CN1073498C - 模塑方法及脱模剂用稀释剂 - Google Patents
模塑方法及脱模剂用稀释剂 Download PDFInfo
- Publication number
- CN1073498C CN1073498C CN95193032A CN95193032A CN1073498C CN 1073498 C CN1073498 C CN 1073498C CN 95193032 A CN95193032 A CN 95193032A CN 95193032 A CN95193032 A CN 95193032A CN 1073498 C CN1073498 C CN 1073498C
- Authority
- CN
- China
- Prior art keywords
- diluent
- surfactant
- releasing agent
- metal pattern
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000003085 diluting agent Substances 0.000 title claims abstract description 34
- 238000000465 moulding Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000006082 mold release agent Substances 0.000 title abstract description 6
- 239000004094 surface-active agent Substances 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000007864 aqueous solution Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 40
- 238000010790 dilution Methods 0.000 claims description 19
- 239000012895 dilution Substances 0.000 claims description 19
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract description 32
- 239000002184 metal Substances 0.000 abstract description 32
- 238000007865 diluting Methods 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 22
- 238000001035 drying Methods 0.000 description 19
- 241000047703 Nonion Species 0.000 description 15
- 230000007797 corrosion Effects 0.000 description 10
- 238000005260 corrosion Methods 0.000 description 10
- 239000001993 wax Substances 0.000 description 10
- 239000002585 base Substances 0.000 description 7
- -1 fatty acid ester Chemical class 0.000 description 7
- 239000003960 organic solvent Substances 0.000 description 6
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 6
- 125000003342 alkenyl group Chemical group 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 239000003112 inhibitor Substances 0.000 description 5
- 238000005342 ion exchange Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 150000001447 alkali salts Chemical class 0.000 description 3
- 125000000129 anionic group Chemical group 0.000 description 3
- 239000003945 anionic surfactant Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002050 silicone resin Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- FQAMAOOEZDRHHB-UHFFFAOYSA-N 1,2,2-trichloro-1,1-difluoroethane Chemical compound FC(F)(Cl)C(Cl)Cl FQAMAOOEZDRHHB-UHFFFAOYSA-N 0.000 description 1
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical compound C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241000221535 Pucciniales Species 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005600 alkyl phosphonate group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 125000004103 aminoalkyl group Chemical group 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 229940008099 dimethicone Drugs 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 239000012184 mineral wax Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000005375 organosiloxane group Chemical group 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Substances C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 102200082816 rs34868397 Human genes 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 235000015393 sodium molybdate Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000000935 solvent evaporation Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/58—Applying the releasing agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/60—Releasing, lubricating or separating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C33/00—Moulds or cores; Details thereof or accessories therefor
- B29C33/56—Coatings, e.g. enameled or galvanised; Releasing, lubricating or separating agents
- B29C33/60—Releasing, lubricating or separating agents
- B29C33/62—Releasing, lubricating or separating agents based on polymers or oligomers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/24—Polyethers
- C10M145/26—Polyoxyalkylenes
- C10M145/28—Polyoxyalkylenes of alkylene oxides containing 2 carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/18—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/24—Polyethers
- C10M145/26—Polyoxyalkylenes
- C10M145/36—Polyoxyalkylenes etherified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/02—Natural products
- C10M159/06—Waxes, e.g. ozocerite, ceresine, petrolatum, slack-wax
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
- C10M2205/022—Ethene
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/14—Synthetic waxes, e.g. polythene waxes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/16—Paraffin waxes; Petrolatum, e.g. slack wax
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/17—Fisher Tropsch reaction products
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/18—Natural waxes, e.g. ceresin, ozocerite, bees wax, carnauba; Degras
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
- C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
- C10M2211/044—Acids; Salts or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/06—Perfluorinated compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/04—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions obtained from monomers containing carbon, hydrogen, halogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2213/00—Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2213/06—Perfluoro polymers
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/08—Amides
- C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/26—Amines
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant Compositions
- C10M2215/28—Amides; Imides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
- C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/042—Siloxanes with specific structure containing aromatic substituents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
- C10M2229/052—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/30—Refrigerators lubricants or compressors lubricants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/32—Wires, ropes or cables lubricants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/34—Lubricating-sealants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/36—Release agents or mold release agents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/38—Conveyors or chain belts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/40—Generators or electric motors in oil or gas winning field
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/42—Flashing oils or marking oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/44—Super vacuum or supercritical use
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/50—Medical uses
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Moulds For Moulding Plastics Or The Like (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
Abstract
本发明提供将脱模剂用水稀释用于模塑时，用含表面活性剂的水溶液形成的稀释剂将上述脱模剂稀释后再加以使用的模塑方法。本发明提供的模塑方法可总是有再现性地得到对金属模的良好湿润性、干燥性和脱模性。
Description
产业上利用的范围
本发明涉及在用金属模将树脂、橡胶等模塑中使用水系脱模剂的模塑方法，以及用于此模塑方法的脱模剂用稀释剂。
现有技术
为了得到树脂、橡胶等模塑品，通常，先在金属模中涂布脱模剂，将模塑用组合物加到金属模中，使该模塑用组合物转变成固体模塑品，然后将固体模塑品从金属模上分离下来。
在这样的模塑中使用的脱模剂，有蜡系、硅氧烷系、含氟化合物系等各种类型，使用时，以在有机溶剂或水中分散或溶解的形式使用。
有机溶剂系的脱模剂因基于有机溶剂的特性，对金属模的湿润性和干燥性良好，因而一般易于使用。
然而，鉴于最近的地球环境和工作环境，例如三氯二氟乙烷(氟冷113)的破坏臭氧层、含氯溶剂的毒性、石油系溶剂的可燃性、毒性等问题，对水系脱模剂的需求变得十分强烈。
另一方面，水系脱模剂通常在使用时当场用水稀释成适当的浓度加以使用。
然而，因为水比有机溶剂蒸发潜热大、干燥性差，当金属模温度在100℃以下时，以往通常用有机溶剂系的脱模剂。而且，与有机溶剂系脱模剂相比，稀释时可见明显的脱模性降低倾向。
关于这些，已知有使用以表面活性剂及水稀释脱模剂的水系脱模剂的模塑方法(特公昭59-32513号、特公平1-26601号)。这种情况与单用水稀释的情况相比，改善了干燥性、脱模性，也可使用于100℃以下的低温模塑。
这种稀释的水系脱模剂中含表面活性剂，因此对金属模的湿润性提高，脱模剂不呈水滴状，因此成为均匀的薄膜状，干燥性提高。而且，与此同时，脱模性、金属模污染也得到改善。
但是，一般说来，通常将蜡、硅氧烷油、硅氧烷树脂或含全氟烷基的化合物用表面活性剂乳化后用作脱模剂。
从而，因稀释前脱模剂中含表面活性剂，一般认为单用水稀释的情况都是相同的，但在实际模塑过程中，因各种模塑材料或金属模形状不同，与之相应地，即使用同样的脱模剂，最适稀释倍数一般也是不同的。因此，对金属模的湿润性随此稀释倍数而大幅度地变动。如特公昭59-32513号、特公平1-26601号所揭示的那样，这在以表面活性剂和水稀释脱模剂而加以使用的方法中也是如此。
发明的目的
本发明的目的是提供可经常地再现性良好地得到对金属模有良好的湿润性、干燥性和脱模性的模塑方法，以及用于该模塑方法的脱模剂用稀释剂。发明的构成
即，本发明涉及在以水稀释而成的脱模剂用于模塑时，预先配制含0.01-1.0重量％表面活性剂的水溶液形成的稀释剂，用此稀释剂水溶液稀释上述脱模剂而加以使用的模塑方法，及在此模塑方法实施中使用的、由含0.01-1重量％表面活性剂的水溶液形成的脱模用稀释剂。
按照本发明的模塑方法和稀释剂，因为在稀释剂中含表面活性剂，因此对金属模的湿润性提高，又因脱模剂不呈水滴状，故形成均匀的薄膜状态，干燥性提高，同时，脱模性、金属模污染也可改善。
此外，在稀释剂中可预先包含最适浓度的表面活性剂，因此其稀释倍数(稀释浓度)通常可被设定在所要求的值，对金属模的湿润性就不变。因此，可按模塑材料或金属模形式的不同而自由选择最适稀释倍数，可使上述湿润性、干燥性、脱模性经常再现性良好地提高。
本发明中，稀释的脱模剂无特别限制，可列举以下蜡系、硅氧烷系、含氟化合物系等。
蜡系，可有如下例子：动物性蜡、植物性蜡、矿物性蜡、合成蜡(脂肪酸酯蜡、脂肪酸酰胺蜡、聚乙烯蜡、微晶蜡、石蜡等)等。
硅氧烷系可列举二甲基硅氧烷油、甲基苯基硅氧烷油、氨基烷基改性二有机硅氧烷、硅氧烷树脂等为例。
含氟化合物系可列举含有全氟烷基或全氟链烯基的化合物，如含有全氟烷基或全氟链烯基的磷酸或基盐、含有全氟烷基或全氟链烯基的羧酸或基盐、含有全氟烷基或全氟链烯基的磺酸或基盐、含有全氟烷基或全氟链烯基的丙烯酰基系聚合物等为例。
这些脱模剂通常以用表面活性剂在成乳化剂或分散剂的形式使用。所用的表面活性剂可以是通常的阴离子型、阳离子型、非离子型和两性表面活性剂，例示于下：
阴离子型表面活性剂：高级脂肪酸碱盐、烷基硫酸盐、烷基磺酸盐、烷基芳基磺酸盐、磷酸烷基酯、含氟羧酸、含氟磺酸等。
阳离子型表面活性剂：高级胺卤酸盐、卤化烷基吡啶、季铵盐、聚氧乙烯烷基胺等。
非离子型表面活性剂：聚氧乙烯烷基醚、聚氧乙烯烷基酯、脱水山梨醇烷基酯、糖酯等。
两性表面活性剂：包含甜菜碱、咪唑啉等。有仲胺、叔胺和季铵盐等。作为阴离子基，羧酸、硫酸酯、磺酸、磷酸酯等是有用的。
用于本发明的稀释剂的表面活性剂，阴离子型、阳离子型、非离子型、两性均可使用，但是，阴离子型、阳离子型、两性等离子型表面活性剂若与异种离子混合，可有凝聚发生。例如，在脱模剂的乳化剂中使用阴离子型表面活性剂时，若在稀释剂中使用阳离子型表面活性剂，乳化状态变得不稳定，不能很好地涂布。
然而，在用非离子型表面活性剂时，无此影响，在任何情况下均能很好地使用，因此，非离子型表面活性剂较佳。
非离子型表面活性剂中，在不降低脱模性这点上，以通式
(R为C8H17-或C9H19-等CmH2m+1(m为5-20的整数)表示的脂肪族烃基，n为2-100的整数)表示的化合物为佳。它们也可一种或二种以上混合使用。
表面活性剂有市售，在本发明中，不是单用水，而是用含表面活性剂的水溶液(稀释剂)将脱模剂进行稀释后再使用。稀释剂中表面活性剂浓度为0.01-1.0重量％，较好为0.1-1.0重量％。此浓度若大于1重量％，脱模性易降低；而小于0.01重量％，则对金属模的湿润性易降低。
脱模剂的稀释倍数以2-100倍为好。此时，脱模剂在稀释成0.01-1重量％，更好为0.1-1重量％浓度后使用时特别有用。
在本发明中，稀释剂中也可合用防蚀剂，例如，亚硝酸钠等具有还原性的防蚀剂，表面活性剂类的防蚀剂均可使用，具体地可以是三洋化成(株)制的Sanhibitor。产业上利用的可能性
按本发明的模塑方法，将脱模剂用水稀释用于模塑时，因用含表面活性剂的水溶液将上述脱模剂稀释后使用，在稀释剂中含表面活性剂，故对金属模的湿润性提高，又因脱模剂不呈水滴状，故成为均匀的薄膜状，干燥性很高，同时，脱模性，金属模污染性也可改善。
此外，在稀释剂中可预先包含最适浓度的表面活性剂，因此其稀释倍数(稀释浓度)通常可设定在所要求的值，对金属模的湿润性就不变。因此，可按模塑材料或金属模形式的不同而自由选择最适稀释倍数，可使上述湿润性、干燥性、脱模性可总是再现性良好地得到提高。
附图的简单说明
图1是将脱模剂的水分蒸发率(干燥性)与其对照数据作比较所作的图。
实施例
以下以实施例对本发明作更详细的说明，这些实施例不是对本发明的限制。实施例1
在1升的三颈烧瓶中加入497g离子交换过的水，用水浴40℃加热。在烧瓶中加入下述结构式的Nonion HS-210(日本油脂公司制)3g，搅拌30分钟，使其完全溶解。将此作为稀释剂(A)。
Nonion HS-210：
然后，在100ml烧杯中加入含氟系水基脱模剂Daifree ME-44(含有效成分4重量％、各种表面活性剂0.2-0.5重量％,Daikin工业公司制〕10g，加入稀释剂(A)40g，搅拌，配制成5倍稀释液。
此5倍稀释液对金属模的湿润性、在金属模上的干燥时间、使用金属模时的脱模性表示在下述表1和图1中。
实施例2
用硅氧烷系水基脱模剂SH-7036(含有效成分38重量％、各种表面活性剂3-10重量％,Torey Dowconing Silicone Co.,Ltd．制)代替实施例1的含氟系水基脱模剂Daifree ME-414。在100ml的烧杯中加入1克SH-7036，加入稀释剂(A)46.5克，搅拌，配制成47.5倍稀释液。
实施例3
用蜡系水基脱模剂EMUSTAR0001(含有效成分40重量％、各种表面活性剂0.5-2重量％，日本Seirou公司制)代替实施例1的含氟系水基脱模剂Daifree ME-414。在100ml的烧杯中加入1克EMUSTAR0001，加入稀释剂(A)49克，搅拌，配制成50倍稀释液。实施例4
除了用如下结构式的Nonion HS-206(日本油脂公司制)5克代替实施例1的Nonion HS-210外，按实施例1同样进行配制。
Nonion HS-206：
实施例5
除了用如下结构式的Nonion HS-220(日本油脂公司制)1克代替实施例1的Nonion HS-210外，按实施例1同样进行配制。
Nonion HS-220：
实施例6
除了用如下结构式的Nonion HS-215(日本油脂公司制)1克代替实施例1的Nonion HS-210外，按实施例1同样进行配制。
Nonion HS-215：
实施例7
在1升的三颈烧瓶中加入离子交换过的水496克，在水浴中40℃加热。在烧瓶中加入Nonion HS-210(日本油脂公司制)3克和水基防蚀剂SanhibitorNo.52(三洋化成工业公司制)1克，搅拌30分钟，使其完全溶解。将此作为稀释剂(B)。
用稀释剂(B)代替实施例1的稀释剂(A)，将Daifree ME-414稀释5倍。此5倍稀释液对金属模的湿润性、在金属模上的干燥时间、使用金属模时的脱模性列于下面的表1，在金属上的防蚀性列于下面的表2。
在表2中，还列出了实施例1、实施例2、实施例3、比较例1、比较例2、比较例3、比较例4。
实施例8
用2克钼酸钠代替实施例7的1克Sanhibitor No.52，其余进行同样的操作。比较例1
用离子交换过的水代替实施例1的稀释剂(A)，将Daifree ME-414稀释5倍，其余进行同样的操作。比较例2
用离子交换过的水代替实施例2的稀释剂(A)，将SH-7036稀释47.5倍，其余进行同样的操作。比较例3
用离子交换过的水代替实施例3的稀释剂(A)，将EMUSTAR0001稀释50倍，其余进行同样的操作。
实施例9
用代替实施例4的Nonion HS-206，其余进行同样的操作。
实施例10
用
[C16H33N(CH3)3]_Cl_代替实施例5的Nonion HS-220，其余进行同样的操作。
实施例11
用
代替实施例6的Nonion HS-210、HS-215，其余进行同样的操作。比较例4
用DaifreeME-414原液代替实施例1的用稀释剂(A)5倍稀释DaifreeME-414，其余进行同样的操作。实施例12-16、比较例5-10
对于实施例1，将表面活性剂和脱模剂的混合量作各种变化，其余进行同样的操作。
结果分别列于下面的表1、表2、表3和图1。各特性的评价如下。
湿润性：在半硬钢S45C硬质镀铬金属模(56mmΦ×10mm)的内表面涂以一定量的液体时的湿润状态。
评价标准 ○：完全均匀地涂布；
Δ：有部分未涂布的地方；
×：因为液体被排斥，有很多未涂布的地方。
干燥性：在25℃×60％的恒温恒湿室中，将铝制金属模(100mmΦ×10mm)置于红外线水分计上，向金属模上涂布恒量0.4克液体，用所连接的计算机画出重量减少率的经时变化。图1表示一例。此处为了方便，将干燥时间分为三阶段。
评价：干燥时间(分钟)
○：4分钟以下；
Δ：4分钟以上，6分钟以下；
×：6分钟以上。
脱模性：将上述湿润性试验中所用的刷涂了脱模剂的金属模在120℃干燥箱中加热10分钟。在此金属模上流上环氧树脂20克，将夹子靠在上面，在120℃×2小时的条件下硬化。室温下放置2小时后，用拉伸试验机测定脱模力。
环氧树脂组成：
Epicoat 828(Shell Chemical Co.Ltd．制) 100份
三亚乙基四胺 8份
此处为了方便，将脱模力分三级评价。
评价：脱模力(g/cm2)
○：200以下；
Δ：200以上，300以下；
×：300以上。
腐蚀程度：
试验方法
在50cc螺线管中加入20克试样，将两面抛光的SS-400钢材(1.6×20×50mm)斜靠在管中，一半浸入液体，放置在25℃×65％的恒温恒湿室中。
判断标准
按以下标准目测腐蚀程度。
0：无变化；
1：气液界面有一些红锈发生；
2：气液界面外也有红锈发生；
3：引起少量腐蚀；
4：腐蚀严重。
表1
| 稀释剂浓度(重量％) | 湿润性 | 干燥性 | 脱模性 | |
| 实施例1实施例2实施例3实施例4实施例5实施例6实施例7实施例8实施例9实施例10实施例11 | 0.60.60.60.990.20.40.60.60.990.20.4 | ○○○○○○○○ΔΔΔ | ○○○○○○○○ΔΔΔ | ○ΔΔ○○○○○ΔΔΔ |
| 比较例1比较例2比较例3 | 000 | ××× | ××× | Δ×× |
表2
| 腐蚀程度 | |||||
| 1日后 | 2日后 | 3日后 | 7日后 | 14日后 | |
| 实施例1 | 1 | 3 | 3 | 4 | 4 |
| 实施例2 | 1 | 3 | 3 | 4 | 4 |
| 实施例3 | 1 | 3 | 4 | 4 | 4 |
| 实施例7 | 0 | 0 | 0 | 0 | 0 |
| 实施例8 | 0 | 0 | 0 | 0 | 0 |
| 比较例1 | 1 | 3 | 3 | 4 | 4 |
| 比较例2 | 1 | 3 | 3 | 4 | 4 |
| 比较例3 | 1 | 3 | 4 | 4 | 4 |
| 比较例4 | 0 | 1 | 2 | 3 | 4 |
表3
| 稀释浓度(重量％) | ME-414(4重量％)混合量 | HS-210浓度(重量％) | HS-210的混合量 | 湿润性 | 干燥性 | 脱模性 | |
| 比较例5 | 8.0 | 10g | 8.0％ | 40g | ○ | ○ | × |
| 比较例6 | 6.0 | 10g | 6.0％ | 40g | ○ | ○ | × |
| 比较例7 | 5.0 | 10g | 5.0％ | 40g | ○ | ○ | Δ |
| 比较例8 | 4.0 | 10g | 4.0％ | 40g | ○ | ○ | Δ |
| 比较例9 | 2.0 | 10g | 2.0％ | 40g | ○ | ○ | Δ |
| 实施例12 | 1.0 | 10g | 1.0％ | 40g | ○ | ○ | ○ |
| 实施例13 | 0.2 | 10g | 0.2％ | 40g | ○ | ○ | ○ |
| 实施例14 | 0.05 | 10g | 0.05％ | 40g | Δ | Δ | Δ |
| 实施例15 | 0.02 | 10g | 0.02％ | 40g | Δ | Δ | Δ |
| 实施例16 | 0.01 | 10g | 0.01％ | 40g | Δ | Δ | Δ |
| 比较例10 | 0.005 | 10g | 0.005％ | 40g | Δ | × | Δ |
从上面的表1和图1、表3的结果，如实施例1-16(特别是实施例1-8、14-16)所示，按本发明用稀释剂稀释脱模剂后加以使用，可使湿润性、干燥性、脱模性提高。从表2的结果，如实施例7、8所示，添加防蚀剂的效果是明显的。
Claims (4)
1．一种模塑方法，其特征在于：将脱模剂用水稀释用于模塑时，预先配制含0.01-1.0重量％表面活性剂的水溶液形成的稀释剂，用此稀释剂水溶液将上述脱模剂稀释后使用。
2．按权利要求1所述的方法，其中使用非离子型表面活性剂作为表面活性剂。
3．按权利要求2所述的方法，其中非离子型表面活性剂以如下通式表示：
其中R为CmH2m+1表示的脂肪烃基，m为选自5-20的整数；n为选自2-100的整数。
4．按权利要求1-3之一所述的方法，其中通过调节稀释剂的浓度将脱模剂的稀释倍数设定为2-100倍。
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP121949/94 | 1994-05-11 | ||
| JP6121949A JPH07304043A (ja) | 1994-05-11 | 1994-05-11 | 成形方法及び離型剤用希釈剤 |
| JP121949/1994 | 1994-05-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1147788A CN1147788A (zh) | 1997-04-16 |
| CN1073498C true CN1073498C (zh) | 2001-10-24 |
Family
ID=14823913
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95193032A Expired - Fee Related CN1073498C (zh) | 1994-05-11 | 1995-05-08 | 模塑方法及脱模剂用稀释剂 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US5853646A (zh) |
| EP (1) | EP0759348B1 (zh) |
| JP (1) | JPH07304043A (zh) |
| KR (1) | KR0174753B1 (zh) |
| CN (1) | CN1073498C (zh) |
| DE (1) | DE69531347T2 (zh) |
| TW (1) | TW326014B (zh) |
| WO (1) | WO1995031321A1 (zh) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5746961A (en) * | 1995-12-04 | 1998-05-05 | Michael J. Stevenson | Method for enhancement of the surfaces of molded plastic products |
| DE10113168A1 (de) * | 2001-03-19 | 2002-09-26 | Bayer Ag | Verwendung von zwitterionischen Verbindungen als Entformungsmittel in Thermoplasten |
| JP2008164791A (ja) * | 2006-12-27 | 2008-07-17 | Canon Chemicals Inc | 導電性ローラの製造方法、現像ローラ及び画像形成装置 |
| JP6396120B2 (ja) * | 2014-08-29 | 2018-09-26 | 精工化学株式会社 | ゴムラテックス用防着剤 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3554910A (en) * | 1968-10-17 | 1971-01-12 | Dow Corning | Organosilane mold lubricants |
| JPS5139676B2 (zh) * | 1972-09-01 | 1976-10-29 | ||
| DE2255310A1 (de) * | 1972-11-11 | 1974-05-22 | Henkel & Cie Gmbh | Trennmittelloesungen fuer die formtrennung von polyurethanschaeumen |
| US4118235A (en) * | 1975-09-18 | 1978-10-03 | Daikin Kogyo Co., Ltd. | Mold release agent |
| JPS59166596A (ja) * | 1983-03-14 | 1984-09-19 | Nippon Mektron Ltd | 離型剤 |
| JPH0378244A (ja) * | 1989-08-21 | 1991-04-03 | Mitsubishi Electric Corp | 半導体装置 |
| JPH0780190B2 (ja) * | 1990-02-09 | 1995-08-30 | 信越化学工業株式会社 | 離型剤 |
| JP2972824B2 (ja) * | 1990-11-16 | 1999-11-08 | 株式会社ネオス | 水性離型剤 |
| JPH05301228A (ja) * | 1992-04-28 | 1993-11-16 | Daikin Ind Ltd | 離型剤 |
-
1994
- 1994-05-11 JP JP6121949A patent/JPH07304043A/ja active Pending
-
1995
- 1995-05-08 DE DE69531347T patent/DE69531347T2/de not_active Expired - Fee Related
- 1995-05-08 WO PCT/JP1995/000876 patent/WO1995031321A1/ja active IP Right Grant
- 1995-05-08 KR KR1019960706288A patent/KR0174753B1/ko not_active Expired - Fee Related
- 1995-05-08 CN CN95193032A patent/CN1073498C/zh not_active Expired - Fee Related
- 1995-05-08 US US08/737,136 patent/US5853646A/en not_active Expired - Fee Related
- 1995-05-08 EP EP95917514A patent/EP0759348B1/en not_active Expired - Lifetime
- 1995-07-28 TW TW084107848A patent/TW326014B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| US5853646A (en) | 1998-12-29 |
| DE69531347D1 (de) | 2003-08-28 |
| EP0759348A1 (en) | 1997-02-26 |
| DE69531347T2 (de) | 2004-04-15 |
| WO1995031321A1 (fr) | 1995-11-23 |
| KR0174753B1 (ko) | 1999-10-01 |
| KR970702780A (ko) | 1997-06-10 |
| JPH07304043A (ja) | 1995-11-21 |
| TW326014B (en) | 1998-02-01 |
| EP0759348B1 (en) | 2003-07-23 |
| EP0759348A4 (en) | 1997-09-24 |
| CN1147788A (zh) | 1997-04-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1054800C (zh) | 非粘着性组合物 | |
| US10392409B2 (en) | Functionalized F-POSS materials as additives to polymers | |
| US7547732B2 (en) | Compositions of fluorochemical surfactants | |
| CN109228057B (zh) | 一种轮胎脱模剂及其制备方法 | |
| US4889677A (en) | Process for curing tire employing a bladder lubricant | |
| JP4880616B2 (ja) | モノマーフルオロ界面活性剤の組成物 | |
| CN1564860A (zh) | 清洁组合物 | |
| JP2005509708A (ja) | フッ素化シランを水性送達するための組成物 | |
| EP2479216B1 (en) | Emulsion and mold release agent comprising the emulsion | |
| CN1477147A (zh) | 具有多官能团的油类化学制品的合成和该油类化学制品及其用途 | |
| CN1876709A (zh) | 聚四氟乙烯的水性分散体及其生产方法 | |
| CN104120015B (zh) | 一种防锈防腐润滑性冷却性好的切削液及其制备方法 | |
| CN1073498C (zh) | 模塑方法及脱模剂用稀释剂 | |
| CN1497022A (zh) | 用于水基减震材料的增稠剂 | |
| CN1148481C (zh) | 一种聚丙烯细旦短纤维油剂 | |
| EP2497566B1 (en) | Polyfluoroalkyl phosphonate salt emulsifying agent and mold release agent comprising same as active ingredient | |
| CN110281433A (zh) | 一种橡胶成型工业用脱模剂及其制备方法 | |
| CN1249293C (zh) | 合成纤维处理剂组合物 | |
| CN1446860A (zh) | 低水中摩擦阻力涂层及降低水中基材上摩擦力的方法 | |
| JP2006321764A (ja) | 含フッ素有機ケイ素化合物及び含フッ素界面活性剤 | |
| CN110862861A (zh) | 水基型脱模剂及其制备方法 | |
| CN104120004B (zh) | 一种质量稳定分散均匀的水性切削液及其制备方法 | |
| CN105175274B (zh) | 一种长效环保型隔离剂及其制备方法 | |
| US6387166B1 (en) | Polishes comprising aminoorganopolysiloxanes containing fluoro groups | |
| CN111704955A (zh) | 一种抗冻水基切削液及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20011024 |