EP0429323B2 - Giess-Pfanne mit feuerfester Bodenbeschichtung zur Behandlung von Metall und Verfahren zur Herstellung einer derartigen feuerfesten Beschichtung - Google Patents
Giess-Pfanne mit feuerfester Bodenbeschichtung zur Behandlung von Metall und Verfahren zur Herstellung einer derartigen feuerfesten Beschichtung Download PDFInfo
- Publication number
- EP0429323B2 EP0429323B2 EP90403059A EP90403059A EP0429323B2 EP 0429323 B2 EP0429323 B2 EP 0429323B2 EP 90403059 A EP90403059 A EP 90403059A EP 90403059 A EP90403059 A EP 90403059A EP 0429323 B2 EP0429323 B2 EP 0429323B2
- Authority
- EP
- European Patent Office
- Prior art keywords
- refractory
- ladle
- lining
- independent elements
- joints
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002184 metal Substances 0.000 title claims abstract description 28
- 238000000576 coating method Methods 0.000 title abstract description 17
- 239000011248 coating agent Substances 0.000 title abstract description 16
- 238000000034 method Methods 0.000 title abstract description 3
- 230000000694 effects Effects 0.000 claims description 6
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims 1
- 239000011449 brick Substances 0.000 description 8
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000011819 refractory material Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 238000005266 casting Methods 0.000 description 3
- 238000007789 sealing Methods 0.000 description 3
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910052849 andalusite Inorganic materials 0.000 description 1
- 238000012550 audit Methods 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000010339 dilation Effects 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910001338 liquidmetal Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000000284 resting effect Effects 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/08—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like for bottom pouring
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/02—Linings
Definitions
- the present invention relates to a pocket for the production of a metal comprising a metal envelope provided, on its internal surface, a refractory wall lining and a lining bottom refractory with a tap hole.
- the present invention also has for subject a process for producing such a coating background refractory.
- a continuous flow distributor with a coating whose bottom is in the form of a gutter of semi-cylindrical section is known from document US-A-3,333,746.
- a bottom refractory lining of a metal container in particular a degassing container of molten steel.
- the container has an envelope metallic and a refractory bottom coating having a tap hole eccentric to the center of said bottom surface.
- the tap hole is bordered with curb bricks to which are connected brick belts.
- the metallic envelope has a bottom inclined towards the tap hole and the upper surface of the refractory lining in contact with liquid metal is parallel to the bottom of the envelope.
- the dilations generate, by a detachment in the center, between the covering and the bottom of the pocket, a buckling of said bottom coating.
- This type of deformation can cause rapid deterioration and falling coating background refractory when emptying the slag.
- the object of the present invention is to avoid, among others, the peeling of the coating bottom refractory of a pocket for the elaboration of metal, for example steel.
- the object of the present invention is thus a pocket for the production of metal comprising a metal envelope provided, on its internal surface, a refractory wall lining and a lining bottom refractory with a tap hole, offset from the center of the surface of said refractory lining, characterized in that the metal shell has a flat bottom and horizontal and the refractory lining surface of bottom in contact with the metal being processed, is formed by a concave surface having a shape general spherical and at any point a directed slope towards the tap hole.
- the refractory lining bottom consists of at least one assembly of elements independent separated by seals, said independent elements obtained by molding being produced and arranged in such a way as to create a vault when the pocket is overturned.
- the refractory lining is consisting of at least one layer of security and at least minus a wear layer, the safety layer being constituted by an assembly of independent elements.
- a pocket for making metal for example of steel, comprising a metal casing 1, by cylindrical example, provided on its internal wall 2 with a refractory lining of wall 3 and a lining bottom refractory 4 provided with a taphole 5.
- the bottom refractory lining 4 is composed a refractory layer whose surface 6 in contact with the metal to be worked out is a concave surface presenting at any point a slope directed towards the hole of casting 5.
- the concave shape 6 of the refractory lining of bottom 4 creates an arch effect when the pocket is overturned and therefore the arch effect prevents detachment said bottom refractory lining 4.
- the bottom refractory lining 4 is consisting of an assembly of several independent elements 4a separated by joints 7 of refractory concrete.
- the independent elements 4a constituting the coating background refractory 4 are made, by example by molding, and each have a specific shape for readjustment to each other others in the bottom of the metal casing 1 of the poached. Their arrangement and shape are determined so as to obtain a vault effect when the pocket is overturned.
- the seals 7 are preferably placed, of a on the one hand, concentrically with tap hole 5 and, on the other part, radiating from this same tap hole, said radiating joints being further offset by one concentric joint to each other.
- the side faces of independent elements 4a are provided with grooves 8 forming on the seals 7, projections which block the sliding of said elements 4a relative to each other to others.
- the grooves 8 extend substantially parallel on the surface of the pocket bottom.
- the independent elements are jointed with permanently variable refractory concrete positive residual, other physical properties sealing concrete are close to those refractory material used for the realization of independent elements 4a.
- the sealing concrete which forms the joints 7 is arranged to balance or compensate for deformations of expansion due to the geometry of the assembly independent elements 4a.
- the refractory lining of the wall has at least one security layer 10 and at least minus a wear layer 11, and the refractory lining background has at least one security layer 12 and at least one wear layer 13.
- the wear layers (11, 13) are made of refractory bricks the quality of which is determined by the conditions of use and the stresses undergone in the different parts of the pocket refractory lining. These bricks can be made from aggregates, especially aluminous, dolomite, magnesia.
- the bricks constituting the security layer 10 and the wear layer 11, for example of semi format universal, are supported on an external shoulder 14 of an annular ramp 15 of masonry start bricks of the refractory lining of the wall.
- the outer shoulder 14 defines two surfaces helical supports 16 and 17 respectively.
- the bearing surface 16 has the width of the layer 10 security wall and the bearing surface 17 has the width of the wear layer 11 of the wall.
- outer shoulder 14 is a means of peripheral blocking of the security layer 12 pocket bottom.
- the pocket bottom security layer 12 On the bottom of the pocket is deposited, in the space delimited by the annular ramp 15, the pocket bottom security layer 12, shaped lenticular and having a sealed planar face 12a on the inner face of the bottom of the metal casing 1 and a face 12b having a concave surface sufficiently spherical having at all points a slope towards the tap hole 5.
- the layer wear base 13 On the concave face 12b is masonry the layer wear base 13 in refractory bricks which marries the shape of the concavity.
- the surface 13b of the bottom wear layer 13, in contact with the metal being worked on, defines a sphere whose center is located on the longitudinal axis tap hole 5.
- the annular ramp 15 and the safety layer 12 both consist of the same material which is generally an aluminous concrete based Andalusite. This refractory concrete must have good cold mechanical resistance and pyroscopic resistance acceptable.
- Fig.4 is a top view of the assembly formed of the annular ramp 15 and the safety layer 12 background.
- the annular ramp 15, on which is molded the outer shoulder 14 forming the two ramps helical starting 16 and 17 respectively bricklaying of refractory lining of wall is cast on site.
- the security layer 12 background consists of a set of elements 20 forming a mosaic and grouted with concrete coefficient of thermal expansion slightly higher than the coefficient of thermal expansion refractory material constituting said elements independent 20.
- the other physical properties of sealing concrete constituting the joints 21 between the independent elements 20 are close to those of refractory material used for making said independent elements 20.
- the seals 21 are arranged so as to balance or to compensate for the expansion deformations due to the geometry of the set of independent elements 20.
- the seals 21 are preferably placed, on the one hand concentrically with the tap hole 5 and on the other hand radiating with respect to this same hole of casting 5, the radiating joints being more placed in staggered relative to each other.
- the lateral faces of the independent elements 20 are also provided with a groove 22 which forms, on the seals 21 cast, projections which block the sliding of the independent elements 20 of the layer security 12 relative to each other.
- a mold 30 formed in a template is used. of the refractory lining 4 or the layer 12 bottom security.
- the mold 30 is made up of a cylinder 31 placed on a convex surface 32 producing the curve of the surface of the refractory lining 4 bottom or 12 bottom security layer of pocket.
- the mold 30 is partitioned with walls vertical 33 whose cross section corresponds to the shape seals (7, 21), said vertical walls 33 being placed so as to determine compartments forming molds for the elements (4a, 20) respectively of the refractory lining (4) at the bottom or security layer 12.
- the elements (4a, 20) of specific shape are referenced. They together constitute either a refractory lining 4 at the bottom, i.e. a layer of security 12 of background of homogeneous physical characteristic.
- such a configuration ensures good flow of steel to the tap hole, point bottom of the surface of the refractory lining of the bottom of the pocket being formed by said tap hole.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
- Cookers (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Claims (11)
- Gießpfanne zur Erschmelzung von Metall, mit einer Metallhülle (1), die auf ihrer Innenseite mit einer hochschmelzenden Wandauskleidung (3, 10, 11) und einer hochschmelzenden Bodenauskleidung (4, 12, 13), welche ein Gießloch (5) trägt, welches exentrisch in Bezug auf die Mitte der Oberfläche der hochschmelzenden Bodenauskleidung (4, 12, 13) angeordnet ist, dadurch gekennzeichnet, daß die Metallhülle (1) einen ebenen und horizontalen Boden aufweist, und die Oberfläche der hochschmelzenden Bodenauskleidung (4, 12, 13), die mit dem in Erschmelzung befindlichen Metall in Berühung steht, durch eine konkave Fläche gebildet ist, welche eine allgemein sphärische Form und an allen Stellen eine zum Gießloch (5) gerichtete Neigung aufweist.
- Gießpfanne nach Anspruch 1, dadurch gekennzeichnet, daß die hochschmelzende Bodenauskleidung (4) der Gießpfanne durch wenigstens eine zusammenfügung unabhängiger Elemente (4a) gebildet ist, welche durch Stoßstellen (7) getrennt sind.
- Gießpfanne nach Anspruch 1, dadurch gekennzeichnet, daß die hochschmelzende Bodenauskleidung wenigstens eine Sicherheitsschicht (12) und wenigstens eine Verschleißschicht (13) aufweist, wobei die Sicherheitsschicht (12) durch eine Zusammenfügung von unabhängigen Elementen (20) gebildet ist, die durch Stoßstellen (21) getrennt sind.
- Gießpfanne nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß in der Zusammenfügung von unabhängigen Elementen (4a, 20), welche die hochschmelzende Bodenauskleidung (4, 12) bilden, die unabhängigen Elemente (4a, 20) so vorgesehen und angeordnet sind, daß sie einen Gewölbeeffekt erzeugen, wenn die Gießpfanne umgedreht wird.
- Gießpfanne nach irgendeinem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß die unabhängigen Elemente (4a, 20) durch Gießen gewonnen sind.
- Gießpfanne nach irgendeinem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß die unabhängigen Elemente (4a, 20) Seitenflächen aufweisen, die mit wenigstens einer Kehle (8, 22) versehen sind, die sich im wesentlichen parallel zur Bodenfläche der Gießpfanne erstreckt.
- Gießpfanne nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß die unabhängigen Elemente (4a, 20) mit einem Beton mit permanenter positiver remanenter Maßänderung vergossen sind.
- Gießpfanne nach irgendeinem der vorstehenden Ansprüche, dadurch gekennzeichnet, daß der Aufbau der unabhängigen Elemente (4a, 20) ein Mosaik bildet, von deren Stoßstellen (7, 21) die einen konzentrisch zum Gießloch (5) und die anderen strahlenförmig in Bezug auf die Gießlöcher (5) sind, wobei die strahlenförmigen Stoßstellen von einer konzentrischen Stoßstelle zur anderen versetzt sind.
- Gießpfanne nach Anspruch 3, dadurch gekennzeichnet, daß die Sicherheitsschicht (12) von einem ringförmigen Gürtel (15) umgeben ist, der geeignet ist, eine Mauerungsablauffläche (16, 17) für die hochschmelzende Auskleidung (10, 11) der Wand der Metallhülle (1) zu bilden.
- Gießpfanne nach Anspruch 9, dadurch gekennzeichnet, daß der ringförmige Gürtel (15) mit im wesentlichen vierseitigem Querschnitt eine äußere Schulter (14) aufweist, welche wenigstens eine wendelförmige Anlagefläche (16, 17) bildet, wobei die Anlagefläche (16, 17) eine Breite hat, die der Dicke wenigstens einer hochschmelzenden Auskleidungsschicht (10, 11) der Wand entspricht.
- Verfahren zur Herstellung einer hochschmelzenden Auskleidung für einen Gießpfannenboden nach einem der vorstehenden Ansprüche, dadurch gekennzeichnet, daßeine Form (30) hergestellt wird, die durch einen sphärischen konvexen Boden (32) gebildet ist und vertikale Wände (33) aufweist, die Fächer bilden, welche der Geometrie der hochschmelzenden Bodenauskleidungselemente (4, 12) entsprechen, wobei die Wände (33) einen Querschnitt haben, der demjenigen der Stoßstellen (7, 21) entspricht,in jedes so gebildete Fach ein ausgewählter hochschmelzender Beton (34) gegossen wird,und nach dem Abbinden des Betons unter Etikettierung jedes der Elemente (4a, 20) der hochschmelzenden Bodenauskleidung, welche eine plane Fläche aufweist, die für ein Inanlagekommen am Boden der Pfanne eingerichtet ist, ausgeformt wird.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT90403059T ATE99580T1 (de) | 1989-11-17 | 1990-10-29 | Giess-pfanne mit feuerfester bodenbeschichtung zur behandlung von metall und verfahren zur herstellung einer derartigen feuerfesten beschichtung. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR898915128A FR2654661B1 (fr) | 1989-11-17 | 1989-11-17 | Poche pour l'elaboration d'un metal munie d'un revetement refractaire le fond et procede de realisation d'un tel revetement refractaire de fond. |
FR8915128 | 1989-11-17 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0429323A1 EP0429323A1 (de) | 1991-05-29 |
EP0429323B1 EP0429323B1 (de) | 1994-01-05 |
EP0429323B2 true EP0429323B2 (de) | 1999-07-14 |
Family
ID=9387513
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP90403059A Expired - Lifetime EP0429323B2 (de) | 1989-11-17 | 1990-10-29 | Giess-Pfanne mit feuerfester Bodenbeschichtung zur Behandlung von Metall und Verfahren zur Herstellung einer derartigen feuerfesten Beschichtung |
Country Status (12)
Country | Link |
---|---|
US (1) | US5948349A (de) |
EP (1) | EP0429323B2 (de) |
JP (1) | JPH0747204B2 (de) |
AT (1) | ATE99580T1 (de) |
AU (1) | AU624276B2 (de) |
CA (1) | CA2030128C (de) |
DE (1) | DE69005798T3 (de) |
DK (1) | DK0429323T4 (de) |
FI (1) | FI92982C (de) |
FR (1) | FR2654661B1 (de) |
TR (1) | TR27294A (de) |
ZA (1) | ZA909214B (de) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2684905B1 (fr) * | 1991-12-17 | 1994-02-18 | Boulonnais Terres Refractaires | Garnissage pour recipient tel que fond de poches de coulee. |
US5879616A (en) * | 1996-01-22 | 1999-03-09 | Harbison-Walker Refractories Company | Metallurgical vessel and method of using the same |
DE19802222C2 (de) * | 1998-01-22 | 2002-08-08 | Intocast Ag Feuerfest Produkte | Behälter für metallurgische Schmelzen |
DE19923419A1 (de) * | 1999-05-21 | 2000-11-23 | Truetzschler Gmbh & Co Kg | Vorrichtung an einer Spinnereivorbereitungsmaschine, z. B. Karde, Reiniger o. dgl., zur Messung von Abständen an Garnituren |
BR0108168A (pt) | 2000-02-08 | 2003-02-25 | Foseco Int | Distribuidor, artigo formado a partir de material refratário e método de formar um distribuidor |
US7468161B2 (en) | 2002-04-15 | 2008-12-23 | Ventana Medical Systems, Inc. | Automated high volume slide processing system |
US11249095B2 (en) | 2002-04-15 | 2022-02-15 | Ventana Medical Systems, Inc. | Automated high volume slide processing system |
US8110142B2 (en) * | 2008-02-18 | 2012-02-07 | North American Refractories Co. | High yield ladle bottoms |
US9005518B2 (en) | 2008-02-18 | 2015-04-14 | North American Refractories Co. | High yield ladle bottoms |
KR101548407B1 (ko) | 2008-11-12 | 2015-08-28 | 벤타나 메디컬 시스템즈, 인코포레이티드 | 시료 운반 슬라이드를 가열하기 위한 방법 및 장치 |
CN101791694A (zh) * | 2010-04-08 | 2010-08-04 | 安徽省凤形耐磨材料股份有限公司 | 铸造用扇形坡面缓冲浇口杯 |
CN102328068A (zh) * | 2011-07-08 | 2012-01-25 | 南阳汉冶特钢有限公司 | 一种钢包包底砌筑方法 |
CN102350495A (zh) * | 2011-10-17 | 2012-02-15 | 中钢集团邢台机械轧辊有限公司 | 长寿命的球化处理包 |
SI2752260T1 (sl) | 2013-01-07 | 2017-03-31 | Refractory Intellectual Property Gmbh & Co. Kg | Ognjevarno keramično dno |
EP2796227B9 (de) * | 2013-04-26 | 2016-12-21 | Refractory Intellectual Property GmbH & Co. KG | Gießpfannenboden und Gießpfanne |
CN103334047A (zh) * | 2013-07-09 | 2013-10-02 | 曲沃县民政福利企业有限公司 | 具有引流装置的球化包盖 |
CA2928900C (en) | 2013-12-13 | 2020-04-14 | Ventana Medical Systems, Inc. | Automated histological processing of biological specimens and associated technology |
US9724756B2 (en) * | 2014-05-09 | 2017-08-08 | North America Refractories Company | Refractory component for lining a metallurgical vessel |
CN104384488A (zh) * | 2014-11-04 | 2015-03-04 | 西宁特殊钢股份有限公司 | 一种防止钢水卷渣的钢包设计方法 |
KR101701982B1 (ko) * | 2015-10-30 | 2017-02-02 | 주식회사 포스코 | 정련 장치 및 방법 |
BR102019024046A2 (pt) * | 2019-11-14 | 2021-05-25 | Saint-Gobain do Brasil Produtos Industriais e para Construção Ltda. | método para revestir fundo de panela de aço |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1292582A (en) * | 1915-09-22 | 1919-01-28 | Westinghouse Electric & Mfg Co | Method of reclaiming turnings of readily-oxidizable metals. |
US3333764A (en) * | 1966-02-01 | 1967-08-01 | Vendo Co | Double lock coin box for vending machines |
US3333746A (en) * | 1966-05-19 | 1967-08-01 | Harbison Walker Refractories | Tundish ladles |
AT319988B (de) * | 1970-06-13 | 1975-01-27 | Didier Werke Ag | Feuerfeste Bodenauskleidung für metallurgische Gefäße |
JPS5415877Y2 (de) * | 1974-08-28 | 1979-06-25 | ||
JPS5234822U (de) * | 1975-09-03 | 1977-03-11 | ||
JPS53126920U (de) * | 1977-03-18 | 1978-10-07 | ||
US4608672A (en) * | 1983-07-14 | 1986-08-26 | Honeywell Inc. | Semiconductor memory |
US4746102A (en) * | 1987-03-20 | 1988-05-24 | Bethlehem Steel Corporation | Drain hole design for ladle |
US4942986A (en) * | 1988-07-13 | 1990-07-24 | Lewis Thomas W | Pressurized tundish for controlling a continuous flow of molten metal |
-
1989
- 1989-11-17 FR FR898915128A patent/FR2654661B1/fr not_active Expired - Lifetime
-
1990
- 1990-10-29 AT AT90403059T patent/ATE99580T1/de not_active IP Right Cessation
- 1990-10-29 DK DK90403059T patent/DK0429323T4/da active
- 1990-10-29 DE DE69005798T patent/DE69005798T3/de not_active Expired - Fee Related
- 1990-10-29 EP EP90403059A patent/EP0429323B2/de not_active Expired - Lifetime
- 1990-11-08 AU AU65884/90A patent/AU624276B2/en not_active Ceased
- 1990-11-15 FI FI905658A patent/FI92982C/fi active IP Right Grant
- 1990-11-16 ZA ZA909214A patent/ZA909214B/xx unknown
- 1990-11-16 CA CA002030128A patent/CA2030128C/fr not_active Expired - Lifetime
- 1990-11-16 JP JP2312588A patent/JPH0747204B2/ja not_active Expired - Fee Related
- 1990-12-04 TR TR01099/90A patent/TR27294A/xx unknown
-
1992
- 1992-10-20 US US07/963,524 patent/US5948349A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
ZA909214B (en) | 1992-06-24 |
JPH03169473A (ja) | 1991-07-23 |
AU6588490A (en) | 1991-05-30 |
ATE99580T1 (de) | 1994-01-15 |
US5948349A (en) | 1999-09-07 |
FI905658A0 (fi) | 1990-11-15 |
CA2030128C (fr) | 1996-10-29 |
DE69005798T2 (de) | 1994-04-28 |
DE69005798D1 (de) | 1994-02-17 |
DE69005798T3 (de) | 2000-01-13 |
FR2654661A1 (fr) | 1991-05-24 |
TR27294A (tr) | 1994-12-28 |
CA2030128A1 (fr) | 1991-05-18 |
FI92982C (fi) | 1995-02-10 |
FI92982B (fi) | 1994-10-31 |
FI905658L (fi) | 1991-05-18 |
AU624276B2 (en) | 1992-06-04 |
EP0429323B1 (de) | 1994-01-05 |
DK0429323T3 (da) | 1994-05-16 |
FR2654661B1 (fr) | 1994-06-10 |
EP0429323A1 (de) | 1991-05-29 |
JPH0747204B2 (ja) | 1995-05-24 |
DK0429323T4 (da) | 1999-11-29 |
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