09-06-2025

4602CJA101021250003 JM

PART-1 : PHYSICS

SECTION-I

1) In a wire of cross-section radius r, free electrons travel with drift velocity v when a current I flows
through the wire. What is the current in another wire of half the radius and of the same material
when the drift velocity is 2v ?

(A) 2I
(B) I
(C) I/2
(D) I/4

2) The charge flowing through a resistor R varies with time t as Q = 3t – 6t2. The heat produced in R
till the current in it becomes zero is :-

(A)

(B)

(C)

(D)

3) A uniform wire of resistance R is stretched uniformly n times and then cut to form five identical
wires. These wires are arranged in the form of a wheat - stone’s bridge. The effective resistance of
the bridge is :

(A)

(B)

(C)

(D)

4) Find resistance of the annular disc between centre and periphery of the disc. The inner and outer
radius of the disc is a and b respectively. The thickness of the disc is t and conductivity of its
material is .

(A)
(B)

(C)

(D)

5) In the given circuit as shown in figure the value of R(in Ω) for which current through 4Ω resistor is

zero.

(A) 1 Ω
(B) 2 Ω
(C) 3 Ω
(D) 4 Ω

6) In the given circuit diagram, a wire is joining points B and D. The current in this wire is:

(A) 4A
(B) 2A
(C) 0.4A
(D) Zero

7) Determine the electromotive force and internal resistance of the following system of batteries :

(A) (12.5V, 3Ω)

(B) (25V, 8Ω)
(C) (25V, 6Ω)
(D) (12.5V, 8Ω)

8) If X, Y and Z in figure are identical lamps, which of the following changes to the brightness of the

lamps occur when switch S is closed?

(A) X stays the same, Y decreases

(B) X increases, Y decreases
(C) X increases, Y stays the same
(D) X decreases, Y increases

9) If internal resistance of a cell is proportional to current drawn from the cell. Then the best
representation of terminal potential difference of a cell with current drawn from cell will be:

(A)

(B)

(C)
(D)

10) Figure shows two V–I curve for two different metallic conductors. If tan θ = then find the

ratio of two resistances :-

(A)
(B) 2

(C)

(D)

11) An electric circuit consists of a battery emf E = 110 V, and internal resistance is 5Ω and two
resistors connected in parallel to the source as shown in figure. Determine the value of R so that

maximum power gets dissipated in resistance R.

(A) 50/11
(B) 50/12
(C) 50
(D) 50/13
12) Total power consumption for the given circuit is :-

(A) 25 W
(B) 50 W
(C) 100 W
(D) 75 W

13) Identical metal plates are located in air at equal distances d from one another. The area of each
plate is equal to A. If plates are interconnected as shown in figure, then the capacitance of system

between points P and Q is :-

(A)

(B)

(C)

(D) None of these

14) Three capacitors of capacitances 5μF, 2μF and 2μF are charged to 20 V, 30 V and 10 V
respectively and then connected in the circuit with polarities as shown. The magnitude of charge

flown through the battery after closing the switch S is

(A) 25μC
(B) 40μC
(C) 50μC
(D) 75μC

15) The plates of a parallel plate condenser are being moved away with a constant speed v. If the
plate separation at any instant of time is d then the rate of change of capacitance with time is
proportional to :-

(A)

(B) d
(C) d2

(D)

16) In the network shown we have three identical capacitors. Each of them can withstand a
maximum 100 V p.d. What maximum voltage can be applied across A and B so that no capacitor gets

spoiled?

(A) 150 V
(B) 120 V
(C) 180 V
(D) 200 V

17) In the circuit, if no current flows through the galvanometer when the key K is closed, the bridge

is balanced. The balancing condition for bridge is

(A)

(B)

(C)

(D)
18) In the circuit shown, when the switch S is closed, then

(A) no charge flows through S

(B) charge flows from A to B
(C) charge flows from B to A
(D) charge flows initially from A to B and later from B to A

19) In the arrangement shown in figure, dielectric constant K1 = 2 and K2 = 3. If the capacitance are

C1 and C2 respectively, then will be : (The gaps shown are negligible)

(A) 1 : 1
(B) 2 : 3
(C) 9 : 5
(D) 25 : 24

20) A light bulb, a capacitor and a battery are connected together as shown here, with switch s
initially open. When the switch s is closed, which one of the following is true

(A) The bulb will light up for an interval when the capacitor charging
(B) The bulb will light up when the capacitor is fully charged
(C) The bulb will not light up at all
(D) The bulb will light up and go off at regular intervals

SECTION-II

1) A parallel-plate capacitor of capacitance 100 μF is connected to a power supply of 200 V. A

dielectric slab of dielectric constant 5 is now inserted into the gap between the plates. Find the
change in the electrostatic energy (in J) of the electric field in the capacitor.

2) In the circuit shown in figure potential difference between point A and B is 16V. Find the current

passing through 2Ω resistance.

3) The series combination of two batteries, both of the same emf 10 V, but different internal
resistance of 20Ω and 5Ω, is connected to the parallel combination of two resistors 30 Ω and R Ω.
The voltage difference across the battery of internal resistance 20Ω is zero, the value of R (in Ω) is :
_______

4) Switch S is closed at t = 0; to begin charging of uncharged capacitor of capacitance C = 15µF

through a resistance R = 20Ω. The time after which potential difference across the capacitor is equal
to that across the resistor is given by αℓn2 milli second. Then write down the value of 10α in OMR

sheet.

5) A capacitor of 2μF is charged as shown in the diagram. When the switch S is turned to position 2,

the percentage of its stored energy dissipated is :

PART-2 : CHEMISTRY

SECTION-I

1) Secondary alcohols on heating with copper at 300°C give

(A) Alkenes
(B) Aldehydes
(C) Ketones
(D) tert-alcohols
2)
The products (x) and (y) are :

(A)

(B)

(C)

(D)

3) What is the final product (major) 'A' in the given reaction ?

(A)

(B)

(C)

(D)

4) The major product formed in the following reaction is :-

(A)

(B)

(C)

(D)

5) If phenyl magnesium bromide and acetaldehyde are the reactants, the product formed after
hydrolysis would be :

(A) Benzyl alcohol

(B) 1-Phenylethanol
(C) 2-Phenylethanol
(D) Acetone

6) Which of the following gives most stable carbocation by dehydration :-

(A) (CH3)2CH—OH
(B) (CH3)3C—OH
(C) CH3—CH2—OH
(D) CH3—CH2—O—CH2—CH3

7) Which of the following reactions would give the best yield of t-butyl methyl ether ?
 (CH3)3C–OH
(A)

(B) (CH3)3C–Br + CH3OH →

(C)
→

(D)

8) B CH = CH – CHO A
A and B are respectively :

CH2CH2CHO,
(A)

CH = CH–CH2OH

CH2CH2CH2OH,
(B)

CH = CH – CH2OH

(C)
CH= CH–CH2OH in both cases

(D)
CH2CH2CH2OH in both cases

9) In the reaction :

which of following compounds will be formed :

(A)

(B)

(C)

(D)

10)
A and B are :

(A)

(B)

(C)

(D)

11) In the given reaction, the product P is:

(A)

(B)
(C)

(D)

12) The structure of the compound that gives tribromo derivative on treatment with bromine water
is -

(A)

(B)

(C)

(D)

13) The main product of the following reaction is

C6H5CH2CH(OH)CH(CH3)2
(A)

(B)

(C)

(D)

14) An unknown alcohol is treated with the "Lucas reagent' to determine whether the alcohol is
primary, secondary or tertiary. Which alcohol reacts fastest and by what mechanism :-

(A) secondary alcohol by SN1

(B) tertiary alcohol by SN1
(C) secondary alcohol by SN2
(D) tertiary alcohol by SN2

15) Correct statement about major product(s) is :

Products

(A) It follow SN1 and racemic mixture of alcohol is obtained

(B) It follow SN1 and racemic mixture of alkyl iodide is obtained
(C) It follow SN2 and racemic mixture of alcohol is obtained
(D) It follow SN2 and racemic mixture of alkyl iodide is obtained

16) Which one of the following is most reactive for SN1 reaction :

(A)

(B)

(C)
(D)

17) Which one of the following is the correct option of reagent for the above conversion?

(A)

(B)

(C)
(D)

18) What is the major product of the following reaction:

(A)

(B)

(C)

(D) None of these

19) The compound

The compound C is

(A) o-Bromotoluene
(B) m-Bromotoluene
(C) p-Bromotoluene
(D) 3-Bromo-2,4,6-trichlorotoluene
20)
A and B are

(A) t-butyl benzene, n-propyl benzene

(B) iso-butyl benzene, iso-propyl benzene
(C) t-butyl benzene, isopropyl benzene
(D) iso-butyl benzene, n-propyl benzene

SECTION-II

1) How many isomers obtained on the monochlorination of 3-methylpentane (Excluding

stereoisomers) :-

2) How many meso compounds are possible from pentane–2, 3, 4–triol :-

3)
[Number of dihalogen derivatives including stereo isomers] (At carbon configuration is fixed)

Then the value of (X + Y) is

4) Total numbers of possible alkene obtained on reaction of with alcoholic KOH.

5) Identify number of substrates those can give SN1 and SN2 reaction both.
 PART-3 : MATHEMATICS

SECTION-I

1) If y = f(x) and
then domain of f(x) is

(A)

(B)

(C)

(D)

2) The value of is
(A)

(B)

(C)

(D)

3) If α, β, γ are the roots of the equation

x3 + mx2 + 3x + m = 0, then
may be equal to

(A)

(B)

(C) π

(D)

4)
(where a > 1) is equal to

(A)

(B)

(C)

(D) 1

5) If ,
then the value of n is equal to

(A) 29
(B) 31
(C) 30
(D) 33

6) If
the minimum value of n is

(A) 3
(B) 2
(C) 1
(D) 5

7)
is equal to

(A)

(B) 1
(C)
(D) 0

8) If α>β>0 are the roots of the equation ax2+bx+1=0,

and ,
then k is equal to

(A) 2β
(B) 2α
(C) α
(D) β

9) If for , ,
2 2
then 5a + b is equal to

(A) 72
(B) 76
(C) 68
(D) 64

10) If f(x + y) = f(x) + f(y) for all x, y ∈ R and f(1) = 1,

then evaluate

(A)

(B)

(C)

(D)
11) is equal to

(A)

(B)

(C)
(D)

12)

If ; x ≠ 0 and f(x) is continuous at x = 0 then f(0) is

(A) 0
(B) 1
(C) e
(D) e–1/2

13)

The value of a + b + c when

is continuous for all x is

(A) 5
(B) 7
(C) 10
(D) 11

14) If f(x)
is continuous function (where n being odd integer), then

(A) bn – an = 1
(B) b2n+1 – a2n+1 = 2
(C) bn – an = –1
(D) bn – an = 0

15)

The value of k + f(0) so that

can be made continuous at x = 0 is

(A) 1
(B) 2

(C)

(D) 0

16) Let f(x) be a function defined by

,
then which of the following is incorrect

(A)

(B)

(C)

(D)
f(x) is continuous function at

17) The number of points of discontinuity of the

function
(where [.] represent G.I.F.) is

(A) 30
(B) 29
(C) 31
(D) None of these

18) Number of points where the function :

(here, f(1) = 0)
is continuous but non-diffrentiable. (Where [ . ] denotes greatest integer function and { } denotes
fraction part function.)

(A) 1
(B) 2
(C) 3
(D) 0

19) If K denotes the sum of squares of all the points 'x' at which the function f(x) = |10 + 3|x| – x2|
is non-differentiable, then value of K is

(A) 50
(B) 51
(C) 52
(D) 53

20) For any y ∈ let cot–1( y) ∈ (0, π) and

tan–1 (y) ∈ . Then the sum of all

the solutions of the equation

for 0 < | y | < 3, is equal to

(A)
(B)
(C)
(D)

SECTION-II

1) If the value of sin–1(sin8)+cos–1(cos6)+tan–1(tan9)=aπ+b where a and b are integers then the value
of 'a – b' is

2)

3) If ,

then range of x is (a, b) then is

4) Number of points of discontinuity of

f(x) = [x2 + 1] in [–2, 2] is (where [.] is G.I.F.)

5) Let f(x) = ,
is differentiable at x = 0, then minimum value of [p + q] equals (where [.] represents greatest
integer function)
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C A C C A B C B D B A C B A D A B A D A

SECTION-II

Q. 21 22 23 24 25
A. 8.00 3.5 30.00 3.00 80.00

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A A D B B D B C A B D B B B A D A B C

SECTION-II

Q. 46 47 48 49 50
A. 4.00 2.00 10.00 3.00 6.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. D C C D B A D B C C A B D B B D C A A C

SECTION-II

Q. 71 72 73 74 75
A. 7.00 2.00 0.25 8.00 6.00
 SOLUTIONS

PART-1 : PHYSICS

1)

I = neνdA

2)

t=

H–

3) Al = nl × A' ⇒ A' =

R' = n2R ⇒R1 =

Req = R1]

4) The resistance of a cross-section perpendicular to the current flow on any radius r and thus
of area is given by

Total resistance
5)
By Kirchoff
10 – 2i – R(i – i1) – 4 = 0

...(i)
10 – 2i – 6 = 0
i=2 ...(ii)
by equation (i) & (ii)
R = 1Ω

6) Current in =8A

Current in BC=

7)

8)
Power across

Finally, , Power
Hence increases, decreases.

9) Given r ∝ i
⇒ r = ki
V = E – ir = E – i(ki)

V = – i2 k + E

10) RA = tan (90 – θ)

RB = tan θ

= cot2 θ = 2

11) Current in resistance R is

Power =
For maximum power

⇒R=

12)
13)
C(y – V) + C(y – x) + Cy = 0
3y – x = V
C(x – 0) + C(x – y) + C(x – V) = 0
3x – y = V

⇒ 8x = 4V ⇒ x = ,y=

⇒ ΔQ =

14)

Therefore, magnitude of charge flown through the battery is

15)

16) When applied p.d. is V across A & B assuming VAC = V1 & VCB = V2 we have, V1 = &
hence

V1 = & V2 =
As V1 & V2 both must not exceed 100 V, the maximum value of applied p.d. across A & B would
be 150 V.

17)
as VA–VB =0, VC–VA = IR1,

VA–VD=IR2, VC–VB= , VB–VA=

..............(i)

...........(ii)

18) For two conductors in series, their potential differences are proportional to their
resistances. For two capacitors in series, their potential differences are inversely proportional
to their capacitances. Hence, A and B are at the same potential and no charge will flow
between them.

19) First arrangement is a parallel combination.

C1' = =

= ( K1 = 2)

and C'2 = = ( K2 = 3)

C1 = C'1 + C'2 = ( parallel combination)

Second one is a series combination :

C1" = = = ,

C2" = = = ,

⇒ C2 = = =

⇒ =

20) Initially when key is closed, the capacitor acts as short-circuit, so bulb will light up. But
finally the capacitor becomes fully charged, so it will act as open circuit, so bulb will not glow.
21)

22)

Combining cells:

Enet =

rnet =
Current in 2W

= = 3.5 A

23)
E1 = E – ir
E2 = E – ir
= 10 – i20 = 0
= 10 – 0.5 × 5
i = 0.5 A
= 7.5 V

i = i1 + i2

0.5 =
x = 30 Ω
 24) VC = VR ⇒
t = RCℓn2

25) Initial energy stored in capacitor 2 μF

Final voltage after switch 2 is ON

Final energy in both the capacitors

So energy dissipated

PART-2 : CHEMISTRY

26) 2° alcohol on oxidation with Cu gives ketone.

27)
28)

29)
It can oxidise 1° Alcohol but not 3° Alcohol. & 1° alcohol is converts with aldehyde.

30)

Concept : PhMgBr = Grignard reagent

CH3CHO = aldehyde
Product is secondary alcohol
Sol. :

Answer : B
31)
Stability order of carbocation is 3° > 2° > 1°

32)
Other's are example of elimination reaction.

33)

34)

35)
3° alcohol does not oxidised

36) MnO2 is a mild oxidising agent. It oxidises only allylic alcohols.

37)
38)

39) The reaction of alcohol with Lucas reagent is mostly SN1 reaction and the rate of reaction
is directly proportional to the stability of carbocation formed in the reaction.
Since, 3° R–OH forms 3° carbocation (most stable) hence, it will react fastest by SN1 reaction.

40)

41) Theory based

42)

43) Alc. KOH is dehydrohalogenating reagent and follow antielimination of H and X.

44)

45)

46) Number of monochloroproducts = number of monovolent radicals

47)
Pseudo chiral carbon present
 So P.O.S. = present
M= =

48) Total 5 dihalogen derivatives are formed including stereoisomers in which two are
diastereomers. ∴ x + y = 10

49) Explain Question :

Asking about total elimination products of

Concept :
E2 elimination reaction takes place on heating with alcoholic KOH.
Solution :
In E2 reaction β-H is removed along with halogen in one step process.

Total 3-different alkenes are formed.

Final Answer : (3)

50) SN1 reaction given by those halides which directly produce 2º or 3º or resonance stable
carbocation.
SN2 reaction given by CH3 or 1º or 2º halides.
Thus (i), (iii), (v), (vii), (x), (xi) will give both SN1 & SN2 reaction both.

PART-3 : MATHEMATICS

51) , x > 0, |y| ≠ 0

52)

cot–1(1 + n(n + 1)) =

cot–1(1 + n(n + 1)) = tan–1(n + 1) – tan–1(n)
= tan–1(49) – tan–1(1)

53) α, β, γ are the roots of equation x3 + mx2 + 3x + m = 0

α + β + γ = –m, αβ + βγ + γα = 3, αβγ = –m

As

So,

54)

55)

56) We have,

{as cot x is decreasing for 0 < x < π}

Since, nearly

2.1 < n < 7.9

n = 3, 4, 5, 6, 7
or minimum value of n = 3

57)

and

58) α, β are roots of ax + bx + 1 = 0

2

are roots of x2 + bx + a = 0,
(by transformation)

x2 + bx + a =

Comparing k = 2α

59)
On expansion,

For limit to be exist a –

a=

and = 17
2 2 2
a + b + 4a = 17 × 4
5a2 + b2 = 68

60) Here, f(x + y) = f(x) + f(y) f(2) = f(1) + f(1) = 2

f(3) = f(1 + 2) = f(1) + f(2) = 3
f(4) = f(1 + 3) = f(1) + f(3) = 4
∴ f(x) = x, for all x ∈ R

61) Using L- Rule

62)

63)

x2 + bx + c = ax2 + 3x + 7 is possible when

a = 1, b = 3 and c = 7

64) at x = 2n, n is odd

a n + 1 = bn – 1
bn – an = 2

65)
f(x) is continuous at x = 0, then =1

66)

67) and whenever

Also, if , then

68)
continuous but not differentiable at x = 1.

69)
∴ x = 5, –5, 0 are points of non-differentiability
∴ K = 52 + 52 = 50

70) Case-I : y ∈ (–3,0)

(∵ y ∈ (–3,0))
Case-I : y ∈ (0,3)

or (rejected)
sum

71) sin–1(sin8) + cos–1cos(6) + tan–1tan9

= sin–1sin(3π – 8) + cos–1cos(2π – 6) + tan–1(9 – 3π)
= 3π – 8 + 2π – 6 + 9 – 3π
= 2π – 5
⇒ a = 2, b = –5
So, a – b = 7

72)

=3–1=2

73)

for this

⇒ –5 < x – 3 < 5
⇒ –2 < x < 8
⇒ x ∈ (–2, 8) ≡ (a, b)
∴ a = –2
b=8

So

74)

2f(x) · f(y) = f (x + y) + f (x – y) ......... (1)

2 f(y) f(x) = f (y + x) + f(y – x) ....... (2)
(1)...... (2) f (x – y) – f(y – x) = 0
putting y = 0 f(x) – f(–x) = 0
H.w.r. to x f'(x) + f'(–x) = 0 ⇒ f'(3) + f'(–3) = 0

75)

It exist only when p > 3 and q ≥ 3, p + q > 6

[p + q]min = 6