JP2019156727A - Cleanser composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a diisostearyl malate which is excellent in usability, does not hinder foaming property and foam quality, and can be blended in a transparent detergent, and a diisostearyl malate and an ionic surfactant. To provide a detergent composition containing the above. SOLUTION: A diester composition of isostearyl alcohol and malic acid derived from a by-product during the production of dimer acid is used. When blended in a cleansing agent, the diester composition has an excellent effect of imparting a small molecule silicone-like finger passage and moist feeling to hair, and an effect of imparting flexibility and moist feeling to skin. Excellent. Further, it does not impair the foaming property and foam quality of the surfactant, and can be easily blended in a formulation that requires transparency in appearance. [Selection diagram] None

Description

  The present invention relates to a detergent composition containing a diester composition of isostearyl alcohol and malic acid derived from a by-product during dimer acid production, and an ionic surfactant.

  In cosmetics, oil is one of the main ingredients blended into most types of dosage forms. Its main purpose is to impart flexibility and emollient to the skin and hair, and further, according to the characteristics of each oil agent, feeling of use, moisture retention, glossiness, cleanability, pigment dispersibility, adhesion, Used for the purpose of improving solubility. Even in detergent applications, oil agents are blended as a greasing agent that imparts flexibility and emollient properties, but at this time, it is required that the foaming properties and foam quality of the surfactant are not impaired, and the appearance is also improved. In prescriptions that require transparency, it is required to be transparent.

  Diisostearyl malate, which is one of the ester oils widely used in cosmetics, has long been used as a highly viscous and highly polar oil agent with excellent safety and stability (for example, Patent Documents 1 to 3). ). Such conventionally used diisostearyl malate is easily compatible with both polar oils and non-polar oils, and is excellent in gloss, affinity with pigments, adhesion to skin, and the like. Therefore, it is widely used as a base oil for makeup cosmetics. It is also used for the purpose of touch adjustment in the fields of skin care and hair care. On the other hand, although diisostearyl malate used conventionally is known as an oil agent having relatively little stickiness as a highly viscous oil, it is not always satisfactory as a feeling of use. Moreover, since the foaming property and foam quality of surfactant were inhibited, the utilization for detergent use was not progressing.

  Diisostearyl malate is a diester obtained by an esterification reaction of malic acid and isostearyl alcohol, and isostearyl alcohol is a generic name for higher alcohols having 18 carbon atoms having a branched alkyl chain. There are several types of compounds in the generally available isostearyl alcohol due to the branched structure, but as diisostearyl malate conventionally used in cosmetics, 5,7, Only compounds using 7-trimethyl-2- (1,3,3-trimethylbutyl) -octan-1-ol are in circulation. This is because quasi-drug ingredients that include the specifications of ingredients for cosmetic varieties that previously included the standards for ingredients that can be blended in cosmetics, and the standards for ingredients that can now be blended as ingredients for quasi-drugs. In the standard 2006 (Kotohara), diisostearyl malate is “a diester of malic acid and 5,7,7-trimethyl-2- (1,3,3-trimethylbutyl) -octane-1-ol”. It is clear from the definition. Actually, as diisostearyl malate currently distributed as a commercial product, NIKKOL DISM (manufactured by Nikko Chemicals), Esterol DISM (manufactured by National Mimatsu), Cosmol 222 (manufactured by Nisshin Oilio), Himalate DIS (manufactured by Higher Alcohol Industry Co., Ltd.), all of which are compounds using the above-mentioned isostearyl alcohol. Therefore, it has not been known at all about diisostearyl malate using other isostearyl alcohol having a branched structure.

JP 62-051610 A JP2003-1113024 JP 2005-330254 A

  Diisostearyl malate that is excellent in feeling of use and does not inhibit foaming properties and foam quality, and can be blended in a cleaning agent of a transparent formulation, and blended with diisostearyl malate and an ionic surfactant A cleaning composition is provided.

  As a result of diligent studies to solve the above-mentioned problems, the present inventors have found that a diester composition of isostearyl alcohol and malic acid derived from a by-product during dimer acid production is blended with a detergent. The present invention was completed by finding that it has an excellent feeling of use and can be easily blended into a transparent formulation without inhibiting foaming properties and foam quality.

  The diester composition of isostearyl alcohol and malic acid derived from the by-product during the production of the dimer acid of the present invention is compared with conventional diisostearyl malate in addition to the functions of conventional diisostearyl malate. In addition, it has an excellent feeling of use such as smoothness, no stickiness, and good fit to the skin, and has a high water-holding property and excellent moisturizing effect. In addition, when blended in a cleaning agent, the diester composition is superior in the effect of imparting a low molecular silicone-like finger feeling and moist feeling to the hair, compared to conventional diisostearyl malate, On the other hand, it is excellent in the effect of imparting flexibility and moist feeling. Furthermore, the foaming property and foam quality of the surfactant are not inhibited, and it can be easily blended into a formulation that requires transparency in appearance.

  The present invention contains a diester composition of isostearyl alcohol and malic acid derived from a by-product during dimer acid production (hereinafter referred to as diisostearyl malate of the present invention), and an ionic surfactant. It is a cleaning composition characterized by doing.

  The isostearyl alcohol used in the production of diisostearyl malate of the present invention is an isostearyl alcohol derived from a by-product during the production of dimer acid, and the details thereof will be described below. First, the dimer acid is a dibasic acid mainly composed of 36 carbon atoms produced by dimerizing an unsaturated fatty acid having 12 to 22 carbon atoms or a lower alcohol ester thereof with a clay catalyst or the like. Industrial manufacturing processes are almost standardized in the industry. During the production of the dimer acid, a monomer acid is generated as a by-product. The monomer acid includes an unsaturated fatty acid that has not participated in dimerization, a linear saturated fatty acid generated by a hydrogen transfer reaction, and isomerism. Branched fatty acids produced by chemical conversion are included. When this monomeric acid is further hydrogenated to form a mixture of a linear saturated fatty acid having a high melting point and a branched fatty acid having a low melting point, and the linear saturated fatty acid having a high melting point is removed by a solvent fractionation method, etc. Fatty acids are obtained. Although the branched fatty acid thus obtained depends on the type of unsaturated fatty acid used in the production of dimer acid, it is generally composed of a branched fatty acid having 18 carbon atoms as a main component and having 12 to 22 carbon atoms in addition to 18 carbon atoms. The branched fatty acids are also contained. The structure of branched fatty acids is not completely clear, but the main ones have a methyl branched structure in which one or two methyl groups are bonded to the main chain, and the position of the bond to the main chain is Not specified. In addition, ethyl branched, propyl branched, cyclic structures, and linear saturated fatty acids that have not been removed by solvent fractionation are also included. As described above, the branched fatty acid produced from the monomeric acid, which is a by-product during the production of dimer acid, is a mixture of various fatty acids, but since it is mainly composed of a branched fatty acid having 18 carbon atoms, it is generally the name of isostearic acid. And is distributed industrially. Such isostearic acid is hydrogenated in the presence of a catalyst to convert the carboxylic acid moiety into an alcohol, which is the isostearyl alcohol used in the present invention. It is a mixture of various higher alcohols whose main component is structure. The isostearyl alcohol derived from such a by-product during the production of dimer acid has a hydroxyl value of 200 to 215 and a viscosity (25 ° C.) of 30 to 70 mPa.s. s can be used, and as commercially available products, PRISOLINE 3515 (manufactured by Croda) and RADIANOL 1980 (manufactured by Oreon) are distributed, and in the present invention, such commercially available products can be used.

  Specific examples of malic acid used in the production of diisostearyl malate of the present invention include L-malic acid, D-malic acid, and DL-malic acid. Any of these can be used in the present invention. These may be used alone or in combination of two or more. Of these, DL-malic acid can be preferably used from the viewpoint of economy.

  Although the manufacturing method of the diisostearyl malate of this invention is not necessarily limited, It can manufacture with the following method. That is, it is obtained by esterifying the raw materials malic acid and isostearyl alcohol at a molar ratio of 1: 1.5 to 1: 2.5, more preferably 1: 1.8 to 1: 2.2. It is done. The conditions for the esterification reaction are not particularly limited, and the reaction is performed by a commonly used method. For example, when using a catalyst, paratoluenesulfonic acid, sulfuric acid, phosphoric acid, hydrochloric acid, methanesulfonic acid, boron trifluoride diethyl ether complex, titanium alcoholate, solid acid catalyst, etc. are used, and heptane, hexane, cyclohexane, toluene as a solvent. , Xylene or the like can be used at 50 to 260 ° C. Alternatively, esterification can be carried out at 100 to 260 ° C. even without solvent and without catalyst. Furthermore, you may refine | purify and use the obtained ester by a normal method as needed. For example, the remaining free carboxylic acid may be removed by washing with an alkaline aqueous solution, or purification such as distillation, steam deodorization, or activated carbon treatment may be performed for the purpose of reducing odor or improving stability. The diisostearyl malate of the present invention thus obtained may contain a monoester, unreacted isostearyl alcohol, or an esterified product of a dimer of malic acid in addition to the diester. Good. As already mentioned, since the isostearyl alcohol used in the present invention is a mixture of various alcohols, the diisostearyl malate of the present invention thus obtained can be produced from various alcohols and malic acid. It is a mixture of diesters.

  The diisostearyl malate of the present invention has a viscosity of 100 to 300 mPa · s at 25 ° C., which is much higher than the viscosity of the conventional diisostearyl malate is about 3,000 mPa · s. It is characterized by being low. For this reason, the feeling of use which has been a drawback of the conventional diisostearyl malate is greatly improved, and it is very advantageous in terms of smoothness, lack of stickiness, and familiarity with the skin. In addition, the diisostearyl malate of the present invention is also characterized by having high water retention. The water content, which is an index of water retention, is 50% or less in the conventional diisostearyl malate, whereas the diisostearyl malate of the present invention is 200 to 400%, which is very useful for imparting moisture retention. Useful for. In addition, the diisostearyl malate of the present invention has an effect of imparting a low molecular silicone-like finger feeling and moist feeling to the hair as compared with conventional diisostearyl malate when blended in a cleaning agent. It is excellent in the effect of imparting flexibility and moist feeling to the skin. Furthermore, the foaming property and foam quality of the surfactant are not inhibited, and it can be easily blended into a formulation that requires transparency in appearance. The blending amount of diisostearyl malate of the present invention into the detergent composition is not particularly limited as long as it does not impair the effects of the present invention, and is usually 0.01 to 20% by weight, preferably 0.8. 05 to 10% by weight.

  In the cleaning composition of the present invention, an ionic surfactant is used together with the diisostearyl malate of the present invention. Examples of the ionic surfactant used in the present invention include an anionic surfactant, a cationic surfactant, and an amphoteric surfactant. These are the main components in detergents. Anionic surfactants are intended to provide basic performance such as detergency and foaming. Cationic surfactants are flexible, antistatic, and bactericidal. For the purpose of imparting a function, the amphoteric surfactant is mainly used as an auxiliary agent for enhancing detergency and foamability. Examples of the anionic surfactant used in the cleaning composition of the present invention include alkyl sulfate ester salt, POE alkyl ether sulfate ester salt, alkylbenzene sulfonate salt, α-olefin sulfonate salt, alkyl sulfonate salt, and α-sulfone salt. Sulfuric acid or sulfonic acid type surfactants such as fatty acid alkyl ester salts, sulfosuccinic acid alkyl ester salts, POE alkyl ether sulfosuccinic acid ester salts, sulfosuccinic acid alkylamide salts; phosphorous such as alkyl phosphoric acid ester salts and POE alkyl ether phosphates Acid type surfactants; N-acyl glutamate, N-acyl aspartate, N-acyl glycine salt, N-acyl alanine salt, N-acyl-N-alkyl-β-alanine salt, N-acyl sarcosine salt, N-acylmethyl taurate, diacyl glu Acylamino acid type surfactants such as Min acid lysine salt; higher fatty acid salt, POE alkyl ether carboxylate, POE fatty acid amide ether carboxylate, a carboxylic acid type surface active agents such as alkenyl succinic acid salts. Examples of the cationic surfactant include monoalkyl quaternary ammonium salts, dialkyl quaternary ammonium salts, benzalkonium-type quaternary ammonium salts, fatty acid amide amine salts, and fatty acid amide quaternary ammonium salts. Examples of amphoteric surfactants include alkyl acetate betaines, fatty acid amide alkyl acetate betaines, alkyl sulfobetaines, fatty acid amide alkyl sulfobetaines, alkylamine oxides, fatty acid amide alkylamine oxides, imidazoline type betaines, and the like. In the cleaning composition of the present invention, it is preferable to use an anionic surfactant as an essential component among these ionic surfactants. There is no restriction | limiting in particular as a compounding quantity to the cleaning composition of the ionic surfactant of this invention, Usually, 0.01-90 weight%, Preferably, it is 0.05-60 weight%.

  A nonionic surfactant can be used in combination with the cleaning composition of the present invention. By using a nonionic surfactant in combination, the detergency can be improved, and when a formulation with a transparent appearance is desired, if the transparency is insufficient with only the ionic surfactant, By combining a nonionic surfactant, a composition having a transparent appearance can be obtained. Nonionic surfactants used in the detergent composition of the present invention include glycerin fatty acid ester, polyglycerin fatty acid ester, polyoxyethylene glycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene Examples include fatty acid esters, polyoxyethylene alkyl ethers, alkyl glucosides, sucrose fatty acid esters, alkyl ether amines, polyoxyethylene sterol ethers, polyoxyethylene lanolin ethers, and fatty acid alkanolamides. Among these, polyoxyethylene glycerin fatty acid ester, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene alkyl ether, and fatty acid alkanolamide are preferable. There is no restriction | limiting in particular as a compounding quantity to the cleaning composition of the nonionic surfactant of this invention, Usually, 0.01 to 40 weight%, Preferably it is 0.05 to 20 weight%.

  A higher fatty acid can be used in combination with the cleaning composition of the present invention. By blending higher fatty acids, it is possible to impart an improvement effect such as damage to the hair. The higher fatty acids used in the cleaning composition of the present invention include lauric acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid, eicosenoic acid, behenic acid, erucin Examples include acids, lignoceric acid, isopalmitic acid, isostearic acid, ricinoleic acid, polyricinoleic acid, hydroxystearic acid, polyhydroxystearic acid, and lanolin fatty acid. Of these, isostearic acid, oleic acid, ricinoleic acid, polyricinoleic acid, and lanolin fatty acid are preferred. There is no restriction | limiting in particular as a compounding quantity to the cleaning composition of the higher fatty acid of this invention, Usually, 0.01-30 weight%, Preferably, it is 0.05-10 weight%.

  The detergent composition containing diisostearyl malate according to the present invention contains, as necessary, water and additives added to normal cosmetics such as oil bases, surfactants, alcohols, humectants, high Molecules, thickeners / gelling agents, antioxidants, antiseptics, bactericides, chelating agents, pH adjusters / acids / alkalis, UV absorbers, whitening agents, solvents, exfoliating / dissolving agents, antipruritics, anti-inflammatory agents , Antiperspirants, refreshing agents, antihistamines, astringents, stimulants, hair-restoring agents / blood circulation promoters, reducing agents / oxidants, polymer powders, hydroxy acids, vitamins and derivatives thereof, saccharides and derivatives thereof In addition, organic acids, enzymes, nucleic acids, hormones, inorganic powders, fragrances, pigments and the like may be contained to the extent that the effects of the present invention are not impaired.

  Examples of oily bases include cetanol, myristyl alcohol, oleyl alcohol, lauryl alcohol, cetostearyl alcohol, stearyl alcohol, aralkyl alcohol, behenyl alcohol, jojoba alcohol, chimyl alcohol, ceralkyl alcohol, batyl alcohol, hexyldecanol, isostearyl alcohol, Higher alcohols such as 2-octyldodecanol and dimer diol; aralkyl alcohols and derivatives such as benzyl alcohol; lauric acid, myristic acid, palmitic acid, stearic acid, isostearic acid, behenic acid, undecylenic acid, 12-hydroxystearic acid, Palmitooleic acid, oleic acid, linoleic acid, linolenic acid, erucic acid, docosahexaenoic acid, eicosapentaenoic acid, isohexa Higher fatty acids such as cannic acid, anteisohenicosanoic acid, long-chain branched fatty acid, dimer acid, hydrogenated dimer acid, and metal soaps such as aluminum salts, calcium salts, magnesium salts, zinc salts, potassium, sodium salts, etc. And nitrogen-containing derivatives such as amides; liquid paraffin (mineral oil), heavy liquid isoparaffin, light liquid isoparaffin, α-olefin oligomer, polyisobutene, hydrogenated polyisobutene, polybutene, squalane, olive-derived squalane, squalene, petrolatum, solid Hydrocarbons such as paraffin; candelilla wax, carnauba wax, rice wax, wax wax, beeswax, montan wax, ozokerite, ceresin, paraffin wax, microcrystalline wax, petrolatum, fisher Tropsch wax, polyethylene wax, waxes such as ethylene / propylene copolymer; palm oil, palm oil, palm kernel oil, safflower oil, olive oil, castor oil, avocado oil, sesame oil, tea oil, evening primrose oil, wheat germ oil, macadamia nut Oil, hazelnut oil, cucumber oil, rosehip oil, meadow foam oil, persic oil, tea tree oil, peppermint oil, corn oil, rapeseed oil, sunflower oil, wheat germ oil, linseed oil, cottonseed oil, soybean oil, peanut oil, rice bran Vegetable oils such as oil, cacao butter, shea fat, hydrogenated coconut oil, hydrogenated castor oil, jojoba oil, hydrogenated jojoba oil; animal properties such as beef tallow, milk fat, horse fat, egg yolk oil, mink oil, turtle oil Fats and oils; animal waxes such as whale wax, lanolin, orange luffy oil; liquid lanolin, reduced lanoli Lanolins such as adsorption purified lanolin, lanolin acetate, liquid lanolin acetate, hydroxy lanolin, polyoxyethylene lanolin, lanolin fatty acid, hard lanolin fatty acid, lanolin alcohol, lanolin alcohol acetate, acetic acid (cetyl lanolyl) ester; lecithin, phosphatidylcholine, Phosphatidylethanolamine, phosphatidylserine, phosphatidylglycerol, phosphatidylinositol, sphingophospholipids such as sphingomyelin, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof, phospholipids such as lysolecithin; hydrogenated soybean phospholipid, partially hydrogenated soybean phospho Phospholipid derivatives such as lipids, hydrogenated egg yolk phospholipids, partially hydrogenated egg yolk phospholipids; cholesterol, dihydrocholesterol, lanostero , Sterols such as dihydrolanosterol, phytosterol and cholic acid; sapogenins; saponins; cholesteryl acetate, cholesteryl nonate, cholesteryl stearate, cholesteryl isostearate, cholesteryl oleate, N-lauroyl-L-glutamate di (cholesteryl / behenyl) / Octyldodecyl), N-lauroyl-L-glutamate di (cholesteryl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / behenyl / octyldodecyl), N-lauroyl-L-glutamate di (phytosteryl / octyldodecyl) ), Acyl sarcosine alkyl esters such as N-lauroyl sarcosine isopropyl, cholesteryl 12-hydroxystearate, macadamia nut oil fatty acid choles Steryl esters such as teryl, macadamia nut oil fatty acid phytosteryl, sunflower seed oil fatty acid phytosteryl, phytosteryl isostearate, soft lanolin fatty acid cholesteryl, hard lanolin fatty acid cholesteryl, long chain branched fatty acid cholesteryl, long chain α-hydroxy fatty acid cholesteryl; phospholipids / cholesterol Complexes, lipid complexes such as phospholipid / phytosterol complexes; octyldodecyl myristate, hexyldecyl myristate, octyldodecyl isostearate, cetyl parimilate, octyldodecyl palmitate, cetyl octanoate, hexyldecyl octanoate, isononanoic acid Isotridecyl, isononyl isononanoate, octyl isononanoate, isotridecyl isononanoate, isodecyl neopentanoate, ne Isotridecyl pentanoate, isostearyl neopentanoate, octyldodecyl neodecanoate, oleyl oleate, octyldodecyl oleate, octyldodecyl ricinoleate, lanolin fatty acid octyldodecyl, dicaprylyl carbonate, hexyldecyl dimethyloctanoate, octyldodecyl erucate, isostearic acid cure Castor oil, ethyl oleate, avocado oil fatty acid ethyl, isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl isostearate, lanolin fatty acid isopropyl, methyl heptyl laurate, methyl heptyl palmitate, methyl heptyl palmitate, methyl isostearate Heptyl, diethyl sebacate, diisopropyl sebacate, dioctyl sebacate, Monoalcohol carboxylic acid esters such as diisopropyl pinate, dibutyloctyl sebacate, diisobutyl adipate, dioctyl succinate, triethyl citrate; cetyl lactate, conventional diisostearyl malate, monoisostearate hydrogenated castor oil, γ- Oxyacid esters such as elcalactone; glyceryl trioctanoate, glyceryl trioleate, glyceryl triisostearate, glyceryl diisostearate, glyceryl tri (caprylic acid / capric acid), tri (caprylic acid / capric acid / myristic acid / stearic acid) ) Glyceryl, hydrogenated rosin triglyceride (hydrogenated ester gum), rosin triglyceride (ester gum), glyceryl behenate, trimethylolpropane trioctanoate, triiso Trimethylolpropane ditearate, neopentyl glycol dioctanoate, neopentyl glycol dicaprate, 2-butyl-2-ethyl-1,3-propanediol dioctanoate, propylene glycol dioleate, pentaerythrityl tetraoctanoate, hydrogenated rosin Pentaerythrityl, triethylhexanoic acid ditrimethylolpropane, (isostearic acid / sebacic acid) ditrimethylolpropane, triethylhexanoic acid pentaerythrityl, (hydroxystearic acid / stearic acid / rosinic acid) dipentaerythrityl, diisostearate diglyceryl, tetraisostearic acid Polyglyceryl, polyglyceryl-10 nonaisostearate, deca (erucic acid / isostearic acid / ricinoleic acid) polyglyceryl- 8, (Hexyldecanoic acid / sebacic acid) diglyceryl oligoester, glycol distearate (ethylene glycol distearate), 3-methyl-1,5-pentanediol dineopentanoate, 2,4-diethyl-1,5-pentane dineopentanoate Polyhydric alcohol fatty acid esters such as diol; alkyl ethers such as dicaprylyl ether; diisopropyl dimerolinoleate, diisostearyl dimerdilinoleate, dimerisolinoleate di (isostearyl / phytosteryl), dimerlinoleic acid ( Phytosteryl / behenyl), dimer dilinoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl), dimer dilinoleate dimer dilinoleyl, diisostearate dimer dilinoleyl Dimer linoleyl hydrogenated rosin condensate, dimer linoleic acid hydrogenated castor oil, dimer acid or dimer diol derivative such as hydroxyalkyl dimer linoleyl ether; coconut oil fatty acid monoethanolamide (cocamide MEA), coconut oil fatty acid diethanolamine (Cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide (palmitamide MEA), palmitic acid diethanolamide ( Fatty acid alkanolamides such as palmitamide DEA) and palm oil fatty acid methylethanolamide (cocamidomethyl MEA); dimethicone (dimethylpolysiloxane) , Highly polymerized dimethicone (polymerized dimethylpolysiloxane), cyclomethicone (cyclic dimethylsiloxane, decamethylcyclopentasiloxane), phenyltrimethicone, diphenyldimethicone, phenyldimethicone, (aminoethylaminopropylmethicone / dimethicone) copolymer, dimethiconol, dimethiconol Cross-polymer, silicone resin, silicone rubber, amino-modified silicone such as aminopropyl dimethicone and amodimethicone, polyether-modified silicone such as cation-modified silicone and dimethicone copolyol, polyglycerin-modified silicone, sugar-modified silicone, carboxylic acid-modified silicone, phosphorus Acid-modified silicone, sulfuric acid-modified silicone, alkyl-modified silicone, fatty acid-modified silicone, alkyl ether-modified silicone Amino acid modified silicone, peptide modified silicone, fluorine modified silicone, cationic modified and polyether modified silicone, amino modified and polyether modified silicone, alkyl modified and polyether modified silicone, amide alkyl modified silicone, amino glycol modified silicone, amino Preferred examples include silicones such as phenyl-modified silicone and polysiloxane / oxyalkylene copolymer; and fluorine-based oils such as perfluorodecane, perfluorooctane, and perfluoropolyether.

  As the humectant / feel improver, glycerin, 1,3-butylene glycol, propylene glycol, 3-methyl-1,3-butanediol, 1,3-propanediol, 2-methyl-1,3-propanediol, Polyols such as trimethylolpropane, pentaerythritol, hexylene glycol, diglycerin, polyglycerin, diethylene glycol, polyethylene glycol, dipropylene glycol, polypropylene glycol, ethylene glycol / propylene glycol copolymer and polymers thereof; diethylene glycol monoethyl ether (Ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, diethylene glycol dibutyl ether, etc. (Eicosane diacid / tetradecanedioic acid) water-soluble esters such as polyglyceryl-10, tetradecanedioic acid polyglyceryl-10, and cyclohexanedicarboxylic acid bisethoxydiglycol; sugars such as sorbitol, xylitol, erythritol, mannitol, maltitol Alcohols; glucose, fructose, galactose, mannose, threose, xylose, arabinose, fucose, ribose, deoxyribose, maltose, trehalose, lactose, raffinose, gluconic acid, glucuronic acid, cyclodextrins (α-, β-, γ- Cyclodextrins and modified cyclodextrins such as maltosylation and hydroxyalkylation), β-glucan, chitin, chitosan, heparin and derivatives, pectin, arabino Sugars and derivatives thereof such as galactan, dextrin, dextran, glycogen, ethyl glucoside, glucosylethyl methacrylate polymer or copolymer; hyaluronic acid, sodium hyaluronate; sodium chondroitin sulfate; mucoitin sulfate, caroline sulfate, keratosulfate, dermatan Sulfuric acid; white jellyfish extract; white jellyfish polysaccharide; fructans such as inulin and levan; fucoidan; tuberose polysaccharide, naturally occurring polysaccharide; organic acids such as citric acid, tartaric acid and lactic acid and salts thereof; urea; 2-pyrrolidone-5 -Carboxylic acid and salts thereof such as sodium; betaine (trimethylglycine), proline, hydroxyproline, arginine, lysine, serine, glycine, alanine, phenylalanine, tyrosine, β-alanine, threonine Amino acids and salts thereof such as glutamic acid, glutamine, asparagine, aspartic acid, cysteine, cystine, methionine, leucine, isoleucine, valine, tryptophan, histidine, taurine; collagen, fish-derived collagen, atelocollagen, gelatin, elastin, collagenolytic peptide, Hydrolyzed collagen, hydroxypropylammonium chloride hydrolyzed collagen, elastin degrading peptide, keratin degrading peptide, hydrolyzed keratin, conchiolin degrading peptide, hydrolyzed conchiolin, silk proteolytic peptide, hydrolyzed silk, lauroyl hydrolyzed silk sodium, soybean proteolytic Peptides, wheat proteolytic peptides, hydrolyzed wheat proteins, casein degrading peptides, acylated peptides and other protein peptides and their Derivatives; acylated peptides such as palmitoyl oligopeptide, palmitoyl pentapeptide, palmitoyl tetrapeptide; silylated peptides; lactic acid bacteria culture solution, yeast extract, eggshell membrane protein, bovine submandibular gland mucin, hypotaurine, sesameignan glycoside, Glutathione, albumin, whey; choline chloride, phosphorylcholine; placenta extract, aerostin, collagen, aloe extract, hamamelis water, loofah water, chamomile extract, licorice extract, comfrey extract, silk extract, Izayoi rose extract, yarrow extract Animal / plant extract components such as eucalyptus extract and merirot extract, natural ceramide (type 1, 2, 3, 4, 5, 6), hydroxyceramide, pseudoceramide, glycosphingolipid, ceramide and sugar ceramide-containing extract Ceramides can be mentioned as preferred.

Preferred examples of the surfactant include an anionic surfactant, a nonionic surfactant, a cationic surfactant, an amphoteric surfactant, and a polymer surfactant. There is no restriction | limiting in particular in HLB of surfactant, It can use from about 1 low thing to about 20 high thing, It is also preferable to combine a low thing and a high thing of HLB. Examples of preferable surfactants include fatty acid salts such as potassium laurate and potassium myristate; alkyl sulfates such as sodium lauryl sulfate, triethanolamine lauryl sulfate, and ammonium lauryl sulfate; laureth Polyoxyethylene alkyl sulfates such as sodium sulfate and laureth sulfate triethanolamine; cocoyl methyl taurine sodium, cocoyl methyl taurine potassium, lauroyl methyl taurine sodium, myristoyl methyl taurine sodium, lauroyl methyl alanine sodium, lauroyl sarcosine sodium, lauroyl sarcosine triethanol Acyl N-methyl amino acid salts such as amines and sodium methylalanine lauroylglutamate; Cocoyl Glue Acyl amino acid salts such as sodium phosphate, triethanolamine cocoyl glutamate, sodium lauroyl glutamate, sodium myristoyl glutamate, sodium stearoyl glutamate, ditriethanolamine palmitoyl aspartate, cocoylalanine triethanolamine, lysine Na dilauroyl glutamate; sodium laureth acetate, etc. Polyoxyethylene alkyl ether acetates; succinic acid ester salts such as sodium lauroyl monoethanolamide succinate; fatty acid alkanolamide ether carboxylates; acyl lactates; polyoxyethylene fatty amine sulfates; fatty acid alkanolamide sulfates; Fatty acid glyceride sulfate such as coconut oil fatty acid sodium glycerin sulfate; Oxyethylene sulfate; Olefin sulfonate such as sodium α-olefin sulfonate; Alkyl sulfosuccinate such as disodium lauryl sulfosuccinate and dioctyl sodium sulfosuccinate; Disodium laureth sulfosuccinate, monolauroyl monoethanolamide polyoxyethylene sulfosuccinate Alkyl ether sulfosuccinates such as sodium acid, sodium lauryl polypropylene glycol sulfosuccinate; alkylbenzene sulfonates such as sodium tetradecylbenzenesulfonate and triethanolamine tetradecylbenzenesulfonate; alkylnaphthalenesulfonate; alkanesulfonate; α-sulfo fatty acid methyl ester salt; acyl isethionate; alkyl glycidyl ether sulfonate Alkyl sulfoacetates; alkyl ether phosphates such as sodium laureth phosphate, sodium dilaures phosphate, sodium trilaureth phosphate, sodium monooles phosphate; alkyl phosphate esters such as potassium lauryl phosphate; sodium caseinate; alkyl aryl ether phosphorus Acid salts; fatty acid amide ether phosphates; phospholipids such as phosphatidylglycerol, phosphatidylinositol, phosphatidic acid, cyclic lysophosphatidic acid or salts thereof; silicone-based shades such as carboxylic acid-modified silicone, phosphate-modified silicone, and sulfate-modified silicone Nonionic surfactants such as ionic surfactants, laureth (polyoxyethylene lauryl ether), ceteth (polyoxyethylene cetyl ether), steale Various polyoxyethylene addition numbers such as bis (polyoxyethylene stearyl ether), behenes (polyoxyethylene behenyl ether), isosteares (polyoxyethylene isostearyl ether), octyldecesses (polyoxyethylene octyldodecyl ether) Polyoxyethylene alkyl ethers; polyoxyethylene alkyl phenyl ethers; polyoxyethylene hydrogenated castor oil, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil monoisostearate, polyoxyethylene hydrogenated castor oil triisostearate, Castor oil and hardened castor oil derivatives such as polyoxyethylene hydrogenated castor oil monopyroglutamic acid monoisostearic acid diester, polyoxyethylene hardened castor oil maleic acid; Polyoxyethylene cholesterol; polyoxyethylene cholestanol; polyoxyethylene lanolin; polyoxyethylene reduced lanolin; polyoxyethylene polyoxypropylene cetyl ether, polyoxyethylene polyoxypropylene 2-decyltetradecyl ether; Polyoxyethylene / polyoxypropylene monobutyl ether, polyoxyethylene / polyoxypropylene hydrogenated lanolin, polyoxyethylene / polyoxypropylene alkyl ethers such as polyoxyethylene / polyoxypropylene glycerin ether; polyoxyethylene / polyoxypropylene glycol ; (Poly) glycerin polyoxypropylene glycol such as PPG-9 diglyceryl; Glyceryl isostearate, glyceryl isostearate, glyceryl palmitate, glyceryl myristate, glyceryl oleate, glyceryl palm oil fatty acid, mono-cotton oil fatty acid glycerin, glyceryl monoerucate, glyceryl sesquioleate, glycerin α, α'-pyroglutamate oleate, monostearate Glycerin fatty acid partial esters such as glyceryl malic acid; polyglyceryl stearate-2, 3, 4, 5, 6, 8, 8, disglyceryl-6, 10, polyglyceryl tristearate 2, polyglyceryl-10 decastearate, polyglyceryl-2 isostearate, 3, 4, 5, 6, 6, 8, diisostearate polyglyceryl-2 (diglyceryl diisostearate), 3, 1 Polyglyceryl-2 triisostearate, polyglyceryl-2 tetraisostearate, polyglyceryl-10 decaisostearate, polyglyceryl-2 oleate, 3, 4, 5, 6, 8, 10, dioleate polyglyceryl- 6, polyglyceryl fatty acid ester such as polyglyceryl-2 trioleate, polyglyceryl-10 decaoleate; ethylene glycol mono fatty acid ester such as ethylene glycol monostearate; propylene glycol mono fatty acid ester such as propylene glycol monostearate; pentaerythritol moiety Fatty acid ester; sorbitol partial fatty acid ester; maltitol partial fatty acid ester; maltitol ether; sorbitan monooleate, sorbitan monoisostearate Sorbitan fatty acid esters such as sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan trioleate, diglycerol sorbitan penta-2-ethylhexylate, diglycerol sorbitan tetra-2-ethylhexylate; Sugar derivatives partial esters such as sucrose fatty acid ester, methyl glucoside fatty acid ester and undecylenic acid trehalose; alkyl glucoside such as caprylyl glucoside; alkyl polyglycoside; glycolipid such as mannosyl erythritol lipid; lanolin alcohol; reduced lanolin; Stearate, polyethylene glycol diisostearate, polyoxyethylene monooleate, polyoxyethylene dioleate, etc. Polyoxyethylene fatty acid mono- and diesters; polyoxyethylene propylene glycol fatty acid esters; polyoxyethylene monooleates such as polyoxyethylene glycerin monostearate, polyoxyethylene glycerin monoisostearate, polyoxyethylene glycerin triisostearate Polyoxyethylene glycerin fatty acid esters such as polyoxyethylene sorbitan monooleate; polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate, polyoxyethylene sorbitan monooleate, and other polyoxyethylene sorbitan fatty acid esters; poly Oxyethylene sorbitol monolaurate, polyoxyethylene sorbitol monooleate, polyoxyethylene Polyoxyethylene sorbitol fatty acid esters such as bitol pentaoleate and polyoxyethylene sorbitol monostearate; Polyoxyethylene methyl glucoside fatty acid ester; Polyoxyethylene alkyl ether fatty acid ester; Polyoxyethylene animal and vegetable oils such as polyoxyethylene sorbitol beeswax Alkyl glyceryl ethers such as isostearyl glyceryl ether, chimyl alcohol, ceralkyl alcohol and batyl alcohol; polyhydric alcohol alkyl ethers; polyoxyethylene alkylamines; tetrapolyoxyethylene / tetrapolyoxypropylene-ethylenediamine condensates; Natural surfactants such as saponins and sophorolipids; polyoxyethylene fatty acid amides; coconut oil fatty acid monoethano Luamide (cocamide MEA), coconut oil fatty acid diethanolamide (cocamide DEA), lauric acid monoethanolamide (lauramide MEA), lauric acid diethanolamide (lauramide DEA), lauric acid monoisopropanolamide (lauramide MIPA), palmitic acid monoethanolamide Fatty acid alkanolamides such as (partamide MEA), palmitic acid diethanolamide (partamide DEA), and palm oil fatty acid methylethanolamide (cocamidomethyl MEA); alkyl such as lauramine oxide, cocamamine oxide, stearamine oxide, and behenamine oxide Polydimethyl ether oxide; alkyl ethoxy dimethyl amine oxide; polyoxyethylene alkyl mercaptan; polyether such as dimethicone copolyol Silicone-based nonionic surfactants such as silicone-modified silicones, polysiloxane / oxyalkylene copolymers, polyglycerin-modified silicones, sugar-modified silicones, etc .; for cationic surfactants, behentrimonium chloride, steartrimonium chloride Alkyltrimethylammonium chloride such as cetrimonium chloride and lauryltrimonium chloride; alkyltrimethylammonium bromide such as stearyltrimonium bromide; dialkyldimethylammonium chloride such as distearyldimonium chloride and dicocodimonium chloride; stearamidepropyldimethylamine; Fatty acid amidoamines such as stearamide ethyl diethylamine and salts thereof; alkyl ether amines such as stearoxypropyldimethylamine; and Salt or quaternary salt of fatty acid amide type quaternary ammonium salt such as ethyl sulfate long chain branched fatty acid (12-31) aminopropylethyldimethylammonium, ethyl lanolin sulfate fatty acid aminopropylethyldimethylammonium; polyoxyethylene alkylamine and its Alkylamine salt; fatty acid amidoguanidinium salt; alkyl etheraminemonium salt; alkyltrialkylene glycol ammonium salt; benzalkonium salt; benzethonium salt; pyridinium salt such as cetylpyridinium chloride; imidazolinium salt Alkyl isoquinolinium salts; dialkyl morpholinium salts; polyamine fatty acid derivatives; amino-modified silicones such as aminopropyl dimethicone and amodimethicone; cation-modified silicones; And silicone-based cationic surfactants such as polyether-modified silicones, amino-modified and polyether-modified silicones, etc .; in amphoteric surfactants, N-alkyl-N, N- such as laurylbetaine (lauryldimethylaminoacetic acid betaine) Dimethylamino acid betaine; fatty acid amide alkyl-N, N-dimethylamino acid betaine such as cocamidopropyl betaine and lauramidopropyl betaine; imidazoline type betaine such as sodium cocoamphoacetate and sodium lauroamphoacetate; alkyl sulfobetaine such as alkyldimethyltaurine; alkyl Sulfate-type betaines such as dimethylaminoethanol sulfate; phosphate-type betaines such as alkyldimethylaminoethanol phosphate; phosphatidylcholine, phosphatidylethanolamine , Sphingophospholipids such as phosphatidylserine and sphingomyelin, lysolecithin, hydrogenated soybean phospholipid, partially hydrogenated soybean phospholipid, hydrogenated egg yolk phospholipid, partially hydrogenated egg yolk phospholipid, and phospholipids such as hydroxylated lecithin; silicone Preferred examples of the polymeric surfactant include polyvinyl alcohol, sodium alginate, starch derivatives, tragacanth gum, acrylic acid / alkyl methacrylate copolymer; and various silicone surfactants.

  Polymers, thickeners and gelling agents include guar gum, locust bean gum, queens seed, carrageenan, galactan, arabic gum, tara gum, tamarind, far selelain, karaya gum, troarooi, cara gum, tragacanth gum, pectin, pectic acid and sodium Salt such as salt, salt such as alginic acid and sodium salt, mannan; starch such as rice, corn, potato, wheat; xanthan gum, dextran, succinoglucan, curdlan, hyaluronic acid and its salt, xanthan gum, pullulan, gellan gum, chitin , Chitosan, agar, gypsum extract, chondroitin sulfate, casein, collagen, gelatin, albumin; methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropi Cellulose, carboxymethylcellulose and its salts such as sodium, methylhydroxypropylcellulose, sodium cellulose sulfate, cellulose dialkyldimethylammonium sulfate, crystalline cellulose, cellulose powder such as cellulose powder; soluble starch, carboxymethyl starch, methylhydroxypropyl starch, Starch-based polymers such as methyl starch, starch derivatives such as hydroxypropyltrimonium chloride, octenyl succinate corn starch and aluminum; alginic acid derivatives such as sodium alginate and propylene glycol alginate; polyvinylpyridone (PVP), polyvinyl alcohol (PVA), Vinyl pydridone-vinyl alcohol copolymer, polyvinyl methyl ether Polyethylene glycol, polypropylene glycol, polyoxyethylene / polyoxypropylene copolymer; amphoteric methacrylic acid such as (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer, (acrylates / stearyl acrylate / ethylamine methacrylate oxide) copolymer, etc. Ester copolymer; (Dimethicone / vinyl dimethicone) crosspolymer, (alkyl acrylate / diacetone acrylamide) copolymer, (alkyl acrylate / diacetone acrylamide) copolymer AMP; Polyvinyl acetate partial saponification product, maleic acid copolymer; Vinylpyrrolidone / dialkylaminoalkyl methacrylate copolymer; acrylic resin alkanolamine; polyester, water-dispersible polyester; Kurylamide; Polyacrylic acid ester copolymer such as polyethyl acrylate, carboxyvinyl polymer, polyacrylic acid and its sodium salt, acrylic acid / methacrylic acid ester copolymer; acrylic acid / alkyl methacrylate Polymer: Cationized cellulose such as polyquaternium-10, diallyldimethylammonium chloride / acrylamide copolymer such as polyquaternium-7, acrylic acid / diallyldimethylammonium chloride copolymer such as polyquaternium-22, and acrylic acid such as polyquaternium-39・ Diallyldimethylammonium chloride / acrylamide copolymer, acrylic acid / cationized methacrylic acid ester copolymer, acrylic acid / cationized methacrylic acid amide copolymer, polyquaternium Acrylic acid / methyl acrylate / methacrylamidopropyltrimethylammonium chloride copolymer such as 47, methacrylic acid choline ester polymer; cationized polysaccharides such as cationized oligosaccharide, cationized dextran, guar hydroxypropyltrimonium chloride; Polyethyleneimine; Cationic polymer; Polymer of 2-methacryloyloxyethyl phosphorylcholine such as polyquaternium-51 and copolymer with butyl methacrylate copolymer; Acrylic resin emulsion, polyethyl acrylate emulsion, polyacrylalkyl ester emulsion, Polymer emulsions such as polyvinyl acetate resin emulsion, natural rubber latex, synthetic latex; nitrocellulose; polyurethanes and various copolymers; various silicones Various silicone-based copolymers such as acrylic-silicone graft copolymers; various fluoropolymers; 12-hydroxystearic acid and its salts; dextrin fatty acid esters such as dextrin palmitate and dextrin myristate; silicic anhydride, Smoke-like silica (ultrafine silicic anhydride), aluminum magnesium silicate, magnesium magnesium silicate, metal soap, dialkyl phosphate metal salt, bentonite, hectorite, organically modified clay mineral, sucrose fatty acid ester, fructooligosaccharide fatty acid ester It is mentioned as preferable.

  Solvents and propellants include ethanol, 2-propanol (isopropyl alcohol), butanol, isobutyl alcohol and other lower alcohols; propylene glycol, 1,3-butylene glycol, diethylene glycol, dipropylene glycol, isopentyl diol and other glycols Diethylene glycol monoethyl ether (ethoxydiglycol), ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, triethylene glycol monoethyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, propylene glycol monoethyl ether, dipropylene glycol monoethyl ether Glycol ethers such as ethylene glycol monoethyl ether Glycol ether esters such as acetate, diethylene glycol monoethyl ether acetate, propylene glycol monoethyl ether acetate; Glycol esters such as diethoxyethyl succinate, ethylene glycol disuccinate; benzyl alcohol, benzyloxyethanol, propylene carbonate, dialkyl carbonate , Acetone, ethyl acetate, N-methylpyrrolidone; toluene; fluorocarbon, next-generation flon; propellants such as LPG, dimethyl ether, carbon dioxide, and the like are preferable.

  Antioxidants include tocopherol derivatives such as tocopherol (vitamin E) and tocopherol acetate; BHT, BHA; gallic acid derivatives such as propyl gallate; vitamin C (ascorbic acid) and / or derivatives thereof; erythorbic acid and derivatives thereof; Preferred are sulfites such as sodium sulfite; bisulfites such as sodium bisulfite; thiosulfates such as sodium thiosulfate; metabisulfites; thiotaurine, hypotaurine; thioglycerol, thiourea, thioglycolic acid, cysteine hydrochloride As mentioned. Preferred examples of the reducing agent include thioglycolic acid, cysteine, cysteamine and the like. Preferred examples of the oxidizing agent include aqueous hydrogen peroxide, ammonium persulfate, sodium bromate, and percarbonate.

  Antibacterial agents or antiseptics include parabens (hydroxybenzoic acid esters) such as methylparaben, ethylparaben, propylparaben and butylparaben; phenoxyethanol; 1,2-pentanediol, 1,2-hexanediol, 1,2-octane 1,2-alkanediols such as diol; alkyl glyceryl ethers such as 2-ethylhexyl glyceryl ether (ethylhexyl glycerin); salicylic acid; sodium benzoate; isothiazoline derivatives such as methyl chloroisothiazolinone and methylisothiazolinone; Dehydroacetic acid and its salts; phenols; halogenated bisphenols such as triclosan, acid amides, quaternary ammonium salts; trichlorocarbanide, zinc pyrithione, benzoyl chloride Luconium, benzethonium chloride, sorbic acid, chlorhexidine, chlorhexidine gluconate, halocarban, hexachlorophene, hinokitiol; other phenols such as phenol, isopropylphenol, cresol, thymol, parachlorophenol, phenylphenol, sodium phenylphenol; phenylethyl alcohol , Photosensitizers, antibacterial zeolite, and silver ion are preferable, but when used as an antibacterial agent or antiseptic agent for antiseptic purposes, phenoxyethanol; 1 from the viewpoint of safety of cosmetics or skin external preparations; 1,2-alkanediols such as 1,2-pentanediol, 1,2-hexanediol, 1,2-octanediol; alkyl glyceres such as 2-ethylhexyl glyceryl ether It is more preferred to use ethers.

  Examples of chelating agents include edetate (ethylenediaminetetraacetate) such as EDTA, EDTA2Na, EDTA3Na, and EDTA4Na; hydroxyethylethylenediaminetriacetate such as HEDTA3Na; pentetate (diethylenetriaminepentaacetate); phytic acid; Phosphonic acid and its sodium salt; sodium oxalate; polypolyamino acids such as polyaspartic acid and polyglutamic acid; sodium polyphosphate, sodium metaphosphate, phosphoric acid; sodium citrate, citric acid, alanine, dihydroxyethylglycine Gluconic acid, ascorbic acid, succinic acid, and tartaric acid are preferable. pH adjusters / acids / alkalis include citric acid, sodium citrate, lactic acid, sodium lactate, glycolic acid, succinic acid, acetic acid, sodium acetate, malic acid, tartaric acid, fumaric acid, phosphoric acid, hydrochloric acid, sulfuric acid, monoethanol Amine, diethanolamine, triethanolamine, isopropanolamine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, arginine, hydroxylation Sodium, potassium hydroxide, aqueous ammonia, guanidine carbonate, and ammonium carbonate are preferable.

  Examples of powders include mica, talc, kaolin, sericite, montmorillonite, kaolinite, mica, muscovite, phlogopite, synthetic mica, red mica, biotite, permiculite, magnesium carbonate, calcium carbonate, aluminum silicate, silica Barium acid, calcium silicate, magnesium silicate, strontium silicate, metal tungstate, magnesium, zeolite, barium sulfate, calcined calcium sulfate, calcium phosphate, fluorine apatite, hydroxyapatite, ceramic powder, bentonite, smectite, clay, mud, Metal soap (e.g. zinc myristate, calcium palmitate, aluminum stearate), calcium carbonate, bengara, yellow iron oxide, black iron oxide, ultramarine, bitumen, carbon black, titanium oxide, fine particles and ultrafine Titanium oxide, zinc oxide, fine and ultrafine zinc oxide, alumina, silica, fumed silica (ultrafine silica), titanium mica, fish scale foil, boron nitride, photochromic pigment, synthetic fluorophlogopite, fine particle composite powder Body, gold, aluminum, etc., various sizes and shapes of inorganic powders, and these are treated with various surface treatment agents such as hydrogen silicone, cyclic hydrogen silicone, or other silane or titanium coupling agents Inorganic powders such as hydrophobized or hydrophilized powders; starch, cellulose, nylon powder, polyethylene powder, polymethyl methacrylate powder, polystyrene powder, copolymer resin powder of styrene and acrylic acid, polyester powder, Benzoguanamine resin powder, polyethylene terephthalate, polymethyl Organic powders and surface-treated powders of various sizes and shapes, such as methacrylate powder, polyethylene terephthalate / aluminum / epoxy powder, urethane powder, silicone powder, Teflon (registered trademark) powder, organic-inorganic composite powder Is preferable. Inorganic salts include sodium chloride-containing salts such as salt, common salt, rock salt, sea salt, natural salt; potassium chloride, aluminum chloride, calcium chloride, magnesium chloride, bittern, zinc chloride, ammonium chloride; sodium sulfate, aluminum sulfate, Aluminum sulfate / potassium sulfate (alum), aluminum sulfate / ammonium sulfate, barium sulfate, calcium sulfate, potassium sulfate, magnesium sulfate, zinc sulfate, iron sulfate, copper sulfate; sodium phosphates such as 1Na, 2Na and 3Na phosphates, phosphoric acid Potassium, calcium phosphates and magnesium phosphates are preferred.

  Examples of ultraviolet absorbers include paraaminobenzoic acid, paraaminobenzoic acid monoglycerin ester, N, N-dipropoxyparaaminobenzoic acid ethyl ester, N, N-diethoxyparaaminobenzoic acid ethyl ester, and N, N-dimethylparaaminobenzoic acid ethyl ester. Benzoic acid-based ultraviolet absorbers such as esters, N, N-dimethylparaaminobenzoic acid butyl ester, N, N-dimethylparaaminobenzoic acid ethyl ester; Anthranilic acid-based ultraviolet absorbers such as homomenthyl-N-acetylanthranilate; Salicylic acid And salicylic acid-based purple such as sodium salt, amyl salicylate, menthyl salicylate, homomenthyl salicylate, octyl salicylate, phenyl salicylate, benzyl salicylate, p-isopropanol phenyl salicylate Line absorber: Octyl cinnamate, ethyl-4-isopropyl cinnamate, methyl-2,5-diisopropyl cinnamate, ethyl-2,4-diisopropyl cinnamate, methyl-2,4-diisopropyl cinnamate, propyl-p- Methoxycinnamate, isopropyl-p-methoxycinnamate, isoamyl-p-methoxycinnamate, 2-ethylhexyl p-methoxycinnamate (octyl paramethoxycinnamate), 2-ethoxyethyl-p-methoxycinnamate (sinoxate), Cyclohexyl-p-methoxycinnamate, ethyl-α-cyano-β-phenylcinnamate, 2-ethylhexyl α-cyano-β-phenylcinnamate (octocrine), glyceryl mono-2-ethylhexanoyl-diparamethoxy Cinnamic acid-based UV absorbers such as namate, ferulic acid and derivatives thereof; 2,4-dihydroxybenzophenone, 2,2′-dihydroxy-4-methoxybenzophenone, 2,2′-dihydroxy-4,4′-dimethoxybenzophenone, 2,2 ′, 4,4′-tetrahydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone (oxybenzone-3), 2-hydroxy-4-methoxy-4′-methylbenzophenone, 2-hydroxy-4-methoxybenzophenone -5-sulfonate, 4-phenylbenzophenone, 2-ethylhexyl-4'-phenyl-benzophenone-2-carboxylate, 2-hydroxy-4-n-octoxybenzophenone, 4-hydroxy-3-carboxybenzophenone, etc. Benzophenone purple 3- (4'-methylbenzylidene) -d, l-camphor, 3-benzylidene-d, l-camphor; 2-phenyl-5-methylbenzoxazole; 2,2'-hydroxy-5 2- (2′-hydroxy-5′-t-octylphenyl) benzotriazole; 2- (2′-hydroxy-5′-methylphenylbenzotriazole; dibenzalazine; dianisoylmethane; 5- (3 , 3-dimethyl-2-norbornylidene) -3-pentan-2-one; dibenzoylmethane derivatives such as 4-t-butylmethoxydibenzoylmethane; octyl triazone; urocanic acid derivatives such as urocanic acid and ethyl urocanate; 2- (2′-hydroxy-5′-methylphenyl) benzotriazole, 1- ( , 4-dimethoxyphenyl) -4,4-dimethyl-1,3-pentanedione, dimethoxybenzylidenedioxoimidazolidinepropionate 2-ethylhexyl, etc., hydantoin derivatives, phenylbenzimidazolazosulfonic acid, terephthalylidene dicamphsulfone Preference is given to acids, drometrizole trisiloxane, methyl anthranilate, rutin and its derivatives, oryzanol and its derivatives.

  Vitamins and their derivatives include vitamin A such as retinol, retinol acetate, retinol palmitate; thiamine hydrochloride, thiamine sulfate, riboflavin, riboflavin acetate, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine dipalmitate, Flavin adenine dinucleotide, cyanocobalamin, folic acid, nicotinic acid such as nicotinic acid amide / benzyl nicotinate, vitamin B group such as choline; vitamin C such as ascorbic acid and its sodium salt; vitamin D; α, Vitamin Es such as β, γ, δ-tocopherol; other vitamins such as pantothenic acid and biotin; ascorbic acid phosphates such as ascorbic acid phosphate sodium salt and ascorbic acid phosphate magnesium salt; Ascorbic acid fatty acid esters such as corobic acid tetraisopalmitic acid ester, ascorbyl stearate, ascorbyl palmitate and ascorbyl dipalmitate, ascorbic acid alkyl ether such as ascorbic acid ethyl ether, ascorbic acid glucoside such as ascorbic acid-2-glucoside and Ascorbic acid derivatives such as fatty acid esters and tocopheryl phosphate ascorbyl; vitamin derivatives such as tocopherol nicotinate, tocopherol acetate, tocopherol acetate, tocopherol linoleate, tocopherol phosphate, tocopherol phosphate etc., tocotrienol, and other various vitamin derivatives Is preferable.

  Anti-inflammatory and anti-inflammatory agents include glycyrrhizic acid and its derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, guaiazulene, allantoin, indomethacin, zinc oxide, hydrocortisone acetate, prednisone, diphedramine hydrochloride, chlorpheniramine maleate; peach leaf extract A plant extract such as a koji leaf extract is preferable. Plant growth and tinctures such as assembly extract, red pepper tincture, ginger tincture, ginger extract, cantalis tincture; capsaicin, nonyl acid valenylamide, gingeron, ictamol, tannic acid Borneol, cyclandelate, cinnarizine, trazoline, acetylcholine, verapamil, cephalanthin, γ-oryzanol, cephalanthin, vitamin E and nicotinic acid tocopherol, acetic acid tocopherol and other derivatives, γ-oryzanol, nicotinic acid, nicotinic acid amide, nicotinic acid benzyl Derivatives such as ester, inositol hexanicotinate, nicotine alcohol, allantoin, photosensitizer 301, photosensitizer 401, capronium chloride, pentadecanoic acid monoglyceride, Preferable examples include flavonol derivatives, stigmasterol or stigmasteranol, its glycosides, and minoxidil. Preferred hormones include estradiol, estrone, ethinyl estradiol, cortisone, hydrocortisone, prednisone and the like. Other remedies such as anti-wrinkle agents, anti-aging agents, squeeze agents, cooling sensations, warming sensation agents, wound healing promoters, irritation relievers, analgesics, cell activators include retinols, retinoic acids, retinoin Acid tocopheryl; derivatives such as lactic acid, glycolic acid, gluconic acid, fruit acid, salicylic acid and glycosides / esterified products thereof, α- or such as hydroxycapric acid, long chain α-hydroxy fatty acid, long chain α-hydroxy fatty acid cholesteryl β-hydroxy acids and derivatives thereof; γ-aminobutyric acid, γ-amino-β-hydroxybutyric acid; carnitine; carnosine; creatine; ceramides, sphingosines; caffeine, xanthine and the like; and coenzyme Q10, carotene, lycopene , Astaxanthin, lutein, α-lipoic acid, platinum nanocolloid, fullerenes, etc. Antioxidant / active oxygen scavengers; catechins; flavones such as quercetin; isoflavones; gallic acid and ester sugar derivatives; polyphenols such as tannin, sesamin, protoanthocyanidin, chlorogenic acid, apple polyphenol; rutin and glycosides, etc. Derivatives of hesperidin and glycosides; lignan glycosides; licorice extract-related substances such as grabrizine, glabrene, liquiritin, and isoliquiritin; lactoferrin; shogaol, gingerol; fragrance substances such as menthol, camphor, cedrol, and derivatives thereof Preferred examples include capsaicin, vanillin and the like and derivatives; insect repellents such as diethyltoluamide; and complexes of physiologically active substances and cyclodextrins.

  As plant / animal / microbe extracts, Iris extract, Ashitaba extract, Asunaro extract, Asparagus extract, Avocado extract, Achacha extract, Almond extract, Altea extract, Arnica extract, Aloe extract, Apricot extract, Ginkgo biloba extract, Ginkgo biloba extract , Incheon extract, Fennel extract, Turmeric extract, Oolong tea extract, Peony extract, Ages extract, Echinacea leaf extract, Enmeo extract, Ogon extract, Oat extract, Auren extract, Barley extract, Panax ginseng extract, Hypericum extract, Odori extract , Dutch mustard extract, orange extract, dried sea water, seaweed extract, oyster leaf extract, oyster extract, hydrolyzed elastin, hydrolyzed wheat powder, hydrolysis Luc, Cascon extract, Chamomile extract, Oil-soluble chamomile extract, Carrot extract, Kawara mugi extract, Oat extract, Calcade extract, Licorice extract, Oil-soluble Licorice extract, Kiwi extract, Kiou extract, Cyprid extract, Quina extract, Cucumber extract, Kiri leaf extract, Guanosine, guava extract, cucumber extract, gardenia extract, kumazasa extract, clara extract, walnut extract, chestnut extract, grapefruit extract, clematis extract, black rice extract, brown sugar extract, black vinegar, chlorella extract, mulberry extract, gentian extract, Gentian pepper extract, tea Extract, yeast extract, kokuboku extract, coffee extract, burdock extract, rice extract, rice fermented extract, rice bran fermented extract, rice germ oil, comfrey extract, Lagen, Cowberry extract, Saishin extract, Psycho extract, Saitai extract, Saffron extract, Salvia extract, Salmon extract, Sasa extract, Hawthorn extract, Sansha extract, Salamander extract, Shiitake extract, Giant extract, Shikon extract, Perilla extract, Linden extract, Shimosukeso Extract, jatoba extract, peonies extract, ginger cucumber extract, ginger root extract, white birch extract, white jellyfish extract, horsetail extract, stevia extract, stevia fermented product, west river willow extract, horse chestnut extract, hawthorn extract, elderberry extract, yarrow extract , Mint extract, sage extract, mallow extract, nematode extract, essence extract, Sakuhakuhi extract, Diou extract, Dai Extract, peanut extract, thyme extract, dandelion extract, lichen extract, tea extract, clove extract, chigaya extract, chimpi extract, tea tree oil, tea tea extract, red pepper extract, red snapper extract, red snapper extract, red spruce extract, red spruce extract, tomato Extract, natto extract, carrot extract, garlic extract, wild rose extract, hibiscus extract, bacmond extract, lotus extract, parsley extract, birch extract, honey, hamamelis extract, parietalia extract, hyacinth extract, bisabolol, cypress extract, bifidobacteria extract, Loquat extract, dandelion extract, burdock extract, bukkuri extract, butcher bloom extract, grape extract, grape seed extract, propolis, loofah extract, Safflower extract, peppermint extract, body extract, button extract, hop extract, squid extract, pine extract, maroonnier extract, mizubasho extract, mukuroji extract, melissa extract, mozuku extract, peach extract, cornflower extract, eucalyptus extract, yukinoshita extract, yuzu extract, lily extract, Yokuinin extract, mugwort extract, lavender extract, green tea extract, eggshell membrane extract, apple extract, rooibos tea extract, litchi extract, lettuce extract, lemon extract, forsythia extract, forsythia extract, rose extract, rosemary extract, roman chamomile extract, royal jelly Extracts such as an extract and a bitumen extract are preferred.

  Examples of the antipruritic agent include diphenhydramine hydrochloride, chlorpheniramine maleate, camphor, substance-P inhibitor, and the like. Examples of the exfoliating / dissolving agent include salicylic acid, sulfur, resorcin, selenium sulfide, pyridoxine and the like. Examples of the antiperspirant include chlorohydroxyaluminum, aluminum chloride, zinc oxide, and zinc paraphenol sulfonate. Examples of the refreshing agent include menthol and methyl salicylate. Examples of the astringent include citric acid, tartaric acid, lactic acid, aluminum sulfate / potassium sulfate, and tannic acid. Examples of enzymes include superoxide dismutase, catalase, lysozyme chloride, lipase, papain, pancreatin, protease, and the like. Preferred nucleic acids include ribonucleic acid and salts thereof, deoxyribonucleic acid and salts thereof, and adenosine triphosphate disodium.

  As perfumes, acetyl cedrene, amylcinnamaldehyde, allyl amyl glycolate, β-ionone, iso-Esuper, isobutyl quinoline, Iris oil, Iron, indole, ylang ylang oil, undecanal, undecenal, γ-undecalactone, Estragole, eugenol, oak moss, opoponax resinoid, orange oil, eugenol, auranthiol, galac solid, carvacrol, L-carvone, camphor, cannon, carrot seed oil, clove oil, methyl cinnamate, geraniol, geranyl nitrile , Isobornyl acetate, geranyl acetate, dimethylbenzyl carvinyl acetate, styrylyl acetate, cedolyl acetate, terpinel acetate, pt-butylcyclohexyl acetate, vetiberyl acetate, benzyl acetate, vinegar Linalyl, isopentyl salicylate, benzyl salicylate, sandalwood oil, santalol, cyclamenaldehyde, cyclopentadecanolide, methyl dihydrojasmonate, dihydromilsenol, jasmine absolute, jasmine lactone, cis-jasmon, citral, citronenol, citronellal, Cinnamon bark oil, 1,8-cineole, cinnamaldehyde, stylax resinoid, cedarwood oil, cedrene, cedrol, celery seed oil, thyme oil, damascon, damassenone, thymol, tuberose absolute, decanal, decalactone, terpineol, γ-terpinene, Tripral, Nellore, Nonanal, 2,6-Nonadienol, Nonalactone, Patchouli alcohol, Vanilla absolute , Vanillin, basil oil, patchouli oil, hydroxycitronellal, α-pinene, piperitone, phenethyl alcohol, phenylacetaldehyde, petitglen oil, hexylcinnamaldehyde, cis-3-hexenol, peruvian valsum, vetiver oil, vetiverol, peppermint oil, Pepper oil, heliotropin, bergamot oil, benzyl benzoate, borneol, milresinoid, musk ketone, methylnonylacetaldehyde, γ-methylyonone, menthol, L-menthol, L-menthol, eucalyptus oil, β-yonone, lime oil, lavender oil, Synthetic and natural fragrances such as D-limonene, linalool, rilal, rireal, lemon oil, rose absolute, rose oxide, rose oil, rosemary oil, various essential oils, and various blended fragrances It is mentioned as preferred.

  As pigments / colorants / dyes / pigments, brown 201, black 401, purple 201, purple 401, blue 1, blue 2, blue 201, blue 202, blue 203, blue 204 , Blue 205, Blue 403, Blue 404, Green 3, Green 201, Green 202, Green 204, Green 205, Green 3, Green 401, Green 402, Red 102, Red 104-1, red 105-1, red 106, red 2, red 3, red 201, red 202, red 203, red 204, red 205, red 206, red 207 , Red 208, Red 213, Red 214, Red 215, Red 218, Red 219, Red 220, Red 221, Red 223, Red 225, Red 226, Red 227, Red 28, red 230-1, red 230-2, red 231, red 232, red 3, red 401, red 404, red 405, red 501, red 502, red 503 Red 504, red 505, red 506, orange 201, orange 203, orange 204, orange 205, orange 206, orange 207, orange 401, orange 402, orange 403, yellow 201, yellow 202-1, yellow 202-2, yellow 203, yellow 204, yellow 204, yellow 205, yellow 4, yellow 401, yellow 402, yellow 403-1, yellow 404, yellow 405, Yellow 406, Yellow 407, Yellow 5 and other legal dyes; Acid Red 14 and other acidic dyes; Arianor Sienna Brown, Arianor Madder Red, Arianor Steel Blue, Arianor Straw Yellow and other basic dyes; HC Yellow 2 Nitro dyes such as HC Yellow 5, HC Red 3, 4-hydoxypropylamino-3-nitrophenol, N, N'-bis (2-hydroxyethyl) -2-nitro-p-phenylenediamine, HC Blue 2, Basic Blue 26, etc. Dyes; inorganic white pigments such as titanium dioxide and zinc oxide; inorganic red pigments such as iron oxide (Bengara) and iron titanate; inorganic brown pigments such as γ-iron oxide; inorganic yellow pigments such as yellow iron oxide and loess Pigments; inorganic black pigments such as black iron oxide and low-order titanium oxide; inorganic purple pigments such as mango violet and cobalt violet; inorganic green pigments such as chromium oxide, chromium hydroxide and cobalt titanate; ultramarine and bitumen Inorganic blue pigments: Titanium oxide coated mica, titanium oxide coated bismuth oxychloride, titanium oxide coated talc, colored titanium oxide coated mica, bismuth oxychloride, fish scale foil, pearl pigments; aluminum powder, Metal powder pigments such as perpowder and gold; anthraquinones such as astaxanthin and alizarin; anthocyanidins, β-carotene, catenal, capsanthin, chalcone, calsamine, quercetin, crocin, chlorophyll, curcumin, naphthoquinones such as cochineal, shikonin, bixin, Natural pigments and dyes such as flavones, betacyanidine, henna, hemoglobin, lycopene, riboflavin, rutin; p-phenylenediamine, toluene-2,5-diamine, o-, m-, or p-aminophenol, m-phenylene Oxidative dye intermediates and couplers such as diamine, 5-amino-2-methylphenol, resorcin, 1-naphthol, 2,6-diaminopyridine, and salts thereof; auto-oxidizing dyes such as indoline; dihydroxyacetone is preferred And the like as correct ones.

  Preferred examples of water include normal water, purified water, hard water, soft water, natural water, deep sea water, electrolytic alkaline ionized water, electrolytic acidic ionized water, ionic water, and clustered water.

  In addition to these, cosmetic raw material standards, blending ingredient standard by cosmetic varieties, Japan Cosmetic Industry Association ingredient display name list, INCI dictionary (The International Cosmetic Ingredient Dictionary and Handbook), quasi-drug raw material standards, Japanese pharmacopoeia, pharmaceutical additives Ingredients listed in standards, official food additives, etc., and Japanese and foreign patent publications and patent publications (including publications and republications) in which the international patent classification IPC belongs to the classification of A61K7 and A61K8 It is possible to contain known cosmetic ingredients, pharmaceutical ingredients, food ingredients, etc., such as the ingredients described, in known combinations, blending ratios and blending amounts.

  As the types of the detergent composition of the present invention, for hair, oil shampoo, cream shampoo, conditioning shampoo, dandruff shampoo, hair color shampoo, shampoo with integrated rinse, etc .; rinse, treatment, hair pack, Conditioners such as hair mists; For skin, cleansing foams, cleansing creams, cleansing milks, cleansing lotions, cleansing gels, cleansing oils, cleansing masks, washing powders, facial cleansing powders; cosmetic soaps, transparent soaps, medicated soaps, liquids Soaps such as soaps, shaving soaps and synthetic cosmetic soaps; body cleansing agents such as body shampoos are preferred.

  Examples of the dosage form of the cleaning composition of the present invention include emulsified cosmetics such as an oil-in-water (O / W) type, a water-in-oil (W / O) type, a W / O / W type, and an O / W / O type. , Oily cosmetics, solid cosmetics, liquid cosmetics, kneaded cosmetics, stick cosmetics, volatile oil cosmetics, powder cosmetics, jelly cosmetics, gel cosmetics, paste cosmetics Examples of preferable dosage forms include emulsion polymer cosmetics, sheet cosmetics, mist cosmetics, and spray cosmetics.

  The following examples further illustrate the present invention in detail but are not to be construed to limit the scope thereof.

Synthesis Example 1 Synthesis of diisostearyl malate of the present invention From DL-malic acid 220 g (1.64 mol), a by-product during the production of dimer acid in a 3 L reactor equipped with a stirrer, thermometer and gas introduction tube 889 g of isostearyl alcohol to be induced (3.28 mol, manufactured by RADIANOL 1980 Oreon Co., Ltd.) and 231 g of heptane as a solvent were charged, heated to 100 ° C. to 120 ° C. while blowing nitrogen, and refluxed for 6 hours. After completion of the reaction, the unreacted carboxylic acid was washed away with an aqueous sodium hydroxide solution, and the organic layer was concentrated. Obtained as a liquid oil.

Comparative Synthesis Example 1 Conventional Synthesis of Diisostearyl Malate As isostearyl alcohol, 5,7,7-trimethyl-2- (1,3,3-trimethylbutyl) -octan-1-ol (Fine oxocol 180, Synthesis was performed in the same manner as in Synthesis Example 1 except that Nissan Chemical Industries, Ltd. was used, and 1018 g (yield 97%) of the target diisostearyl malate was obtained as an almost colorless viscous liquid oil.

<Physical property evaluation>
About the diisostearyl malate of the present invention obtained in Synthesis Example 1, the conventional diisostearyl malate obtained in Comparative Synthesis Example 1, and the commercial products A to D of diisostearyl malate, the acid value, The saponification value, hydroxyl value, refractive index, viscosity, and water content were measured. The results are shown in Table 1. The refractive index was measured at 20 ° C. using a refractometer (Model 3, manufactured by ATAGO). The viscosity was measured at 25 ° C. using a Brookfield viscometer (TVB-10, manufactured by Toki Sangyo Co., Ltd.). The water content was measured according to the method for measuring the water content of lanolin in the British Pharmacopoeia (BP).

<Evaluation of feeling of use>
Regarding the diisostearyl malate of the present invention obtained in Synthesis Example 1, the conventional diisostearyl malate obtained in Comparative Synthesis Example 1, and commercial products A to D of diisostearyl malate, the feeling of use evaluated. The evaluation was based on the sensory sensation of seven panelists, and the following three evaluation criteria were evaluated: smoothness when applied to the skin, stickiness, and familiarity with the skin. The results are shown in Table 1.

Smoothness ◎: Very smooth ○: Smooth △: Slightly not smooth ×: Not smooth at all

Stickiness ◎: Very little stickiness ○: Less stickiness △: Slightly sticky ×: Very sticky

Familiarity to skin ◎: Very familiar F: Good familiar △: Somewhat familiar ×: Not familiar at all

  From the results shown in Table 1, the diisostearyl malate of the present invention has a low viscosity compared to the conventional diisostearyl malate, and the feeling of use such as smoothness, stickiness and familiarity with the skin was very excellent. . Moreover, since the moisture content was very high compared with the conventional diisostearyl malate, it turned out that it is very useful for provision of moisture retention. Furthermore, since the refractive index was high compared with the conventional diisostearyl malate, it turned out that it is useful for provision of glossiness.

Formulation in Transparent Formulation In the composition shown in Table 2, diisostearyl malate of the present invention obtained in Synthesis Example 1, conventional diisostearyl malate obtained in Comparative Synthesis Example 1, tri as a control A detergent containing diglyceryl isostearate was prepared. The appearance of the obtained cleaning agent at the initial stage and after storage at 5 ° C./2 weeks was visually observed, and the transparency was evaluated according to the following evaluation criteria. The results are shown in Table 2.

○: Transparency △: Slightly cloudy ×: Cloudy

  From the results shown in Table 2, it was considered that the diisostearyl malate of the present invention was more easily solubilized by a surfactant than the conventional diisostearyl malate and could be easily blended into a transparent formulation. . Moreover, it turned out that the thing (Examples 2 and 3) which mix | blended the nonionic surfactant was excellent in transparency rather than the thing (Example 1) which a nonionic surfactant is unblended. .

Evaluation of hair shampoo Hair shampoos having the compositions shown in Table 3 and blended with diisostearyl malate of the present invention obtained in Synthesis Example 1 were prepared (Examples 4 and 5). For comparison, a hair shampoo (Comparative Examples 7 to 9) containing conventional malic acid diester, dimethicone or squalane and a hair shampoo containing no oil agent (Comparative Example 10) were prepared, and transparency, usability, and cuticle The peeling suppression effect was evaluated. Transparency was evaluated by the following evaluation criteria by visually observing the appearance at the initial stage and after storage at 5 ° C./2 weeks. The feeling of use and the effect of inhibiting cuticle peeling were performed by the following methods. The obtained results are also shown in Table 3.

○: Transparency △: Slightly cloudy ×: Cloudy

<Usage evaluation method>
A healthy black-haired human hair was bleached once with a two-component bleaching agent to produce 5 g of damaged hair bundle. Sensory evaluation was performed about the foaming property and foam quality at the time of washing | cleaning at the time of wash | cleaning the produced hair | bristle bundle with each hair shampoo, the finger feeling at the time of rinsing, and the moist feeling after drying. The evaluation points were the following five levels, and the results were shown as an average of five panelists.

5 points: Very good 4 points: Good 3 points: Neither 2 points: Slightly bad 1 point: Bad

<Cuticle peeling inhibition evaluation method>
Healthy black-haired human hair was bleached twice with a two-part bleaching agent and once with a permanent treatment agent to produce a damaged hair bundle 5 g. The process of applying and washing 0.5 g of each hair shampoo of Example 4, Example 5 or Comparative Example 10 to 5 g of this hair bundle was repeated 7 times. After one hair was taken out from the hair bundle thus obtained and loosely knotted, the hair surface was observed with a scanning electron microscope (JSM-IT100 InTouchScope) at a magnification of about 500 times. The cuticle peeling inhibitory effect was evaluated from the obtained images according to the following evaluation criteria.

◯: Cuticle peeling improved compared to before treatment Δ: Cuticle peeling slightly improved compared to before treatment ×: Cuticle peeled no difference compared to before treatment

From the results of Table 3, the shampoo containing the diisostearyl malate of the present invention was superior in transparency as compared to the shampoo containing the comparative oil agent. In addition, foaming properties and foam quality are also superior to the comparative oil agent, and are equivalent to the absence of oil agent, and it is found that diisostearyl malate of the present invention does not inhibit the foaming property and foam quality of the surfactant. It was. The combing at the time of washing and after drying was also superior to conventional diisostearyl malate and squalane and almost the same as dimethicone. The moist feeling after drying was superior to that of dimethicone. Further, it was found that foaming properties and combing effects were further improved by adding isostearic acid. Moreover, it turned out that the diisostearyl malate of this invention is excellent in the peeling inhibitory effect of a cuticle.

Hair Treatment Evaluation A hair treatment was prepared by blending the diisostearyl malate of the present invention obtained in Synthesis Example 1 with the composition shown in Table 4 (Example 6). For comparison, a conventional hair treatment containing a malic acid diester (Comparative Example 11) and a hair treatment containing no oil agent (Comparative Example 12) were prepared. Evaluated. Evaluation was performed in the same manner as hair shampoo evaluation, and the results are shown in Table 4.

  From the results shown in Table 4, the diisostearyl malate of the present invention was superior in finger feeling and moist feeling after drying and superior in the effect of inhibiting cuticle peeling, as compared with conventional diisostearyl malate.

Body Shampoo Evaluation A body shampoo having the composition shown in Table 5 and blended with diisostearyl malate of the present invention obtained in Synthesis Example 1 was prepared (Example 7). For comparison, a conventional body shampoo formulated with malic acid diester (Comparative Example 13) and a body shampoo containing no oil agent (Comparative Example 14) were prepared. The amount of foam when foaming, the fineness of foam, The smoothness and moist feeling after towel drying were evaluated. The evaluation was performed as follows, and the results are shown in Table 5.

<The amount of foam>
30 g of each body shampoo was put into a commercially available cooking mixer and stirred for 1 minute, and the foam formed in the mixer was transferred to a graduated cylinder, and the amount of foam was measured. The evaluation results are shown in the following three stages.

○: The amount of foam is 1.5 times or more higher than that of the non-formation product. △: The amount of foam is 1.2 times or more larger than that of the no-configuration product.

<Fine fineness>
Each body shampoo was filled into a 100 mesh container with a pump dispenser and pushed to fill the petri dish with foam. The foam was observed from the top surface with a microscope at a magnification of 50 times, and the fineness of the foam was evaluated in the following three stages.

○: Foam is finer than that of the unblended product △: Foam is slightly finer than that of the unblended product ×: No change from the unblended product

<Smoothness when rinsing>
Put each body shampoo into a container with a 100 mesh pump dispenser, take 5 pushes into the palm, rub your palm so that both palms reciprocate together, reciprocate both hands 10 times, and then wash with 38 ° C hot water The smoothness of the skin was evaluated according to the following three levels.

○: Smooth feeling compared to unblended product △: Slightly smooth feel compared to unblended product ×: No change from unblended product

<Moist feeling after towel drying>
After the above smoothness evaluation, the moist feeling of the skin after towel drying was evaluated in the following three stages.

○: The skin is moist compared to the non-mixed product △: The skin is moist a little compared to the non-mixed product ×: No change from the non-mixed product

  From the results of Table 5, the diisostearyl malate of the present invention is superior in foam amount and foam quality compared to conventional diisostearyl malate, and is also excellent in smoothness during washing and moist feeling after drying. It was a thing.

Example 7 Facial Cleansing Foam This facial cleansing foam had good foaming and was able to provide effects such as providing a smooth and smooth feel to the skin.
Component Blending amount (% by weight)
----------------------------------
Part A Oleic acid K 10.0
Palmitic acid K 10.0
Lauric acid K 4.0
Lauroyl aspartate Na 3.5
Cocoyl Glycine K 3.5
Diester of Synthesis Example 1 0.5
Isostearic acid 0.2
PEG 1500 10.0
Glycerin 15.0
Glyceryl monostearate1.0
Plandool-LG2 (Nippon Seika) 0.3
Part B Tremoist-SL (Nippon Seika) 1.0
Betaine 1.0
Trehalose 0.5
Polyquaternium-7 0.5
Polyquaternium-39 0.5
Methylparaben 0.15
Purified water Total amount of 100 ----------------------------------
(Preparation method)
Part A was weighed and dissolved by heating to about 80 ° C. Part B was weighed and heated to about 80 ° C. B was gradually added to A with stirring, and the mixture was cooled to 40 ° C. after mixing.

Example 8 Facial Cleansing Foam This facial cleansing foam had fine foam, good foaming, rinsed from the time of washing, and maintained a moist feel until washing up.
Component Blending amount (% by weight)
--------------------------------
Part A Diester of Synthesis Example 1 0.1
(Coconut fatty acid / hydrogenated beef tallow fatty acid) glutamic acid Na 30.0
Cocoyl Glycine K 5.0
LUSPLAN PI-DA (Nippon Seika) 0.2
Lauric acid diethanolamide 3.0
Distearate glycol 0.5
Tocopherol 0.1
Cholesterol 0.1
PEG-8 5.0
PEG-32 10.0
Glycerin 14.0
Propylparaben 0.1
Part B Methylparaben 0.2
Polyquaternium-51 1.0
Tremoist-SL (Nippon Seika) 0.5
Crystalline cellulose 0.3
Polyquaternium-7 0.8
Purified water Total amount of 100 --------------------------------
(Preparation method)
Part A was weighed and dissolved by heating to about 80 ° C. Part B is weighed and heated to about 80 ° C. B was gradually added to A with stirring, and the mixture was cooled to 40 ° C. after mixing.

Example 9 Body Shampoo This body shampoo was foamy, washed well and moistened, and the skin was soft.
Component Blending amount (% by weight)
--------------------------------
Diester of Synthesis Example 1 0.25
Cocoyl Methyl Taurine Na 10.0
Lauroyl hydrolyzed silk Na 6.0
Lauroylmethylalanine Na 10.0
Cocoamphoacetate Na (30%) 4.0
Cocamidopropyl betaine (30%) 10.0
Olefin (C14-16) sulfonic acid Na 5.0
Dilauroyl glutamate lysine Na 0.05
Polyquaternium-10 1.3
Guar hydroxypropyltrimonium chloride 0.8
Acetyl hyaluronic acid Na 0.02
Cocamide DEA 3.0
Glycerin 5.0
Methylparaben 0.2
Purified water Total amount of 100 --------------------------------
(Preparation method)
All components were heated at about 80 ° C. and stirred and mixed uniformly.

Example 10 Body Shampoo This body shampoo was foamy, and the addition of the diester of Synthesis Example 1 and oleic acid moistened the skin and gave the skin a soft feeling.
Component Blending amount (% by weight)
--------------------------------
Diester of Synthesis Example 1 0.5
Plandool-LG2 (Nippon Seika) 0.1
Potash soap base solution 25.0
Cocoyl Methyl Taurine Na 6.0
Cocamidomethyl MEA 5.0
Dilauroyl glutamate lysine Na 0.05
Polyquaternium-10 1.3
Guar hydroxypropyltrimonium chloride 0.8
Hydroxypropyltrimonium hyaluronate 0.05
Acetyl hyaluronic acid Na 0.02
Oleic acid 0.1
Arginine 0.1
Glycerin 5.0
Hydrolyzed hydrogenated starch 0.3
Glucosyl trehalose 0.3
EDTA-2Na 0.05
Benzoic acid Na 0.1
Methylparaben 0.2
Purified water Total amount of 100 --------------------------------
(Preparation method)
All components were heated at about 80 ° C. and stirred and mixed uniformly.

Example 11 Hand Soap This hand soap had good foaming, moistened after washing, and provided a soft feeling of the skin.
Component Blending amount (% by weight)
-------------------------------
Part A Cocoyl Isethionate Na 1.0
Glycerin 30.0
Diester of Synthesis Example 1 0.5
Part B benzalkonium chloride 0.05
Lauroyl sarcosine salt 12.0
Myristoyl methyl taurine sodium 2.0
Polyglyceryl laurate-6 2.0
Palm oil fatty acid diethanolamide 2.0
PEG-7 palm oil fatty acid glyceryl 2.0
Synthetic latex 0.1
Risinoleic acid 0.1
Arginine 0.1
Nitrocellulose 0.1
Sorbitol 8.0
Hydrolyzed conchiolin 0.1
1,3-butylene glycol 8.0
Phenoxyethanol 0.8
Purified water Total amount of 100 --------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved. Part B was added to part A, heated to about 80 ° C. and uniformly dissolved, and then cooled.

Example 12 Non-silicone shampoo This shampoo was foamy, excellent in fingering after washing and after drying, moist hair, and capable of damage care.
Component Blending amount (% by weight)
--------------------------------
Diester of Synthesis Example 1 0.5
Plandool-LG2 (Nihon Seika) 0.03
Neosolute-AquaS (Nippon Seika) 0.1
Tremoist-SL (Nippon Seika) 0.5
Laureth-4 carboxylic acid Na (28%) 10.0
Laureth-6 carboxylic acid 4.0
Cocamidopropyl betaine (30%) 10.0
Lauroylmethylalanine Na (30%) 5.0
Isostearic acid 0.3
Cocamidomethyl MEA 3.0
Hydroxyl Na 1% solution 0.5
Polyquaternium-10 0.8
Distearate glycol 0.5
Polyquaternium-7 0.5
Benzoic acid Na 0.3
EDTA-2Na 0.05
Phenoxyethanol 0.4
Purified water Total amount of 100 --------------------------------
(Preparation method)
All components were heated at about 80 ° C. and stirred and mixed uniformly.

Example 13 Dandruff Shampoo This shampoo was a shampoo capable of suppressing dandruff, imparting a moist feeling and gloss to hair without using silicone, and providing a smooth finger passage.
Component Blending amount (% by weight)
-----------------------------------
Part A Diester of Synthesis Example 1 0.5
Lauroylmethylalanine Na (30%) 13.0
Cocamidopropyl betaine (30%) 20.0
Cocoa glutamic acid TEA (30%) 5.0
Cocamide DEA 1.0
Glycerin 1.0
Glyceryl caprylate 0.4
Glyceryl undecylenate 0.1
Neosolute-AquaS (Nippon Seika) 1.0
Sorbitol 1.6
Miconazole nitrate 0.75
Polyquaternium-7 0.3
Part B: Benzoic acid Na 0.4
Na chloride 0.2
Purified water Total amount of 100 parts C assembly extract 3.0
Polyquaternium-10 0.2
Guar hydroxypropyltrimonium chloride 0.1
Polyquaternium-47 0.1
Isopropyl methylphenol 0.1
Piroctone olamine 0.1
Purified water 9.3
-----------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 14 Shampoo This shampoo is excellent in foaming, and by adding the diester of Synthesis Example 1 and isostearic acid, it is easy to touch without using silicone, and can give a feeling of use that is refreshing and smooth. there were.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 0.2
Isostearic acid 0.2
Diethylhexyl sebacate (Nippon Seika) 1.0
Plandool-LG2 (Nippon Seika) 0.3
Elcalactone DES (Nippon Seika) 0.3
Part B ammonium laureth sulfate 5.0
Laureth sulfate Na (25%) 10.0
Lauryl hydroxysultain (30%) 10.0
Distearate glycol 0.5
Toluenesulfonic acid 0.3
Stearoxypropyldimethylamine 0.5
Neopentyl glycol diethylhexanoate 0.4
Isodecyl glyceryl ether 0.4
Cocamidomethyl MEA 1.0
Myristyl alcohol 0.7
Laureth-4 0.3
Laureth-16 0.2
Phenoxyethanol 0.3
Part C Methylparaben 0.2
Arginine 0.5
Benzoic acid Na 0.3
Purified water Total amount of 100 parts D Polyquaternium-10 0.2
Guar hydroxypropyltrimonium chloride 0.1
Tremoist-SL (Nippon Seika) 3.0
Purified water 6.7
---------------------------------
(Preparation method)
Part A and B, which had been mixed and dissolved in advance, were uniformly mixed at about 80 ° C. (part E). The part C set aside was heated to about 60 ° C. and made uniform. C. Part C was gradually added to part E with stirring and mixed uniformly, and then cooled to about 50.degree. Furthermore, D part was added and mixed uniformly. .

Example 15 Shampoo This shampoo was excellent in foaming, good in fingering, and was able to give a refreshing finish and a smooth feeling of use.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 1.0
Isostearic acid 0.3
PPG-3 caprylyl ether 1.0
Neopentyl glycol diheptanoate 1.0
Plandool-ISS (Nihon Seika) 0.3
Ceramide 2 0.001
Ceramide 5 0.004
Part B Cocoyl Sarcosine Na 3.0
Laureth sulfate Na (27%) 9.0
Lauryl hydroxysulfobetaine (30%) 7.0
Cocamide DEA 1.5
Polyquaternium-61 0.5
Distearate glycol 0.5
Polyglyceryl oleate-10 0.2
PEG-150 stearate 1.0
DPG 2.0
Phenoxyethanol 0.6
Part C EDTA-2Na 0.05
PPG-2 arginine 0.5
Methylparaben 0.15
Benzoic acid Na 0.3
Purified water Total amount of 100 parts D Polyquaternium-10 0.5
Polyquaternium-7 0.2
Arginine 0.3
Purified water 9.0
---------------------------------
(Preparation method)
Part A and B, which had been mixed and dissolved in advance, were uniformly mixed at about 80 ° C. (part E). The part C set aside was heated to about 60 ° C. and made uniform. C. Part C was gradually added to part E with stirring and mixed uniformly, and then cooled to about 50.degree. Furthermore, D part was added and mixed uniformly.

Example 16 Shampoo This shampoo was excellent in foaming, was easy to pass through without using silicone, and was able to give a moist wash and a smooth feeling of use.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 0.3
Polyricinoleic acid 0.3
Neosolute-MP (Nippon Seika) 0.3
Neosolute-DE (Nippon Seika) 0.2
Lauroyl sarcosine TEA (30%) 3.0
Cocoa glutamic acid TEA (30%) 8.0
Laureth sulfate Na (27%) 10.0
Palm nuclear fatty acid amidopropyl betaine (30%) 5.0
Cocamidomethyl MEA 1.0
Palm oil fatty acid PEG-7 glyceryl 0.3
Ascorbyl tetrahexyl decanoate 0.5
Lauric acid PEG-2 1.3
Cocoyl Arginine Ethyl PCA 0.1
Phenoxyethanol 0.3
Part B EDTA-2Na 0.05
Methylparaben 0.2
Benzoic acid Na 0.3
Purified water Total amount of 100 parts C Polyquaternium-10 0.5
Polyquaternium-49 0.1
Ethanol 3.0
Purified water 4.8
---------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 17 Shampoo This shampoo was excellent in foaming, and was able to give a moist wash-up and a smooth feeling of use.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 1.0
LUSPLAN DD-DA5 (Nippon Seika) 0.1
Cetanol 0.3
Myristic acid 0.1
PEG-2 caprylylamine 1.0
Ammonium xylenesulfonate 1.0
Lauroamphoacetate Na (30%) 7.0
Laureth sulfate Na (27%) 10.0
Distearate glycol 0.5
Palm oil fatty acid PEG-7 glyceryl 0.3
Myristic acid PPG-3 benzyl ether 0.5
Dimethicone (1 million cps) 0.3
Dodecylbenzenesulfonic acid Na 2.0
Sunflower wax 0.01
Polyquaternium-64 0.5
PPG-7 0.5
Cetrimonium chloride (30%) 1.0
Phenoxyethanol 0.3
Part B EDTA-2Na 0.05
Ethylenediamine disuccinic acid 3Na 0.1
Benzoic acid Na 0.3
Polyquaternium-10 0.1
Guar hydroxypropyltrimonium chloride 0.3
Hydroxypropyltrimonium hyaluronate 0.3
Purified water Amount to be 100 in total C part Tremoist-TP (Nippon Seika) 0.05
Carbomer 0.1
Arginine 1.0
Hydroxide Na 0.1
Na chloride 0.5
Purified water 10.0
---------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 18 Shampoo This shampoo is excellent in foaming, and by adding the diester of Synthesis Example 1, lanolin fatty acid and isostearic acid, it is easy to finger without using silicone, and can give a moist wash and a smooth feeling of use. It was a thing.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 2.0
Lanolin fatty acid 0.1
Isostearic acid 0.1
Laureth sulfosuccinate 2Na (26%) 10.0
Lauroamphoacetate Na (30%) 7.0
Lauryl sulfate TEA (40%) 6.0
Laureth-2 1.0
Dioleic acid PEG-120 methyl glucose 1.0
Tetraoleic acid Solves-60 3.5
Caprylyl glucoside 0.3
Distearate glycol 0.5
PEG-2 cocamine 1.2
PEG-60 hydrogenated castor oil 0.5
Neopentyl glycol diheptanoate 0.3
Glyceryl oleate 0.8
Phenoxyethanol 0.3
Part B EDTA-2Na 0.05
Methylparaben 0.15
Purified water Total amount of 100 part C Polyquaternium-10 0.1
Guar hydroxypropyltrimonium chloride 0.3
Na chloride 0.3
Ascorbic acid 0.3
Hyaluronic acid Na 0.3
Purified water 19.3
---------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 19 Shampoo This shampoo was excellent in foaming, was easy to pass through without using silicone, and was able to give a moist wash and a smooth feeling of use.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 2.0
Isostearic acid 0.1
Cocoyl Methyl Taurine Na (30%) 8.0
Cocamidopropyl betaine (30%) 5.0
Laureth sulfate Na (25%) 6.0
Laureth-2 1.0
Tetraoleic acid Solves-60 3.5
Caprylyl glucoside 0.3
Cocamide DEA 3.0
PEG-20 hydrogenated castor oil 0.5
Neopentyl glycol diheptanoate 0.3
Ethyl oleate 0.3
Part B EDTA-2Na 0.05
Methylparaben 0.15
Propanediol 0.5
Purified water Total amount of 100 part C Polyquaternium-10 0.1
Guar hydroxypropyltrimonium chloride 0.3
Na chloride 0.3
Ascorbic acid 0.3
Suizenjinori polysaccharide 0.1
Purified water 19.3
---------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 20 Shampoo This shampoo was excellent in foaming, good to touch without using silicone, and was able to give a moist wash and a smooth feeling of use.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 1.5
Oleic acid 0.3
Laureth sulfate Na (27%) 20.0
Hydrogenated palm oil fatty acid PEG-200 glyceryl 1.0
Cocobetaine (25%) 8.0
Glycerin 1.0
Polysorbate 20 0.5
Palm oil fatty acid PEG-7 glyceryl 0.4
PPG-2 cocamide 0.3
PEG-60 hydrogenated castor oil 1.0
Tocopherol 0.03
Bisabolol 0.01
Part B: Benzoic acid Na 0.4
Na chloride 0.5
Arginine 0.2
3-O-ethylascorbic acid (Nippon Seika) 0.1
Purified water Total amount of 100 Polyquaternium-10 0.3
Part C Phenoxyethanol 0.6
Phenethyl alcohol 0.2
Ethylhexyl glycerin 0.2
---------------------------------
(Preparation method)
Part A and B, which had been mixed and dissolved in advance, were uniformly mixed at about 80 ° C. (part E). The mixture was gradually cooled with stirring, and C part was added at 60 ° C.

Example 21 Shampoo This shampoo is excellent in foaming, and by adding the diester of Synthesis Example 1, isostearic acid and oleic acid, it is easy to touch without using silicone, and can give a moist wash and a smooth feeling of use. It was a thing.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 0.5
Isostearic acid 0.5
Oleic acid 0.3
Plandool-MAS (Nippon Seika) 0.2
Diethylhexyl sebacate (Nippon Seika) 0.5
Sunflower seed oil 0.1
Hybrid sunflower oil 0.3
Cocoyl Methyl Taurine Na 3.0
Cocamidopropyl betaine (30%) 8.0
Laureth sulfate Na (27%) 10.0
Cocoamphoacetate Na (30%) 5.0
Cocamidomethyl MEA 3.0
Distearate glycol 0.5
DPG 0.3
Cocoylthreonine Na 1.0
Dilauroyl glutamate lysine Na 0.05
PPG-70 glyceryl 0.7
Cocoyl Arginine Ethyl PCA 0.2
Phenoxyethanol 0.6
Part B EDTA-2Na 0.05
Betaine 1.0
PEG-40 0.3
Purified water Total amount of 100 part C Polyquaternium-10 0.3
Hydroxypropyltrimonium hyaluronate 0.3
Locust bean hydroxypropyltrimonium chloride 0.1
Panthenol 0.5
Na chloride 0.3
Menthol 0.3
Ethanol 3.0
Purified water 9.4
---------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 50 ° C.

Example 22 Shampoo This shampoo was excellent in foaming, was easy to pass through without using silicone, and was able to give a moist washing finish and a smooth feeling of use.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 0.5
Plandool-ISS (Nippon Seika) 0.2
Plandool-DP (Nippon Seika) 0.1
Lauroylmethylalanine Na 8.0
Palm nuclear fatty acid amidopropyl betaine (30%) 5.0
Cocamidomethyl MEA 2.0
Distearate glycol 0.5
DPG 0.3
Cocoylthreonine Na 1.0
Behendimonium ethyl stearyl phosphate 0.1
Lauric acid PEG-2 1.3
Cocoyl Arginine Ethyl PCA 0.2
Na propionate 0.1
Part B EDTA-2Na 0.05
Benzoic acid Na 0.3
Purified water Amount in total of 100 parts C Guar hydroxypropyltrimonium chloride 0.5
Na chloride 0.3
Purified water 9.4
---------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 23 Body Shampoo This body shampoo was excellent in foaming and was able to give a moist wash-up and a smooth feeling of use.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 0.5
Lauric acid 5.0
Myristic acid 8.0
Palmitic acid 3.0
Laureth sulfate Na (27%) 6.0
Distearate glycol 0.5
Glycerin 10.0
Shea fat 0.2
Cholesterol 0.3
PEG-8 3.0
Sorbitol 1.0
Cocamidomethyl MEA 1.0
Part B EDTA-2Na 0.05
Etidronic acid 3Na 0.10
Methylparaben 0.15
Purified water Total amount of 100 parts C Hydroxypropyl methylcellulose 0.2
Marcote 550 3.0
Phenoxyethanol 0.5
Purified water 9.4
---------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 24 Body Shampoo This body shampoo was excellent in foaming and was able to give a moist wash-up and a smooth feeling of use.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 0.5
Plandool-G (Nippon Seika) 0.2
Cocamidopropyl betaine 7.0
Cocoyl Glycine K 5.0
Cocamide DEA 2.0
PEG-80 sorbitan laurate 3.0
Lauroyl glutamate Na 4.0
DPG 2.5
Palm oil alkyl glucoside 3.0
Glycerin 10.0
Cetanol 0.2
PEG-8 3.0
Pentylene glycol 2.0
Part B EDTA-2Na 0.05
Etidronic acid 3Na 0.10
Butylcarbamic acid propynyl iodide 0.01
Methylparaben 0.15
Purified water Total amount of 100 parts C (styrene / alkyl acrylate) copolymer 0.2
Guar hydroxypropyltrimonium chloride 0.5
Phenoxyethanol 0.5
Purified water 8.8
---------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 60 ° C.

Example 25 Body Shampoo This body shampoo was a transparent and low-viscosity dosage form, had excellent foam-forming properties at the time of pump former discharge, and was able to give a moist wash-out and a smooth feeling of use.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 0.5
Cocamidopropyl betaine 7.0
Cocoyl Glycine K 5.0
Isostearic acid 0.1
Cocamidomethyl MEA 2.0
Lauroyl aspartate TEA 4.0
Propanediol 2.5
Decylglucoside 3.0
Glycerin 10.0
Pentylene glycol 2.0
Part B EDTA-2Na 0.05
Methylparaben 0.15
Polyquaternium-7 1.0
Purified water Total amount of 100 parts C Ethanol 5.0
Menthol 0.3
Phenoxyethanol 0.5
Purified water 8.8
---------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was taken in a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and part C was added at about 50 ° C.

Example 26 Flushing Hair Treatment This treatment was able to improve hair damage and give a slick feel like silicone. Further, after washing with shampoo, no residual feeling on the hair was felt.
Component Blending amount (% by weight)
--------------------------------
Part A Diester of Synthesis Example 1 0.5
Dodecane 3.0
Oleic acid 0.5
LUSPLAN SR-DM4 (Nippon Seika) 0.4
Behenyl alcohol 4.0
Cetanol 2.0
Behentrimonium chloride 2.0
Stearamidopropyldimethylamine 1.0
Glyceryl stearate 0.4
PPG-9 Diglyceryl 0.2
Polyglyceryl-2 diisostearate0.1
Hydrogenated lecithin 0.1
Adsorbed purified lanolin 0.2
Neopentyl glycol dioctanoate 0.5
Diethylhexyl sebacate (Nippon Seika) 0.5
Tocopherol 0.05
Part B Glycerin 0.2
DPG 0.2
Panthenol 0.1
Hydroxycellulose 0.02
Phenoxyethanol 0.6
Edetic acid 3Na 0.01
Purified water Total amount of 100 parts C Arginine 0.10
--------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved uniformly. B was taken in another container, heated to about 80 ° C., and dissolved uniformly. Part C was taken in another container, a part of purified water was added and dissolved, and then part A was stirred. Further, part B was gradually added and mixed uniformly and cooled.

Example 27 Washing Hair Treatment This treatment was able to improve hair damage and give a smooth feeling like silicone. Further, after washing with shampoo, no residual feeling on the hair was felt.
Component Blending amount (% by weight)
---------------------------------
Part A Diester of Synthesis Example 1 0.1
Neosolu-Aquilio (Nippon Seika) 2.0
Cetrimonium chloride (25%) 3.8
Caprylyl glucoside (50%) 0.8
Cetanol 4.0
Phenoxyethanol 0.5
Part B Ethanol 5.0
Part C Polyquaternium-7 0.4
Polyquaternium-39 0.5
Purified water Total amount of 100 ---------------------------------
(Preparation method)
Part C was heated to about 80 ° C. and dissolved. Next, part A was heated to about 80 ° C. and dissolved. Part A was added with stirring, part A was mixed uniformly, and then cooled to about 40 ° C. Next, part B was added and mixed uniformly.

Example 28 Hair Treatment This treatment was able to improve hair damage and give a smooth feeling like silicone. Further, after washing with shampoo, no residual feeling on the hair was felt.
Component Blending amount (% by weight)
------------------------------
Part A Diester of Synthesis Example 1 6.0
Plandool-H (Nippon Seika) 2.0
Plandool-LG3 (Nippon Seika) 2.0
Cetanol 6.0
Dimethicone (1000cs) 2.0
Dibutylethylhexanoylglutamide 0.2
Isostearic acid 0.2
Aminopropyl dimethicone 0.4
Behentrimonium chloride (80%) 2.4
Distearyldimonium chloride (75%) 0.8
Glyceryl stearate 0.8
Part B Phenoxyethanol 0.5
Purified water Amount to be 100 in total C part Hydrolyzed keratin (20%) 1.5
------------------------------
(Preparation method)
Part B was heated to about 80 ° C. and dissolved uniformly. Part A was added to a separate container, heated and dissolved. Part B was gradually added to part A, mixed uniformly, and cooled. Part C was added at around 40 ° C. and mixed uniformly.

Example 29 Hair Treatment This treatment was able to improve hair damage and give a smooth feeling like silicone. Further, after washing with shampoo, no residual feeling on the hair was felt.
Component Blending amount (% by weight)
--------------------------------
Part A Diester of Synthesis Example 1 0.5
Dodecane 3.0
Behenyl alcohol 4.0
Cetanol 2.0
Behentrimonium chloride 2.0
Stearamidopropyldimethylamine 1.0
Glyceryl stearate 0.4
PPG-9 Diglyceryl 0.2
Polyglyceryl-2 diisostearate0.1
Hydrogenated lecithin 0.1
Adsorbed purified lanolin 0.2
Dibutyl lauroylglutamide 0.3
Dibutylethylhexylglutamide 0.3
Neopentyl glycol dioctanoate 0.5
Diethylhexyl sebacate (Nippon Seika) 0.5
Neosolu-Aquilio (Nippon Seika) 1.0
Tocopherol 0.05
Part B Glycerin 0.2
DPG 0.2
Hydrolyzed collagen 0.1
Panthenol 0.1
Hydroxycellulose 0.02
Polyquaternium-10 0.05
Phenoxyethanol 0.2
Citric acid appropriate amount Edetic acid 3Na 0.01
Pentethic acid 0.02
Purified water Total amount of 100 parts C Arginine 0.10
--------------------------------
(Preparation method)
Part A was heated to about 80 ° C. and dissolved uniformly. B was taken in another container, heated to about 80 ° C., and dissolved uniformly. Part C was taken in another container, a part of purified water was added and dissolved, and then part A was stirred. Further, part B was gradually added and mixed uniformly and cooled.

In the above formulation, details of the components described by the product name are as follows.

* Plandool-H: Dimer linoleic acid (phytosteryl / isostearyl / cetyl / stearyl / behenyl)
* Plandool-G: Dimer dilinoleic acid dimer dilinoleyl bis (behenyl / isostearyl / phytosteryl)
O Plandool-DP: Bisdiglyceryl polyacyl adipate-2
O Plandool-ISS: Phytosteryl isostearate O Plandool-SUN: Sunflower seed oil fatty acid phytosteryl O Plandool-MAS: Macadamia nut oil fatty acid phytosteryl O Plandool-LG2: Dilauroyl glutamate (phytosteryl / octyldodecyl)
○ Plandool-LG3: dilauroyl glutamate (phytosteryl / octyldodecyl / behenyl)
〇LUSPLAN PI-DA: Dimer dilinoleic acid di (isostearyl / phytosteryl)
O LUSPLAN DD-DA5: Dimer dilinoleic acid dimer dilinoleyl O LUSPLAN SR-DM4: Dimer dilinoleic acid dimer dilinoleyl, tri (caprylic acid / capric acid) glyceryl O Neosolue-Aqulio: bisethoxydiglycol cyclohexanedicarboxylate ○ Neosolue-AquaS: (eicosandioic acid / tetradecanedioic acid) polyglyceryl-10, glycerin ○ Neosolue-MP: dineopentanoic acid methylpentanediol ○ Neosolue-DE: dineopentanoic acid methylpentanediol ○ Tremoist-SL: white jellyfish polysaccharide aqueous solution (1 %)
〇 Elcalactone DES: γ-docosalactone, diethyl sebacate

Claims (5)

A cleaning composition comprising the following components (A) and (B):
(A) Diester composition of isostearyl alcohol and malic acid derived from by-products during dimer acid production, having a viscosity at 25 ° C. of 100 to 300 mPa · s (B) ionic surfactant   The cleaning composition according to claim 1, further comprising (C) a nonionic surfactant.   Furthermore, (D) higher fatty acid is contained, The cleaning composition of Claim 1 or 2 characterized by the above-mentioned.   The cleaning composition according to any one of claims 1 to 3, wherein the cleaning composition is for hair. The cleaning composition according to claim 4, which is substantially free of a silicone compound.