AR043813A1 - Procedimiento para la preparacion de hidroperoxidos por oxidacion catalitica de etilbenceno - Google Patents
Procedimiento para la preparacion de hidroperoxidos por oxidacion catalitica de etilbencenoInfo
- Publication number
- AR043813A1 AR043813A1 ARP040101090A ARP040101090A AR043813A1 AR 043813 A1 AR043813 A1 AR 043813A1 AR P040101090 A ARP040101090 A AR P040101090A AR P040101090 A ARP040101090 A AR P040101090A AR 043813 A1 AR043813 A1 AR 043813A1
- Authority
- AR
- Argentina
- Prior art keywords
- group
- hydrocarbonyl
- compound
- rings
- cyclic
- Prior art date
Links
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 title abstract 4
- 150000002432 hydroperoxides Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 230000003197 catalytic effect Effects 0.000 title 1
- 125000003118 aryl group Chemical group 0.000 abstract 5
- 150000001875 compounds Chemical class 0.000 abstract 4
- 125000004122 cyclic group Chemical group 0.000 abstract 4
- 125000006651 (C3-C20) cycloalkyl group Chemical group 0.000 abstract 3
- 125000003860 C1-C20 alkoxy group Chemical group 0.000 abstract 3
- 229910052736 halogen Inorganic materials 0.000 abstract 3
- 150000002367 halogens Chemical class 0.000 abstract 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 3
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 abstract 2
- -1 ethylbenzene Chemical class 0.000 abstract 2
- 229930195733 hydrocarbon Natural products 0.000 abstract 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract 2
- 150000001339 alkali metal compounds Chemical class 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000007789 gas Substances 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 125000005496 phosphonium group Chemical group 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04M—TELEPHONIC COMMUNICATION
- H04M1/00—Substation equipment, e.g. for use by subscribers
- H04M1/02—Constructional features of telephone sets
- H04M1/0202—Portable telephone sets, e.g. cordless phones, mobile phones or bar type handsets
- H04M1/026—Details of the structure or mounting of specific components
- H04M1/0266—Details of the structure or mounting of specific components for a display module assembly
- H04M1/027—Details of the structure or mounting of specific components for a display module assembly including magnifying means
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C409/00—Peroxy compounds
- C07C409/02—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides
- C07C409/04—Peroxy compounds the —O—O— group being bound between a carbon atom, not further substituted by oxygen atoms, and hydrogen, i.e. hydroperoxides the carbon atom being acyclic
- C07C409/08—Compounds containing six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
- C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C407/00—Preparation of peroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/27—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
- C07C45/32—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
- C07C45/33—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
- C07C45/34—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
- C07C45/36—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in compounds containing six-membered aromatic rings
-
- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04M—TELEPHONIC COMMUNICATION
- H04M1/00—Substation equipment, e.g. for use by subscribers
- H04M1/02—Constructional features of telephone sets
- H04M1/0202—Portable telephone sets, e.g. cordless phones, mobile phones or bar type handsets
- H04M1/0206—Portable telephones comprising a plurality of mechanically joined movable body parts, e.g. hinged housings
- H04M1/0208—Portable telephones comprising a plurality of mechanically joined movable body parts, e.g. hinged housings characterized by the relative motions of the body parts
- H04M1/0214—Foldable telephones, i.e. with body parts pivoting to an open position around an axis parallel to the plane they define in closed position
- H04M1/0216—Foldable in one direction, i.e. using a one degree of freedom hinge
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Signal Processing (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
La presente trata de un procedimiento para preparar hidroperóxidos a partir de sus hidrocarburos correspondientes que comprende la oxidación de dichos hidrocarburos, particularmente etilbenceno, con un gas que contiene oxígeno en presencia de un catalizador que comprende un compuesto imido cíclico y un compuesto seleccionado del grupo constituido por un compuesto de metal alcalino o su mezcla. Reivindicación 2: Procedimiento según la reivindicación 1 en el que dicho compuesto imido cíclico es el compuesto de fórmula (1): en la que X es un radical oxilo o un grupo O-R1, en el que R1 se selecciona del grupo constituido por H, halógeno, hidroxilo, alquilo C1-6, arilo C6-18, cicloalquilo C3-20, alcoxi C1-20, -CO-R2, en el que R2 es un grupo hidrocarbonilo C1-20, -O-CO-R3, en el que R3 es un grupo hidrocarbonilo C1-20 o un grupo carboxilo, o -CO-O-R2, en el que R2 es un grupo hidrocarbonilo C1-20; A es -CR4=CR5- o -CR4-CR5, en el que: (i) R4 y R5 se seleccionan independientemente el grupo constituido por H, halógeno, hidroxilo, alquilo C1-6, arilo C6-18, cicloalquilo C3-20, alcoxi C1-20, -CO-R2, en el que R2 es un grupo hidrocarbonilo C1-20, -O-CO-R3, en el que R3 es un grupo hidrocarbonilo C1-20 o un grupo carboxilo, o -CO-O-R2, en el que R2 es un grupo hidrocarbonilo C1-20; o (ii) R4 y R5 tomados juntos con los átomos de C a los que se les agrega forman un grupo cíclico, conteniendo dicho grupo cíclico de 1 a 8 anillos, o bien fusionados o bien unidos, siendo dichos anillos, anillos aromáticos o anillos no aromáticos, teniendo cada anillo de 3 a 18 miembros seleccionados del grupo constituido por átomos de C y heteroátomos y siendo opcionalmente sustituidos con uno o más sustituyentes seleccionados del grupo constituido por nitro, grupo fosfino, grupo fosfonio, halógeno, hidroxilo, alquilo C1-6, arilo C6-18, cicloalquilo C3-20,alcoxi C1-20.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03380211A EP1520853B1 (en) | 2003-09-24 | 2003-09-24 | Process for preparation of hydroperoxides |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR043813A1 true AR043813A1 (es) | 2005-08-17 |
Family
ID=34307049
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP040101090A AR043813A1 (es) | 2003-09-24 | 2004-04-01 | Procedimiento para la preparacion de hidroperoxidos por oxidacion catalitica de etilbenceno |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7038089B2 (es) |
| EP (1) | EP1520853B1 (es) |
| JP (1) | JP4693354B2 (es) |
| KR (1) | KR100854179B1 (es) |
| AR (1) | AR043813A1 (es) |
| AT (1) | ATE453619T1 (es) |
| DE (1) | DE60330775D1 (es) |
| ES (1) | ES2339111T3 (es) |
| PT (1) | PT1520853E (es) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101687784B (zh) * | 2007-08-22 | 2014-11-12 | 埃克森美孚化学专利公司 | 烃的氧化 |
| US8658836B2 (en) * | 2007-10-31 | 2014-02-25 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| EP2220039B1 (en) * | 2007-10-31 | 2016-07-27 | ExxonMobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| EP2098505A1 (en) | 2008-03-06 | 2009-09-09 | ExxonMobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| EP2098504A1 (en) | 2008-03-06 | 2009-09-09 | ExxonMobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| JP2011525195A (ja) * | 2008-08-26 | 2011-09-15 | エクソンモービル・ケミカル・パテンツ・インク | アルキルベンゼンヒドロペルオキシドの製造方法 |
| WO2010042273A1 (en) * | 2008-10-10 | 2010-04-15 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| CN104529853A (zh) * | 2008-12-15 | 2015-04-22 | 埃克森美孚化学专利公司 | 烷基芳族化合物的氧化 |
| EP2470501A2 (en) * | 2009-08-28 | 2012-07-04 | ExxonMobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| WO2011066037A1 (en) | 2009-11-25 | 2011-06-03 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| CN103097351B (zh) | 2010-09-14 | 2016-03-09 | 埃克森美孚化学专利公司 | 环己基苯的氧化方法 |
| WO2012036829A1 (en) | 2010-09-14 | 2012-03-22 | Exxonmobil Chemical Patents Inc. | Oxidation of hydrocarbons |
| US9096509B2 (en) | 2012-01-18 | 2015-08-04 | Exxonmobil Chemical Patents Inc. | Process for producing phenol |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3949004A (en) | 1971-03-16 | 1976-04-06 | Atlantic Richfield Company | Hydroperoxide production |
| US3816540A (en) | 1971-05-24 | 1974-06-11 | Petro Tex Chem Corp | Preparation of hydro-peroxides by autoxidation |
| US4066706A (en) | 1975-04-21 | 1978-01-03 | Halcon International, Inc. | Preparation of ethylbenzene hydroperoxide |
| US4158022A (en) | 1976-12-01 | 1979-06-12 | Gulf Research & Development Company | Preparation of ethylbenzene hydroperoxide |
| US4262143A (en) | 1979-02-16 | 1981-04-14 | Halcon International, Inc. | Preparation of hydroperoxides |
| JPS55149247A (en) | 1979-05-09 | 1980-11-20 | Mitsui Petrochem Ind Ltd | Preparation of aromatic hydroperoxide |
| JPS5888358A (ja) * | 1981-11-19 | 1983-05-26 | Nippon Steel Chem Co Ltd | ９−ハイドロパ−オキシ−９−置換フルオレンの製造法 |
| JPS59190965A (ja) * | 1983-04-08 | 1984-10-29 | Sumitomo Chem Co Ltd | トリイソプロピルベンゼントリヒドロペルオキシドの製造法 |
| US4602118A (en) | 1984-11-09 | 1986-07-22 | Exxon Research And Engineering Co. | Liquid phase oxidation of organic compounds to their hydroperoxides |
| JPH0967337A (ja) | 1995-08-30 | 1997-03-11 | Mitsui Petrochem Ind Ltd | アリールアルキルヒドロペルオキシド類の製造方法 |
| JP3822265B2 (ja) | 1995-08-30 | 2006-09-13 | 三井化学株式会社 | アリールアルキルヒドロペルオキシド類の製造方法 |
| JP4756719B2 (ja) | 1997-02-17 | 2011-08-24 | ダイセル化学工業株式会社 | 酸化触媒系、酸化方法および酸化物の製造方法 |
| JP3985174B2 (ja) | 1997-07-09 | 2007-10-03 | 三井化学株式会社 | ヒドロペルオキシド類の製造方法 |
| EP0916655B1 (en) | 1997-11-13 | 2003-04-02 | Shell Internationale Researchmaatschappij B.V. | Process for preparing organic hydroperoxides |
| RU2128647C1 (ru) | 1998-03-24 | 1999-04-10 | Акционерное общество "Нижнекамскнефтехим" | Способ получения гидропероксида этилбензола |
| TWI269788B (en) | 1999-12-14 | 2007-01-01 | Daicel Chem | Process for preparing ketone, alcohol and hydroperoxide |
| DE10015874A1 (de) | 2000-03-30 | 2001-10-11 | Creavis Tech & Innovation Gmbh | Verfahren zur Herstellung von aromatischen Alkoholen insbesondere Phenol |
| DE10015880A1 (de) * | 2000-03-30 | 2001-10-11 | Creavis Tech & Innovation Gmbh | Verfahren zur Oxidation von Kohlenwasserstoffen |
| TWI294308B (es) | 2000-11-15 | 2008-03-11 | Daicel Chem | |
| JP4601805B2 (ja) | 2000-11-24 | 2010-12-22 | ダイセル化学工業株式会社 | シクロヘキサンの酸化方法 |
| EP1238704B1 (en) | 2001-03-09 | 2015-01-21 | Daicel Chemical Industries, Ltd. | Catalyst comprising a cyclic imide compound and process for producing organic compounds using the catalyst |
| US20030136603A1 (en) | 2002-01-22 | 2003-07-24 | Parghi Kaumil H. | Parghi ergomobile |
-
2003
- 2003-09-24 AT AT03380211T patent/ATE453619T1/de not_active IP Right Cessation
- 2003-09-24 ES ES03380211T patent/ES2339111T3/es not_active Expired - Lifetime
- 2003-09-24 EP EP03380211A patent/EP1520853B1/en not_active Expired - Lifetime
- 2003-09-24 DE DE60330775T patent/DE60330775D1/de not_active Expired - Lifetime
- 2003-09-24 PT PT03380211T patent/PT1520853E/pt unknown
-
2004
- 2004-01-22 US US10/762,792 patent/US7038089B2/en not_active Expired - Fee Related
- 2004-02-06 KR KR1020040007949A patent/KR100854179B1/ko not_active IP Right Cessation
- 2004-02-26 JP JP2004051137A patent/JP4693354B2/ja not_active Expired - Fee Related
- 2004-04-01 AR ARP040101090A patent/AR043813A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20050065381A1 (en) | 2005-03-24 |
| EP1520853B1 (en) | 2009-12-30 |
| ATE453619T1 (de) | 2010-01-15 |
| PT1520853E (pt) | 2010-04-08 |
| KR20050030091A (ko) | 2005-03-29 |
| JP4693354B2 (ja) | 2011-06-01 |
| DE60330775D1 (de) | 2010-02-11 |
| JP2005097234A (ja) | 2005-04-14 |
| ES2339111T3 (es) | 2010-05-17 |
| US7038089B2 (en) | 2006-05-02 |
| EP1520853A1 (en) | 2005-04-06 |
| KR100854179B1 (ko) | 2008-08-26 |
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