ES2464528T1 - Agentes espumantes y composiciones que contienen olefinas sustiuidas con flúor, y métodos de espumación - Google Patents
Agentes espumantes y composiciones que contienen olefinas sustiuidas con flúor, y métodos de espumación Download PDFInfo
- Publication number
- ES2464528T1 ES2464528T1 ES13166417.9T ES13166417T ES2464528T1 ES 2464528 T1 ES2464528 T1 ES 2464528T1 ES 13166417 T ES13166417 T ES 13166417T ES 2464528 T1 ES2464528 T1 ES 2464528T1
- Authority
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- Spain
- Prior art keywords
- foam
- blowing agent
- composition
- forming
- formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000000203 mixture Substances 0.000 title claims 17
- 238000000034 method Methods 0.000 title claims 5
- 238000005187 foaming Methods 0.000 title claims 2
- 150000001336 alkenes Chemical class 0.000 title 1
- 239000004088 foaming agent Substances 0.000 title 1
- 239000004604 Blowing Agent Substances 0.000 claims abstract 22
- 150000001875 compounds Chemical class 0.000 claims abstract 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract 4
- 229910052801 chlorine Inorganic materials 0.000 claims abstract 3
- 229910052731 fluorine Inorganic materials 0.000 claims abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052794 bromium Inorganic materials 0.000 claims abstract 2
- 239000001257 hydrogen Substances 0.000 claims abstract 2
- 229910052740 iodine Inorganic materials 0.000 claims abstract 2
- 239000006260 foam Substances 0.000 claims 29
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 5
- 229920005862 polyol Polymers 0.000 claims 5
- 150000003077 polyols Chemical class 0.000 claims 5
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims 4
- 229920000582 polyisocyanurate Polymers 0.000 claims 4
- 239000011495 polyisocyanurate Substances 0.000 claims 4
- 229920001187 thermosetting polymer Polymers 0.000 claims 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims 3
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims 3
- 229920002635 polyurethane Polymers 0.000 claims 3
- 239000004814 polyurethane Substances 0.000 claims 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 claims 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229920005830 Polyurethane Foam Polymers 0.000 claims 2
- 239000003054 catalyst Substances 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims 2
- 150000002170 ethers Chemical class 0.000 claims 2
- 239000003063 flame retardant Substances 0.000 claims 2
- 150000002367 halogens Chemical group 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims 2
- 239000012948 isocyanate Substances 0.000 claims 2
- 150000002513 isocyanates Chemical class 0.000 claims 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims 2
- 239000011496 polyurethane foam Substances 0.000 claims 2
- 239000004094 surface-active agent Substances 0.000 claims 2
- 229920001169 thermoplastic Polymers 0.000 claims 2
- 239000004416 thermosoftening plastic Substances 0.000 claims 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- 239000000654 additive Substances 0.000 claims 1
- 150000001298 alcohols Chemical class 0.000 claims 1
- 150000001299 aldehydes Chemical class 0.000 claims 1
- 125000002947 alkylene group Chemical group 0.000 claims 1
- 239000001273 butane Substances 0.000 claims 1
- 239000003086 colorant Substances 0.000 claims 1
- 125000001511 cyclopentyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C1([H])[H] 0.000 claims 1
- 150000005690 diesters Chemical class 0.000 claims 1
- NKDDWNXOKDWJAK-UHFFFAOYSA-N dimethoxymethane Chemical compound COCOC NKDDWNXOKDWJAK-UHFFFAOYSA-N 0.000 claims 1
- KLKFAASOGCDTDT-UHFFFAOYSA-N ethoxymethoxyethane Chemical compound CCOCOCC KLKFAASOGCDTDT-UHFFFAOYSA-N 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 125000001153 fluoro group Chemical group F* 0.000 claims 1
- 238000011065 in-situ storage Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 239000001282 iso-butane Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims 1
- 150000003254 radicals Chemical class 0.000 claims 1
- 239000007921 spray Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/228—Forming foamed products
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/12—Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
- C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/20—Ternary blends of expanding agents
- C08J2203/202—Ternary blends of expanding agents of physical blowing agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/04—Condensation polymers of aldehydes or ketones with phenols only
- C08J2361/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Molding Of Porous Articles (AREA)
Abstract
Un agente de soplado, que comprende: (a) al menos un fluoroalqueno de Fórmula I: XCF2R3-z(I) en que X es un radical C1, C2, C3, C4 o C5 insaturado, sustituido o no sustituido, cada uno de los R es independientemente Cl, F, Br, I o H, y z es 1 a 3, con la condición de que si Br está presente en el compuesto, entonces el compuesto no incluye hidrógeno; y (b) al menos uno o más agentes de co-soplado.
Claims (15)
- REIVINDICACIONES1. Un agente de soplado, que comprende:(a) al menos un fluoroalqueno de Fórmula I:XCF2R3-z(I)en que X es un radical C1, C2, C3, C4 o C5 insaturado, sustituido o no sustituido, cada uno de los R es independientemente Cl, F, Br, I o H, y z es 1 a 3, con la condición de que si Br está presente en el compuesto, entonces el compuesto no incluye hidrógeno; y(b) al menos uno o más agentes de co-soplado.
-
- 2.
- El agente de soplado de la reivindicación 1, en donde el fluoroalqueno de Fórmula (I), en donde X es alquileno C3 sustituido con flúor y/o cloro.
-
- 3.
- El agente de soplado de la reivindicación 1, en donde dicho compuesto de Fórmula (I) tiene al menos cuatro (4) sustituyentes halógeno, preferiblemente en donde dichos al menos cuatro (4) sustituyentes halógeno comprenden al menos tres sustituyentes F.
-
- 4.
- El agente de soplado de cualquier reivindicación precedente, en donde dicho al menos un agente de co-soplado se selecciona del grupo que consiste en agua, CO2, CFCs, HCCs, HCFCs, alcoholes C1-C5, aldehídos C1-C4, cetonas C1-C4, éteres C1-C4, hidrocarburos C3-C6 o un segundo fluoroalqueno de fórmula (I) y combinaciones de dos o más de éstos, preferiblemente en donde dichos hidrocarburos se seleccionan del grupo que consiste en isopentano, pentano normal, ciclopentano, butano e isobutano, y combinaciones de dos o más de éstos, y/o preferiblemente en donde el fluoroalqueno de fórmula (I) es HFCO-1233zd y/o en donde los éteres C1-C4 son un éter tal como dimetil-éter y dietil-éter, o un diéter tal como dimetoxi-metano y dietoxi-metano.
-
- 5.
- Un agente de soplado según la reivindicación 4, en donde el agente de soplado es ciclopentano, preferiblemente en una cantidad de aproximadamente 5% en peso a aproximadamente 80% en peso de la composición de agente de soplado total.
-
- 6.
- El agente de soplado de cualquier reivindicación precedente, en donde dicho al menos un compuesto de Fórmula
(I) está presente en la composición en cantidades de al menos 5% en peso del agente de soplado. -
- 7.
- Una composición espumable que comprende un agente formador de espuma y un agente de soplado según cualquier reivindicación precedente, preferiblemente en donde dicho agente formador de espuma comprende al menos un componente de espuma termoendurecible, preferiblemente seleccionado de una composición capaz de formar una espuma de poliuretano, comprendiendo un componente termoendurecible una composición capaz de formar una espuma de poliisocianurato o una composición capaz de formar composiciones de espuma fenólicas.
-
- 8.
- Una composición de premezcla de espuma que comprende poliol y un agente de soplado según cualquier reivindicación precedente.
-
- 9.
- Un método de formar una espuma, que comprende añadir a una composición espumable y/o espumante un agente de soplado según cualquier reivindicación precedente.
-
- 10.
- Un método de formar una espuma de poliuretano o poliisocianurato, que comprende combinar un isocianato, un poliol o mezcla de polioles y un agente de soplado según cualquier reivindicación precedente; y otros materiales tales como catalizadores, tensioactivos, ignífugos, colorantes u otros aditivos.
-
- 11.
- Una composición de premezcla, que comprende:
- (a)
- un primer componente que comprende un isocianato; y
- (b)
- un segundo componente que comprende un poliol o mezcla de polioles, un tensioactivo, un catalizador, un ignífugo y un agente de soplado según cualquier reivindicación precedente.
-
- 12.
- Un método de formar una espuma de poliuretano o de poliisocianurato, mezclando el primer y segundo componentes según se define en la reivindicación 11.
-
- 13.
- Un método de formar una espuma de un componente, preferiblemente una espuma de poliuretano que contiene un agente de soplado según cualquier reivindicación precedente.
-
- 14.
- Un método para la producción de una espuma termoendurecible según una cualquiera de las reivindicaciones 9, 10, 11, 12 ó 13, en el que la composición de agente de soplado comprende iso-pentano, pentano normal y/o ciclopentano, preferiblemente en una cantidad de aproximadamente 5% en peso a aproximadamente 80% en peso
de la composición de agente de soplado total. -
- 15.
- Una espuma que comprende una pluralidad de celdillas poliméricas y una composición contenida en al menos una de dichas celdillas, comprendiendo dicha composición:
5 (a) al menos un agente de soplado según cualquier reivindicación precedente, preferiblemente en donde la espuma es una espuma termoendurecible, preferiblemente seleccionada de poliuretano, poliisocianurato y espuma fenólica, o preferiblemente, en donde la espuma es una espuma termoplástica, preferiblemente una espuma termoplástica extrudida.10 16. La espuma de la reivindicación 15, en forma de uno o más de un bloque, una plancha, un estratificado, un panel preparado in situ, una espuma aplicada por pulverización, una espuma rígida, una espuma de celdillas abiertas, una espuma de celdillas cerradas, una espuma flexible, una espuma de piel integral, una espuma para refrigeradores, una espuma de panel, una espuma para refrigeradores/congeladores o una espuma para congeladores.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US69385305P | 2005-06-24 | 2005-06-24 | |
| US693853P | 2005-06-24 | ||
| US78473106P | 2006-03-21 | 2006-03-21 | |
| US784731P | 2006-03-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2464528T1 true ES2464528T1 (es) | 2014-06-03 |
Family
ID=37595995
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES13166417.9T Pending ES2464528T1 (es) | 2005-06-24 | 2006-06-26 | Agentes espumantes y composiciones que contienen olefinas sustiuidas con flúor, y métodos de espumación |
| ES09173778T Active ES2338519T7 (es) | 2005-06-24 | 2006-06-26 | Espuma de aislamiento térmico que comprende HFO-1233zd como agente de soplado |
| ES13166420.3T Active ES2438525T3 (es) | 2005-06-24 | 2006-06-26 | Espuma termoestable que comprende HFCO-1233zd como agente de expansión |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES09173778T Active ES2338519T7 (es) | 2005-06-24 | 2006-06-26 | Espuma de aislamiento térmico que comprende HFO-1233zd como agente de soplado |
| ES13166420.3T Active ES2438525T3 (es) | 2005-06-24 | 2006-06-26 | Espuma termoestable que comprende HFCO-1233zd como agente de expansión |
Country Status (15)
| Country | Link |
|---|---|
| EP (3) | EP1893715A2 (es) |
| JP (12) | JP2008546892A (es) |
| KR (9) | KR20160018846A (es) |
| CN (1) | CN103497351B (es) |
| CA (1) | CA2613090C (es) |
| DE (3) | DE13166420T1 (es) |
| DK (2) | DK2660282T3 (es) |
| ES (3) | ES2464528T1 (es) |
| HK (1) | HK1243109A1 (es) |
| MX (4) | MX359510B (es) |
| MY (3) | MY155122A (es) |
| PL (1) | PL2154223T6 (es) |
| PT (1) | PT2154223E (es) |
| TW (5) | TW201336906A (es) |
| WO (1) | WO2007002703A2 (es) |
Families Citing this family (80)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090253820A1 (en) * | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
| US20110037016A1 (en) * | 2003-10-27 | 2011-02-17 | Honeywell International Inc. | Fluoropropene compounds and compositions and methods using same |
| US9499729B2 (en) * | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
| US8008244B2 (en) | 2004-04-29 | 2011-08-30 | Honeywell International Inc. | Compositions of tetrafluoropropene and hydrocarbons |
| TWI558685B (zh) * | 2005-06-24 | 2016-11-21 | 哈尼威爾國際公司 | 含有經氟取代之烯烴之組合物 |
| SG166810A1 (en) * | 2005-11-01 | 2010-12-29 | Du Pont | Methods for making foams using blowing agents comprising unsaturated fluorocarbons |
| US9695267B2 (en) | 2009-08-11 | 2017-07-04 | Honeywell International Inc. | Foams and foamable compositions containing halogenated olefin blowing agents |
| US9000061B2 (en) | 2006-03-21 | 2015-04-07 | Honeywell International Inc. | Foams and articles made from foams containing 1-chloro-3,3,3-trifluoropropene (HFCO-1233zd) |
| GB2441006A (en) * | 2006-08-17 | 2008-02-20 | Ineos Fluor Holdings Ltd | Fluid Composition |
| ES2651445T3 (es) * | 2007-03-27 | 2018-01-26 | Dow Global Technologies Llc | Espuma polimérica de calidad de agentes de expansión de alqueno fluorado |
| US11091602B2 (en) | 2007-03-29 | 2021-08-17 | Arkema Inc. | Blowing agent compositions of carbon dioxide and hydrochlorofluoroolefins |
| US9738768B2 (en) | 2007-03-29 | 2017-08-22 | Arkema Inc. | Blowing agent composition of hydrochlorofluoroolefin |
| ES2377420T3 (es) * | 2007-03-29 | 2012-03-27 | Arkema, Inc. | Agentes de expansión de hidrofluoropropeno para poliestireno |
| US8895635B2 (en) | 2007-03-29 | 2014-11-25 | Arkema Inc. | Blowing agent compositions of hydrochlorofluoroolefins |
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