KR870005023A - 경화생성물의 제조방법 - Google Patents
경화생성물의 제조방법 Download PDFInfo
- Publication number
- KR870005023A KR870005023A KR860009771A KR860009771A KR870005023A KR 870005023 A KR870005023 A KR 870005023A KR 860009771 A KR860009771 A KR 860009771A KR 860009771 A KR860009771 A KR 860009771A KR 870005023 A KR870005023 A KR 870005023A
- Authority
- KR
- South Korea
- Prior art keywords
- catalyst
- group
- phosphane
- carbon atoms
- process according
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims 11
- 239000003054 catalyst Substances 0.000 claims 6
- 150000001875 compounds Chemical class 0.000 claims 6
- 125000004432 carbon atom Chemical group C* 0.000 claims 5
- 229920001577 copolymer Polymers 0.000 claims 4
- 239000004215 Carbon black (E152) Substances 0.000 claims 3
- 150000002118 epoxides Chemical group 0.000 claims 3
- 229930195733 hydrocarbon Natural products 0.000 claims 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims 2
- 239000005922 Phosphane Substances 0.000 claims 2
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 claims 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 2
- 229910000064 phosphane Inorganic materials 0.000 claims 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 claims 2
- KYVBNYUBXIEUFW-UHFFFAOYSA-N 1,1,3,3-tetramethylguanidine Chemical compound CN(C)C(=N)N(C)C KYVBNYUBXIEUFW-UHFFFAOYSA-N 0.000 claims 1
- SGUVLZREKBPKCE-UHFFFAOYSA-N 1,5-diazabicyclo[4.3.0]-non-5-ene Chemical compound C1CCN=C2CCCN21 SGUVLZREKBPKCE-UHFFFAOYSA-N 0.000 claims 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000002879 Lewis base Substances 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 1
- 239000007983 Tris buffer Substances 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 150000001408 amides Chemical class 0.000 claims 1
- 150000001409 amidines Chemical class 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 1
- 239000002585 base Substances 0.000 claims 1
- ZDBIRELPHMTOGQ-UHFFFAOYSA-N bis[(4-methoxyphenyl)methyl]-methylphosphane Chemical compound C1=CC(OC)=CC=C1CP(C)CC1=CC=C(OC)C=C1 ZDBIRELPHMTOGQ-UHFFFAOYSA-N 0.000 claims 1
- 239000007795 chemical reaction product Substances 0.000 claims 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims 1
- 239000003822 epoxy resin Substances 0.000 claims 1
- 125000004185 ester group Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims 1
- 150000007527 lewis bases Chemical class 0.000 claims 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 1
- 239000011976 maleic acid Substances 0.000 claims 1
- CNRMAYYJMYPPHU-UHFFFAOYSA-N methanetricarboxamide Chemical group NC(=O)C(C(N)=O)C(N)=O CNRMAYYJMYPPHU-UHFFFAOYSA-N 0.000 claims 1
- UJNZOIKQAUQOCN-UHFFFAOYSA-N methyl(diphenyl)phosphane Chemical compound C=1C=CC=CC=1P(C)C1=CC=CC=C1 UJNZOIKQAUQOCN-UHFFFAOYSA-N 0.000 claims 1
- -1 methyldi-p-tolifane Chemical compound 0.000 claims 1
- 229910052760 oxygen Inorganic materials 0.000 claims 1
- 239000001301 oxygen Substances 0.000 claims 1
- RDBMUARQWLPMNW-UHFFFAOYSA-N phosphanylmethanol Chemical compound OCP RDBMUARQWLPMNW-UHFFFAOYSA-N 0.000 claims 1
- 229920000768 polyamine Polymers 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 229920000728 polyester Polymers 0.000 claims 1
- 229920000642 polymer Polymers 0.000 claims 1
- 229920005862 polyol Polymers 0.000 claims 1
- 150000003077 polyols Chemical class 0.000 claims 1
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 1
- 229920005989 resin Polymers 0.000 claims 1
- 239000011347 resin Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000007858 starting material Substances 0.000 claims 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 claims 1
- RAVACSWYIIPFFV-UHFFFAOYSA-N tris[(4-methoxyphenyl)methyl]phosphane Chemical compound C1=CC(OC)=CC=C1CP(CC=1C=CC(OC)=CC=1)CC1=CC=C(OC)C=C1 RAVACSWYIIPFFV-UHFFFAOYSA-N 0.000 claims 1
- JABYJIQOLGWMQW-UHFFFAOYSA-N undec-4-ene Chemical compound CCCCCCC=CCCC JABYJIQOLGWMQW-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/83—Chemically modified polymers
- C08G18/833—Chemically modified polymers by nitrogen containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
- C08G18/8093—Compounds containing active methylene groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Polyurethanes Or Polyureas (AREA)
- Epoxy Resins (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
내용 없음
Description
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
Claims (15)
- 적어도 2개의 하기 일반식(Ⅰ)의 그룹을 함유하는 화합물(A)와, 하기 구조식(Ⅱ)의 메탄트리카-복스 아미드 단위를 함유하고타입의 활성 수소 원자를 갖는 그룹을 적어도 2개 이상 함유하는 화합물(B)를 촉매의 존재하에 반응시켜 올리고머 및/또는 폴리머 가교결합된 반응생성물을 형성시킴을 특징으로하여 경화생성물을 제조하는 방법.상기식에서,X는 -CO이고,R1은 수소 또는 탄소수 1 내지 10의 탄화수소 라디칼이며,R2는 수소, 탄소수 1 내지 10의 탄화수소 라디칼, 탄소수 12까지의 1가 알콜의 라디칼 R4를 함유하는 에스테르 그룹, -CN, -NO2, 또는 CO-NHR1- 또는 CO-R1-그룹이고,R3는 R2와 동일한 의미를 가지며, R2및 R3는 서로 같거나 다르다.
- 제1항에 있어서, 촉매로서 루이스(Lewis) 염기 또는 브뢴스테드염기가 사용되는 방법.
- 제1항 또는 제2항에 있어서, 촉매로서 아미드, 구아니딘, 아미딘, 포스판, 4급 암모늄 플루오라이드 또는 하이드록사이드 및 알칼리금속 알콜레이트로 이루어진 그룹 중에서 선택된 적어도 하나의 화합물이 사용되는 방법.
- 제1항 내지 3항중 어느 하나에 있어서, 촉매로서 N,N,N,N-테트라메틸구아니딘, 1,5-디아자비사이클로 [4.3.0]논-5-엔, 1,8-디아자비사이클로 [5.4.0] 운데크-7-엔 또는 1,4 -디아자비사이클로 [2.2.2]옥탄이 사용되는 방법.
- 제1항 내지 3항 중의 어느 하나에 있어서, 촉매로서 트리스하이드록시메틸포스평, 트리스디메틸아미노메틸포스판, 트리페닐포스판, 메틸디-p-톨리포스판, 트리스-p-아니실포스판, 메틸디페닐포스판, 메틸디-p-아니실포스판 또는 α,α-디메틸벤질이미노트리부틸포스포란이 사용되는 방법.
- 제1항 내지 5항중의 어느 하나에 있어서, 촉매의 사용량이 출발물질의 총 고체 함량에 대해 0.02 내지 2중량인 방법.
- 제1항 내지 6항중의 어느 하나에 있어서, 반응을 0내지 100℃의 온도에서 수행하는 방법.
- 제1항 내지 7항중의 어느 하나에 있어서, 화합물(A)와 (B)가, 활성 수소원자에 대한 활성이 중결합의 비가(0.8 내지 1.2):1내지 1:(0.8내지 1.2)의 범위가 되도록 하는 양으로 사용되는 방법.
- 제1항 내지 8항중의 어느 하나에 있어서, 일반식(Ⅰ)에서 R1및 경우에 따라 R2및 R3가 탄소수 1내지 4의 탄화수소 라디칼을 나타내는 방법.
- 제1항 내지 9항중의 어느 하나에 있어서, 라디칼 R1R2C=CR3-X(Ⅰ)이 2염기성이하이며 탄소원자 2내지 10개를 함유하는 단일불포화되거나 다불포화된 카복실산으로 부터 유도되는 방법.
- 제10항에 있어서, 카복실산이 아크릴산, 메타크릴산 및/또는 말레산인 방법.
- 제1항 내지 11항중의 어느 하나에 있어서, 화합물(A)에서 그룹(Ⅰ)이 폴리올 또는 폴리아민의 라디칼에 부찻되는 방법.
- 제1항 내지 12항중의 어느 하나에 이어서, 화합물(A)가 OH그룹을 함유하는 폴리에스테르 그룹을 함유하는 코폴리머, 에폭사이드 그룹을 함유하는 코폴리머 또는 에폿사이드 수지 및/또는 아민수지로부터 유도되는 방법.
- 제13항에 있어서, OH그룹을 함유하는 코폴리머가 40내지 250의 OH수를 갖는 방법.
- 제13항에 있어서, 에폭사이드 그룹을 함유하는 코폴리머가 1내지 10%의 에폭사이드 산소를 함유하는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP3541140.6 | 1985-11-21 | ||
| DE19853541140 DE3541140A1 (de) | 1985-11-21 | 1985-11-21 | Haertungsprodukt auf basis von olefinisch ungesaettigten verbindungen und wasserstoffaktiven verbindungen, verfahren zu dessen herstellung und darauf basierende zwei-komponentenlacke |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR870005023A true KR870005023A (ko) | 1987-06-04 |
| KR950007997B1 KR950007997B1 (ko) | 1995-07-24 |
Family
ID=6286451
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1019860009771A KR950007997B1 (ko) | 1985-11-21 | 1986-11-19 | 경화성 혼합물 |
Country Status (22)
| Country | Link |
|---|---|
| US (1) | US5159024A (ko) |
| EP (1) | EP0224158B1 (ko) |
| JP (1) | JPH0816152B2 (ko) |
| KR (1) | KR950007997B1 (ko) |
| CN (1) | CN1013117B (ko) |
| AR (1) | AR245157A1 (ko) |
| AT (1) | ATE98965T1 (ko) |
| AU (1) | AU588399B2 (ko) |
| BR (1) | BR8605727A (ko) |
| CA (1) | CA1282536C (ko) |
| CS (1) | CS274283B2 (ko) |
| DD (1) | DD260072A5 (ko) |
| DE (2) | DE3541140A1 (ko) |
| DK (1) | DK555586A (ko) |
| ES (1) | ES2061437T3 (ko) |
| FI (1) | FI89930C (ko) |
| IE (1) | IE62801B1 (ko) |
| MX (1) | MX4392B (ko) |
| NO (1) | NO169549C (ko) |
| PL (1) | PL149347B1 (ko) |
| PT (1) | PT83783B (ko) |
| ZA (1) | ZA868795B (ko) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3733552A1 (de) * | 1987-10-03 | 1989-04-13 | Herberts Gmbh | Kathodisch abscheidbares waessriges elektrotauchlack-ueberzugsmittel und dessen verwendung |
| DE3734916A1 (de) * | 1987-10-15 | 1989-04-27 | Hoechst Ag | Haertungskomponente fuer kunstharze, diese enthaltende haertbare mischungen sowie deren verwendung |
| DE3932517A1 (de) * | 1989-09-29 | 1991-04-11 | Herberts Gmbh | Bindemittelzusammensetzung und deren verwendung in ueberzugsmitteln |
| DE4133704A1 (de) * | 1991-10-11 | 1993-04-15 | Herberts Gmbh | Katalysatorfreies einkomponenten-ueberzugsmittel und dessen verwendung zur herstellung von saeurebestaendigen lackierungen |
| DE4213671A1 (de) * | 1992-04-25 | 1993-10-28 | Herberts Gmbh | Verfahren zur Rückgewinnung des Oversprays von wäßrigen Überzugsmitteln beim Spritzauftrag in Spritzkabinen |
| BE1005775A3 (nl) * | 1992-04-29 | 1994-01-25 | Dsm Nv | Bindmiddelsamenstelling voor oplosmiddel- of watergebaseerde coatings. |
| DE4225104C1 (de) * | 1992-07-30 | 1993-12-09 | Herberts Gmbh | Überzugsmittel und dessen Verwendung bei der Herstellung von Überzügen mit rasch bearbeitbarer Oberfläche |
| DE4225105C1 (de) * | 1992-07-30 | 1993-12-09 | Herberts Gmbh | Überzugsmittel und dessen Verwendung bei der Herstellung von Überzügen mit rasch bearbeitbarer Oberfläche |
| DE4237492A1 (de) * | 1992-11-06 | 1994-05-11 | Herberts Gmbh | Wäßrige Bindemittelzusammensetzung, diese enthaltende Überzugsmittel und deren Verwendung |
| DE4237490A1 (de) * | 1992-11-06 | 1994-05-11 | Herberts Gmbh | Überzugsmittel und dessen Verwendung zur Herstellung von säurebeständigen Lackierungen |
| EP0672072B1 (en) * | 1993-09-22 | 1998-08-05 | Ashland Oil, Inc. | Polyurethane reaction system having a blocked catalyst combination |
| CA2164994A1 (en) * | 1994-12-24 | 1996-06-25 | Heinz Dietholf Becker | Binder composition, coating agents containing it, and use thereof |
| JPH08283627A (ja) * | 1995-04-12 | 1996-10-29 | Nippon Paint Co Ltd | 塗料用一液熱硬化性樹脂組成物 |
| DE19528878A1 (de) * | 1995-08-05 | 1997-02-06 | Herberts Gmbh | Wäßrige Überzugsmittel unter Verwendung von Polyalkylenglykoldialkylethern und Verfahren zur Mehrschichtlackierung |
| AU721485B2 (en) * | 1996-10-30 | 2000-07-06 | Ems-Patent Ag | Heat curable coating compounds |
| GB2323599A (en) * | 1997-03-18 | 1998-09-30 | Courtaulds Plc | Compositions curable by a Michael reaction |
| US7256241B2 (en) | 2000-01-21 | 2007-08-14 | Cyclics Corporation | Methods for polymerizing macrocyclic polyester oligomers using catalyst promoters |
| US6906147B2 (en) | 2002-03-20 | 2005-06-14 | Cyclics Corporation | Catalytic systems |
| RU2265621C2 (ru) * | 2000-03-13 | 2005-12-10 | Акцо Нобель Н.В. | Композиция, включающая соединение с изоцианатной функциональной группой, соединение, способное реагировать с изоцианатами, и сокатализатор |
| US7750109B2 (en) | 2000-09-01 | 2010-07-06 | Cyclics Corporation | Use of a residual oligomer recyclate in the production of macrocyclic polyester oligomer |
| US7767781B2 (en) * | 2000-09-01 | 2010-08-03 | Cyclics Corporation | Preparation of low-acid polyalkylene terephthalate and preparation of macrocyclic polyester oligomer therefrom |
| JP2004507599A (ja) | 2000-09-01 | 2004-03-11 | サイクリクス コーポレイション | 線形ポリエステルを、大環状オリゴエステル組成物および大環状オリゴエステルに変換する方法 |
| US7304123B2 (en) | 2001-06-27 | 2007-12-04 | Cyclics Corporation | Processes for shaping macrocyclic oligoesters |
| US7071291B2 (en) | 2001-06-27 | 2006-07-04 | Cyclics Corporation | Isolation, formulation and shaping of macrocyclic oligoesters |
| US6787632B2 (en) | 2001-10-09 | 2004-09-07 | Cyclics Corporation | Organo-titanate catalysts for preparing pure macrocyclic oligoesters |
| KR20030053018A (ko) * | 2001-12-21 | 2003-06-27 | 다이니혼 잉키 가가쿠 고교 가부시키가이샤 | 경화성 수지 조성물 및 아크릴로일기, 치환된메타크릴레이트기 및 β-디카르보닐기를 갖는 올리고머또는 폴리머의 제조 방법 |
| US8013068B2 (en) * | 2003-01-02 | 2011-09-06 | Rohm And Haas Company | Michael addition compositions |
| DE102015105983A1 (de) | 2015-04-20 | 2016-10-20 | Mankiewicz Gebr. & Co. Gmbh & Co. Kg | Verbesserte Beschichtungssysteme, deren Verwendung zur Beschichtung von Bauteilen sowie damit beschichtete Bauteile für Land- und Baumaschinen |
| CN113437438A (zh) * | 2020-03-06 | 2021-09-24 | 厦门大学 | 一种环氧树脂改性陶瓷隔膜及其制备方法和应用 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4928653B1 (ko) * | 1970-04-21 | 1974-07-29 | ||
| DE2612783C3 (de) * | 1976-03-25 | 1981-11-05 | Hoechst Ag, 6000 Frankfurt | Biurete, Verfahren zu ihrer Herstellung und deren Verwendung |
| DE2631949A1 (de) * | 1976-07-15 | 1978-01-19 | Bayer Ag | Strahlen-haertende bindemittel |
| DE2639491B1 (de) * | 1976-09-02 | 1978-02-02 | Hoechst Ag | Einbrennlacke auf der Grundlage von freie Hydroxylgruppen enthaltenden Polyester- und/oder Alkydharzen und blockierten Polyisocyanaten |
| DE3046409A1 (de) * | 1980-12-10 | 1982-07-15 | Bayer Ag, 5090 Leverkusen | Beschichtungsmittel und ein verfahren zur herstellung von ueberzuegen |
| ATE46178T1 (de) * | 1984-04-04 | 1989-09-15 | Hoechst Ag | Umsetzungsprodukt von olefinisch ungesaettigten verbindungen mit wasserstoffaktiven verbindungen, verfahren zu dessen herstellung und darauf basierende 2-komponentenlacke. |
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1985
- 1985-11-21 DE DE19853541140 patent/DE3541140A1/de not_active Withdrawn
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1986
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- 1986-11-15 EP EP86115895A patent/EP0224158B1/de not_active Expired - Lifetime
- 1986-11-15 AT AT86115895T patent/ATE98965T1/de not_active IP Right Cessation
- 1986-11-15 ES ES86115895T patent/ES2061437T3/es not_active Expired - Lifetime
- 1986-11-18 DD DD86296387A patent/DD260072A5/de not_active IP Right Cessation
- 1986-11-19 CS CS839886A patent/CS274283B2/cs unknown
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- 1986-11-19 AR AR86305949A patent/AR245157A1/es active
- 1986-11-19 US US06/932,635 patent/US5159024A/en not_active Expired - Fee Related
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- 1986-11-19 KR KR1019860009771A patent/KR950007997B1/ko not_active IP Right Cessation
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- 1986-11-20 AU AU65536/86A patent/AU588399B2/en not_active Ceased
- 1986-11-20 NO NO864643A patent/NO169549C/no unknown
- 1986-11-20 JP JP61275473A patent/JPH0816152B2/ja not_active Expired - Lifetime
- 1986-11-20 DK DK555586A patent/DK555586A/da not_active Application Discontinuation
- 1986-11-20 PT PT83783A patent/PT83783B/pt not_active IP Right Cessation
- 1986-11-20 ZA ZA868795A patent/ZA868795B/xx unknown
- 1986-11-20 PL PL1986262500A patent/PL149347B1/pl unknown
- 1986-11-20 CN CN86107731A patent/CN1013117B/zh not_active Expired
- 1986-11-20 BR BR8605727A patent/BR8605727A/pt not_active IP Right Cessation
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