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EP2978019B1 - Procédé de fabrication de corps assemblé et procédé de fabrication de substrat de module de puissance - Google Patents

Procédé de fabrication de corps assemblé et procédé de fabrication de substrat de module de puissance Download PDF

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Publication number
EP2978019B1
EP2978019B1 EP14769861.7A EP14769861A EP2978019B1 EP 2978019 B1 EP2978019 B1 EP 2978019B1 EP 14769861 A EP14769861 A EP 14769861A EP 2978019 B1 EP2978019 B1 EP 2978019B1
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Prior art keywords
copper
ceramic substrate
filler metal
manufacturing
metal
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German (de)
English (en)
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EP2978019A1 (fr
EP2978019A4 (fr
Inventor
Nobuyuki Terasaki
Yoshiyuki Nagatomo
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Mitsubishi Materials Corp
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Mitsubishi Materials Corp
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/48—Manufacture or treatment of parts, e.g. containers, prior to assembly of the devices, using processes not provided for in a single one of the groups H01L21/18 - H01L21/326 or H10D48/04 - H10D48/07
    • H01L21/4814—Conductive parts
    • H01L21/4846—Leads on or in insulating or insulated substrates, e.g. metallisation
    • H01L21/4853—Connection or disconnection of other leads to or from a metallisation, e.g. pins, wires, bumps
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00—Details of semiconductor or other solid state devices
    • H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
    • H01L23/36—Selection of materials, or shaping, to facilitate cooling or heating, e.g. heatsinks
    • H01L23/373—Cooling facilitated by selection of materials for the device or materials for thermal expansion adaptation, e.g. carbon
    • H01L23/3735—Laminates or multilayers, e.g. direct bond copper ceramic substrates
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B37/00—Joining burned ceramic articles with other burned ceramic articles or other articles by heating
    • C04B37/02—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles
    • C04B37/023—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used
    • C04B37/026—Joining burned ceramic articles with other burned ceramic articles or other articles by heating with metallic articles characterised by the interlayer used consisting of metals or metal salts
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/12—Metallic interlayers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/12—Metallic interlayers
    • C04B2237/121—Metallic interlayers based on aluminium
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/12—Metallic interlayers
    • C04B2237/122—Metallic interlayers based on refractory metals
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/12—Metallic interlayers
    • C04B2237/124—Metallic interlayers based on copper
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/02—Aspects relating to interlayers, e.g. used to join ceramic articles with other articles by heating
    • C04B2237/12—Metallic interlayers
    • C04B2237/126—Metallic interlayers wherein the active component for bonding is not the largest fraction of the interlayer
    • C04B2237/127—The active component for bonding being a refractory metal
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/32—Ceramic
    • C04B2237/36—Non-oxidic
    • C04B2237/366—Aluminium nitride
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/30—Composition of layers of ceramic laminates or of ceramic or metallic articles to be joined by heating, e.g. Si substrates
    • C04B2237/40—Metallic
    • C04B2237/407—Copper
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/70—Forming laminates or joined articles comprising layers of a specific, unusual thickness
    • C04B2237/708—Forming laminates or joined articles comprising layers of a specific, unusual thickness of one or more of the interlayers
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2237/00—Aspects relating to ceramic laminates or to joining of ceramic articles with other articles by heating
    • C04B2237/50—Processing aspects relating to ceramic laminates or to the joining of ceramic articles with other articles by heating
    • C04B2237/72—Forming laminates or joined articles comprising at least two interlayers directly next to each other
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
    • H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
    • H01L2224/26—Layer connectors, e.g. plate connectors, solder or adhesive layers; Manufacturing methods related thereto
    • H01L2224/31—Structure, shape, material or disposition of the layer connectors after the connecting process
    • H01L2224/32—Structure, shape, material or disposition of the layer connectors after the connecting process of an individual layer connector
    • H01L2224/321—Disposition
    • H01L2224/32151—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive
    • H01L2224/32221—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked
    • H01L2224/32225—Disposition the layer connector connecting between a semiconductor or solid-state body and an item not being a semiconductor or solid-state body, e.g. chip-to-substrate, chip-to-passive the body and the item being stacked the item being non-metallic, e.g. insulating substrate with or without metallisation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L23/00—Details of semiconductor or other solid state devices
    • H01L23/34—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements
    • H01L23/46—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements involving the transfer of heat by flowing fluids
    • H01L23/473—Arrangements for cooling, heating, ventilating or temperature compensation ; Temperature sensing arrangements involving the transfer of heat by flowing fluids by flowing liquids

Definitions

  • Patent Document 1 when the ceramic substrate and the copper sheets are bonded together using the Ag-Cu-Ti-based brazing filler metal, there is a problem in that the high melting point of the Ag-Cu-Ti-based brazing filler metal causes the ceramic substrate to be degraded due to heat.
  • the copper member and the active metal material through solid-phase diffusion bonding during the heating treatment, and it becomes possible to suppress the generation of bumps on the bonding interface caused by the generation of the liquid phases of Cu and the active metal in the bonding interface and a change in the thickness.
  • the active metal since the active metal is interposed between the liquid-phase filler metal and the copper member, the liquid-phase filler metal does not come into direct contact with the copper member, and it is possible to reliably suppress the generation of bumps on the bonding interface and a change in the thickness.
  • the active metal material may be a Ti material.
  • Ti is melted into the liquid-phase filler metal, and thus the surface of the ceramic substrate can be reliably wetted with the liquid-phase filler metal, and it becomes possible to reliably bond the ceramic member and the copper member.
  • another aspect of the method for manufacturing a power-module substrate of the present invention is a method for manufacturing a power-module substrate having a ceramic substrate, a circuit layer made of copper or a copper alloy, and a metal layer made of copper or a copper alloy, the circuit layer being disposed on one surface of the ceramic substrate, and the metal layer being disposed on the other surface of the ceramic substrate, in which the ceramic substrate and the circuit layer may be bonded together using the above-described method for manufacturing a bonded body. After bonding the circuit layer to one surface of the ceramic substrate, the metal layer may be bonded to the other surface of the ceramic substrate. Therefore, it is possible to form the circuit layer at a relatively low temperature, and thus degradation of the ceramic substrate during bonding can be suppressed.
  • the method for manufacturing a power-module substrate of the present invention is a method for manufacturing a power-module substrate having a ceramic substrate, a circuit layer made of copper or a copper alloy, and a metal layer made of copper or a copper alloy, the circuit layer being disposed on one surface of the ceramic substrate, and the metal layer being disposed on the other surface of the ceramic substrate, in which the circuit layer and the metal layer may be bonded onto both surfaces of the ceramic substrate respectively using the above-described method for manufacturing the bonded body. Therefore, it is possible to form the circuit layer at a relatively low temperature, and thus degradation of the ceramic substrate during bonding can be suppressed.
  • the bonding layer 2 for example, a Sn-Ag-based solder material, a Sn-In-based solder material, or a Sn-Ag-Cu-based solder material is used.
  • the ceramic substrate 11, the filler metals 25, the active metal materials 26, and the copper sheets 22 and 23 are loaded and heated in a vacuum-heating furnace in a state of being pressurized in the lamination direction at 1 kgf/cm 2 to 35 kgf/cm 2 (98 kPa to 3430 kPa) (heating treatment step S02).
  • the pressure in the vacuum-heating furnace is set in a range of 10 -6 Pa to 10 -3 Pa
  • the heating temperature is set in a range of 560°C to 650°C
  • the heating time is set in a range of 30 minutes to 360 minutes.
  • the melting point of the filler metal 25 is set to 710°C or lower, it is possible to make the filler metal form a liquid phase at a lower temperature than in a case in which the Ag-Cu-Ti-based brazing filler metal is used.
  • the ceramic substrate 11 and the copper sheets 22 and 23 are bonded together using the filler metals 25 which do not contain Ag, it is possible to reduce the manufacturing cost more than in a case in which the Ag-Cu-Ti-based brazing filler metal is used.
  • the power-module substrate 110 includes the ceramic substrate 11, the circuit layer 112 disposed on one surface (the upper surface in Fig. 5 ) of the ceramic substrate 11, and a metal layer 113 disposed on the other side (the lower surface in Fig. 5 ) of the ceramic substrate 11.
  • the circuit layer 112 is formed by bonding a conductive metal sheet of copper or a copper alloy to one surface of the ceramic substrate 11.
  • the circuit layer 112 is formed by bonding a rolled sheet of copper having a purity of 99.99% by mass or greater.
  • the thickness of the circuit layer 112 is set in a range of 0.1 mm to 1.0 mm and, in the present embodiment, is set to 0.4 mm.
  • the semiconductor element 3 is bonded to the upper surface of the circuit layer 112 in the power-module substrate 110 through a solder material (semiconductor element-bonding step S15).
  • the brazing filler metals are disposed on the copper member sides, and the heating treatment is carried out, it is also possible to bond the ceramic member and the copper member.
  • a filler metal 225 is disposed between the active metal material 226 and a copper member 222, and a heating treatment is carried out in a state in which the active metal material and the filler metal are laminated and pressured in the lamination direction, the active metal material 226 and the copper member 222 can be bonded together.
  • an aluminum sheet having a purity of 99.99% was laminated on the other surface of the ceramic substrate through an Al-Si-based brazing filler metal, the components were loaded and heated in a vacuum-heating furnace at 640°C for 30 minutes in a state of being pressurized in the lamination direction at a pressure of 5 kgf/cm 2 (490 kPa), whereby an aluminum sheet was bonded to the other surface of the ceramic substrate, and a power-module substrate of Invention Example 11 was obtained.
  • the initial bonding area referred to an area to be bonded before bonding, that is, the area of the circuit layer in the present embodiment.
  • the ultrasonic flaw detector exfoliation was observed at white portions in the bonding portion, and thus the area of these white portions was considered as the exfoliation area.
  • Bonding rate % Initial bonding area ⁇ Exfoliation area Initial bonding area ⁇ 100
  • the present invention relates to a method for manufacturing a power-module substrate in which a ceramic member and a copper member can be bonded together at a low temperature and, furthermore, the manufacturing cost is low.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • General Physics & Mathematics (AREA)
  • Physics & Mathematics (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Cooling Or The Like Of Semiconductors Or Solid State Devices (AREA)
  • Ceramic Products (AREA)

Claims (12)

  1. Procédé de fabrication d'un corps collé formé par collage d'un organe en céramique constitué d'un organe en céramique et d'un organe en cuivre constitué de cuivre ou d'un alliage de cuivre, le procédé comprenant :
    une étape de stratification consistant à stratifier l'organe en céramique et l'organe en cuivre par l'intermédiaire d'un matériau de métal actif et d'un métal de charge ayant un point de fusion de 710 °C ou moins ; et
    une étape de traitement thermique consistant à chauffer l'organe en céramique et l'organe en cuivre stratifiés ensemble pour coller l'organe en céramique et l'organe en cuivre dans un état où ils sont soumis dans la direction de stratification à une pression de 0,098 MPa à 3,43 MPa (1 kgf/cm2 à 35 kgf/cm2),
    dans lequel le métal de charge est un métal de charge de brasage ayant une température du liquidus de 450 °C ou plus ou un matériau de soudure ayant une température du liquidus inférieure à 450 °C,
    le métal de charge de brasage est l'un quelconque choisi dans le groupe d'un métal de charge de brasage à base de Cu-P, d'un métal de charge de brasage à base de Cu-Sn et d'un métal de charge de brasage à base de Cu-Al, et
    le matériau de soudure est un matériau de soudure à base de Cu-P-Sn-Ni ou un matériau de soudure à base de Cu-Sn.
  2. Procédé de fabrication d'un corps collé selon la revendication 1,
    dans lequel le métal de charge est disposé sur l'organe en céramique, et le matériau de métal actif est disposé sur l'organe en cuivre dans l'étape de stratification.
  3. Procédé de fabrication d'un corps collé selon la revendication 1 ou 2,
    dans lequel le métal de charge est le métal de charge de brasage.
  4. Procédé de fabrication d'un corps collé selon la revendication 1,
    dans lequel le métal de charge de brasage est le métal de charge de brasage à base de Cu-P ou le métal de charge de brasage à base de Cu-Al.
  5. Procédé de fabrication d'un corps collé selon la revendication 1 ou 2,
    dans lequel le métal de charge est le matériau de soudure.
  6. Procédé de fabrication d'un corps collé selon la revendication 1,
    dans lequel le matériau de soudure est le matériau de soudure à base de Cu-P-Sn-Ni.
  7. Procédé de fabrication d'un corps collé selon l'une quelconque des revendications 1 à 6,
    dans lequel le matériau de métal actif est un matériau de Ti.
  8. Procédé de fabrication d'un substrat de module de puissance ayant un substrat en céramique et une couche de circuit constituée de cuivre ou d'un alliage de cuivre, la couche de circuit étant disposée sur une première surface du substrat en céramique, le procédé comprenant
    le collage de la couche de circuit sur la première surface du substrat en céramique au moyen du procédé de fabrication d'un corps collé selon l'une quelconque des revendications 1 à 7.
  9. Procédé de fabrication d'un substrat de module de puissance ayant un substrat en céramique, une couche de circuit constituée de cuivre ou d'un alliage de cuivre, et une couche de métal constituée de cuivre ou d'un alliage de cuivre, la couche de circuit étant disposée sur une première surface du substrat en céramique, et la couche de métal étant disposée sur l'autre surface du substrat en céramique, le procédé comprenant :
    le collage de la couche de circuit et de la couche de métal respectivement sur les deux surfaces du substrat en céramique au moyen du procédé de fabrication d'un corps collé selon l'une quelconque des revendications 1 à 7.
  10. Procédé de fabrication d'un substrat de module de puissance ayant un substrat en céramique, une couche de circuit constituée de cuivre ou d'un alliage de cuivre, et une couche de métal constituée d'aluminium ou d'un alliage d'aluminium, la couche de circuit étant disposée sur une première surface du substrat en céramique, et la couche de métal étant disposée sur l'autre surface du substrat en céramique, le procédé comprenant :
    le collage de la couche de circuit sur la première surface du substrat en céramique au moyen du procédé de fabrication d'un corps collé selon l'une quelconque des revendications 1 à 7, et
    le collage de la couche de métal sur l'autre surface du substrat en céramique après collage du substrat en céramique et de la couche de circuit.
  11. Procédé de fabrication d'un corps collé selon la revendication 2,
    dans lequel une épaisseur du métal de charge est de 5 µm à 150 µm.
  12. Procédé de fabrication d'un corps collé selon la revendication 2,
    dans lequel une épaisseur du matériau de métal actif est de 1 µm à 20 µm.
EP14769861.7A 2013-03-18 2014-03-17 Procédé de fabrication de corps assemblé et procédé de fabrication de substrat de module de puissance Active EP2978019B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2013055517A JP5672324B2 (ja) 2013-03-18 2013-03-18 接合体の製造方法及びパワーモジュール用基板の製造方法
PCT/JP2014/057121 WO2014148425A1 (fr) 2013-03-18 2014-03-17 Procédé de fabrication de corps collé et procédé de fabrication de substrat de module de puissance

Publications (3)

Publication Number Publication Date
EP2978019A1 EP2978019A1 (fr) 2016-01-27
EP2978019A4 EP2978019A4 (fr) 2016-11-02
EP2978019B1 true EP2978019B1 (fr) 2018-01-31

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US (1) US10199237B2 (fr)
EP (1) EP2978019B1 (fr)
JP (1) JP5672324B2 (fr)
KR (1) KR102220852B1 (fr)
CN (1) CN105190869B (fr)
TW (1) TWI609461B (fr)
WO (1) WO2014148425A1 (fr)

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JP6111764B2 (ja) * 2013-03-18 2017-04-12 三菱マテリアル株式会社 パワーモジュール用基板の製造方法
JP5672324B2 (ja) 2013-03-18 2015-02-18 三菱マテリアル株式会社 接合体の製造方法及びパワーモジュール用基板の製造方法
JP6079505B2 (ja) 2013-08-26 2017-02-15 三菱マテリアル株式会社 接合体及びパワーモジュール用基板
JP6127833B2 (ja) * 2013-08-26 2017-05-17 三菱マテリアル株式会社 接合体の製造方法及びパワーモジュール用基板の製造方法
KR102131484B1 (ko) * 2013-08-26 2020-07-07 미쓰비시 마테리알 가부시키가이샤 접합체 및 파워 모듈용 기판
JP5720839B2 (ja) * 2013-08-26 2015-05-20 三菱マテリアル株式会社 接合体及びパワーモジュール用基板
JP6256176B2 (ja) 2014-04-25 2018-01-10 三菱マテリアル株式会社 接合体の製造方法、パワーモジュール用基板の製造方法
CN109075135B (zh) * 2016-01-22 2022-04-05 三菱综合材料株式会社 接合体、功率模块用基板、接合体的制造方法及功率模块用基板的制造方法
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WO2014148425A1 (fr) 2014-09-25
EP2978019A1 (fr) 2016-01-27
JP2014183118A (ja) 2014-09-29
US10199237B2 (en) 2019-02-05
TW201508870A (zh) 2015-03-01
EP2978019A4 (fr) 2016-11-02
CN105190869A (zh) 2015-12-23
US20160013073A1 (en) 2016-01-14
KR20150133194A (ko) 2015-11-27
TWI609461B (zh) 2017-12-21
CN105190869B (zh) 2018-08-10
KR102220852B1 (ko) 2021-02-25

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