MX166378B - Carbonato calcico estabilizado frente a los acidos, procedimiento para su produccion y metodo para su uso en la manufactura de papel acido - Google Patents
Carbonato calcico estabilizado frente a los acidos, procedimiento para su produccion y metodo para su uso en la manufactura de papel acidoInfo
- Publication number
- MX166378B MX166378B MX024828A MX2482891A MX166378B MX 166378 B MX166378 B MX 166378B MX 024828 A MX024828 A MX 024828A MX 2482891 A MX2482891 A MX 2482891A MX 166378 B MX166378 B MX 166378B
- Authority
- MX
- Mexico
- Prior art keywords
- acid
- calcium carbonate
- weak
- procedure
- manufacture
- Prior art date
Links
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 title abstract 8
- 239000002253 acid Substances 0.000 title abstract 7
- 229910000019 calcium carbonate Inorganic materials 0.000 title abstract 4
- 238000004519 manufacturing process Methods 0.000 title 2
- 238000000034 method Methods 0.000 title 2
- 229920001131 Pulp (paper) Polymers 0.000 title 1
- 150000007513 acids Chemical class 0.000 title 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 abstract 3
- 239000002585 base Substances 0.000 abstract 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 abstract 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract 2
- 239000003715 calcium chelating agent Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 abstract 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 abstract 1
- 239000000061 acid fraction Substances 0.000 abstract 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- -1 alkali metal salt Chemical class 0.000 abstract 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004327 boric acid Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/69—Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F11/00—Compounds of calcium, strontium, or barium
- C01F11/18—Carbonates
- C01F11/185—After-treatment, e.g. grinding, purification, conversion of crystal morphology
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/02—Compounds of alkaline earth metals or magnesium
- C09C1/021—Calcium carbonates
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/63—Inorganic compounds
- D21H17/67—Water-insoluble compounds, e.g. fillers, pigments
- D21H17/675—Oxides, hydroxides or carbonates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/10—Particle morphology extending in one dimension, e.g. needle-like
- C01P2004/11—Particle morphology extending in one dimension, e.g. needle-like with a prismatic shape
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Paper (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
La presente invención se refiere a un carbonato cálcico finamente dividido y estabilizado frente a los ácidos caracterizado por ser una mezcla de por lo menos alrededor de 0.1 por ciento en peso compuesto seleccionado entre el grupo formado por un agente quelatante de calcio y una base conjugada, que es una sal metálica alcalina de un ácido débil, junto con por lo menos alrededor de 0.1 por ciento en peso de un ácido débil, de manera que cuando se selecciona la base conjugada, la fracción de ácido débil de la misma y el ácido débil son iguales o son diferentes y están seleccionados entre el grupo formado por ácido fosfórico, ácido metafosfórico, ácido hezametafosfórico, ácido cítrico, ácido bórico, ácido sulfuroso, ácido acético y mezclas de los mismos, estando constituido el resto hasta 100 por ciento en peso por carbonato cálcico finamente dividido , de manera que el carbonato cálcico está recubierto por el agente quelantante del calcio o la base conjugada y el ácido débil y en equilibrio con ellos.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/491,366 US5043017A (en) | 1990-03-09 | 1990-03-09 | Acid-stabilized calcium carbonate, process for its production and method for its use in the manufacture of acidic paper |
Publications (1)
Publication Number | Publication Date |
---|---|
MX166378B true MX166378B (es) | 1993-01-04 |
Family
ID=23951903
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX024828A MX166378B (es) | 1990-03-09 | 1991-03-08 | Carbonato calcico estabilizado frente a los acidos, procedimiento para su produccion y metodo para su uso en la manufactura de papel acido |
Country Status (11)
Country | Link |
---|---|
US (1) | US5043017A (es) |
EP (1) | EP0445952B1 (es) |
JP (1) | JP3127001B2 (es) |
KR (1) | KR930001213B1 (es) |
AU (2) | AU7276691A (es) |
BR (1) | BR9100922A (es) |
CA (1) | CA2035808C (es) |
DE (1) | DE69121605T2 (es) |
ES (1) | ES2091866T3 (es) |
FI (2) | FI108155B (es) |
MX (1) | MX166378B (es) |
Families Citing this family (64)
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US5269818A (en) * | 1990-03-13 | 1993-12-14 | Pfizer Inc | Rhombohedral calcium carbonate and accelerated heat-aging process for the production thereof |
US5227025A (en) * | 1990-03-13 | 1993-07-13 | Pfizer Inc | Rhombohedral calcium carbonate and accelerated heat-aging process for the production thereof |
WO1992021613A1 (en) * | 1991-06-04 | 1992-12-10 | Minerals Technologies, Inc. | Precipitated calcium carbonate particles from basic calcium carbonate |
PL170873B1 (en) * | 1992-04-03 | 1997-01-31 | Minerals Tech Inc | Method of obtaining precipitated calcium carbonate in the form of clusters |
US5380361A (en) * | 1993-03-12 | 1995-01-10 | Minerals Technologies, Inc. | Modified filler material for alkaline paper and method of use thereof in alkaline paper making |
US5360515A (en) * | 1993-08-25 | 1994-11-01 | The Research Foundation Of The State University Of New York | Method for reducing thermal and light-induced brightness reversion in lignin-containing pulps |
US5531821A (en) * | 1995-08-24 | 1996-07-02 | Ecc International Inc. | Surface modified calcium carbonate composition and uses therefor |
US5599388A (en) * | 1995-08-24 | 1997-02-04 | Ecc International Inc. | Acid resistant calcium carbonate composition containing an aluminum salt, uses therefor and processes for its production |
US5593488A (en) * | 1995-08-24 | 1997-01-14 | Ecc International Inc. | Acid resistant calcium carbonate composition and uses therefor |
US5593489A (en) * | 1995-10-20 | 1997-01-14 | Ecc International Inc. | Acid resistant carbonate composition containing an aluminum or magnesium hydroxide methods of preparation and uses therefor |
US5647902A (en) * | 1995-10-20 | 1997-07-15 | Ecc International Inc. | Stabilized calcium carbonate composition using sodium carbonate and mixtures of acids and uses therefor |
US5711799A (en) * | 1996-03-13 | 1998-01-27 | Ecc International Inc. | Acid tolerant calcium carbonate composition and uses therefor |
US6083317A (en) * | 1996-11-05 | 2000-07-04 | Imerys Pigments, Inc. | Stabilized calcium carbonate composition using sodium silicate and one or more weak acids or alum and uses therefor |
US6228161B1 (en) * | 1996-12-30 | 2001-05-08 | Minerals Technologies Inc. | Use of calcium carbonate in an acidic aqueous media |
US5913973A (en) * | 1997-07-08 | 1999-06-22 | Ecc International Inc. | Method for producing high solids aqueous acid-resistant calcium carbonate suspensions and product thereof |
FI103520B1 (fi) | 1998-03-03 | 1999-07-15 | Aga Ab | Parannetut paperinvalmistusmenetelmät |
US6504975B1 (en) | 1998-09-17 | 2003-01-07 | Matsushita Electric Industrial Co., Ltd. | Coupling lens and semiconductor laser module |
FR2787802B1 (fr) * | 1998-12-24 | 2001-02-02 | Pluss Stauffer Ag | Nouvelle charge ou pigment ou mineral traite pour papier, notamment pigment contenant du caco3 naturel, son procede de fabrication, compositions les contenant, et leurs applications |
FI104003B1 (fi) | 1999-02-08 | 1999-10-29 | Aga Ab | Stabiloitu täyteaine, sen valmistus ja käyttö |
US6251356B1 (en) | 1999-07-21 | 2001-06-26 | G. R. International, Inc. | High speed manufacturing process for precipitated calcium carbonate employing sequential perssure carbonation |
US6440209B1 (en) | 2000-02-09 | 2002-08-27 | Engelhard Corpoartion | Composite pigments comprising in-situ precipitated metal carbonate crystals |
US20030213937A1 (en) * | 2001-02-22 | 2003-11-20 | Isaac Yaniv | Precipitated aragonite and a process for producing it |
US20030161894A1 (en) * | 2001-09-05 | 2003-08-28 | 3P Technologies Ltd. | Precipitated aragonite and a process for producing it |
US6685908B1 (en) | 2000-03-06 | 2004-02-03 | 3P Technologies Ltd. | Precipitated aragonite and a process for producing it |
US7048900B2 (en) | 2001-01-31 | 2006-05-23 | G.R. International, Inc. | Method and apparatus for production of precipitated calcium carbonate and silicate compounds in common process equipment |
US7056419B2 (en) * | 2002-09-30 | 2006-06-06 | American Air Liquide, Inc. | Methods for modifying electrical properties of papermaking compositions using carbon dioxide |
FR2852600B1 (fr) * | 2003-03-18 | 2005-06-10 | Nouveau pigment mineral contenant du carbonate de calcium, suspension aqueuse le contenant et ses usages | |
FR2871474B1 (fr) * | 2004-06-11 | 2006-09-15 | Omya Development Ag | Nouveau pigment mineral sec contenant du carbonate de calcium, suspension aqueuse le contenant et ses usages |
US20060003117A1 (en) * | 2004-06-14 | 2006-01-05 | Specialty Minerals (Michigan) Inc. | Ink jet recording paper |
KR20170001758A (ko) * | 2004-12-22 | 2017-01-04 | 솔베이(소시에떼아노님) | 알칼리 토금속 카르보네이트의 내산성 입자 |
EP1752499A1 (en) | 2005-07-25 | 2007-02-14 | Omya Development AG | Process to disperse and/or grind and/or concentrate calcium carbonate in aqueous media using an aqueous solution containing zirconium compounds |
US7964063B2 (en) * | 2006-08-11 | 2011-06-21 | Georgia Tech Research Corporation | Methods and compositions for papermaking |
DK1974807T3 (da) * | 2007-03-21 | 2010-06-14 | Omya Development Ag | Fremgangsmåde til fjernelse af endokrint forstyrrende forbindelser |
SI1974806T1 (sl) * | 2007-03-21 | 2012-01-31 | Omya Development Ag | Postopek za čiščenje vode |
EP2053162A1 (en) | 2007-10-26 | 2009-04-29 | SAPPI Netherlands Services B.V. | Coating formulation for an offset paper and paper coated therewith |
DE602007009124D1 (de) | 2007-12-12 | 2010-10-21 | Omya Development Ag | Verfahren zur Herstellung von oberflächenreaktives Fällungskalziumkarbonat |
US8034759B2 (en) * | 2008-10-31 | 2011-10-11 | Ecolab Usa Inc. | Enhanced stability peracid compositions |
EP2264109B1 (en) | 2009-06-15 | 2012-01-25 | Omya Development AG | Process for preparing surface-reacted calcium carbonate and its use |
ME01441B (me) | 2009-06-15 | 2012-12-31 | Omya Development Ag | Postupak za dobijanje površinski izreagovanog kalcijum karbonata primenom slabe kiseline |
SI2377900T1 (sl) * | 2010-04-16 | 2013-12-31 | Omya International Ag | Postopek za pripravo površinsko modificiranega mineralnega materiala, izhajajoči proizvodi in njihova uporaba |
US8387282B2 (en) | 2010-04-26 | 2013-03-05 | Nike, Inc. | Cable tightening system for an article of footwear |
US8586156B2 (en) | 2010-05-04 | 2013-11-19 | International Paper Company | Coated printable substrates resistant to acidic highlighters and printing solutions |
EP2596169A1 (en) | 2010-07-23 | 2013-05-29 | International Paper Company | Coated printable substrates providing higher print quality and resolution at lower ink usage |
JP5903215B2 (ja) * | 2011-02-28 | 2016-04-13 | シスメックス株式会社 | ループスアンチコアグラント検出用試薬キット及びループスアンチコアグラントの存否を判定する方法 |
CN102702795B (zh) * | 2012-05-02 | 2014-03-05 | 石家庄市三兴钙业有限公司 | 聚氨酯胶专用纳米碳酸钙的制备方法 |
SI2679638T1 (sl) | 2012-06-28 | 2015-11-30 | Omya International Ag | Vodna mineralna in/ali polnilna in/ali pigmentna suspenzija z visoko vrednostjo trdnih delcev v kislinskem ph okolju |
WO2016033446A1 (en) | 2014-08-29 | 2016-03-03 | Blue Planet, Ltd. | Carbonate pigments, and methods for making and using the same |
EP3045503A1 (en) | 2015-01-15 | 2016-07-20 | Omya International AG | Surface-treated calcium carbonate with improved stability in environments with a pH of 4.5 to 7 |
CA2997940A1 (en) * | 2015-09-08 | 2017-03-16 | Nippon Paper Industries Co., Ltd. | Complexes of calcium phosphate microparticles and fibers as well as processes for preparing them |
EP3275948A1 (en) | 2016-07-25 | 2018-01-31 | Omya International AG | Process for preparing surface-reacted calcium carbonate |
CA3035937A1 (en) | 2016-09-08 | 2018-03-15 | Schaefer Kalk Gmbh & Co. Kg | Composite powder containing calcium carbonate and having microstructured particles |
JP7098624B2 (ja) * | 2016-09-08 | 2022-07-11 | シェーファー・カーク・ゲーエムベーハー・ウント・コンパニー・カーゲー | 炭酸カルシウムを含有し、阻害性炭酸カルシウムを有する微細構造粒子を有する、複合粉末 |
AU2017324138B2 (en) * | 2016-09-08 | 2022-04-07 | Karl Leibinger Asset Management Gmbh & Co. Kg | Method for producing an implant using a calcium carbonate-containing composite powder comprising microstructured particles |
RU2738378C2 (ru) * | 2016-09-08 | 2020-12-11 | Шефер Кальк Гмбх Унд Ко. Кг | Кальцийкарбонатная добавка |
RU2743294C2 (ru) * | 2016-09-08 | 2021-02-16 | Карл Лайбингер Медицинтехник Гмбх Унд Ко. Кг | Способ изготовления импланта из композиционного порошка с микроструктурированными частицами, содержащими ингибирующий карбонат кальция |
WO2018046276A1 (de) | 2016-09-08 | 2018-03-15 | Karl Leibinger Medizintechnik Gmbh & Co. Kg | Implantat enthaltend inhibierendes calciumcarbonat |
PL3509733T3 (pl) | 2016-09-08 | 2020-11-16 | Schaefer Kalk Gmbh & Co. Kg | Zawierający sól wapnia proszek kompozytowy z cząstkami z mikrostrukturą |
RU2676292C1 (ru) * | 2017-12-19 | 2018-12-27 | Федеральное государственное унитарное предприятие "Комбинат "Электрохимприбор" | Способ получения карбоната кальция |
US11040898B2 (en) * | 2018-06-05 | 2021-06-22 | The Regents Of The University Of California | Buffer-free process cycle for CO2 sequestration and carbonate production from brine waste streams with high salinity |
EP3725851A1 (en) | 2019-04-16 | 2020-10-21 | Omya International AG | Process for preparing surface-reacted calcium carbonate |
BR112021023624A2 (pt) | 2019-06-14 | 2022-01-04 | Univ California | Enriquecimento de cátion alcalino e eletrólise de água para prover mineralização de co2 e gerenciamento de carbono em escala global |
KR20240093572A (ko) | 2021-10-18 | 2024-06-24 | 더 리전트 오브 더 유니버시티 오브 캘리포니아 | Mg(oh)2 생산 및 co2 광물화를 가능하도록 하는 해수 전기분해 |
US12246993B2 (en) | 2022-02-21 | 2025-03-11 | Carbonbuilt | Methods and systems for biomass-derived CO2 sequestration in concretes and aggregates |
EP4508020A1 (en) | 2022-04-12 | 2025-02-19 | CarbonBuilt | Process for production of hydraulic-carbonating binder systems through mechanochemical activation of minerals |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2059624A1 (de) * | 1969-12-04 | 1971-06-09 | Rohan George Alexander | Kalkpulver und Verfahren zu seiner Herstellung |
US4115187A (en) * | 1970-03-31 | 1978-09-19 | Welwyn Hall Research Association | Agglomerated fillers used in paper |
GB1347071A (en) * | 1971-07-01 | 1974-02-13 | Starch Products Ltd | Paper fillers |
GB1447566A (en) * | 1974-02-14 | 1976-08-25 | Ici Ltd | Production of calcium carbonate |
JPS5390199A (en) * | 1977-01-20 | 1978-08-08 | Shiraishi Kogyo Kaisha Ltd | Method of modifying calcium carbonate |
JPS53129200A (en) * | 1977-04-18 | 1978-11-10 | Shiraishi Kogyo Kk | Dispersant for calcium carbonate |
US4244933A (en) * | 1978-04-05 | 1981-01-13 | Shiraishi Kogyo Kaisha, Ltd. | Calcium carbonate particles and processes for preparing same |
JPS5686015A (en) * | 1979-12-12 | 1981-07-13 | Mitsubishi Electric Corp | Sampling signal malfunction monitor |
US4793985A (en) * | 1982-08-23 | 1988-12-27 | J. M. Huber Corporation | Method of producing ultrafine ground calcium carbonate |
DE3587060T2 (de) * | 1984-10-18 | 1993-05-19 | Pfizer | Kugelfoermiges ausgefaelltes calciumcarbonat, seine herstellung und seine verwendung. |
-
1990
- 1990-03-09 US US07/491,366 patent/US5043017A/en not_active Expired - Lifetime
-
1991
- 1991-02-06 CA CA002035808A patent/CA2035808C/en not_active Expired - Lifetime
- 1991-02-27 DE DE69121605T patent/DE69121605T2/de not_active Expired - Lifetime
- 1991-02-27 ES ES91301573T patent/ES2091866T3/es not_active Expired - Lifetime
- 1991-02-27 EP EP91301573A patent/EP0445952B1/en not_active Expired - Lifetime
- 1991-03-07 BR BR919100922A patent/BR9100922A/pt not_active IP Right Cessation
- 1991-03-08 FI FI911183A patent/FI108155B/fi active
- 1991-03-08 AU AU72766/91A patent/AU7276691A/en not_active Abandoned
- 1991-03-08 MX MX024828A patent/MX166378B/es unknown
- 1991-03-08 KR KR1019910003718A patent/KR930001213B1/ko not_active IP Right Cessation
- 1991-03-11 JP JP03127002A patent/JP3127001B2/ja not_active Expired - Lifetime
-
1993
- 1993-05-20 AU AU38703/93A patent/AU665634B2/en not_active Ceased
-
2000
- 2000-12-12 FI FI20002724A patent/FI111972B/fi active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
US5043017A (en) | 1991-08-27 |
JP3127001B2 (ja) | 2001-01-22 |
CA2035808C (en) | 1997-03-04 |
AU3870393A (en) | 1993-08-05 |
EP0445952B1 (en) | 1996-08-28 |
FI20002724L (fi) | 2000-12-12 |
DE69121605T2 (de) | 1997-03-06 |
KR910016627A (ko) | 1991-11-05 |
JPH04227665A (ja) | 1992-08-17 |
EP0445952A1 (en) | 1991-09-11 |
AU665634B2 (en) | 1996-01-11 |
FI108155B (fi) | 2001-11-30 |
KR930001213B1 (ko) | 1993-02-22 |
FI111972B (fi) | 2003-10-15 |
FI911183A0 (fi) | 1991-03-08 |
ES2091866T3 (es) | 1996-11-16 |
DE69121605D1 (de) | 1996-10-02 |
CA2035808A1 (en) | 1991-09-10 |
BR9100922A (pt) | 1991-11-05 |
AU7276691A (en) | 1991-10-10 |
FI911183L (fi) | 1991-09-10 |
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