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CN104642347A - Agricultural insecticidal and bactericidal composition - Google Patents

Agricultural insecticidal and bactericidal composition Download PDF

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Publication number
CN104642347A
CN104642347A CN201410393584.3A CN201410393584A CN104642347A CN 104642347 A CN104642347 A CN 104642347A CN 201410393584 A CN201410393584 A CN 201410393584A CN 104642347 A CN104642347 A CN 104642347A
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active component
insecticidal
rice
weight
water
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袁静
陈杰
朱冰春
邢家华
孔小林
郁季平
胡冬松
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Zhejiang Chemical Industry Research Institute Co Ltd
Sinochem Lantian Co Ltd
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Zhejiang Chemical Industry Research Institute Co Ltd
Sinochem Lantian Co Ltd
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Abstract

本发明公开了一种含有氯氟氰虫酰胺和噻呋酰胺的杀虫杀菌组合物,且两者之间的重量配比为1:50~50:1。本发明提供的杀虫杀菌组合物,能够同时防治水稻害虫和病害、扩大防治谱、做到一药多治。The invention discloses an insecticidal and bactericidal composition containing cyantraniliprole and thiafuramide, and the weight ratio between the two is 1:50-50:1. The insecticidal and fungicidal composition provided by the invention can simultaneously prevent and control rice pests and diseases, expand the control spectrum, and achieve multiple treatments with one medicine.

Description

一种农用杀虫杀菌组合物A kind of agricultural insecticide and fungicide composition

技术领域technical field

本发明属于农用杀虫和杀菌领域,具体涉及一种含有氯氟氰虫酰胺和噻呋酰胺的杀虫杀菌组合物。The invention belongs to the field of agricultural insecticide and bactericide, and in particular relates to an insecticide and bactericide composition containing cyantraniliprole and thifuramide.

背景技术Background technique

在水稻栽培中,同时面临着害虫和病害,常见的害虫如稻纵卷叶螟、二化螟和大螟等,常见的病害如水稻纹枯病、稻瘟病和稻曲病等,对农业生产带来较大影响。现有技术中,我国用于水稻生长期的农药主要为单一防治虫害或单一防治病害,可同时防治虫害和病害的产品开发很少,农民需要多次施药才能达到防治害虫和病害的目的。In rice cultivation, we are faced with pests and diseases at the same time. Common pests such as rice leaf roller, rice stem borer and rice borer, etc., common diseases such as rice sheath blight, rice blast and rice false smut, etc. have great impact on agricultural production have a greater impact. In the prior art, the pesticides used in the growing season of rice in my country are mainly single pest control or single disease control. There are few products that can control pests and diseases at the same time. Farmers need to apply pesticides multiple times to achieve the purpose of pest and disease control.

因此,开发防治水稻苗期病虫害的杀虫杀菌组合物,对于推进农业规模化发展具有积极意义。Therefore, the development of insecticidal and fungicidal compositions for preventing and controlling rice seedling diseases and insect pests has positive significance for promoting the large-scale development of agriculture.

发明内容Contents of the invention

本发明的目的在于提供一种含有氯氟氰虫酰胺和噻呋酰胺的杀虫杀菌组合物,能够同时防治水稻害虫和病害、扩大防治谱、做到一药多治。The object of the present invention is to provide an insecticidal and fungicidal composition containing cyantraniliprole and thiafluxamide, which can simultaneously prevent and control rice pests and diseases, expand the control spectrum, and achieve multiple treatments with one drug.

为达到发明目的本发明采用的技术方案是:For achieving the purpose of the invention, the technical scheme adopted by the present invention is:

一种农业杀虫杀菌组合物,其特征在于所述杀虫杀菌组合物含有两种活性组分,第一种活性组分为如下结构式(I)所示的3-氯-N1-(2-甲基-4-七氟异丙基苯基)-N2-(1-甲基-1-氰基乙基)邻苯二甲酰胺,An agricultural insecticidal and bactericidal composition, characterized in that the insecticidal and bactericidal composition contains two active components, the first active component being 3-chloro-N 1 -(2 -Methyl-4-heptafluoroisopropylphenyl)-N 2 -(1-methyl-1-cyanoethyl)phthalamide,

第二种活性组分为具有如下结构式(II)所示的2',6'-二溴-2-甲基-4'-三氟甲氧基-4-三氟甲基-1,3-噻二唑-5-羟酰苯胺,The second active ingredient is 2',6'-dibromo-2-methyl-4'-trifluoromethoxy-4-trifluoromethyl-1,3- Thiadiazole-5-hydroxyanilide,

且所述第一种活性组分与第二种活性组分的重量配比为1:50~50:1。And the weight ratio of the first active component to the second active component is 1:50˜50:1.

本发明所述杀虫杀菌组合物中,上述结构式(I)所示的3-氯-N1-(2-甲基-4-七氟异丙基苯基)-N2-(1-甲基-1-氰基乙基)邻苯二甲酰胺简称“氯氟氰虫酰胺”,属于邻苯二甲酰胺类杀虫剂,其杀虫活性与氟虫双酰胺基本相同,属于鱼尼丁受体作用剂类杀虫剂,这类化合物可与鱼尼丁受体结合,导致Ca2+释放的失控和流失,使肌肉细胞的收缩功能瘫痪,是全新作用机制的化合物。经药剂处理后的害虫表现为进食迅速停止、乏力、反胃和肌肉瘫痪,直至死亡。这类杀虫剂杀虫谱广、残效期长、毒性低,对环境友好,与现有的各类杀虫剂无交互抗性。可以有效地防治各种鳞翅目害虫及某些鞘翅目幼虫、成虫,还可以用于防治蚂蚁、白蚁等害虫。In the insecticidal and fungicidal composition of the present invention, the 3-chloro-N 1 -(2-methyl-4-heptafluoroisopropylphenyl)-N 2 -(1-methanol) represented by the above structural formula (I) -1-cyanoethyl)phthalamide referred to as "Cytraniliprole", which belongs to the phthalamide insecticides, its insecticidal activity is basically the same as that of flubendiamide, and belongs to ryanodine Receptor-acting agent insecticides, this type of compound can bind to ryanodine receptors, leading to uncontrolled and loss of Ca 2+ release, paralyzing the contraction function of muscle cells, and it is a compound with a new mechanism of action. The pests treated with the pesticide showed rapid cessation of feeding, fatigue, nausea and muscle paralysis, until death. This type of insecticide has a wide insecticidal spectrum, a long residual effect period, low toxicity, is environmentally friendly, and has no cross-resistance with existing various insecticides. It can effectively control various Lepidoptera pests and some Coleoptera larvae and adults, and can also be used to control pests such as ants and termites.

本发明所述杀虫杀菌组合物中,上述结构式(II)所示的2',6'-二溴-2-甲基-4'-三氟甲氧基-4-三氟甲基-1,3-噻二唑-5-羟酰苯胺简称“噻呋酰胺”,是一种新型苯酰胺类内吸治疗性低毒广谱性杀菌剂,具有强内吸传导性和长持效性。噻呋酰胺对丝核菌属、柄锈菌属、黑粉菌属、腥黑粉菌属、伏革菌属、核腔菌属等致病真菌均有活性,尤其对担子菌纲真菌引起的病害如纹枯病、立枯病等有特效,可广泛应用于水稻、麦类、花生、棉花、甜菜、咖啡、马铃薯、草坪等多种作物。In the insecticidal and fungicidal composition of the present invention, 2',6'-dibromo-2-methyl-4'-trifluoromethoxy-4-trifluoromethyl-1 represented by the above structural formula (II) , 3-thiadiazole-5-hydroxyanilide, referred to as "thiafuramide", is a new type of benzamide systemic therapeutic low toxicity broad-spectrum fungicide with strong systemic conductivity and long-lasting effect. Thiofuramide is active against pathogenic fungi such as Rhizoctonia, Puccinia, Stiltia, Tilletia, Puccinia, and Sclerotinia, especially for fungi caused by Basidiomycetes. Diseases such as sheath blight and blight have special effects, and can be widely used in rice, wheat, peanuts, cotton, sugar beets, coffee, potatoes, lawns and other crops.

本发明所述的农业杀虫杀菌组合物中,含有活性组分的量取决于单独使用时化合物的施用量,也取决于一种化合物与另一种化合物的比例以及增效作用的程度。本发明所述的农业杀虫杀菌组合物中,上述第一种活性组分氯氟氰虫酰胺与第二种活性组分噻呋酰胺的重量配比优选为1:20~20:1,进一步优选为1:9~5:1。In the agricultural insecticidal and fungicidal composition of the present invention, the amount of active components depends on the application amount of the compound when used alone, and also depends on the ratio of one compound to another compound and the degree of synergistic effect. In the agricultural insecticidal and fungicidal composition of the present invention, the weight ratio of the first active component cyantraniliprole and the second active component thifluxamide is preferably 1:20 to 20:1, further Preferably it is 1:9 to 5:1.

本发明所述的农业杀虫杀菌组合物可以被配制成杀虫杀菌剂,当被配制成杀虫杀菌剂时,所述杀虫杀菌剂中含有以重量计0.5~95%的杀虫杀菌组合物,其余为农业上可接受的载体和助剂。进一步地,作为优选的方式,所述杀虫杀菌剂中含有以重量计20%~70%的杀虫杀菌组合物。The agricultural insecticidal and bactericidal composition of the present invention can be formulated as an insecticidal and bactericidal agent, and when formulated as an insecticidal and bactericidal agent, the insecticidal and bactericidal agent contains 0.5 to 95% by weight of the insecticidal and bactericidal combination substances, and the rest are agriculturally acceptable carriers and adjuvants. Further, as a preferred mode, the insecticide and fungicide contains 20% to 70% by weight of the insecticide and fungicide composition.

合适的固体载体包括:矿物类,植物类,合成填料类和无机盐类。其中矿物类包括硅酸盐类,碳酸盐类,硫酸盐类和氧化物类。硅酸盐类例如高岭土,海泡石,珍珠陶土,蒙脱土,云母,蛭石,叶蜡石,滑石。碳酸盐类例如:碳酸钙,白云石。硫酸盐类如硫酸铵,硫酸钠,硫酸钙。氧化物类如生石灰,镁石灰,硅藻土。植物类例如:柑橘渣,玉米棒芯,谷壳粉,稻壳,大豆秸粉,烟草粉,胡桃壳,锯木粉。合成填料类如沉淀碳酸钙水合物,沉淀碳酸钙,白炭黑。无机盐类例如氯化钾,氯化钠。Suitable solid carriers include: minerals, plants, synthetic fillers and inorganic salts. The minerals include silicates, carbonates, sulfates and oxides. Silicates such as kaolin, sepiolite, nacrite, montmorillonite, mica, vermiculite, pyrophyllite, talc. Carbonates such as: calcium carbonate, dolomite. Sulfates such as ammonium sulfate, sodium sulfate, calcium sulfate. Oxides such as quicklime, magnesium lime, diatomaceous earth. Vegetables such as: citrus pomace, corn cob, chaff powder, rice husk, soybean straw powder, tobacco powder, walnut shell, sawdust. Synthetic fillers such as precipitated calcium carbonate hydrate, precipitated calcium carbonate, white carbon black. Inorganic salts such as potassium chloride, sodium chloride.

液体载体包括水和有机溶剂。当有效成分为水乳剂或悬乳剂时,有机溶剂起到增溶和防冻作用。合适的有机溶剂包括芳烃,例如苯、二甲苯、甲苯、烷基苯、烷基萘和氯代芳烃;氯代脂肪烃,例如氯乙烯、三氯甲烷、二氯甲烷、氯仿、四氯化碳和多氯乙烷;脂肪烃,例如石油馏分、环己烷、轻质矿物油和石蜡。醇类例如甲醇,乙醇,异丙醇、丁醇、异丁醇,乙二醇、丙二醇、丙三醇、脂肪醇等;醚类例如甲基乙二醇醚,乙基乙二醇醚,石油醚。酮类例如丙酮、甲乙酮、甲基异丁基酮、环己酮以及异氟尔酮、N-甲基-吡咯烷酮;特种溶剂还有二甲基甲酰胺,二甲基亚砜,聚乙二醇,已腈;植物油及甲基化植物油。上述有机溶剂既可以单独使用,也可以混合使用,还可以与水一起混合使用。Liquid carriers include water and organic solvents. When the active ingredient is water emulsion or suspoemulsion, the organic solvent plays the role of solubilization and antifreeze. Suitable organic solvents include aromatics such as benzene, xylene, toluene, alkylbenzenes, alkylnaphthalenes, and chlorinated aromatics; chlorinated aliphatics such as vinyl chloride, chloroform, methylene chloride, chloroform, carbon tetrachloride and polychloroethanes; aliphatic hydrocarbons such as petroleum distillates, cyclohexane, light mineral oils and paraffins. Alcohols such as methanol, ethanol, isopropanol, butanol, isobutanol, ethylene glycol, propylene glycol, glycerol, fatty alcohols, etc.; ethers such as methyl glycol ether, ethyl glycol ether, petroleum ether. Ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone and isophorone, N-methyl-pyrrolidone; special solvents also include dimethylformamide, dimethyl sulfoxide, polyethylene glycol , has been nitrile; vegetable oil and methylated vegetable oil. The above-mentioned organic solvents may be used alone, or in combination, or in combination with water.

本发明所述助剂可以根据需要包括表面活性剂、消泡剂、增稠剂、助悬剂和防冻剂中的一种或几种,还可以根据需要包括本行业常用的其他助剂。The auxiliary agent of the present invention may include one or more of surfactants, defoamers, thickeners, suspending agents and antifreezing agents as required, and may also include other auxiliary agents commonly used in this industry as required.

表面活性剂可以是乳化剂、分散剂、稳定剂或湿润剂;可以是离子型的或非离子型的。合适的表面活性剂包括:聚丙烯酸和木质素磺酸的钠盐和钙盐;分子中含有至少12个碳原子的脂肪酸或脂肪胺与环氧乙烷和/环氧丙烷的缩聚产物;甘油、十二烷醇-1、十四烷醇-1、山梨醇、蔗糖或季戊四醇的脂肪酸酯;及它们与环氧乙烷和/或环氧丙烷的缩聚产物;它们的缩聚产物的硫酸盐或磺酸盐;在分子中至少含有10个碳原子的硫酸或磺酸的碱金属或碱土金属盐,较佳的为钠盐,如十二烷基硫酸钠、仲烷基硫酸钠、磺化蓖麻油的钠盐、烷芳基磺酸钠和十二烷基苯磺酸钠;环氧乙烷的聚合物、环氧乙烷和环氧丙烷的共聚物。Surfactants can be emulsifiers, dispersants, stabilizers or wetting agents; can be ionic or nonionic. Suitable surfactants include: sodium and calcium salts of polyacrylic acid and lignosulfonic acid; polycondensation products of fatty acids or fatty amines having at least 12 carbon atoms in the molecule with ethylene oxide and/or propylene oxide; glycerol, Fatty acid esters of 1-lauryl alcohol, 1-myristyl alcohol, sorbitol, sucrose or pentaerythritol; and their polycondensation products with ethylene oxide and/or propylene oxide; sulfate salts or Sulfonates; alkali or alkaline earth metal salts, preferably sodium, of sulfuric or sulfonic acids containing at least 10 carbon atoms in the molecule, such as sodium lauryl sulfate, sodium secondary alkyl sulfate, ricinium sulfonate Sodium salt of sesame oil, sodium alkylarylsulfonate and sodium dodecylbenzenesulfonate; polymer of ethylene oxide, copolymer of ethylene oxide and propylene oxide.

乳化剂包括非离子型乳化剂和市售的乳化剂。非离子型乳化剂优选聚氧乙烯脂肪酸脂、聚氧乙烯脂肪醇醚和聚氧乙烯脂肪氨,例如乙氧基化蓖麻油、聚氧乙烯(n20)苯乙基酚基醚油酸酯、烷基芳基聚氧乙烯聚氧丙烯醚、烷基芳基甲醛树脂聚氧乙烯醚、三苯乙烯基酚聚氧乙烯(n20),醚磷酸化三乙醇胺盐、二苯乙基酚基聚氧乙烯醚(n18)甲醛缩合物、二苯基酚聚氧乙烯(n18)聚氧丙烯醚(n20)等。市售的乳化剂包括:农乳0201B、农乳0203B、农乳100#、农乳500#、农乳600#、农乳600-2#、农乳1601、农乳2201、农乳NP-10、农乳NP-15、农乳507#、农乳OX-635、农乳OX-622、农乳OX-653、农乳OX-667、农乳CS-7、宁乳36#Emulsifiers include nonionic emulsifiers and commercially available emulsifiers. Nonionic emulsifiers are preferably polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers and polyoxyethylene fatty ammonia, such as ethoxylated castor oil, polyoxyethylene (n 20 ) phenethylphenol ether oleate, Alkylaryl polyoxyethylene polyoxypropylene ether, alkylaryl formaldehyde resin polyoxyethylene ether, tristyrylphenol polyoxyethylene (n 20 ), ether phosphorylated triethanolamine salt, diphenylethylphenol polyoxyethylene Oxyethylene ether (n 18 ) formaldehyde condensate, diphenylphenol polyoxyethylene (n 18 ) polyoxypropylene ether (n 20 ), etc. Commercially available emulsifiers include: Agricultural Milk 0201B, Agricultural Milk 0203B, Agricultural Milk 100 # , Agricultural Milk 500 # , Agricultural Milk 600 # , Agricultural Milk 600-2 # , Agricultural Milk 1601, Agricultural Milk 2201, Agricultural Milk NP-10 , Nongru NP-15, Nongru 507 # , Nongru OX-635, Nongru OX-622, Nongru OX-653, Nongru OX-667, Nongru CS-7, Ningru 36 # .

本发明所述的分散剂包括:木质素磺酸钠、拉开粉、木质素磺酸钙、甲基萘磺酸甲醛缩合物、萘磺酸甲醛缩合物、亚甲基萘磺酸钠、油酸甲基氨基乙基磺酸钠、环氧聚醚、对叔丁基醚、二丁基萘磺酸甲醛缩合物、磷酸盐如六偏磷酸钠、烷基酚聚氧乙烯基磷酸盐、烷基酚聚氧乙烯基醚甲醛缩合物硫酸盐、N-甲基-脂肪酰基-牛磺酸钠烷基酚聚氧乙烯醚甲醛缩合物、芳烷基酚聚氧乙烯醚磷酸酯烷基酚聚氧乙烯醚、蓖麻油环氧乙烷加成物、环氧乙烷-环氧丙烷嵌段共聚物烷基酚聚氧乙烯醚甲醛缩合物、烷基酚聚氧乙烯聚氧丙烯醚和甲基纤维素。The dispersant of the present invention includes: sodium lignosulfonate, pull-open powder, calcium lignosulfonate, methylnaphthalenesulfonic acid formaldehyde condensate, naphthalenesulfonic acid formaldehyde condensate, sodium methylenenaphthalenesulfonate, oil Sodium acid methyl amino ethyl sulfonate, epoxy polyether, p-tert-butyl ether, dibutyl naphthalene sulfonic acid formaldehyde condensate, phosphates such as sodium hexametaphosphate, alkylphenol polyoxyethylene phosphate, alkanes Alkylphenol polyoxyethylene ether formaldehyde condensate sulfate, N-methyl-fatty acyl-taurine sodium alkylphenol polyoxyethylene ether formaldehyde condensate, aralkylphenol polyoxyethylene ether phosphate ester alkylphenol poly Oxyethylene ether, castor oil ethylene oxide adduct, ethylene oxide-propylene oxide block copolymer alkylphenol polyoxyethylene ether formaldehyde condensate, alkylphenol polyoxyethylene polyoxypropylene ether and methyl cellulose.

本发明所述的湿润剂包括:月桂醇硫酸钠、烷基醇聚氧乙烯基醚硫酸钠、辛基酚聚氧乙烯基醚硫酸盐、烷基酚聚氧乙烯基醚甲醛缩合物硫酸盐、烷基磺酸钠、十二烷基苯磺酸钠、烷基萘磺酸钠、烷基丁二酸磺酸盐、月桂醇聚氧乙烯基醚磺酸钠、烷酰胺基牛磺酸钠、脂肪醇聚氧乙烯基醚、烷基酚聚氧乙烯基醚、聚氧乙烯聚氧丙烯嵌段聚合物、失水山梨醇脂肪酸酯聚氧乙烯基醚等。The wetting agent of the present invention includes: sodium lauryl sulfate, sodium alkyl alcohol polyoxyethylene ether sulfate, octylphenol polyoxyethylene ether sulfate, alkylphenol polyoxyethylene ether formaldehyde condensate sulfate, Sodium Alkyl Sulfonate, Sodium Dodecyl Benzene Sulfonate, Sodium Alkyl Naphthalene Sulfonate, Alkyl Succinate Sulfonate, Sodium Lauryl Polyoxyethylene Ether Sulfonate, Sodium Alkylamide Taurate, Fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene ether, polyoxyethylene polyoxypropylene block polymer, sorbitan fatty acid ester polyoxyethylene ether, etc.

本发明所述的增稠剂,既可以是人工合成的,例如羧甲基醇、聚乙烯醇或聚乙酸乙烯酯;也可以是天然的水溶性聚合物,例如黄原胶、明胶、阿拉伯树胶、聚乙烯吡咯烷酮、硅酸铝镁、聚乙烯醇、聚乙二醇、酚醛树脂、虫胶、羧甲基纤维素和海藻酸钠等。The thickener of the present invention can be artificially synthesized, such as carboxymethyl alcohol, polyvinyl alcohol or polyvinyl acetate; it can also be a natural water-soluble polymer, such as xanthan gum, gelatin, gum arabic , polyvinylpyrrolidone, aluminum magnesium silicate, polyvinyl alcohol, polyethylene glycol, phenolic resin, shellac, carboxymethyl cellulose and sodium alginate, etc.

本发明所述的消泡剂优选为:泡敌、硅酮类、C8~10脂肪醇、C10~20饱和脂肪酸类及酰胺等。The defoaming agent described in the present invention is preferably: foam enemy, silicones, C 8 ~ 10 fatty alcohols, C 10 ~ 20 saturated fatty acids and amides, etc.

当本发明所述的农业杀虫杀菌组合物被配制成杀虫杀菌剂时,所述杀虫杀菌剂可以为可湿性粉剂、悬浮剂、悬乳剂、微乳剂、水乳剂、水分散性颗粒剂或胶囊剂。When the agricultural insecticide and fungicide composition of the present invention is formulated as an insecticide and fungicide, the insecticide and fungicide can be wettable powder, suspension concentrate, suspoemulsion, microemulsion, water emulsion, water dispersible granule or capsules.

为可湿性粉剂时,由以下重量百分比的组分组成:氯氟氟虫酰胺0.1%~80%、噻呋酰胺0.1%~80%、湿润剂2%~10%、分散剂5%~10%、填料8~90%。按配方要求,将原药、各种助剂及填料等充分混合,经超细粉碎机粉碎后,即得到加工产品。When it is a wettable powder, it consists of the following components in weight percentage: 0.1% to 80% of flubendiamide, 0.1% to 80% of thifuramide, 2% to 10% of wetting agent, and 5% to 10% of dispersant , Filling 8 ~ 90%. According to the requirements of the formula, the original drug, various additives and fillers are fully mixed, and the processed product is obtained after being pulverized by an ultra-fine pulverizer.

为悬浮剂时,氯氟氟虫酰胺0.1%~50%、噻呋酰胺0.1%~60%、湿润剂1%~5%、分散剂1%~8%、增稠剂0.1%~1%、防冻剂2%~5%,水补齐至100%。按配方要求,以水为介质,将原药、分散剂、润湿剂、助悬剂和防冻剂等混合均匀再加入砂磨机中砂磨至一定粒径,过滤后加入增稠剂剪切搅拌均匀,配制所需浓度的悬浮剂即可。For suspending agent, flubendiamide 0.1%-50%, thifluzamide 0.1%-60%, wetting agent 1%-5%, dispersant 1%-8%, thickener 0.1%-1%, Antifreeze 2% ~ 5%, water to make up to 100%. According to the formula requirements, use water as the medium, mix the original drug, dispersant, wetting agent, suspending agent and antifreeze, and then add it into the sand mill to grind to a certain particle size, filter and add thickener to shear Stir evenly, and prepare the suspending agent of the required concentration.

为微乳剂时,氯氟氟虫酰胺0.1%~40%、噻呋酰胺0.1%~40%、乳化剂1%~12%、助溶剂0%~10%、稳定剂0%~5%、溶剂0%~40%,水补齐至100%。按配方要求,将各组分一起加入到反应釜中,搅拌均匀并完全溶解,慢慢加入纯净水,边加边搅拌,混合搅拌制得微乳剂。When it is a microemulsion, 0.1% to 40% of flubendiamide, 0.1% to 40% of thifuramide, 1% to 12% of emulsifier, 0% to 10% of cosolvent, 0% to 5% of stabilizer, solvent 0%~40%, make up to 100% with water. According to the requirements of the formula, all the components are put into the reaction kettle together, stirred evenly and completely dissolved, then slowly add pure water, stir while adding, and mix and stir to prepare the microemulsion.

为水乳剂时,氯氟氟虫酰胺0.1%~80%、噻呋酰胺0.1%~60%、乳化剂1%~20%、助溶剂0%~15%、稳定剂0%~5%、溶剂10%~40%,水补齐至100%。按配方要求,将各组分一起加入到反应釜中,搅拌均匀并完全溶解,慢慢加入纯净水,边加边搅拌,混合搅拌制得水乳剂。When it is an emulsion in water, 0.1%-80% of flubendiamide, 0.1%-60% of thifuramide, 1%-20% of emulsifier, 0%-15% of co-solvent, 0%-5% of stabilizer, solvent 10%~40%, make up to 100% with water. According to the formula requirement, add all the components into the reaction kettle together, stir evenly and completely dissolve, add pure water slowly, stir while adding, and mix and stir to obtain the water emulsion.

为悬乳剂时,氯氟氟虫酰胺0.1%~50%、噻呋酰胺0.1%~50%、溶剂1%~5%、分散剂1%~5%、乳化剂1%~10%、湿润剂1%~5%、稳定剂1%~5%、防冻剂0%~5%、增稠剂0%~5%、消泡剂0%~5%,水补齐至100%。按配方要求,将一种有效成分按照水乳剂的制备方法配制成水乳剂,另一有效成分按照悬浮剂的制备方法制成悬浮剂,然后再将两者混合搅拌均匀,即得悬乳剂。For suspoemulsion, 0.1% to 50% of flubendiamide, 0.1% to 50% of thifuramide, 1% to 5% of solvent, 1% to 5% of dispersant, 1% to 10% of emulsifier, wetting agent 1% to 5%, stabilizer 1% to 5%, antifreeze 0% to 5%, thickener 0% to 5%, defoamer 0% to 5%, water to 100%. According to the formula requirements, one active ingredient is prepared into water emulsion according to the preparation method of water emulsion, and the other active ingredient is prepared into suspending agent according to the preparation method of suspending agent, and then the two are mixed and stirred evenly to obtain suspoemulsion.

为水分散粒剂时,氯氟氟虫酰胺0.1%~80%、噻呋酰胺0.1%~80%、表面活性剂0%~2%、湿润剂1%~15%、分散剂1%~15%、崩解剂1%~10%、稳定剂0%~5%,填料补齐至100%。将原药和粉状载体、分散剂、润湿剂及填料等进行混合粉碎,再加水捏合后,加入装有一定规格筛网的造粒机中进行造粒。然后再经干燥、筛分(按筛网范围)即得颗粒状产品。按配方要求,将原药和粉状载体、分散剂、润湿剂及填料等进行混合粉碎,再加水捏合后,加入装有一定规格筛网的造粒机中进行造粒。然后再经干燥、筛分(按筛网范围)即得颗粒状产品。For water dispersible granules, 0.1% to 80% of flubendiamide, 0.1% to 80% of thifuramide, 0% to 2% of surfactant, 1% to 15% of wetting agent, and 1% to 15% of dispersant %, disintegrating agent 1%~10%, stabilizer 0%~5%, and filling up to 100%. Mix and pulverize the original drug, powdery carrier, dispersant, wetting agent and filler, add water and knead, then add to a granulator equipped with a certain size screen for granulation. Then dry and sieve (according to the range of the sieve) to obtain granular products. According to the formula requirements, mix and pulverize the original drug, powdery carrier, dispersant, wetting agent and filler, add water and knead, then add to a granulator equipped with a certain size screen for granulation. Then dry and sieve (according to the range of the sieve) to obtain granular products.

为微胶囊悬浮剂时,氯氟氟虫酰胺0.1%~30%、噻呋酰胺0.1%~40%、乳化剂1%~20%、溶剂1%~20%、增稠剂0%~10%、防冻剂0%~10%、稳定剂0%~5%、消泡剂0%~5%、微囊载体1%~10%,水补齐至100%。用微胶囊载体将有效成分和乳化剂、溶剂和稳定剂包封成细小微胶囊,粒径D90≤50μm,用水与防冻剂、增稠剂、消泡剂形成载体制成悬浮体系。For microcapsule suspensions, flubendiamide 0.1%-30%, thifuramide 0.1%-40%, emulsifier 1%-20%, solvent 1%-20%, thickener 0%-10% , 0% to 10% of antifreeze, 0% to 5% of stabilizer, 0% to 5% of defoamer, 1% to 10% of microcapsule carrier, and make up to 100% with water. The active ingredients, emulsifier, solvent and stabilizer are encapsulated into fine microcapsules with a microcapsule carrier, the particle size D90≤50μm, and water, antifreeze, thickener, and defoamer form a carrier to make a suspension system.

本发明所述的农业杀虫杀菌组合物可以直接制成成品制剂形式,即组合物中各物质已经混合,直接用于杀虫;组合物的成分也可以以由单独制剂提供,使用前在桶(罐)中直接混合。本发明的浓缩物通常与水混合得到所需活性物质的浓度。The agricultural insecticidal and fungicidal composition of the present invention can be directly made into a finished preparation form, that is, each material in the composition has been mixed and used directly for insecticide; (tank) for direct mixing. The concentrates of the present invention are generally mixed with water to obtain the desired concentration of active substance.

本发明提供的杀虫杀菌组合物和杀虫杀菌剂适合用于防治水稻害虫和病害,所述水稻害虫为稻纵卷叶螟、二化螟和大螟,水稻病害为水稻纹枯病、稻瘟病和稻曲病。The insecticidal and bactericidal composition and the insecticidal and bactericidal agent provided by the present invention are suitable for preventing and controlling rice pests and diseases. Blight and rice smut.

本发明所述的杀虫杀菌组合物施用场所为水稻田。本发明所述杀虫杀菌组合物在田间的施用剂量优选为100g a.i./hm2~150g a.i./hm2。本发明所述的农业杀虫杀菌组合物可以按普通的方法施用,如浇注、喷射、喷雾。施用量随气候条件或作物状态变化,施用时间可以在害虫危害之前或之后。保护作用的持续时间通常与组合物中单个化合物的含量有关,也与外界因素相关,例如气候,但通过使用适当的剂型可以减缓气候的影响。The place where the insecticidal and fungicidal composition of the present invention is applied is a paddy field. The dosage of the insecticidal and fungicidal composition of the present invention in the field is preferably 100g ai/hm 2 -150g ai/hm 2 . The agricultural insecticidal and fungicidal composition of the present invention can be applied by common methods, such as pouring, spraying and spraying. The amount of application varies with climatic conditions or crop status, and the application time can be before or after pest damage. The duration of the protective effect is usually related to the content of the individual compounds in the composition, but also to external factors, such as climate, which can be mitigated by using appropriate formulations.

本发明所述的农业杀虫杀菌组合物也可以与其它具有除草、杀菌性能的化合物混合使用,也可以与杀线虫剂、防护剂、生长调节剂、植物营养素或土壤调节剂混合使用。The agricultural insecticidal and fungicidal composition of the present invention can also be used in combination with other compounds with herbicidal and bactericidal properties, and can also be used in combination with nematicides, protective agents, growth regulators, plant nutrients or soil regulators.

本发明所述的杀虫杀菌组合物与现有技术相比具有以下优点:Compared with the prior art, the insecticidal and fungicidal composition of the present invention has the following advantages:

该杀虫杀菌组合物能够同时防治水稻害虫和病害、扩大防治谱、做到一药多治,解决在各种病虫害同时发生危害时重复多次施药给使用者带来的不便,以及重复施药可能造成的药害等不利影响。The insecticidal and bactericidal composition can prevent and control rice pests and diseases at the same time, expand the control spectrum, achieve multiple treatments with one drug, and solve the inconvenience caused by repeated application of pesticides when various diseases and insect pests occur at the same time. Adverse effects such as drug injury that may be caused by the drug.

具体实施方式Detailed ways

下面结合具体实施例来对本发明进行进一步说明,但并不将本发明局限于这些具体实施方式。本领域技术人员应该认识到,本发明涵盖了权利要求书范围内所可能包括的所有备选方案、改进方案和等效方案。The present invention will be further described below in conjunction with specific examples, but the present invention is not limited to these specific implementations. Those skilled in the art will realize that the present invention covers all alternatives, modifications and equivalents as may be included within the scope of the claims.

本发明中所有固体制剂的配比中百分比均为重量百分比,液体制剂的配比中百分比均为体积百分比;生物活性部分的处理剂量均为有效含量。The proportioning percentages of all solid preparations in the present invention are weight percentages, and the proportioning percentages of liquid preparations are volume percentages; the treatment doses of biologically active parts are all effective contents.

一、生物活性测定1. Determination of biological activity

为了进一步了解氯氟氰虫酰胺和噻呋酰胺的组合物的毒力,进行了大量配方筛选试验。试验参照杀虫剂农药室内生物测定试验准则(农业行业标准NY/T1154.7-2006)和创制农药生物活性评价SOP(杀虫剂卷),二化螟采用浸渍法。In order to further understand the toxicity of the combination of cyantraniliprole and thiafuramide, a large number of formulation screening tests were carried out. The test refers to the Indoor Bioassay Test Guidelines for Insecticides and Pesticides (Agricultural Industry Standard NY/T1154.7-2006) and the SOP for the Evaluation of Bioactivity of Pesticides (Insecticide Volume), and the dipping method was used for Chilo borer.

共毒系数若大于120,表明有增效作用;若小于80,表明为拮抗作用;若大于80小于120,表明为相加作用。If the co-toxicity coefficient is greater than 120, it indicates a synergistic effect; if it is less than 80, it indicates an antagonistic effect; if it is greater than 80 but less than 120, it indicates an additive effect.

氯氟氰虫酰胺与噻呋酰胺联合增效作用见下表1,测试对象为二化螟(Chilosuppressalis)。The combined synergistic effect of cyantraniliprole and thiafuramide is shown in Table 1 below, and the test object is Chilosuppressalis.

表1、氯氟氰虫酰胺与噻呋酰胺混配联合增效作用Table 1. Synergistic effect of mixing cyantraniliprole and thiafuramide

配方formula 配比Proportion LC50(mg/L) LC50 (mg/L) 共毒系数co-toxicity coefficient 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 1:501:50 0.9530.953 106.51106.51 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 1:201:20 0.9810.981 103.46103.46 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 1:91:9 0.8380.838 121.12121.12 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 1:71:7 0.8130.813 124.85124.85 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 1:4.81:4.8 0.8040.804 126.24126.24 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 1:2.51:2.5 0.8100.810 125.30125.30 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 1:21:2 0.7890.789 128.64128.64 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 1:1.61:1.6 0.7840.784 129.46129.46 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 1:1.21:1.2 0.7920.792 128.16128.16 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 3:13:1 0.9040.904 112.28112.28 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 5:15:1 0.8890.889 114.17114.17 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 20:120:1 0.9780.978 103.78103.78 氯氟氰虫酰胺:噻呋酰胺Cyantraniliprole: Thiofuramide 50:150:1 1.0091.009 100.59100.59 噻呋酰胺Thiofuramide -- >500.0>500.0 --

氯氟氰虫酰胺Cyantraniliprole -- 1.0151.015 --

注:混剂中LC50为氯氟氰虫酰胺浓度。Note: LC 50 in the mixture is the concentration of cyantraniliprole.

从表1试验结果可知:氯氟氰虫酰胺·噻呋酰胺混配对供试靶标均有很高的活性,氯氟氰虫酰胺与噻呋酰胺混配后表现出相加或增效作用,混剂的活性高于对照单剂或相当,二者可以进行复配。From the test results in Table 1, it can be seen that the mixture of cyantraniliprole and thifluxamide has very high activity on the tested targets, and the combination of cyantraniliprole and thiafluxamide shows an additive or synergistic effect. The activity of the agent is higher than or equivalent to that of the control single agent, and the two can be compounded.

二、制剂配制2. Preparation

实施例1:40%氯氟氰虫酰胺·噻呋酰胺可湿性粉剂Example 1: 40% cyantraniliprole-thifuramide wettable powder

氯氟氰虫酰胺15%,噻呋酰胺25%,十二烷基苯磺酸钠1.8%,白碳黑10%,木质素磺酸钠10%,轻质碳酸钙补足至100%。Cyflunraniliprole 15%, Thiofuramide 25%, Sodium Dodecyl Benzene Sulfonate 1.8%, White Carbon Black 10%, Sodium Lignosulfonate 10%, Light Calcium Carbonate make up to 100%.

实施例2:52%氯氟氰虫酰胺·噻呋酰胺可湿性粉剂Example 2: 52% cyantraniliprole · thifuramide wettable powder

氯氟氰虫酰胺20%,噻呋酰胺32%,十二烷基硫酸钠1.5%,萘磺酸甲醛缩合物5%,木质素磺酸钠3%,白碳黑8%,轻质碳酸钙补足至100%。Cyflunraniliprole 20%, Thiofuramide 32%, Sodium Lauryl Sulfate 1.5%, Naphthalene Sulfonate Formaldehyde Condensate 5%, Sodium Lignosulfonate 3%, White Carbon Black 8%, Light Calcium Carbonate Top up to 100%.

实施例3:50%氯氟氰虫酰胺·噻呋酰胺水分散粒剂Example 3: 50% cyantraniliprole and thifuramide water dispersible granules

氯氟氰虫酰胺20%,噻呋酰胺30%,木质素磺酸钠15%,甲基萘磺酸钠甲醛缩合物5%,,膨润土10%,高岭土补足至100%。20% cyantraniliprole, 30% thifluzamide, 15% sodium lignosulfonate, 5% sodium methylnaphthalene sulfonate formaldehyde condensate, 10% bentonite, and 100% kaolin.

实施例4:70%氯氟氰虫酰胺·噻呋酰胺水分散粒剂Embodiment 4: 70% chloroflufluraniliprole · Thiofuramide water dispersible granules

氯氟氰虫酰胺20%,噻呋酰胺50%,木质素磺酸钠15%,甲基萘磺酸钠甲醛缩合物5%,膨润土10%,高岭土补足至100%。Cyflunraniliprole 20%, Thiofuramide 50%, Sodium Lignosulfonate 15%, Sodium Naphthalene Sulfonate Formaldehyde Condensate 5%, Bentonite 10%, Kaolin Supplemented to 100%.

实施例5:60%氯氟氰虫酰胺·噻呋酰胺水分散粒剂Example 5: 60% cyantraniliprole and thifuramide water dispersible granules

氯氟氰虫酰胺20%,噻呋酰胺40%,木质素磺酸钠15%,甲基萘磺酸钠甲醛缩合物5%,膨润土10%,高岭土补足至100%。Cyflunraniliprole 20%, Thiofuramide 40%, Sodium Lignosulfonate 15%, Sodium Naphthalene Sulfonate Formaldehyde Condensate 5%, Bentonite 10%, Kaolin Supplemented to 100%.

实施例6:25%氯氟氰虫酰胺·噻呋酰胺悬浮剂Example 6: 25% Chlorflucyantraniliprole Thiofuramide Suspension Concentrate

氯氟氰虫酰胺10%,噻呋酰胺15%,拉开粉1.5%,Soproplot SC3%,黄原胶0.15%,硅酸镁铝1.5%,418G0.3%,BIT0.05%,水补足至100%。Cyantraniliprole 10%, Thiofuramide 15%, Pull Opening Powder 1.5%, Soproplot SC 3%, Xanthan Gum 0.15%, Magnesium Aluminum Silicate 1.5%, 418G 0.3%, BIT 0.05%, water up to 100%.

实施例7:22%氯氟氰虫酰胺·噻呋酰胺悬浮剂Example 7: 22% Chlorflucytraniliprole Thiofuramide Suspension Concentrate

氯氟氰虫酰胺10%,噻呋酰胺12%,聚羧酸盐5%,白碳黑0.3%,凹凸棒土1.0%,磷酸二氢钾0.2%,乙二醇4%,磷酸三丁酯0.2%,水补足至100%。Cyflunraniliprole 10%, Thiofuramide 12%, Polycarboxylate 5%, White Carbon Black 0.3%, Attapulgite 1.0%, Potassium Dihydrogen Phosphate 0.2%, Ethylene Glycol 4%, Tributyl Phosphate 0.2%, make up to 100% with water.

实施例8:35%氯氟氰虫酰胺·噻呋酰胺悬浮剂Example 8: 35% cyantraniliprole-thifuramide suspension concentrate

氯氟氰虫酰胺10%,噻呋酰胺25%,苯乙基酚聚氧乙烯聚氧丙烯醚3%,硅酸铝镁1.0%,黄原胶0.1%,丙二醇聚氧乙烯聚氧丙烯醚1.0%,水补足至100%。Cyflunraniliprole 10%, Thiofuramide 25%, Phenylphenol Polyoxyethylene Polyoxypropylene Ether 3%, Aluminum Magnesium Silicate 1.0%, Xanthan Gum 0.1%, Propylene Glycol Polyoxyethylene Polyoxypropylene Ether 1.0 %, make up to 100% with water.

实施例9:30%氯氟氰虫酰胺·噻呋酰胺悬浮剂Example 9: 30% cyantraniliprole-thifuramide suspension concentrate

氯氟氰虫酰胺10%,噻呋酰胺20%,苯乙基酚聚氧乙烯聚氧丙烯醚3%,硅酸铝镁1.0%,黄原胶0.1%,丙二醇聚氧乙烯聚氧丙烯醚1.0%,水补足至100%。Cyflunraniliprole 10%, Thiofuramide 20%, Phenylphenol Polyoxyethylene Polyoxypropylene Ether 3%, Aluminum Magnesium Silicate 1.0%, Xanthan Gum 0.1%, Propylene Glycol Polyoxyethylene Polyoxypropylene Ether 1.0 %, make up to 100% with water.

实施例10:0.6%氯氟氰虫酰胺·噻呋酰胺微乳剂Example 10: 0.6% cyantraniliprole-thifuramide microemulsion

氯氟氰虫酰胺0.1%,噻呋酰胺0.5%,异丙醇10%,三甲苯30%,丙二醇聚氧乙烯聚氧丙烯醚20%,水补足至100%。Cyflunraniliprole 0.1%, Thiofuramide 0.5%, Isopropanol 10%, Trimethylbenzene 30%, Propylene Glycol Polyoxyethylene Polyoxypropylene Ether 20%, and water to make up to 100%.

三、田间药效试验3. Field drug efficacy test

将实施例1、实施例2、实施例3、实施例4、实施例5、实施例6、实施例7、实施例8、实施例9和实施例10配制的杀虫杀菌剂对二化螟、稻纵卷叶螟和水稻纹枯病进行田间防治效果测试。试验地位于浙江省绍兴市孙端镇,为单季杂交稻。施药量为450kg/hm2。各制剂实施例用量为100g a.i./hm2~120g a.i./hm2,20%氯氟氰虫酰胺悬浮剂:45g a.i./hm2,24%噻呋酰胺悬浮剂:75g a.i./hm2。使用“合美”HM-16A型背负式电动喷雾器,植株叶面均匀喷雾。小区面积:25m2,4次重复,随机区组排列。The insecticide and fungicide prepared by embodiment 1, embodiment 2, embodiment 3, embodiment 4, embodiment 5, embodiment 6, embodiment 7, embodiment 8, embodiment 9 and embodiment 10 are effective to Chilo borer , rice leaf roller and rice sheath blight to conduct field control effect tests. The experimental site is located in Sunduan Town, Shaoxing City, Zhejiang Province, and it is a single-season hybrid rice. The application rate is 450kg/hm 2 . The dosage of each preparation example is 100g ai/hm 2 -120g ai/hm 2 , 20% cyantraniliprole suspension: 45g ai/hm 2 , 24% thifuramide suspension: 75g ai/hm 2 . Use the "Hemei" HM-16A knapsack electric sprayer to spray evenly on the leaves of the plants. Plot area: 25m 2 , repeated 4 times, arranged in random blocks.

试验结果表明:使用实施例1、实施例2、实施例3、实施例4、实施例5、实施例6、实施例7、实施例8、实施例9和实施例10配制的杀虫杀菌剂,药后10d对稻纵卷叶螟、二化螟和水稻纹枯病防效分别为80.4%~96.9%、83.2%~97.4%和86.2%~95.4%。同样试验条件下,噻呋酰胺对稻纵卷叶螟和二化螟的防效低于10%、对水稻纹枯病的防效为84.4%,氯氟氰虫酰胺对对稻纵卷叶螟和二化螟的防效分别为85.5%和87.2%、对水稻纹枯病的防效低于10%。由此可见,氯氟氰虫酰胺·噻呋酰胺能同时防治稻纵卷叶螟、二化螟和水稻纹枯病,且持效期长。Test result shows: use the insecticide bactericide of embodiment 1, embodiment 2, embodiment 3, embodiment 4, embodiment 5, embodiment 6, embodiment 7, embodiment 8, embodiment 9 and embodiment 10 preparation 10 days after application, the control effects on rice leaf roller, rice stem borer and rice sheath blight were 80.4%-96.9%, 83.2%-97.4% and 86.2%-95.4%, respectively. Under the same test conditions, the control effect of thifluzamide on rice leaf roller and rice stem borer was less than 10%, and the control effect on rice sheath blight was 84.4%. The control effects of rice stem borer and rice stem borer were 85.5% and 87.2%, respectively, and the control effects of rice sheath blight were less than 10%. It can be seen that cyantraniliprole and thiafluxamide can control rice leaf roller, rice stem borer and rice sheath blight at the same time, and the effect period is long.

表2、田间药效试验结果Table 2. Field drug efficacy test results

Claims (10)

1.一种农业杀虫杀菌组合物,其特征在于所述杀虫杀菌组合物含有两种活性组分,第一种活性组分为如下结构式(I)所示的3-氯-N1-(2-甲基-4-七氟异丙基苯基)-N2-(1-甲基-1-氰基乙基)邻苯二甲酰胺,1. An agricultural insecticidal and bactericidal composition, characterized in that the insecticidal and bactericidal composition contains two active components, the first active component being 3-chloro-N 1 - as shown in the following structural formula (I): (2-Methyl-4-heptafluoroisopropylphenyl)-N 2 -(1-methyl-1-cyanoethyl)phthalamide, 第二种活性组分为具有如下结构式(II)所示的2',6'-二溴-2-甲基-4'-三氟甲氧基-4-三氟甲基-1,3-噻二唑-5-羟酰苯胺,The second active ingredient is 2',6'-dibromo-2-methyl-4'-trifluoromethoxy-4-trifluoromethyl-1,3- Thiadiazole-5-hydroxyanilide, 且所述第一种活性组分与第二种活性组分的重量配比为1:50~50:1。And the weight ratio of the first active component to the second active component is 1:50˜50:1. 2.按照权利要求1所述的农业杀虫杀菌组合物,其特征在于所述第一种活性组分与第二种活性组分的重量配比为1:20~20:1。2. The agricultural insecticidal and fungicidal composition according to claim 1, characterized in that the weight ratio of the first active component to the second active component is 1:20˜20:1. 3.按照权利要求2所述的农业杀虫杀菌组合物,其特征在于所述第一种活性组分与第二种活性组分的重量配比为1:9~5:1。3. The agricultural insecticidal and fungicidal composition according to claim 2, characterized in that the weight ratio of the first active component to the second active component is 1:9˜5:1. 4.按照权利要求1至3之一所述的农业杀虫杀菌组合物,其特征在于所述杀虫杀菌组合物被配制成杀虫杀菌剂,所述杀虫杀菌剂中含有以重量计0.5~95%的杀虫杀菌组合物,其余为农业上可接受的载体和助剂。4. According to the agricultural insecticide and fungicide composition described in one of claims 1 to 3, it is characterized in that the insecticide and fungicide composition is formulated as an insecticide and fungicide, and the insecticide and fungicide contains 0.5 by weight ~95% of the insecticidal and fungicidal composition, and the rest are agriculturally acceptable carriers and adjuvants. 5.按照权利要求4所述的农业杀虫杀菌组合物,其特征在于所述杀虫杀菌剂中含有以重量计20%~70%的杀虫杀菌组合物。5. The agricultural insecticidal and fungicidal composition according to claim 4, characterized in that the insecticidal and fungicidal agent contains 20% to 70% by weight of the insecticidal and fungicidal composition. 6.按照权利要求4所述的农业杀虫杀菌组合物,其特征在于所述杀虫杀菌剂为可湿性粉剂、悬浮剂、悬乳剂、微乳剂、水乳剂、水分散性颗粒剂或胶囊剂。6. according to the described agricultural insecticide composition of claim 4, it is characterized in that said insecticide is wettable powder, suspending agent, suspoemulsion, microemulsion, water emulsion, water dispersible granule or capsule . 7.按照权利要求6所述的农业杀虫杀菌组合物,其特征在于:所述可湿性粉剂中以重量计由以下组分组成:第一种活性组分0.1%~80%、第二种活性组分0.1%~80%、湿润剂2%~10%、分散剂5%~10%、填料8~90%;7. The agricultural insecticidal and fungicidal composition according to claim 6, characterized in that: the wettable powder consists of the following components by weight: the first active component is 0.1% to 80%, the second active component Active ingredient 0.1%-80%, wetting agent 2%-10%, dispersant 5%-10%, filler 8-90%; 所述悬浮剂中以重量计由以下组分组成:第一种活性组分0.1%~50%、第二种活性组分0.1%~60%、湿润剂1%~5%、分散剂1%~8%、增稠剂0.1%~1%、防冻剂2%~5%,水补齐至100%;The suspension consists of the following components by weight: 0.1% to 50% of the first active component, 0.1% to 60% of the second active component, 1% to 5% of a wetting agent, and 1% of a dispersant ~8%, thickener 0.1%~1%, antifreeze 2%~5%, water to 100%; 所述微乳剂中以重量计由以下组分组成:第一种活性组分0.1%~40%、第二种活性组分0.1%~40%、乳化剂1%~12%、助溶剂0%~10%、稳定剂0%~5%、溶剂0%~40%,水补齐至100%;The microemulsion consists of the following components by weight: 0.1% to 40% of the first active component, 0.1% to 40% of the second active component, 1% to 12% of emulsifier, and 0% of cosolvent ~10%, stabilizer 0%~5%, solvent 0%~40%, water to 100%; 所述水乳剂中以重量计由以下组分组成:第一种活性组分0.1%~80%、第二种活性组分0.1%~60%、乳化剂1%~20%、助溶剂0%~15%、稳定剂0%~5%、溶剂10%~40%,水补齐至100%;The water emulsion consists of the following components by weight: 0.1% to 80% of the first active component, 0.1% to 60% of the second active component, 1% to 20% of emulsifier, and 0% of cosolvent ~15%, stabilizer 0%~5%, solvent 10%~40%, water to 100%; 所述悬乳剂中以重量计由以下组分组成:第一种活性组分0.1%~50%、第二种活性组分0.1%~50%、溶剂1%~5%、分散剂1%~5%、乳化剂1%~10%、湿润剂1%~5%、稳定剂1%~5%、防冻剂0%~5%、增稠剂0%~5%、消泡剂0%~5%,水补齐至100%;The suspoemulsion consists of the following components by weight: 0.1% to 50% of the first active component, 0.1% to 50% of the second active component, 1% to 5% of solvent, and 1% to 50% of dispersant 5%, emulsifier 1%~10%, wetting agent 1%~5%, stabilizer 1%~5%, antifreeze agent 0%~5%, thickener 0%~5%, defoamer 0%~ 5%, make up to 100% with water; 所述水分散粒剂中以重量计由以下组分组成:第一种活性组分0.1%~80%、第二种活性组分0.1%~80%、表面活性剂0%~2%、湿润剂1%~15%、分散剂1%~15%、崩解剂1%~10%、稳定剂0%~5%,填料补齐至100%;The water-dispersible granules are composed of the following components by weight: 0.1% to 80% of the first active component, 0.1% to 80% of the second active component, 0% to 2% of surfactant, wetting 1% to 15% of agent, 1% to 15% of dispersant, 1% to 10% of disintegrant, 0% to 5% of stabilizer, filling up to 100%; 所述微胶囊悬浮剂中以重量计由以下组分组成:第一种活性组分0.1%~30%、第二种活性组分0.1%~40%、乳化剂1%~20%、溶剂1%~20%、增稠剂0%~10%、防冻剂0%~10%、稳定剂0%~5%、消泡剂0%~5%、微囊载体1%~10%,水补齐至100%。The microcapsule suspension consists of the following components by weight: 0.1% to 30% of the first active component, 0.1% to 40% of the second active component, 1% to 20% of emulsifier, and 1% of solvent %~20%, thickener 0%~10%, antifreeze 0%~10%, stabilizer 0%~5%, defoamer 0%~5%, microcapsule carrier 1%~10%, water supplement Align to 100%. 8.按照权利要求1至3之一所述的农业杀虫杀菌组合物的应用,其特征在于所述杀虫杀菌组合物被用于防治水稻害虫和病害。8. The application of the agricultural insecticidal and fungicidal composition according to any one of claims 1 to 3, characterized in that the insecticidal and fungicidal composition is used to control rice pests and diseases. 9.按照权利要求8所述的农业杀虫杀菌组合物的应用,其特征在于所述水稻害虫为稻纵卷叶螟、二化螟和大螟,水稻病害为水稻纹枯病、稻瘟病和稻曲病。9. According to the application of the agricultural insecticidal and fungicidal composition according to claim 8, it is characterized in that said rice pests are rice leaf rollers, rice stem borers and rice borers, and rice diseases are rice sheath blight, rice blast and Rice smut. 10.按照权利要求8所述的农业杀虫杀菌组合物的应用,其特征在于所述杀虫杀菌组合物在田间的施用剂量为100g a.i./hm2~150g a.i./hm210. The application of the agricultural insecticidal and fungicidal composition according to claim 8, characterized in that the dosage of the insecticidal and fungicidal composition in the field is 100g ai/hm 2 -150g ai/hm 2 .
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