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MX2021013145A - Mezclas compatibilizadas de ester polioles de tereftalato y agentes de expansion de hidrocarburos. - Google Patents

Mezclas compatibilizadas de ester polioles de tereftalato y agentes de expansion de hidrocarburos.

Info

Publication number
MX2021013145A
MX2021013145A MX2021013145A MX2021013145A MX2021013145A MX 2021013145 A MX2021013145 A MX 2021013145A MX 2021013145 A MX2021013145 A MX 2021013145A MX 2021013145 A MX2021013145 A MX 2021013145A MX 2021013145 A MX2021013145 A MX 2021013145A
Authority
MX
Mexico
Prior art keywords
terepthalate
polyol ester
expanding agents
hydrocarbon
blowing agent
Prior art date
Application number
MX2021013145A
Other languages
English (en)
Inventor
Luigi Bertucelli
Giuseppe Vairo
Terra Federico La
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of MX2021013145A publication Critical patent/MX2021013145A/es

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C08G18/4213—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from terephthalic acid and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/09—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture
    • C08G18/092—Processes comprising oligomerisation of isocyanates or isothiocyanates involving reaction of a part of the isocyanate or isothiocyanate groups with each other in the reaction mixture oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/2815—Monohydroxy compounds
    • C08G18/283—Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
    • C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
    • C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/141—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2101/00—Manufacture of cellular products
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0025—Foam properties rigid
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00—Foam properties
    • C08G2110/0041—Foam properties having specified density
    • C08G2110/005—< 50kg/m3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2115/00—Oligomerisation
    • C08G2115/02—Oligomerisation to isocyanurate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2471/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2471/02—Polyalkylene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2487/00—Characterised by the use of unspecified macromolecular compounds, obtained otherwise than by polymerisation reactions only involving unsaturated carbon-to-carbon bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Las composiciones de poliol formuladas contienen un poliol poliéster a base de ácido tereftálico, un agente de expansión de hidrocarburo C4-7 y un tensioactivo no iónico que tiene un equilibrio hidrófilo-lipófilo superior a 13 hasta 18.5. Las composiciones de poliol formuladas exhiben una estabilidad de almacenamiento sorprendentemente buena y resisten la estratificación en capas. Las composiciones son útiles para fabricar espumas rígidas de poliuretano y/o poliisocianurato. La buena compatibilidad del agente de expansión conduce a una estructura celular mejorada en las espumas.
MX2021013145A 2019-05-16 2020-04-20 Mezclas compatibilizadas de ester polioles de tereftalato y agentes de expansion de hidrocarburos. MX2021013145A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT201900006906 2019-05-16
PCT/US2020/028917 WO2020231603A1 (en) 2019-05-16 2020-04-20 Compatibilized blends of terephalate ester polyols and hydrocarbon blowing agents

Publications (1)

Publication Number Publication Date
MX2021013145A true MX2021013145A (es) 2021-12-10

Family

ID=67875946

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2021013145A MX2021013145A (es) 2019-05-16 2020-04-20 Mezclas compatibilizadas de ester polioles de tereftalato y agentes de expansion de hidrocarburos.

Country Status (6)

Country Link
US (1) US20220227916A1 (es)
EP (1) EP3969496A1 (es)
JP (1) JP7617856B2 (es)
CN (1) CN113728028B (es)
MX (1) MX2021013145A (es)
WO (1) WO2020231603A1 (es)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20240368334A1 (en) 2021-07-01 2024-11-07 Evonik Operations Gmbh Production of rigid polyurethane or polyisocyanurate foam
EP4524172A1 (en) 2023-09-12 2025-03-19 PCC ROKITA Spolka Akcyjna Pir and pur-pir polyol composition

Family Cites Families (22)

* Cited by examiner, † Cited by third party
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US5464562A (en) 1995-04-24 1995-11-07 Basf Corporation Polyoxyalkylene polyether monool polyurethane foam additive
DE19620816A1 (de) 1996-05-23 1997-11-27 Wacker Chemie Gmbh Zu flammabweisende Elastomere vernetzbare Organopolysiloxanmassen
US5922779A (en) 1997-10-10 1999-07-13 Stepan Company Polyol blends for producing hydrocarbon-blown polyurethane and polyisocyanurate foams
US6359022B1 (en) 1997-10-10 2002-03-19 Stepan Company Pentane compatible polyester polyols
US6245826B1 (en) 1998-02-09 2001-06-12 Basf Corporation Isocyanate-based rigid foam
JP2000057609A (ja) 1998-08-07 2000-02-25 Toshiba Corp 制御装置
US20030020042A1 (en) * 1999-02-05 2003-01-30 Wilson Joe C. Stable polyester polyol composition
EP1219653A1 (en) * 2000-12-29 2002-07-03 Huntsman International Llc Rigid polyurethane or urethane-modified polyisocyanurate foams and processes for their preparation
WO2004076517A1 (ja) * 2003-02-25 2004-09-10 Sanyo Chemical Industries, Ltd. ポリウレタン樹脂水性分散体およびそれを用いたシート材料
EP1984415B1 (en) 2006-02-15 2011-01-05 Stepan Company Compatibilizing surfactants for polyurethane polyols and resins
JP5437570B2 (ja) * 2006-10-05 2014-03-12 ベック株式会社 硬質ポリウレタンフォーム積層体の形成方法
JP5026896B2 (ja) 2006-12-11 2012-09-19 ベック株式会社 ポリオール組成物及び硬質ポリウレタンフォームの製造方法
EP2165718A1 (de) 2008-09-19 2010-03-24 Bayer MaterialScience AG Wundauflage mit einer Polyurethan-Schaumschicht und einer Deckschicht aus thermoplastischem Polymer
JP5544724B2 (ja) * 2009-02-18 2014-07-09 東ソー株式会社 水性ポリウレタン樹脂組成物およびこれを用いたフィルム成型体
US20110028624A1 (en) * 2009-07-30 2011-02-03 Genovique Specialties Holdings Corporation Polymer Compositions That Include High Solvating Plasticizer And Surfactant
US20140186611A1 (en) * 2011-06-29 2014-07-03 Dow Global Technologies Llc Polyol formulations for improved green strength of polyisocyanurate rigid foams
IN2014CN04925A (es) * 2012-01-02 2015-09-18 Basf Se
EP2722144A1 (de) * 2012-10-19 2014-04-23 Bayer MaterialScience AG Reaktionssystem zur Herstellung von PUR- und PIR Hartschaumstoffen enthaltend Schichtsilikate
JP2014125516A (ja) * 2012-12-26 2014-07-07 Kao Corp 硬質ポリウレタンフォーム製造用ポリオール混合物
JP6568250B2 (ja) 2017-03-02 2019-08-28 株式会社エフコンサルタント 硬化性組成物及び被覆方法
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WO2020076539A1 (en) * 2018-10-09 2020-04-16 Dow Global Technologies Llc A rigid polyurethane foam formulation and foam made therefrom

Also Published As

Publication number Publication date
EP3969496A1 (en) 2022-03-23
JP2022533617A (ja) 2022-07-25
JP7617856B2 (ja) 2025-01-20
CN113728028A (zh) 2021-11-30
US20220227916A1 (en) 2022-07-21
CN113728028B (zh) 2024-09-27
WO2020231603A1 (en) 2020-11-19

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