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EP1107338B1 - Lithium manganese compound oxide and non-aqueous electrolyte secondary battery - Google Patents

Lithium manganese compound oxide and non-aqueous electrolyte secondary battery Download PDF

Info

Publication number
EP1107338B1
EP1107338B1 EP00125329A EP00125329A EP1107338B1 EP 1107338 B1 EP1107338 B1 EP 1107338B1 EP 00125329 A EP00125329 A EP 00125329A EP 00125329 A EP00125329 A EP 00125329A EP 1107338 B1 EP1107338 B1 EP 1107338B1
Authority
EP
European Patent Office
Prior art keywords
lithium
lithium manganese
manganese
temperature
manganese oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP00125329A
Other languages
German (de)
English (en)
French (fr)
Other versions
EP1107338A3 (en
EP1107338A2 (en
Inventor
Tatsuji Numata
Chika Kanbe
Yoshitada Tomioka
Masato Shirakata
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
NEC Corp
Original Assignee
NEC Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by NEC Corp filed Critical NEC Corp
Publication of EP1107338A2 publication Critical patent/EP1107338A2/en
Publication of EP1107338A3 publication Critical patent/EP1107338A3/en
Application granted granted Critical
Publication of EP1107338B1 publication Critical patent/EP1107338B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01GCOMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00Compounds of manganese
    • C01G45/12Complex oxides containing manganese and at least one other metal element
    • C01G45/1221Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1242Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/04Processes of manufacture in general
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/61Micrometer sized, i.e. from 1-100 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00Particle morphology
    • C01P2004/60Particles characterised by their size
    • C01P2004/62Submicrometer sized, i.e. from 0.1-1 micrometer
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/16Pore diameter
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/40Electric properties
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/36Selection of substances as active materials, active masses, active liquids
    • H01M4/48Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present invention relates to a lithium manganese compound oxide and a non-aqueous electrolyte secondary battery using the same as a positive electrode active material.
  • the non-aqueous electrolyte secondary batteries are larger in volume capacitance density or weight capacitance density and higher in output voltage than the aqueous electrolyte secondary battery. For this reason, the non-aqueous electrolyte secondary batteries are highly attractive for application not only to powers for small devices but also to powers for large devices.
  • the content of sulfur is not more than 0.10 % by weight.
  • the lithium manganese compound oxide was dried at a temperature of 300°C in an air for 12 hours and then placed at a temperature of 22°C and a relative humidity of 50% for 48 hours and subsequently heated by a thermo-balance at a temperature rising rate of 2°C/min up to 250°C (TGA-7) to find a reduction in weight for evaluation of the re-adsorbed moisture content.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)
EP00125329A 1999-11-30 2000-11-30 Lithium manganese compound oxide and non-aqueous electrolyte secondary battery Expired - Lifetime EP1107338B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP34017399 1999-11-30
JP34017399A JP3456181B2 (ja) 1999-11-30 1999-11-30 リチウムマンガン複合酸化物およびそれを用いた非水電解液二次電池

Publications (3)

Publication Number Publication Date
EP1107338A2 EP1107338A2 (en) 2001-06-13
EP1107338A3 EP1107338A3 (en) 2001-08-01
EP1107338B1 true EP1107338B1 (en) 2004-08-18

Family

ID=18334437

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00125329A Expired - Lifetime EP1107338B1 (en) 1999-11-30 2000-11-30 Lithium manganese compound oxide and non-aqueous electrolyte secondary battery

Country Status (6)

Country Link
US (1) US20030091900A1 (ja)
EP (1) EP1107338B1 (ja)
JP (1) JP3456181B2 (ja)
KR (1) KR100397189B1 (ja)
CN (1) CN1147950C (ja)
DE (1) DE60013075T2 (ja)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100373670C (zh) * 2002-03-01 2008-03-05 松下电器产业株式会社 正极活性物质及其制造方法以及非水电解质二次电池
JP4805545B2 (ja) * 2004-03-17 2011-11-02 日本碍子株式会社 リチウム二次電池
KR101132575B1 (ko) 2006-10-20 2012-04-05 이화여자대학교 산학협력단 망간 산화물 나노구조체의 장단축비를 조절하는 방법 및이를 이용한 망간 산화물 나노구조체의 제조방법
JP4673286B2 (ja) * 2006-12-25 2011-04-20 日本電工株式会社 So4濃度が質量比で0.31%以下である三酸化二マンガンの製造方法
KR100989901B1 (ko) * 2007-05-07 2010-10-26 한양대학교 산학협력단 리튬 이차 전지용 양극 활물질의 제조방법, 이 방법으로제조된 리튬 이차 전지용 양극 활물질 및 이를 포함하는리튬 이차 전지
JP5278332B2 (ja) * 2008-07-09 2013-09-04 パナソニック株式会社 リチウム一次電池用電解二酸化マンガンとその製造方法およびそれを用いたリチウム一次電池
WO2010038424A1 (ja) * 2008-10-01 2010-04-08 戸田工業株式会社 非水電解液二次電池用マンガン酸リチウム粒子粉末及びその製造方法、並びに非水電解液二次電池
US20110070491A1 (en) * 2009-08-28 2011-03-24 Sion Power Corporation Electrochemical cells comprising porous structures comprising sulfur
JP5544798B2 (ja) * 2009-09-14 2014-07-09 東ソー株式会社 マンガン酸リチウムの製造方法及びそれに用いる二酸化マンガン
CN102347479A (zh) * 2010-08-06 2012-02-08 无锡晶石新型能源有限公司 一种加工锂离子电池用电解二氧化锰的方法及装置
US8980126B2 (en) 2010-10-08 2015-03-17 Semiconductor Energy Laboratory Co., Ltd. Electrode material and method for manufacturing power storage device
WO2012090749A1 (ja) * 2010-12-28 2012-07-05 三井金属鉱業株式会社 リチウム二次電池用正極活物質の製造方法
US9118077B2 (en) 2011-08-31 2015-08-25 Semiconductor Energy Laboratory Co., Ltd. Manufacturing method of composite oxide and manufacturing method of power storage device
US9249524B2 (en) 2011-08-31 2016-02-02 Semiconductor Energy Laboratory Co., Ltd. Manufacturing method of composite oxide and manufacturing method of power storage device
WO2013100070A1 (ja) * 2011-12-27 2013-07-04 三井金属鉱業株式会社 スピネル型リチウムマンガン遷移金属酸化物
KR101542050B1 (ko) 2012-04-17 2015-08-06 주식회사 엘지화학 낮은 함습성의 전극 활물질 및 이를 포함하는 리튬 이차전지
JP6253106B2 (ja) * 2012-05-14 2017-12-27 Necエナジーデバイス株式会社 二次電池用正極電極、二次電池、及びそれらの製造方法
KR102228322B1 (ko) * 2012-11-13 2021-03-15 도다 고교 가부시끼가이샤 비수전해질 이차 전지용 망간산리튬 입자 분말 및 그의 제조 방법, 및 비수전해질 이차 전지
JP6470070B2 (ja) * 2014-08-25 2019-02-13 株式会社東芝 正極及び非水電解質電池
CN114933332A (zh) * 2022-06-06 2022-08-23 安徽博石高科新材料股份有限公司 一种复合原料生产锰酸锂的方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69601679T2 (de) * 1995-09-06 1999-07-22 Fuji Photo Film Co., Ltd., Minami-Ashigara, Kanagawa Lithium-Ionen Sekundärbatterie
US5792442A (en) * 1995-12-05 1998-08-11 Fmc Corporation Highly homogeneous spinel Li1+X Mn2-X O4 intercalation compounds and method for preparing same
JPH09245836A (ja) * 1996-03-08 1997-09-19 Fuji Photo Film Co Ltd 非水電解質二次電池
JP3929548B2 (ja) * 1997-04-21 2007-06-13 ソニー株式会社 非水電解液二次電池の製造方法
JPH11157841A (ja) * 1997-12-03 1999-06-15 Mitsui Mining & Smelting Co Ltd Li−Mn複合酸化物及びその製法、非水電解液二次電池

Also Published As

Publication number Publication date
EP1107338A3 (en) 2001-08-01
DE60013075D1 (de) 2004-09-23
CN1147950C (zh) 2004-04-28
KR20010052015A (ko) 2001-06-25
DE60013075T2 (de) 2005-09-08
US20030091900A1 (en) 2003-05-15
CN1305237A (zh) 2001-07-25
KR100397189B1 (ko) 2003-09-13
JP3456181B2 (ja) 2003-10-14
EP1107338A2 (en) 2001-06-13
JP2001155734A (ja) 2001-06-08

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