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DK1556320T3 - Fremgangsmåde til fremstilling af 1,3-propandiol - Google Patents

Fremgangsmåde til fremstilling af 1,3-propandiol Download PDF

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Publication number
DK1556320T3
DK1556320T3 DK03779422.9T DK03779422T DK1556320T3 DK 1556320 T3 DK1556320 T3 DK 1556320T3 DK 03779422 T DK03779422 T DK 03779422T DK 1556320 T3 DK1556320 T3 DK 1556320T3
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DK
Denmark
Prior art keywords
ruthenium
catalyst
metal
hydroxypropionic acid
group
Prior art date
Application number
DK03779422.9T
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English (en)
Inventor
Xiangsheng Meng
Timothy Abraham
Paris Tsobanakis
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Novozymes As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication of DK1556320T3 publication Critical patent/DK1556320T3/da

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
    • C12C11/00—Fermentation processes for beer
    • C12C11/02—Pitching yeast

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  • Organic Chemistry (AREA)
  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Mycology (AREA)
  • Biochemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • General Engineering & Computer Science (AREA)
  • General Health & Medical Sciences (AREA)
  • Genetics & Genomics (AREA)
  • Microbiology (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Claims (22)

1
1. Fremgangsmåde til fremstilling af 1,3-propandiol omfattende at hydrere 3-hydroxypropionsyre i en væskefase, i tilstedeværelsen af en katalysator 5 omfattende ruthenium.
2. Fremgangsmåde ifølge krav 1 hvor væskefasen vælges fra gruppen bestående afvand, organisk opløsningsmiddel som ikke er hydrogenerbart, og en blanding af vand og det organiske opløsningsmiddel. 10
3. Fremgangsmåde ifølge krav 1, hvor katalysatoren omfattende ruthenium vælges fra gruppen bestående af rutheniummetal og forbindelser af rutheniummetal.
4. Fremgangsmåde ifølge krav 1 hvor rutheniumkatalysatoren omfatter en støttet rutheniumkatalysator.
5. Fremgangsmåde ifølge krav 4, hvor den støttede rutheniumkatalysator omfatter ruthenium på en kulstofstøtte. 20
6. Fremgangsmåde ifølge krav 1, hvor temperaturen er fra omkring 20°C til omkring 250°C.
7. Fremgangsmåde ifølge krav 1, hvor trykket er fra omkring 137895 Pa til 25 omkring 27579029 Pa.
8. Fremgangsmåde til fremstilling af 1,3-propandiol omfattende at hydrere 3-hydroxypropionsyre eller en C1-C20 alkylester deraf i en væskefase, i tilstedeværelsen af en katalysator omfattende, i kombination, en 30 rutheniumkatalysator og mindst en eller flere yderligere metalkatalysator(er) hvor det yderligere metal er valgt fra gruppen bestående af molybdæn, tungsten, titanium, zirkonium, niobium, vanadium, krom, og blandinger deraf.
9. Fremgangsmåde ifølge krav 8, hvor forbindelsen er 3-hydroxypropionsyre. 35 2
10. Fremgangsmåde ifølge krav 8, hvor forbindelsen er en C1-C5 ester af 3-hydroxypropionsyre.
11. Fremgangsmåde ifølge krav 8, hvor væskefasen vælges fra gruppen 5 bestående afvand, organisk opløsningsmiddel som ikke er hydrogenerbart, og en blanding af vand og det organiske opløsningsmiddel.
12. Fremgangsmåde ifølge krav 8, hvor rutheniumkatalysatoren vælges fra gruppen bestående af rutheniummetal og forbindelser af rutheniummetal. 10
13. Fremgangsmåde ifølge krav 8, hvor rutheniumkatalysatoren omfatter en støttet rutheniumkatalysator.
14. Fremgangsmåde ifølge krav 13, hvor den støttede rutheniumkatalysator 15 omfatter ruthenium på en kulstofstøtte.
15. Fremgangsmåde ifølge krav 8, hvor den yderligere metalkatalysator omfatter et metal eller en forbindelse af metallet, hvor metallet vælges fra gruppen bestående af molybdæn, tungsten, titanium, zirkonium, niobium, vanadium, 20 krom, og blandinger deraf.
16. Fremgangsmåde ifølge krav 15, hvor metallet er molybdæn.
17. Fremgangsmåde ifølge krav 8, hvor den yderligere metalkatalysator omfatter 25 en støttet metalkatalysator.
18. Fremgangsmåde ifølge krav 8, hvor temperaturen er fra omkring 20°C til omkring 250°C.
19. Fremgangsmåde ifølge krav 8, hvor trykket er fra omkring 137895 Pa til omkring 27579029 Pa.
20. Fremgangsmåde ifølge krav 8, hvor katalysatoren omfatter ruthenium på en kulstofstøtte og en yderligere metalkatalysator valgt fra gruppen bestående af 35 molybdæn og en molybdænoxid. 3
21. Fremgangsmåde ifølge krav 20, hvor forbindelsen er 3-hydroxypropionsyre.
22. Fremgangsmåde ifølge krav 1 eller 8, hvor 3-hydroxypropionsyren fremstilles fra en gensplejset organisme. 5
DK03779422.9T 2002-11-01 2003-10-30 Fremgangsmåde til fremstilling af 1,3-propandiol DK1556320T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US42306802P 2002-11-01 2002-11-01
PCT/US2003/034470 WO2004041421A2 (en) 2002-11-01 2003-10-30 Process for preparation of 1,3-propanediol

Publications (1)

Publication Number Publication Date
DK1556320T3 true DK1556320T3 (da) 2015-06-08

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
DK03779422.9T DK1556320T3 (da) 2002-11-01 2003-10-30 Fremgangsmåde til fremstilling af 1,3-propandiol

Country Status (10)

Country Link
US (1) US7126034B2 (da)
EP (1) EP1556320B1 (da)
JP (1) JP2006504788A (da)
CN (1) CN100381411C (da)
AU (1) AU2003285106A1 (da)
BR (1) BR0315969B1 (da)
CA (1) CA2503967A1 (da)
DK (1) DK1556320T3 (da)
MX (1) MXPA05004561A (da)
WO (1) WO2004041421A2 (da)

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Also Published As

Publication number Publication date
AU2003285106A1 (en) 2004-06-07
JP2006504788A (ja) 2006-02-09
MXPA05004561A (es) 2005-07-26
BR0315969B1 (pt) 2013-03-19
US20050283029A1 (en) 2005-12-22
CA2503967A1 (en) 2004-05-21
US7126034B2 (en) 2006-10-24
EP1556320A2 (en) 2005-07-27
EP1556320B1 (en) 2015-05-13
CN100381411C (zh) 2008-04-16
WO2004041421A3 (en) 2004-06-10
EP1556320A4 (en) 2006-06-21
CN1711228A (zh) 2005-12-21
BR0315969A (pt) 2005-09-20
WO2004041421A2 (en) 2004-05-21

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