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DE09173778T1 - Wärmeisolierender Schaumstoff, der HFO-1233zd als Treibmittel enthält - Google Patents

Wärmeisolierender Schaumstoff, der HFO-1233zd als Treibmittel enthält Download PDF

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Publication number
DE09173778T1
DE09173778T1 DE09173778T DE09173778T DE09173778T1 DE 09173778 T1 DE09173778 T1 DE 09173778T1 DE 09173778 T DE09173778 T DE 09173778T DE 09173778 T DE09173778 T DE 09173778T DE 09173778 T1 DE09173778 T1 DE 09173778T1
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DE
Germany
Prior art keywords
foam
hfco
blowing agent
trifluoropropene
chloro
Prior art date
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Pending
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DE09173778T
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English (en)
Inventor
James M. Geneva Bowman
David J. Williams
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Honeywell International Inc
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Honeywell International Inc
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=37595995&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE09173778(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Honeywell International Inc filed Critical Honeywell International Inc
Publication of DE09173778T1 publication Critical patent/DE09173778T1/de
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/144Halogen containing compounds containing carbon, halogen and hydrogen only
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143Halogen containing compounds
    • C08J9/144Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/22After-treatment of expandable particles; Forming foamed products
    • C08J9/228Forming foamed products
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/02Halogenated hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00Compositions of unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/12Organic compounds only containing carbon, hydrogen and oxygen atoms, e.g. ketone or alcohol
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/14Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/16Unsaturated hydrocarbons
    • C08J2203/162Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/18Binary blends of expanding agents
    • C08J2203/182Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00Foams characterized by the expanding agent
    • C08J2203/20Ternary blends of expanding agents
    • C08J2203/202Ternary blends of expanding agents of physical blowing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2361/00Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
    • C08J2361/04Condensation polymers of aldehydes or ketones with phenols only
    • C08J2361/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04Polyurethanes

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Molding Of Porous Articles (AREA)

Abstract

Wärmedämmschaum, umfassend mehrere Polymerzellen und eine in mindestens einer der Zellen enthaltene Zusammensetzung, die mindestens ein HFCO-1233zd (1-Chlor-3,3,3-trifluorpropen) umfassendes Treibmittel umfaßt.

Claims (14)

  1. Wärmedämmschaum, umfassend mehrere Polymerzellen und eine in mindestens einer der Zellen enthaltene Zusammensetzung, die mindestens ein HFCO-1233zd (1-Chlor-3,3,3-trifluorpropen) umfassendes Treibmittel umfaßt.
  2. Wärmedämmschaum nach Anspruch 1, bei dem es sich um einen geschlossenzelligen Schaum handelt.
  3. Schaum nach Anspruch 1 mit einem k-Faktor (BTU in/h ft2 °F) bei 40°F von höchstens etwa 0,14, vorzugsweise höchstens 0,135, vorzugsweise höchstens 0,13.
  4. Schaum nach Anspruch 1 mit einem k-Faktor (BTU in/h ft2 °F) bei 75°F von höchstens etwa 0,16, vorzugsweise höchstens 0,15, vorzugsweise höchstens 0,145.
  5. Schaum nach Anspruch 1, bei dem es sich um einen Polyurethanschaum, einen Polyisocyanuratschaum oder einen Phenolschaum handelt.
  6. Schaum nach Anspruch 1, wobei das Treibmittel aus HFCO-1233zd besteht.
  7. Schaum nach Anspruch 1, wobei das HFCO-1233zd in dem Treibmittel in Mengen von etwa 5 Gew.-% bis etwa 95 Gew.-%, bezogen auf das Treibmittel, vorliegt.
  8. Schaum nach Anspruch 1, wobei es sich bei dem HFCO-1233zd um cis-HFCO-1233zd handelt.
  9. Schaum nach Anspruch 1, wobei es sich bei dem HFCO-1233zd um trans-HFCO-1233zd handelt.
  10. Schaum nach Anspruch 1, wobei die Zusammensetzung ferner mindestens ein Cotreibmittel enthält.
  11. Schaum nach Anspruch 1, wobei das mindestens eine Cotreibmittel aus der Gruppe bestehend aus Wasser, CO2, FCKWs, H-CKWs, H-FCKWs, C1-C5-Alkoholen, C1-C4-Aldehyden, C1-C4-Ketonen, C1-C4-Ethern und Kombinationen von zwei oder mehr davon ausgewählt ist.
  12. Wärmedämmschaum nach einem der vorhergehenden Ansprüche, bei dem es sich um einen duroplastischen Schaum handelt, der gegenüber unter Verwendung des gleichen Treibmittels in der gleichen Menge, aber ohne HFCO-1233zd (1-Chlor-3,3,3-trifluorpropen), hergestellten Schäumen eine verbesserte Wärmeleitfähigkeit aufweist.
  13. Verfahren zur Bereitstellung eines Wärmedämmschaums nach einem der vorhergehenden Ansprüche, bei dem man (a) eine Treibmittelzusammensetzung, die mindestens ein HFCO-1233zd (1-Chlor-3,3,3-trifluorpropen) umfassendes Treibmittel umfaßt, bereitstellt; (b) die Treibmittelzusammensetzung zu einer verschäumbaren Zusammensetzung gibt und (c) die verschäumbare Zusammensetzung zur Bildung eines Schaums oder einer zelligen Struktur zur Reaktion bringt.
  14. Verwendung von HFCO-1233zd (1-Chlor-3,3,3-trifluorpropen) zur Verbesserung der Wärmeleitfähigkeit eines duroplastischen Wärmedämmschaums gegenüber unter Verwendung des gleichen Treibmittels in der gleichen Menge, aber ohne HFCO-1233zd (1-Chlor-3,3,3-trifluorpropen), hergestellten Schäumen.
DE09173778T 2005-06-24 2006-06-26 Wärmeisolierender Schaumstoff, der HFO-1233zd als Treibmittel enthält Pending DE09173778T1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US69385305P 2005-06-24 2005-06-24
US693853P 2005-06-24
US78473106P 2006-03-21 2006-03-21
US784731P 2006-03-21

Publications (1)

Publication Number Publication Date
DE09173778T1 true DE09173778T1 (de) 2010-08-26

Family

ID=37595995

Family Applications (3)

Application Number Title Priority Date Filing Date
DE13166420.3T Pending DE13166420T1 (de) 2005-06-24 2006-06-26 Schaumbildner und Zusammensetzungen mit fluorsubstituierten Olefinen sowie Schäumungsverfahren
DE13166417.9T Pending DE13166417T1 (de) 2005-06-24 2006-06-26 Schaumbildner und Zusammensetzungen mit fluorsubstituierten Olefinen sowie Schäumungsverfahren
DE09173778T Pending DE09173778T1 (de) 2005-06-24 2006-06-26 Wärmeisolierender Schaumstoff, der HFO-1233zd als Treibmittel enthält

Family Applications Before (2)

Application Number Title Priority Date Filing Date
DE13166420.3T Pending DE13166420T1 (de) 2005-06-24 2006-06-26 Schaumbildner und Zusammensetzungen mit fluorsubstituierten Olefinen sowie Schäumungsverfahren
DE13166417.9T Pending DE13166417T1 (de) 2005-06-24 2006-06-26 Schaumbildner und Zusammensetzungen mit fluorsubstituierten Olefinen sowie Schäumungsverfahren

Country Status (15)

Country Link
EP (3) EP1893715A2 (de)
JP (12) JP2008546892A (de)
KR (9) KR20160018846A (de)
CN (1) CN103497351B (de)
CA (1) CA2613090C (de)
DE (3) DE13166420T1 (de)
DK (2) DK2660282T3 (de)
ES (3) ES2464528T1 (de)
HK (1) HK1243109A1 (de)
MX (4) MX359510B (de)
MY (3) MY155122A (de)
PL (1) PL2154223T6 (de)
PT (1) PT2154223E (de)
TW (5) TW201336906A (de)
WO (1) WO2007002703A2 (de)

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