EP1107338B1 - Lithium manganese compound oxide and non-aqueous electrolyte secondary battery - Google Patents
Lithium manganese compound oxide and non-aqueous electrolyte secondary battery Download PDFInfo
- Publication number
- EP1107338B1 EP1107338B1 EP00125329A EP00125329A EP1107338B1 EP 1107338 B1 EP1107338 B1 EP 1107338B1 EP 00125329 A EP00125329 A EP 00125329A EP 00125329 A EP00125329 A EP 00125329A EP 1107338 B1 EP1107338 B1 EP 1107338B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- lithium
- lithium manganese
- manganese
- temperature
- manganese oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
- C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/16—Pore diameter
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a lithium manganese compound oxide and a non-aqueous electrolyte secondary battery using the same as a positive electrode active material.
- the non-aqueous electrolyte secondary batteries are larger in volume capacitance density or weight capacitance density and higher in output voltage than the aqueous electrolyte secondary battery. For this reason, the non-aqueous electrolyte secondary batteries are highly attractive for application not only to powers for small devices but also to powers for large devices.
- the content of sulfur is not more than 0.10 % by weight.
- the lithium manganese compound oxide was dried at a temperature of 300°C in an air for 12 hours and then placed at a temperature of 22°C and a relative humidity of 50% for 48 hours and subsequently heated by a thermo-balance at a temperature rising rate of 2°C/min up to 250°C (TGA-7) to find a reduction in weight for evaluation of the re-adsorbed moisture content.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP34017399 | 1999-11-30 | ||
JP34017399A JP3456181B2 (ja) | 1999-11-30 | 1999-11-30 | リチウムマンガン複合酸化物およびそれを用いた非水電解液二次電池 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1107338A2 EP1107338A2 (en) | 2001-06-13 |
EP1107338A3 EP1107338A3 (en) | 2001-08-01 |
EP1107338B1 true EP1107338B1 (en) | 2004-08-18 |
Family
ID=18334437
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00125329A Expired - Lifetime EP1107338B1 (en) | 1999-11-30 | 2000-11-30 | Lithium manganese compound oxide and non-aqueous electrolyte secondary battery |
Country Status (6)
Country | Link |
---|---|
US (1) | US20030091900A1 (ja) |
EP (1) | EP1107338B1 (ja) |
JP (1) | JP3456181B2 (ja) |
KR (1) | KR100397189B1 (ja) |
CN (1) | CN1147950C (ja) |
DE (1) | DE60013075T2 (ja) |
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100373670C (zh) * | 2002-03-01 | 2008-03-05 | 松下电器产业株式会社 | 正极活性物质及其制造方法以及非水电解质二次电池 |
JP4805545B2 (ja) * | 2004-03-17 | 2011-11-02 | 日本碍子株式会社 | リチウム二次電池 |
KR101132575B1 (ko) | 2006-10-20 | 2012-04-05 | 이화여자대학교 산학협력단 | 망간 산화물 나노구조체의 장단축비를 조절하는 방법 및이를 이용한 망간 산화물 나노구조체의 제조방법 |
JP4673286B2 (ja) * | 2006-12-25 | 2011-04-20 | 日本電工株式会社 | So4濃度が質量比で0.31%以下である三酸化二マンガンの製造方法 |
KR100989901B1 (ko) * | 2007-05-07 | 2010-10-26 | 한양대학교 산학협력단 | 리튬 이차 전지용 양극 활물질의 제조방법, 이 방법으로제조된 리튬 이차 전지용 양극 활물질 및 이를 포함하는리튬 이차 전지 |
JP5278332B2 (ja) * | 2008-07-09 | 2013-09-04 | パナソニック株式会社 | リチウム一次電池用電解二酸化マンガンとその製造方法およびそれを用いたリチウム一次電池 |
WO2010038424A1 (ja) * | 2008-10-01 | 2010-04-08 | 戸田工業株式会社 | 非水電解液二次電池用マンガン酸リチウム粒子粉末及びその製造方法、並びに非水電解液二次電池 |
US20110070491A1 (en) * | 2009-08-28 | 2011-03-24 | Sion Power Corporation | Electrochemical cells comprising porous structures comprising sulfur |
JP5544798B2 (ja) * | 2009-09-14 | 2014-07-09 | 東ソー株式会社 | マンガン酸リチウムの製造方法及びそれに用いる二酸化マンガン |
CN102347479A (zh) * | 2010-08-06 | 2012-02-08 | 无锡晶石新型能源有限公司 | 一种加工锂离子电池用电解二氧化锰的方法及装置 |
US8980126B2 (en) | 2010-10-08 | 2015-03-17 | Semiconductor Energy Laboratory Co., Ltd. | Electrode material and method for manufacturing power storage device |
WO2012090749A1 (ja) * | 2010-12-28 | 2012-07-05 | 三井金属鉱業株式会社 | リチウム二次電池用正極活物質の製造方法 |
US9118077B2 (en) | 2011-08-31 | 2015-08-25 | Semiconductor Energy Laboratory Co., Ltd. | Manufacturing method of composite oxide and manufacturing method of power storage device |
US9249524B2 (en) | 2011-08-31 | 2016-02-02 | Semiconductor Energy Laboratory Co., Ltd. | Manufacturing method of composite oxide and manufacturing method of power storage device |
WO2013100070A1 (ja) * | 2011-12-27 | 2013-07-04 | 三井金属鉱業株式会社 | スピネル型リチウムマンガン遷移金属酸化物 |
KR101542050B1 (ko) | 2012-04-17 | 2015-08-06 | 주식회사 엘지화학 | 낮은 함습성의 전극 활물질 및 이를 포함하는 리튬 이차전지 |
JP6253106B2 (ja) * | 2012-05-14 | 2017-12-27 | Necエナジーデバイス株式会社 | 二次電池用正極電極、二次電池、及びそれらの製造方法 |
KR102228322B1 (ko) * | 2012-11-13 | 2021-03-15 | 도다 고교 가부시끼가이샤 | 비수전해질 이차 전지용 망간산리튬 입자 분말 및 그의 제조 방법, 및 비수전해질 이차 전지 |
JP6470070B2 (ja) * | 2014-08-25 | 2019-02-13 | 株式会社東芝 | 正極及び非水電解質電池 |
CN114933332A (zh) * | 2022-06-06 | 2022-08-23 | 安徽博石高科新材料股份有限公司 | 一种复合原料生产锰酸锂的方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE69601679T2 (de) * | 1995-09-06 | 1999-07-22 | Fuji Photo Film Co., Ltd., Minami-Ashigara, Kanagawa | Lithium-Ionen Sekundärbatterie |
US5792442A (en) * | 1995-12-05 | 1998-08-11 | Fmc Corporation | Highly homogeneous spinel Li1+X Mn2-X O4 intercalation compounds and method for preparing same |
JPH09245836A (ja) * | 1996-03-08 | 1997-09-19 | Fuji Photo Film Co Ltd | 非水電解質二次電池 |
JP3929548B2 (ja) * | 1997-04-21 | 2007-06-13 | ソニー株式会社 | 非水電解液二次電池の製造方法 |
JPH11157841A (ja) * | 1997-12-03 | 1999-06-15 | Mitsui Mining & Smelting Co Ltd | Li−Mn複合酸化物及びその製法、非水電解液二次電池 |
-
1999
- 1999-11-30 JP JP34017399A patent/JP3456181B2/ja not_active Expired - Lifetime
-
2000
- 2000-11-29 KR KR10-2000-0071535A patent/KR100397189B1/ko active IP Right Grant
- 2000-11-30 DE DE60013075T patent/DE60013075T2/de not_active Expired - Lifetime
- 2000-11-30 CN CNB001336568A patent/CN1147950C/zh not_active Expired - Fee Related
- 2000-11-30 EP EP00125329A patent/EP1107338B1/en not_active Expired - Lifetime
- 2000-11-30 US US09/726,019 patent/US20030091900A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
EP1107338A3 (en) | 2001-08-01 |
DE60013075D1 (de) | 2004-09-23 |
CN1147950C (zh) | 2004-04-28 |
KR20010052015A (ko) | 2001-06-25 |
DE60013075T2 (de) | 2005-09-08 |
US20030091900A1 (en) | 2003-05-15 |
CN1305237A (zh) | 2001-07-25 |
KR100397189B1 (ko) | 2003-09-13 |
JP3456181B2 (ja) | 2003-10-14 |
EP1107338A2 (en) | 2001-06-13 |
JP2001155734A (ja) | 2001-06-08 |
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