22-06-2025

1803CJA101029250035 JM

PART-1 : PHYSICS

SECTION-I

1) Two identical metal plates are given positive charges Q1 and Q2 (< Q1) respectively. If they are
brought close together to form a parallel plate capacitor with capacitance C, the potential difference
between them is :-

(A)

(B)

(C)

(D)

2) Figure shows the capacitors in steady state, with S open. When S is closed :-

(A) Both batteries supply energy & heat is lost.

(B) Both batteries supply energy to increase the energy of both the capacitors separately
(C) One battery supplies & other absorbs energy and no heat loss takes place.
(D) One battery supplies energy, other absorbs and heat is lost in the process.

3) 4 capacitors are connected as shown, connected with a battery. Breakdown voltages of each
capacitor C1, C2, C3 & C4 are 60 V, 50V, 90 V & 150 V respectively. If potential difference of battery
is increased from zero, then the capacitor which will breakdown first will be (given that C1 = 1 µF,

C2 = 2 µF, C3 = 3 µF, C4 = 4 µF)

(A) C1
(B) C2
(C) C3
(D) C4

4) Identical metal plates are located in air at equal distances d from one another. The area of each
plate is equal to A. If plates are interconnected as shown in figure, then the capacitance of system

between points P and Q is :-

(A)

(B)

(C)

(D) None of these

5) In wheat stone's bridge shown in the adjoining figure galvanometer gives no deflection on

pressing the key, the balance condition for the bridge is :-

(A)

(B)

(C)

(D)

6) In the circuit shown below, initiallly the switch is open and the capacitors are uncharged. The
ratio of current through 2Ω resistor, just after the switch is closed and a long time after the switch is
closed :

(A) 2 : 1
(B) 1 : 2
(C) 3 : 1
(D) 1 : 3

7) Diagram shows 6 identical air capacitors connected to an ideal battery (V). In this condition,
charge on capacitor C6 is Q1. Now a dielectric whose dielectric constant is 2, is put between the
plates of C4 so that it occupies the entire space between the plates. Now charge on C6 becomes Q2.

Then should be :-

(A)

(B)

(C)

(D)

8) In figure an arrangement of three identical capcitors is shown along with a switch S and a battery
B. If the switch S is closed, then the ratio of the energy of the capacitors system in the final steady

state to the initial state is :

(A) 2 : 1
(B) 4 : 3
(C) 3 : 2
(D) 3 : 4

9) Four capacitors are connected as shown in figure to a 30 V battery. The potential difference

between points b and a is :

(A) 5 V
(B) 9 V
(C) 10 V
(D) 13 V

10) Find the potential difference across AB. If voltage of ideal battery 5 Volt is :

(A) 4 V
(B) 2 V
(C) 1 V
(D) None of these

11) Capacitor 3 in circuit shown below is a variable capacitor. Graph shows the electric potential
across capacitor 1 versus C3. The electric potential V across the battery and capacitance C1 is :-

(A) 2V, 8 µF
(B) 10V, 6 µF
(C) 10V, 8 µF
(D) 10V, 12 µF

12) An air capacitor having capacity C0 is filled with dielectric as shown in figure. then the new
capacitance of system will be

(A) C0
(B) 2C0
(C) 3C0
(D) 4C0

13) In the adjoining diagram two geometrically identical capacitors A and B are connected to a
battery. Air is filled between the plates of C1 and a dielectric is filled between the plates of C2, then-

(A) q1 < q2
(B) q1 > q2
(C) q1 = q2
(D) None of these

14) If capacitor connected across AB is charged to Q and then switch is shifted to 2 from 1. The heat
released after that :-

(A)

(B)
(C)

(D) Zero

15) In the circuit shown in figure, the equivalent capacitance between the points X and Y is :

(A)
(B)
(C)
(D)

16) Initially capacitor is uncharged and at t = 0 switch is closed. The value of i after a very long time

is :-

(A) 6A
(B) 5A
(C) 7A
(D) 4A

17) The switch S in the circuit diagram figure is closed at t = 0. The charge on each capacitor at any

time t is

–2t/3RC
(A) q(t) = EC (1 – e )
–t/2RC
(B) q(t) = EC (1 – e )
–t/3RC
(C) q(t) = EC (1 – e )
–3t/2RC
(D) q(t) = EC (1 – e )

18) In the given circuit diagram when the current reaches steady state in the circuit, the charge on
the capacitor of capacitance C will be :

(A)

(B)

(C) CE

(D)

19) A 10 μF condenser is charged to a potential of 100 volt. It is now connected to another

uncharged condenser. The common potential reached is 40 volt. The capacitance of second
condenser is

(A) 2 μF
(B) 15 μF
(C) 10 μF
(D) 22 μF

20) A parallel plate capacitor is connected from a cell and then isolated from it. Two dielectric slabs
of dielectric constant K and 2K are now introduce in the region between upper half and lower half of
the plate (as shown in figure). The electric field intensity in upper half of dielectric is E1 and lower

half is E2 then

(A) E1 = 2E2
(B) Electrostatic potential energy of upper half is less than that of lower half
(C) Induced charges on both slabs are same
(D) Charge distribution on the plates remains same after insertion of dielectric

SECTION-II

1) In the circuit shown, a potential difference of 60V is applied across AB. The potential difference
(in V) between the points M and N is:

2) In a parallel plate capacitor set up, the plate area of capacitor is 2 m2 and the plates are separated
by 1m. If the space between the plates are filled with a dielectric material of thickness 0.5 m and
area 2m2 (see fig.) the capacitance of the set-up will be ______ ε0. (Dielectric constant of the material

= 3.2) (Round off to the Nearest Integer)

3) A capacitor and three resistors are used to make a circuit as shown. Initially the capacitor is

0
charged by Q . When switch is closed total heat is dissipated in 4R resistor then value of is :

4) 10 identical capacitors are connected as shown. The capacitance of each capacitor is 30 μF. The

equivalent capacitance between A and B is x µF then find .

5) Find the time constant for given circuit if (in )

PART-2 : CHEMISTRY

SECTION-I

1) The correct order of reactivity of PhMgBr with following compounds will be.
(C6H5)2CO, CH3 – CH = O , (CH3)2 C = O
(1) (2) (3)

(A) 1 > 2 > 3

(B) 2 > 3 > 1
(C) 3 > 2 > 1
(D) 1 > 3 > 2

2) Complete the reaction :

Product

(A)

(B)

(C)

(D)

3) In the reaction sequence :

(X) & (Y) respectively are

(A)

(B)

(C)

(D)

4) 5 mole H2O(ℓ) at 373 K and 1 atm is converted into H2O(g) at 373 K and 5 atm. ΔG for this process
is
[Given: R = 2 cal/K-mol]

(A) Zero
(B) 1865 ℓn 5 Cal
(C) 3730 ℓn 5 Cal
(D) –3730 ℓn 5 Cal

5) For 1 mole of an ideal monoatomic gas on moving from one state to another state, the
temperature of gas is doubled and its pressure become 4 times. Then entropy change in the process
will be :

(A)

(B)

(C) 2R ln 2

(D)

6) In the reaction,

Final product C is.

(A) Ethylene
(B) Acetyl chloride
(C) Acetaldehyde
(D) Acetylene

7) An ideal gas is subjected to two different reversible expansion

processes and from same initial state to same final volume. Which of the following statements is
correct regarding the two process

(A) Work done in second process is more as compared to first process

(B) Magnitude of work done can be compared only by knowing values of k1 and k2
(C) Heat capacity of gas for the two process is same
(D) Final state for the two processes will be same

8) The order of reactivity of alkyl halide in the reaction R–X + Mg RMgX is

(A) RI > RBr > RCl

(B) RCl > RBr > RI
(C) RBr > RCl > RI
(D) RBr > RI> RCl

9) Which of the following compounds will provide a tertiary alcohol on reaction with excess of
CH3MgBr followed by hydrolysis?

(A)

(B)

(C)

(D)

10) Which of the following compound gives tertiary alcohol with CH3MgBr?

(A) C6H5CHO
(B) C2H5CO2CH3
(C) C2H5COOH
(D)

11)
End product C is ?

(A)

(B)

(C)

(D)
12) In the given reaction ‘A’ can be

(A) benzyl bromide

(B) bromobenzene
(C) cyclohexyl bromide
(D) methyl bromide

13)

(A)

(B)

(C)

(D) HO – CH2 – CH2 – CH2 – CH2 – OH

14) Primary alkyl halides react with dialkyl copper reagent to give

(A) alkyl copper halides

(B) alkenes
(C) alkenyl halides
(D) alkanes

15) Calculate ΔH when 2 moles of solid benzoic acid undergo complete combustion at 300K if :

C6H5COOH(s) + O2(g) → 7CO2(g) + 3H2O(l)

ΔUreaction = – 750 kJ/mole
[R = 8 Joule/ mole-K]

(A) – 751.2 kJ
(B) – 752.4 kJ
(C) – 1501.2 kJ
(D) – 1502.4 kJ

16) One mole of a gas absorbs 200J of heat at constant volume. Its temperature rises from 298 K
to 308 K. The change in internal energy is :-

(A) 200 J
(B) –200 J

(C)
200 × J

(D)
200 × J

17) What is ΔU for the process described by figure. Heat supplied during the process q = 200 kJ.

(A) +50 kJ
(B) –50 kJ
(C) –150 kJ
(D) + 150 kJ

18)

For which process will ΔG° and ΔH° at 300K are expected to be most similar -

(A) 2Fe(s) + Al2O3(s) → 2Al(s) + Fe2O3(s)

(B) 2Na(s) + 2H2O(l) → 2NaOH(aq.) + H2(g)
(C) 2NO2(g) → N2O4(g)
(D) 2H2(g) + O2(g) → 2H2O(l)

19) Vapour pressure of water is 0.01 atm at 27ºC. Calculate ΔG for following change.
H2O (l, 0.01 atm, 27ºC) → H2O(g, 0.01atm, 27ºC)

(A) zero
(B) 300 R ln (0.01)
(C) 300 R
(D) –300 R

20) 4 gm of He gas is expanded isothermally at 300K from 1 litre to 10 litre. The change in entropy
of the gas is :
[Atomic mass : He = 4]

(A) 2 cal
(B) –2 cal
(C) –4.6 cal
(D) 4.6 cal

SECTION-II

1) A system undergoes a process in which ΔU = + 300J, while absorbing 400J of heat energy and
undergoing an expansion against 0.5 bar. What is the change in volume (in L)

2)
Find the maximum value of 'X'.

3) (1 mole)
Find value of x.

4) Among the following the number of state variable is ______.

Internal energy (U)
Volume (V)
Heat (q)
Enthalpy (H)

5) A carnot cycle has an efficiency of 40%. Its low temperature reservoir is at 9°C. What is
the temperature of source ?

PART-3 : MATHEMATICS

SECTION-I

1) The value of is equal to (where C is integration constant)

(A) x sin2x + C
(B) x . sin 2x + C
(C) x2 . sin2x + C
(D) x2 . sin x + C
2)

(A)
(B)
(C)
(D)

3) The integral dx, is equal to : (where c is a constant of integration)

(A)

(B)

(C)

(D)

4) The value of is equal to

(where C is integration constant)

(A)

(B) sin 3x + 3 sinx + C

(C) 3sin 3x + sinx + C
(D) sin 3x + sinx + C

5)

(A)

(B)

(C)

(D)

6) If where C is a constant of integration, then f(2) is equal to :

(A)

(B)
(C)

(D)

7) The value of is equal to

(A)

(B)

(C)

(D)

8) is equal to ________.
(where C is constant of integration)

(A)

(B)

(C)

(D)

9) The value of is equal to

(A)
(B)
(C)
(D)

10) The evaluation of is:

(A)

(B)
(C)

(D)

11) is equal to :

(A)

(B)

(C)

(D)

12) is equal to :

(A)

(B)

(C)

(D)

13) =

(A)
(B)
(C)
(D) None of these

14)

(A)
n2
(B) 2 n 2
(C) n 2
(D) – n 2

15) The value of is

(A)

(B)

(C)

(D)

16) = _______ + C.

(A)

(B)
(C)
(D)

17) If
is equal to (where, C is the constant of integration)

(A)
(B)
(C)
(D)

18) where c is a constant and g(1) = 0, then

(A)
(B)
(C)
(D)

19) equal to
(A) x sec2 x – ln |sec x + tan x| + C
(B) x sec x – ln |sec x + tan x| + C
(C) x sec x + ln |sec x| + C
(D) x sec2 x – ln |sec x| + C

20) Let , where E is an arbitrary

constant then which of the following is correct ? (A, B, C, D are real constants)

(A) A + D = C + 2B
(B) A + D = C – 2B
(C) A + D = C + B
(D) A + D = C – B

SECTION-II

1) (Where [.] represent greatest integer function.

2) If (λ = 2k, k ∈ N) then λ is equal to

3) If , (where C is constant of integration), then

is

4) If = ƒ(x) + where c is constant of integration, , then the

value of ƒ '''(0) is

5) If cosec2xdx = ln |g(x)| + c and , then value of :

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D D B B B C A B D C C D A A D A C A B B

SECTION-II

Q. 21 22 23 24 25
A. 30 3 7 6 6

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B B B C A A A A A B B B B D D A A A A D

SECTION-II

Q. 46 47 48 49 50
A. 2 2 2 3 197

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A A B A B B C C A C B D A A B D A B B B

SECTION-II

Q. 71 72 73 74 75
A. 156 8 8 2 3
 SOLUTIONS

PART-1 : PHYSICS

1)

Within the plates electric fields due to charges Q1 and Q2 are

E1 = and E2 =
As these fields are in opposite directions and Q1 > Q2, the net electric field within the plates is

E = E 1 – E2 =

Hence V = Ed = (Q1 – Q2) =

2)
Hence work done by one battery will be + and other will be – & since
(work by battery 1) + (work by battery) + ΔU ¹ 0

3)
C2 will break first
4)
C(y – V) + C(y – x) + Cy = 0
3y – x = V
C(x – 0) + C(x – y) + C(x – V) = 0
3x – y = V

⇒ 8x = 4V ⇒ x = ,y=

⇒ ΔQ =

5)

For zero deflection.

6)

At t = 0

At t = ,

7)

Q initially =
Q finally =
Initially Qi =

Finally Qf =
Qi : Qf = 3 : 4

8)

9)

10)

∴ 1V

11)
q = C1V1 = CeqV

As C3 → ∞, V1 = V, V = 10V
At C3 = 0, V1 = 2V

⇒ C1 + C2 = 5C2
C1 = 4C2

C2 = 2µF ⇒ C1 = 8µF

12)

13)

E = Emf of battery

Since

14)
Heat

15)

Circuit is redrawn as shown in Figure

In the Circuit, capacitors and are connceted in series. Combination of this is in
parallel with and capacitors.

16) At t = ∞

17) Applying KVL, we get

or

or

or
q(t) = EC (1 – e–t/3RC)

18) It steady state, current through AB = 0

⇒ VAB = VCD

⇒
⇒ QC = CVAB
19) ⇒

⇒ Þ 1000 = 400 + 40C

⇒
C = 15μF

20) As plates are equipotential therefore potential difference is same across both dielectrics

Energy stored

Charge induced

After insertion of dielectric, charge on plates distributes in such a way that potential
difference across both dielectric remains same.

21) Let Q amount of charge flow through the MN branch.

or Q = 30CV.

Potential difference between M and

22) C =

= =
= 3.04 ε0
 23)
Total heat in circuit

and

24)

25) Given circuit can be reduced to:

Time constant

PART-2 : CHEMISTRY

26)

Reactivity of carbonyl carbon σ S + on carbonyl carbon

So, reactivity order :

27)

28)

29)

ΔG1 = ΔG3 = 5 × 2 × 373

= 3730 ℓn 5

30) ΔS = 1 × ln2 + 1 × R ln

31)
Reduction of CH3COOH will produce CH3–CH2–OH(A)
Now reaction of CH3–CH2–OH(A) with PCl5 will produce CH3–CH2–Cl(B).
Now alcoholic KOH with Et–Cl will produce CH2=CH2(C) Ethylene by E2 elemination.
Thus is (1) Ethylene.

32)

33)

In reaction

Since breakup of R – X bond is taking place. Hence weaker is the R – x bond higher will be
reactivity.

34)
Since the given question is single correct choice, the best appropriate option is (A)

35)
36)

37)
38)

39)

Alkanes

40) ΔH = ΔU + ΔngRT
ΔH = 2 × (–750) + (–1) × 8 × 300 × 10–3
ΔH = – 1502.40 kJ

41) At constant volume w = 0

ΔU = q
ΔU = 200 J

42) q = 200 kJ, w =

= – 1.5 bar m3 = – 1.5 × 105 J
= – 150 kJ.
ΔU = q + W
= 200 – 150 =

43)

ΔG° = ΔH° - T ΔS°

for ΔG° = ΔH°
ΔS° = 0
A) 2Fe(s) + Al2O3(s) → 2Al(s) + Fe2O3(s)

44)

Above reaction / phase change would be at equilibrium at 0.01 atm and 27°C,
∴ ΔG = 0

45) Δs = nRln

46) W = 300 – 400 = – 100 J

W = 0.5 × ΔV bar-litre
 ΔV =

47)

48)

49) Internal energy, volume enthalpy are state variable

50)

η=

η = 0.40 = 1 –
TH = TSource = 470 K = 197°C

PART-3 : MATHEMATICS

51)

52)

53) =
54) =

55)

56)

57) Let I =
Put,

58) Let
59) Let

60)

put

61)

Put,
=

62) put 4 + x–2 = t

63)

64)

65)
Put ex = t
ex dx = dt

66)

67)
68) Apply by parts taking f(x) = 1.

69)

= x sec x – ln |sec x + tan x| + C

70) =

= = =

∴
∴ A + D = –1 = C – 2B

71)

72)
73)
put sinx = t

74)

ƒ(x) = + x + c but ƒ (1) = ⇒c=0

hence ƒ (x) =
ƒ ''' (0) = 2

75) log|cosec 2x – cot 2x| + C

= log|tan x| + C

Thus f(x) = log|x| and g(x) = tanx. Now, range g(x) = (–∞, ∞) and dom f(x) = (–∞, ∞) – {0}.

Moreover, g'(x) = sec2x ad f'(x) = for all x ∈ (0, ∞).