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KR102596547B1 - Method for manufacturing dryer sheet - Google Patents

Method for manufacturing dryer sheet Download PDF

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KR102596547B1
KR102596547B1 KR1020230077854A KR20230077854A KR102596547B1 KR 102596547 B1 KR102596547 B1 KR 102596547B1 KR 1020230077854 A KR1020230077854 A KR 1020230077854A KR 20230077854 A KR20230077854 A KR 20230077854A KR 102596547 B1 KR102596547 B1 KR 102596547B1
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최규태
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주식회사 블루워시
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/221Mono, di- or trisaccharides or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/22Carbohydrates or derivatives thereof
    • C11D3/222Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/28Heterocyclic compounds containing nitrogen in the ring
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/36Organic compounds containing phosphorus
    • C11D3/362Phosphates or phosphites
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50Perfumes
    • C11D3/502Protected perfumes
    • C11D3/505Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Molecular Biology (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The present invention relates to a method of manufacturing dryer sheets and, more particularly, to an improved method of manufacturing dryer sheets that are used with laundry when the laundry is washed in a washing machine and then dried in a dryer to increase fiber-softening properties as the laundry dries, to enhance deodorization and antistatic properties, and that are packaged in bundles so that they are easy to remove one by one.

Description

건조기 시트 제조방법{Method for manufacturing dryer sheet}Method for manufacturing dryer sheet}

본 발명은 건조기 시트 제조방법에 관한 것으로, 보다 상세하게는 세탁물을 세탁기로 세탁한 후 건조기에서 건조할 때 세탁물과 함께 사용되어 건조되면서 섬유유연 특성을 증대시키고, 탈취는 물론 정전기방지 특성을 강화시킬 뿐만 아니라, 낱개로 포장되어 있어 하나씩 빼어쓰기 편하도록 개선된 건조기 시트 제조방법에 관한 것이다.The present invention relates to a method of manufacturing a dryer sheet, and more specifically, when washing laundry in a washing machine and then drying it in a dryer, it is used together with the laundry to increase fabric flexibility while drying, deodorize, and strengthen anti-static properties. In addition, it relates to an improved method of manufacturing dryer sheets so that they are individually packaged and can be easily removed and used one by one.

일반적으로 의류의 정전기 방지 및 유연성 부여의 목적으로 세탁시에 흔히 섬유유연제를 사용하고 있으며, 그 사용량이 점차 증가하는 추세에 있다.In general, fabric softeners are commonly used during washing for the purpose of preventing static electricity and providing flexibility to clothes, and the amount of use is gradually increasing.

특히 섬유유연제 처리후의 세탁섬유에서 느낄수 있는 향취는 세제 사용에 따른 세제 찌꺼기의 냄새를 차폐해주는 효과와 의류 착용시 또는 착용 중에 상쾌한 느낌을 지속시켜 주는 이중의 효과를 준다.In particular, the scent that can be felt in laundry fabric after treatment with fabric softener has the dual effect of masking the smell of detergent residue caused by detergent use and maintaining a refreshing feeling when or while wearing clothes.

최근에는 이러한 섬유유연제의 기본 기능인 정전기 방지와 유연성 부여란 측면 이외에도 다양한 기능을 가진 가정용 섬유유연제가 출시되고 있는 상황이다.Recently, home fabric softeners with various functions in addition to preventing static electricity and providing flexibility, which are the basic functions of fabric softeners, are being released.

국내에 시판 중인 가정용 섬유유연제는 보통의 경우 액상 타입되어 있으며, 흔히 일반 세탁기의 헹굼시에 사용되고 있다.Household fabric softeners commercially available in Korea are usually of a liquid type and are commonly used for rinsing regular washing machines.

그러나 최근에 건조기의 보급이 증가함에 따라 세탁후 건조기를 통해 세탁섬유물들을 건조시키는데 이때 강한 고열이 발생되어 세탁시 섬유유연제를 보급하더라도 건조과정에서 그 향이 대부분이 사라져 건조 후 섬유물에서는 향이 거의 나타나지 않은 문제점이 있다.However, with the recent increase in the use of dryers, washed textiles are dried through a dryer after washing. At this time, strong high heat is generated, so even if fabric softener is used during washing, most of the scent is lost during the drying process, so the scent is barely visible in the textiles after drying. There is a problem that is not there.

국내 등록특허 제10-2249682호(2021.05.03.) 건조기용 섬유유연제 시트 및 그 제조방법Domestic registered patent No. 10-2249682 (2021.05.03.) Fabric softener sheet for dryer and manufacturing method thereof

본 발명은 상술한 바와 같은 종래 기술상의 제반 문제점들을 감안하여 이를 해결하고자 창출된 것으로, 세탁물을 세탁기로 세탁한 후 건조기에서 건조할 때 세탁물과 함께 사용되어 건조되면서 섬유유연 특성을 증대시키고, 탈취는 물론 정전기방지 특성을 강화시킬 뿐만 아니라, 낱개로 포장되어 있어 하나씩 빼어쓰기 편하도록 개선된 건조기 시트 제조방법을 제공함에 주된 목적이 있다.The present invention was created in consideration of various problems in the prior art as described above to solve them. When laundry is washed in a washing machine and then dried in a dryer, it is used together with the laundry to increase fabric softening properties while drying, and to deodorize. Of course, the main purpose is to provide an improved method of manufacturing dryer sheets that not only strengthens the anti-static properties, but also allows them to be conveniently removed one by one since they are individually packaged.

본 발명은 상기한 목적을 달성하기 위한 수단으로, 비스코스 원단을 시트 형태로 가공한 상태에서 이 비스코스 원단 시트에 기능성 함침액을 함침시킨 후 일정시간 동안 건조하되, 상기 함침액은 정제수 100중량부에 대해, 시트르산(citric acid) 15중량부, 알파-D-글루코피라노스(α-D-glucopyranose) 10중량부, 데실글루코사이드(Decyl glucoside) 10중량부, 네츄럴베타인(Natural Betain) 10중량부, 알란토인(Allantoin) 5중량부, 모노(2-프로필헵틸)에테르(Mono(2-Propylheptyl)Ether) 5중량부, 라우라미도프로필하이드록시설타인(Lauramidopropyl Hydroxysultaine) 5중량부를 첨가하여 이루어진 건조기 시트를 제공한다.The present invention is a means to achieve the above object. The viscose fabric is processed into a sheet form, the viscose fabric sheet is impregnated with a functional impregnation solution, and then dried for a certain period of time. The impregnation solution is mixed with 100 parts by weight of purified water. For example, 15 parts by weight of citric acid, 10 parts by weight of alpha-D-glucopyranose, 10 parts by weight of Decyl glucoside, 10 parts by weight of Natural Betain, Provides a dryer sheet made by adding 5 parts by weight of Allantoin, 5 parts by weight of Mono(2-Propylheptyl)Ether, and 5 parts by weight of Lauramidopropyl Hydroxysultaine. do.

본 발명에 따르면, 세탁물을 세탁기로 세탁한 후 건조기에서 건조할 때 세탁물과 함께 사용되어 건조되면서 섬유유연 특성을 증대시키고, 탈취는 물론 정전기방지 특성을 강화시킬 뿐만 아니라, 낱개로 포장되어 있어 하나씩 빼어쓰기 편하도록 개선된 효과를 얻을 수 있다.According to the present invention, when laundry is washed in a washing machine and then dried in a dryer, it is used together with the laundry to increase fabric softening properties as it dries, and not only deodorizes but also strengthens anti-static properties, and is individually packaged so that it can be removed one by one. You can get improved effects to make it easier to use.

이하에서는, 본 발명에 따른 바람직한 실시예를 보다 상세하게 설명하기로 한다.Hereinafter, preferred embodiments according to the present invention will be described in more detail.

본 발명에 따른 건조기 시트는 비스코스 원단을 시트 형태로 가공한 상태에서 이 비스코스 원단 시트에 기능성 함침액을 함침시킨 후 일정시간 동안 건조시킨 것이다.The dryer sheet according to the present invention is made by processing viscose fabric into a sheet form, impregnating the viscose fabric sheet with a functional impregnation solution, and then drying it for a certain period of time.

이러한 건조기 시트는 일정크기로 낱개 포장이 가능하며, 원하는 크기로 얼마든지 자유롭게 재단하여 제조할 수 있는 장점이 있다.These dryer sheets can be individually packaged in a certain size and have the advantage of being freely cut and manufactured to the desired size.

여기에서, 상기 비스코스 원단은 목재 펄프에서 얻어진 것으로 상대적으로 싸며 셀룰로오스가 기본물질로써 높은 흡수력, 부드러움 그리고 염색이 쉬운 특성이 있어 자연분해가 잘되는 특징이 있으므로 환경 친화적이다.Here, the viscose fabric is obtained from wood pulp, is relatively cheap, and has cellulose as a base material, which has the characteristics of high absorbency, softness, and easy dyeing, so it is environmentally friendly because it has the characteristics of natural decomposition.

아울러, 상기 함침액은 정제수 100중량부에 대해, 시트르산(citric acid) 15중량부, 알파-D-글루코피라노스(α-D-glucopyranose) 10중량부, 데실글루코사이드(Decyl glucoside) 10중량부, 네츄럴베타인(Natural Betain) 10중량부, 알란토인(Allantoin) 5중량부, 모노(2-프로필헵틸)에테르(Mono(2-Propylheptyl)Ether) 5중량부, 라우라미도프로필하이드록시설타인(Lauramidopropyl Hydroxysultaine) 5중량부를 첨가하여 이루어진다.In addition, the impregnation liquid contains 15 parts by weight of citric acid, 10 parts by weight of alpha-D-glucopyranose, 10 parts by weight of Decyl glucoside, based on 100 parts by weight of purified water. Natural Betain 10 parts by weight, Allantoin 5 parts by weight, Mono(2-Propylheptyl)Ether 5 parts by weight, Lauramidopropyl Hydroxysultaine ) is made by adding 5 parts by weight.

이때, 시트르산은 레몬이나 밀감 따위의 과실 속에 풍부하게 들어 있는 유기산으로, 이온화되어 3가의 음이온으로 작용하는 하이드록시트라이카복실산의 한 종류이나 다른 카복실산보다는 강한 산성을 띠며, 무색무취의 고체 결정으로 물과 알코올에 잘 녹고 신맛이 있어 청량음료, 의약품의 첨가제로 쓰이며, 분자식은 C6H8O7이고, 본 발명에서는 건조시 용출되면서 섬유 유연 효과를 증대시키기 위해 첨가된다.At this time, citric acid is an organic acid abundantly found in fruits such as lemons and tangerines. It is a type of hydroxytricarboxylic acid that ionizes and acts as a trivalent anion, but it is more acidic than other carboxylic acids and is a colorless, odorless solid crystal that dissolves in water and water. It is easily soluble in alcohol and has a sour taste, so it is used as an additive in soft drinks and medicines. Its molecular formula is C 6 H 8 O 7 , and in the present invention, it is added to increase the fabric softening effect as it dissolves during drying.

또한, 알파-D-글루코피라노스는 CAS No. 492-62-6에 해당하는 물질로서, 분자식은 C6H12O6이고, 건조 과정에서 열을 받아 계면활성 기능을 강화시킨다. Additionally, alpha-D-glucopyranose has CAS No. It is a substance corresponding to 492-62-6, and its molecular formula is C 6 H 12 O 6 , and it receives heat during the drying process to strengthen the surface activity function.

그리고, 데실글루코사이드는 CAS No. 68515-73-1에 해당하는 물질로서, 시트르산과 혼합되어 산도가 낮아지면서 세정력을 제공하여 건조시 덩어리진 먼지나 이물 발생을 억제하고 섬유를 부드럽게 하는데 기여한다.And, decylglucoside has CAS No. It is a substance corresponding to 68515-73-1. It is mixed with citric acid and provides cleaning power while lowering the acidity, suppressing the generation of lumpy dust or foreign substances during drying and contributing to softening the fiber.

아울러, 네츄럴베타인은 사탕무로부터 분리 정제하여 얻은 천연 아미노산계 성분으로서, 건조시 섬유에 스며들어 착용시 피부 자극을 억제하고 진정시키는데 기여하여 가려움을 억제하는 장점이 있다.In addition, natural betaine is a natural amino acid-based ingredient obtained by separating and purifying sugar beets, and has the advantage of suppressing itchiness by permeating into the fiber when dried and contributing to soothing and suppressing skin irritation when worn.

뿐만 아니라, 알란토인은 건조시 섬유에 스며들어 착용시 피부 보습 작용에 기여한다.In addition, allantoin penetrates into the fiber when dried and contributes to moisturizing the skin when worn.

또한, 모노(2-프로필헵틸)에테르는 CAS No. 160875-66-1에 해당하는 물질로서, 분자식은 (C2H4O)nC10H22O이고, 정식명칭은 폴리에틸렌옥사이드모노-2-프로필헵틸에테르이며, 섬유 건조시 탈취기능을 강화시키고 원단에 함침시 유화성을 증대시킨다.Additionally, mono(2-propylheptyl)ether has CAS No. It is a substance corresponding to 160875-66-1, the molecular formula is (C 2 H 4 O)nC 10 H 22 O, and the official name is polyethylene oxide mono-2-propylheptyl ether. It strengthens the deodorizing function when drying the fiber and improves the fabric's deodorization function. When impregnated, emulsibility increases.

그리고, 라우라미도프로필하이드록시설타인은 함침액의 점도를 증가시키면서 특히 정전기 방지 기능을 강화시켜 건조시 보풀이 생기지 않도록 억제하는 장점이 있고, 분자구조식은 다음과 같다.In addition, lauramidopropyl hydroxysulsteine has the advantage of increasing the viscosity of the impregnating liquid and especially strengthening the anti-static function to prevent fluffing during drying. The molecular structure is as follows.

덧붙여, 본 발명은 건조시 시트를 구성할 때, 상기 비스코스 원단 시트에 함침액을 함침하기 전에 향료를 스프레이 코팅할 수 있다.In addition, in the present invention, when constructing a sheet during drying, the viscose fabric sheet can be spray-coated with a fragrance before impregnating the viscose fabric sheet with the impregnation solution.

이때, 향료는 미온수 100중량부에 대해, 백리향추출물(thymus quinquecostatus extract) 5중량부, 송진(Pine Sap) 5.5중량부, 글루타티온(glutathione) 5중량부를 첨가혼합하여 조성된다.At this time, the fragrance is prepared by adding and mixing 5 parts by weight of thymus quinquecostatus extract, 5.5 parts by weight of Pine Sap, and 5 parts by weight of glutathione with 100 parts by weight of lukewarm water.

이 경우, 미온수는 약 30-50℃ 온도의 물이고, 백리향추출물은 향기가 백리까지 간다고 해서 붙여진 이름으로, 방향성은 물론 살균성까지 갖춘 천연 살균제로도 활용된다.In this case, lukewarm water is water with a temperature of about 30-50℃, and thyme extract is so named because its scent lasts up to thyme, and is used as a natural disinfectant with not only aromatic properties but also sterilizing properties.

또한, 송진은 청량감을 제공하는 대표적인 천연 항균제이다.Additionally, rosin is a representative natural antibacterial agent that provides a refreshing feeling.

그리고, 글루타티온(glutathione)은 글루탐산, 시스테인, 글라이신 세개의 펩티드로 구성되어 산화와 환원의 순환이 반복되면서 독성 과산화물을 제거하는 특성이 있다.Additionally, glutathione is composed of three peptides: glutamic acid, cysteine, and glycine, and has the property of removing toxic peroxides through repeated cycles of oxidation and reduction.

뿐만 아니라, 본 발명은 건조기 시트의 계면활성력을 높이기 위해 상기 함침액을 구성할 때, 상기 정제수 100중량부에 대해 폴리옥시에틸렌라우릴에테르(Poly oxyethylene Lauryl ether) 5중량부, 벤조구아나민(Benzoguanamine) 3.5중량부, 아인산에스터(phosphite ester) 5.5중량부를 더 첨가할 수 있다.In addition, in the present invention, when composing the impregnation liquid to increase the surface activity of the dryer sheet, 5 parts by weight of polyoxyethylene lauryl ether and benzoguanamine ( Benzoguanamine) 3.5 parts by weight and phosphite ester (5.5 parts by weight) can be additionally added.

이때, 폴리옥시에틸렌라우릴에테르(Poly oxyethylene Lauryl ether)는 Cas 넘버 9002-92-0에 해당하는 물질로서, 음이온, 양이온 등 다른 계면활성제와 상용성이 양호하고, 산, 알카리, 염 등이 공존하는 수용액에서도 우수한 계면활성 작용을 나타낸다.At this time, polyoxyethylene lauryl ether is a substance corresponding to Cas number 9002-92-0, and has good compatibility with other surfactants such as anions and cations, and acids, alkalis, salts, etc. coexist. It exhibits excellent surface activity even in aqueous solutions.

또한, 벤조구아나민(Benzoguanamine)은 Cas 넘버 91-76-9에 해당하는 물질로서, 정전 특성을 유지하여 면서 부착력 안정화를 유지하기 위해 첨가된다.In addition, benzoguanamine is a substance corresponding to Cas number 91-76-9, and is added to maintain electrostatic properties and stabilize adhesion.

아울러, 아인산에스터(phosphite ester)는 특히, 염소성분에 의한 함침성분 분해를 억제하게 된다.In addition, phosphite ester especially inhibits the decomposition of impregnating components due to chlorine components.

이와 같은 건조기 시트는 다음과 같은 방법으로 제조된다.Such dryer sheets are manufactured in the following manner.

먼저, 원단 준비단계가 수행된다.First, a fabric preparation step is performed.

이때, 원단은 앞서 설명하였듯이, 비스코스 원단을 시트상으로 만든 것이다.At this time, as previously explained, the fabric is a viscose fabric made into a sheet.

이어, 향료 스프레이 단계가 수행된다.Next, a perfume spray step is performed.

상기 향료 스프레이 단계는 준비된 원단 표면과 이면에 미온수 100중량부에 대해, 백리향추출물(thymus quinquecostatus extract) 5중량부, 송진(Pine Sap) 5.5중량부, 글루타티온(glutathione) 5중량부를 첨가혼합하여 조성된 향료를 균일하게 뿌린 후 상온에서 2-3시간 동안 안정화시키는 단계이다.The fragrance spray step is prepared by adding and mixing 5 parts by weight of thymus quinquecostatus extract, 5.5 parts by weight of pine sap, and 5 parts by weight of glutathione with 100 parts by weight of lukewarm water on the surface and back of the prepared fabric. This is the step of spraying the fragrance evenly and stabilizing it at room temperature for 2-3 hours.

아울러, 함침액 제조단계가 수행된다.In addition, an impregnating liquid preparation step is performed.

상기 함침액 제조단계에서 제조되는 함침액은 앞서 설명한 바와 같다.The impregnation solution prepared in the impregnation solution preparation step is the same as described above.

함침액이 제조되면, 상기 향료가 스프레이된 비스코스 원단 시트를 함침액에 침지시킨 상태에서 40-60분 동안 유지한 후 꺼내어 상온 건조하는 함침단계가 수행된다.Once the impregnation solution is prepared, an impregnation step is performed in which the viscose fabric sheet sprayed with the fragrance is kept immersed in the impregnation solution for 40-60 minutes, then taken out and dried at room temperature.

함침액 함침 후 건조가 완료되면, 오염방지제를 코팅한 후 건조 포장하는 오염방지제 코팅단계가 수행된다.Once drying is completed after impregnation with the impregnation solution, an anti-fouling agent coating step is performed in which the anti-pollution agent is coated and then dried and packaged.

이때, 상기 오염방지제는 폴리우레탄수지 수용액 100중량부에 대해, 폴리비닐알콜 15중량부, 에틸알콜 2.5중량부, 2-아크릴아미노-2-메틸프로판술폰산(2-Acrylamino-2-methyl propane sulfonic acid) 5중량부, 셀룰로오스 디아세테이트(cellulose diacetate) 4.5중량부, 폴리테트라 플루오로에틸렌(polytetrafluoroethylene) 5중량부, 메틸살리실레이트(Methyl Salicylate) 4.5중량부를 혼합하여 이루어진다.At this time, the anti-fouling agent is 15 parts by weight of polyvinyl alcohol, 2.5 parts by weight of ethyl alcohol, and 2-Acrylamino-2-methyl propane sulfonic acid based on 100 parts by weight of the polyurethane resin aqueous solution. ) 5 parts by weight, 4.5 parts by weight of cellulose diacetate, 5 parts by weight of polytetrafluoroethylene, and 4.5 parts by weight of methyl salicylate.

여기에서, 폴리비닐알콜은 분말 형태로서 10미크론의 입도로 분쇄된 미분을 사용함이 바람직하며, 세정기능을 수행한다.Here, polyvinyl alcohol is preferably in the form of powder and fine powder pulverized to a particle size of 10 microns is used, and performs a cleaning function.

또한, 2-아크릴아미노-2-메틸프로판술폰산(2-Acrylamino-2-methyl propane sulfonic acid)은 Cas 넘버 15214-89-8에 해당하는 유화제로서 수지의 고정력을 증대시켜 분리되지 않도록 하면서 굴곡특성과 인장강도를 강화시킨다.In addition, 2-Acrylamino-2-methyl propane sulfonic acid is an emulsifier corresponding to Cas number 15214-89-8, which increases the fixing power of the resin to prevent separation and improves bending properties and Strengthens tensile strength.

그리고, 셀룰로오스 디아세테이트(cellulose diacetate)는 셀룰로오스를 구성하는 파라노스(pyranose) 고리로 인해 높은 유리전이온도를 갖게 되므로 인장강도, 굴곡강도, 충격강도를 향상시켜 이염방지시트의 유연성을 증대시킴으로써 쉽게 찢어지거나 헤어지지 않도록 하는데 기여한다.In addition, cellulose diacetate has a high glass transition temperature due to the pyranose ring that makes up cellulose, so it improves the tensile strength, flexural strength, and impact strength, thereby increasing the flexibility of the anti-dye transfer sheet and making it easier to tear. It contributes to preventing losing or breaking up.

뿐만 아니라, 폴리테트라 플루오로에틸렌(polytetrafluoroethylene)은 비점착성, 방오 특성을 강화시켜 오염이 쉽게 되지 않도록 하여 청결성을 강화시키기 위해 첨가된다.In addition, polytetrafluoroethylene is added to enhance cleanliness by strengthening non-adhesive and anti-fouling properties to prevent contamination.

아울러, 상기 메틸살리실레이트(Methyl Salicylate)는 무색의 액체로서 시트를 구성하는 원사의 연화에 기여하기 위해 첨가된다.In addition, Methyl Salicylate is a colorless liquid that is added to contribute to softening the yarns that make up the sheet.

이와 같은 본 발명에 따른 건조기 시트의 섬유 유연 효과와 탈취 및 정전기 방지 효과를 확인하기 위해 정전기 발생이 극심한 폴리에스터 90% 이상 함유 섬유를 세탁 후 건조기에서 건조할 때 상술한 건조기 시트 3장을 함께 넣고 건조하였다.In order to check the fiber softening effect and the deodorizing and static electricity prevention effect of the dryer sheet according to the present invention, when drying fibers containing 90% or more of polyester, which generate extreme static electricity, in a dryer after washing, the three dryer sheets described above were placed together. It was dried.

건조 후 정전기 발생여부를 확인한 결과, 정전기 발생이 없었다.As a result of checking whether static electricity was generated after drying, there was no static electricity generated.

또한, 섬유 유연 효과는 사람마다 느끼는 기준이 다를 수 있지만, 15명을 대상으로 테스트한 후 느낌을 확인한 결과, 섬유 유연성이 충분한 것으로 확인되었다.In addition, the standard of feeling the effect of fabric flexibility may vary from person to person, but after testing with 15 people and confirming the feeling, it was confirmed that the fabric flexibility was sufficient.

뿐만 아니라, 탈취의 경우도 주관성이 강하지만, 파인트리 향이 매우 좋다고 답한 사람이 15명중 14명이었다.In addition, although deodorization is highly subjective, 14 out of 15 people responded that the pinetree scent was very good.

Claims (4)

삭제delete 삭제delete 삭제delete 비스코스 원단을 시트상으로 만든 원단 준비단계; 준비된 비스코스 원단 시트의 표면과 이면에 미온수 100중량부에 대해, 백리향추출물(thymus quinquecostatus extract) 5중량부, 송진(Pine Sap) 5.5중량부, 글루타티온(glutathione) 5중량부를 첨가혼합하여 조성된 향료를 균일하게 뿌린 후 상온에서 2-3시간 동안 안정화시키는 향료 스프레이 단계; 상기 비스코스 원단에 함침시킬 함침액을 제조하는 단계; 함침액이 제조되면, 상기 향료가 스프레이된 비스코스 원단 시트를 함침액에 침지시킨 상태에서 40-60분 동안 유지한 후 꺼내어 상온 건조하는 함침단계; 함침액 함침 후 건조가 완료되면, 오염방지제를 코팅한 후 건조 포장하는 오염방지제 코팅단계;를 포함하고,
상기 함침액 제조단계에서 제조되는 함침액은 정제수 100중량부에 대해, 시트르산(citric acid) 15중량부, 알파-D-글루코피라노스(α-D-glucopyranose) 10중량부, 데실글루코사이드(Decyl glucoside) 10중량부, 네츄럴베타인(Natural Betain) 10중량부, 알란토인(Allantoin) 5중량부, 모노(2-프로필헵틸)에테르(Mono(2-Propylheptyl)Ether) 5중량부, 라우라미도프로필하이드록시설타인(Lauramidopropyl Hydroxysultaine) 5중량부를 첨가하여 조성되며;
상기 오염방지제 코팅단계에서 사용되는 오염방지제는 폴리우레탄수지 수용액 100중량부에 대해, 폴리비닐알콜 15중량부, 에틸알콜 2.5중량부, 2-아크릴아미노-2-메틸프로판술폰산(2-Acrylamino-2-methyl propane sulfonic acid) 5중량부, 셀룰로오스 디아세테이트(cellulose diacetate) 4.5중량부, 폴리테트라 플루오로에틸렌(polytetrafluoroethylene) 5중량부, 메틸살리실레이트(Methyl Salicylate) 4.5중량부를 혼합하여 이루어진 것을 특징으로 하는 건조기 시트 제조방법.
A fabric preparation step in which viscose fabric is made into a sheet; A fragrance prepared by adding and mixing 5 parts by weight of thymus quinquecostatus extract, 5.5 parts by weight of Pine Sap, and 5 parts by weight of glutathione to 100 parts by weight of lukewarm water was added to the surface and back of the prepared viscose fabric sheet. Fragrance spraying step of uniformly spraying and stabilizing at room temperature for 2-3 hours; Preparing an impregnating liquid to be impregnated into the viscose fabric; When the impregnation solution is prepared, an impregnation step of maintaining the viscose fabric sheet sprayed with the fragrance in the impregnation solution for 40-60 minutes, then taking it out and drying it at room temperature; When drying is completed after impregnation with the impregnation solution, an anti-fouling agent coating step of coating the anti-pollution agent and then drying and packaging,
The impregnation solution prepared in the impregnation solution preparation step contains 15 parts by weight of citric acid, 10 parts by weight of alpha-D-glucopyranose, and Decyl glucoside, based on 100 parts by weight of purified water. ) 10 parts by weight, Natural Betain 10 parts by weight, Allantoin 5 parts by weight, Mono(2-Propylheptyl)Ether 5 parts by weight, Lauramidopropyl Hydroxide It is formulated by adding 5 parts by weight of Lauramidopropyl Hydroxysultaine;
The antifouling agent used in the antifouling agent coating step is 15 parts by weight of polyvinyl alcohol, 2.5 parts by weight of ethyl alcohol, and 2-acrylamino-2-methylpropanesulfonic acid (2-Acrylamino-2), based on 100 parts by weight of the polyurethane resin aqueous solution. It is characterized by mixing 5 parts by weight of -methyl propane sulfonic acid, 4.5 parts by weight of cellulose diacetate, 5 parts by weight of polytetrafluoroethylene, and 4.5 parts by weight of methyl salicylate. Dryer sheet manufacturing method.
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