincarboxílico (A13.9), metiléster del ácido N-(3,5-dibromo-2-{[5-bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carbonil]amino}-benzoil)-hidrazincarboxílico (A13.10), metiléster del ácido N-(3,5-dibromo-2-{[5-bromo-2-(3-cloro-piridin-2-il)-2H-pirazol-3-carbonil]-amino}-benzoil)-N-metil-hidrazincarboxílico (A13.11) y metiléster del ácido N-(3,5-dibromo-2-{[5-bromo-2-(3-cloropiridin-2-il)-2H-pirazol-3-carbonil]-amino}-benzoil)-N,N-dimetil-hidrazincarboxílico (A13.12); A.14) Compuestos de malononitrilo seleccionados del grupo que consiste en 2-(2,2,3,3,4,4,5,5-octafluoropentil)-2-(3,3,3-trifluoropropil)malononitrilo (CF₂H-CF₂-F₂-F₂-CH₂-C(CN)₂-CH₂-CH₂-CF₃) (A14.1) y 2-(2,2,3,3,4,4,5,5-octafluoropentil)-2-(3,3,4,4,4-pentafluorobutil)-malonodinitrilo (CF₂HCF₂-CF₂-CF₂-CH₂-C(CN)₂-CH₂-CH₂-CF₂-CF₃) (A14.2); A.15) Disruptores microbianos seleccionados del grupo que consiste en Bacillus thuringiensis subesp. Israelensi, Bacillus sphaericus, Bacillus thuringiensis subsp. Aizawa, Bacillus thuringiensis subesp. Kurstaki y Bacillus thuringiensis subesp. Tenebrionis; A.16) Compuestos de aminofuranona seleccionados del grupo que consiste en 4-{[(2-cloro-1,3-tiazol-5-il)metil](2-fluoroetil)amino}furan-2(5H)-ona (A16.1), 4-{[(6-cloropirid-3-il)metil](2-fluoroetil)amino}furan-2(5H)-ona (A16.2), 4-{[(6-cloropirid-3-il)metil](2,2-difluoroetil)amino}furan-2(5H)-ona (
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