15-09-2024

1001CJA106216240113 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A right circular cone of the height h and radius r is suspended in liquid of density (ρ). The density

of cone is 2ρ and its circular face is at a depth . The force exerted by liquid on the curved surface of

cone is :- (Neglect atmospheric pressure)

(A) Zero

(B)

(C) πr2hρg

(D)

2) Helium gas is enclosed in a container closed by a tight fitting piston at its end. There is some
friction between the piston and the walls of the container. Initially the gas is in the situation shown
where the pressure of helium is equal to the atmospheric pressure. Now the gas is heated at a
constant rate so that the piston starts moving at a point of time. Consider the process before this as
process 1 and the process beyond this time till it reaches the stops as process 2.

(A) Process 1 and 2 are both isobaric.

(B) Process 1 and 2 are both isochoric.
(C) Process 1 is isochoric and 2 is isobaric.
(D) Process 1 is isobaric and 2 is isochoric.

3) In four experiments, 2.5 mol of hydrogen gas undergoes reversible isothermal expansions,
starting from the same volume but at different temperatures. The correspond p-V plots are shown in
figure. Rank the situations according to the change in the entropy of the gas, greatest first.

(A) a = c > b = d
(B) a > c > b > d
(C) a = c = b = d
(D) a > b > c > d

4) For four situations for an ideal gas, the table gives the energy transferred to or from the gas as
heat Q and the work W done by the gas, all in joules. Rank the four situations in terms of the

temperature change of the gas, most positive first.

(A) d > b > c > a

(B) d > c > b > a
(C) b > d > c > a
(D) b > d > a > c

SECTION-I (ii)

1) Suppose 2.00 mol of a diatomic gas is taken reversibly around the cycle shown in the T-S diagram
of figure, where S1 = 6.00 J/K and S2 = 8.00 J/K. The molecules do not rotate or oscillate. What is the
energy transferred as heat Q for (a) path 1 → 2, (b) the full cycle? The volume V1 in state 1 is 0.200

m2, What is the volume in (c) state 2 and (d) state 3?

(A) Q12 = 700 J

(B) Qcycle = 40 J
3
(C) V2 ≈ 0.208 m
 3
(D) V3 ≈ 0.283 m

2) A monoatomic gas is compressed by a small amount isothermally. The bulk modulus of the gas
during the process is B. Assume that we have a block of copper whose bulk modulus is the same. The
solid is also compressed by the same amount isothermally. Select the correct statement(s)
comparing the gas and the solid.

(A) The change in internal energy of gas is less than the change in internal energy of the solid.
(B) The heat released by the gas is equal to the heat released by the solid.
(C) The heat released by the gas is more than the heat released by the solid.
(D) The change of internal of gas is more than the change in internal energy of the solid.

3) A solid copper cube of side 10 cm has Young’s modulus of elasticity 1011 N/m2 and Poisson’s ratio
0.32. First, It is subjected to a longitudinal force of 1000 N. Then it is subjected to a pressure of 108
Pa from all the directions. In the third experiment, It is fixed on the table and the block is pushed by

a force of 10,000 N, at the top.

(A) In the first case, the change in length is 10–4 mm.

In the first case, the change in the length of the side transverse to the force applied is 3.2 ×
(B)
10–5 mm.
(C) In the second case, the change in volume is 0.36 cc.
(D) In the third case, the upper edge moves by 2.64 µm.

SECTION-I (iii)

1) We have two concentric blackened highly conducting spherical shells of radius a and b as shown.
The inner shell is maintained at the temperature of T. List-I gives the rate of heat given (in steady
state) out by certain surfaces and List-II gives the numerical expressions for them. Match them.

List-I List-II

rate of heat given by inner shell to the

(P) (1)
inner surface of outer shell

rate of heat given by inner surface of

(Q) (2) 4πa2σT4
outer shell to inner shell
 rate of heat given by outer surface of
(R) (3)
outer shell to the surroundings

rate at which heat given by inner surface

(S) (4) 4πb2σT4
of outer shell is falling on itself.

(5)

(A) P → 2;Q → 5;R → 4;S → 3

(B) P → 2;Q → 3;R → 4;S → 3
(C) P → 2;Q → 1;R → 5;S → 3
(D) P → 5;Q → 4;R → 5;S → 1

2) In four experiments, blocks A and B, starting at different initial temperatures, were brought in
contact in an insulating box and allowed to reach a common final temperature. The entropy changes
for the blocks in the four experiments had the following values (in joules per kelvin), but not
necessarily in the order given. Determine which values for A can go with which values for B.

List-I (Block A) List-II (Block B)

(P) 8 J/K (1) – 3 J/K

(Q) 5 J/K (2) – 8 J/K

(R) 3 J/K (3) – 5 J/K

(S) 9 J/K (4) – 2 J/K

(5) – 1 J/K
(A) P → 2;Q → 3;R → 1;S → 5
(B) P → 1;Q → 2;R → 3;S → 5
(C) P → 3;Q → 1;R → 4;S → 2
(D) P → 1;Q → 2;R → 4;S → 3

3) In the figure shown, the block of density two times that of water is suspended in water with a
string as shown. The coefficient of volume expansion of the solid is one-tenth of that of water. List-I
gives the list of certain actions and List-II gives the effects of those actions. Match them.

List-I List-II

The system is accelerated upwards with an The tension in the string

(P) (1)
acceleration of 10 m/s2. increases
 Another liquid whose density is lesser than
The tension in the string
(Q) that of water and is immiscible in water is (2)
decreases
poured over the top of water

Another liquid whose density is more than that

The tension in the string
(R) of water but less than the solid and is miscible (3)
remains the same
in water is poured over the top of water

The system is heated up (without change in The pressure at the base of

(S) (4)
dimensions of the container) vessel increases

The pressure at the base of

(5)
vessel remains the same
(A) P → 1,4;Q → 3,4;R → 2,4;S → 1,5
(B) P → 1,4;Q → 1,4;R → 3,5;S → 1,4
(C) P → 3,4;Q → 1,4;R → 2,4;S → 1,5
(D) P → 1,4;Q → 3,4;R → 2,4;S → 1

4) Three different objects of same mass in liquid state are cooled in a special refrigerator which
extracts heat at a constant rate from all the three objects. They start at different temperatures and
their temperatures as a function of time are shown in the graph below. List-I gives certain
parameters for each of the object and List-II gives the comparison for the three objects. Match them.

List-I List-II

(P) Melting point (1) 1 > 2 > 3

(Q) Specific heat capacity in liquid state (2) 2 > 3 > 1

(R) Specific heat capacity in solid state (3) 3 > 1 > 2

(S) Latent heat (4) 1 > 3 > 2

(5) 2 > 1 > 3

(A) P → 1;Q → 4;R → 1;S → 2
(B) P → 1;Q → 2;R → 3;S → 5
(C) P → 2;Q → 2;R → 3;S → 2
(D) P → 1;Q → 3;R → 2;S → 4

SECTION-II

1) A soap bubble of radius 1 cm is kept in vacuum. It is filled with diatomic gas. Surface tension =
0.5 N/m. Find the heat required Q (in J) to be given to double it's radius. Neglect the heat capacity of
soap film. Initial temperature = 300 K. Fill 100 Q after rounding off.
2) Four rods of identical dimensions (cross sectional area A and length L) arranged as shown in the
figure. The thermal conductivity of each rod is indicated in the figure. Temperature at junction B is

________°C.

3) A small ball is taken inside a deep lake and projected horizontally with velocity of 20 m/s. After a
long time, it acquires a vertical velocity of 15 m/s. If the radius of the ball is 10mm and the viscosity
of water is 0.007 Pa.s. What is the initial net force on the ball (in mN). (Take : π = 22/7, g = 10 m/s2)

4) Figure represents an insect caught at the midpoint of a spider-web thread. The thread breaks
under a stress of 1.00 × 108 N/m2 and a strain of 2.00. Initially, it was horizontal and had a length of
2.00 cm and a cross-sectional area of 8.00 × 10–12 m2. As the thread was stretched under the weight
of the insect, its volume remained constant. If the weight of the insect puts the thread on the verge
of breaking, what is the insect's mass (in mg)? (Round off to nearest integer.)

5) A helium balloon is allowed to rise to a height such that the pressure is 1/32 of the initial pressure
p1 on the ground. Its initial volume and temperature are V1 and T1 respectively. Assume that the
envelope of the balloon is a perfect insulator and that the process is quasistatic. Calculate the

amount of work done by the gas. If work is p1v1, where a and b are co-prime. Find a + b.

6) A refrigerated cubical container is maintained at an inner temperature of –5° C in a room where

the temperature is 20° C. The side of the cube is 2m and has a 5 mm thick aluminum wall (k = 200
W/mK) which is insulated by a 1 cm layer of cork (k = 0.04 W/mK). How many watts of heat (in W) is
transmitted through the walls to the container?

PART-2 : CHEMISTRY

SECTION-I (i)

1) Which of the following graph is correct for hydrogen gas at 0°C ?

(A)

(B)

(C)

(D)

2) Which of the following is true about gaseous state :

(A) Thermal energy = Molecular attraction

(B) Thermal energy > > Molecular attraction
(C) Thermal energy < < Molecular attraction
(D) Molecular forces > > Those in liquids

3) A system undergoes a process in which the entropy changes is +5.51 JK–1. During the process,
1.50 kJ of heat is added to the system at 300 K. The correct information regarding the process is :

(A) The process is thermodynamically reversible.

(B) The process is thermodynamically irreversible.
(C) The process may or may not be thermodynamically reversible.
(D) The process must be isobaric.

4) ΔG°f is not zero for :

(A) P4 (white)
(B) Sn (Grey)
(C) S8 (Rhombic)
(D) Hg (ℓ)

SECTION-I (ii)

1) According to kinetic theory of gases, for a diatomic molecule :

(A) The pressure exerted by the gas is proportional to the mean velocity of the molecules.
(B) The pressure exerted by the gas is proportional to the mean square velocity of the molecules.
(C) The root mean square velocity is inversely proportional to the temperature.
The mean translational kinetic energy of the molecules is proportional to the absolute
(D)
temperature.

2) A2(g) → 2A(g)
If initially 1 mole of A2 is present at 273 K and 1.1 atm in a container of volume 22.4 litre and after
complete dissociation pressure becomes 1.9 atm. Then which is correct :

(A) Compressibility factor of A2 gas is greater than that of A.

(B) Compressibility factor of A gas is more than that of A.
(C) It is easier to liquefy 'A' as compared to A2.
(D) At STP conditions, A2 may occupy volume greater than 22.7 litre/mole.

3) Select correct statement(s) :

For an ideal gas (undergoing no association or dissociation), adiabatic free expansion and
(A)
isothermal free expansion are identical for same volume change v1 to v2.
An ideal monoatomic gas follows the process P5V7 = constant. If heat is withdrawn from the
(B)
system, then temperature of gas increases.

(C)
For a cyclic process, .
(D) Adiabatic process is always iso-entropic process.

SECTION-I (iii)

1)

Boyle's temperature (TB): TB of CO2 = 350°C, TB of CH4 = 60°C and TC of H2 = –240ºC

List-I List-II

CO 2 gas in low pressure

(P) (1) PV = nRT
region & temperature 573 K.

Gas is more
CO2 gas in very high pressure
(Q) (2) compressible with
region & temperature 623 K
respect to an ideal gas.
 Gas cannot be
CH 4 gas at 333 K & in low liquefied at any
(R) (3)
pressure region. pressure at given
temperature.

Molar volume of gas is

lesser than that of
H2 gas in low pressure region
(S) (4) i d e a l g a s a t s a m e
& temperature 20 K.
pressure and
temperature.

Repulsive forces
(5)
dominate
(A) P → 2,3;Q → 3;R → 1;S → 2,4
(B) P → 2,3,4,5;Q → 3,5;R → 1,3;S → 2,4
(C) P → 2,3,4;Q → 3,5;R → 1,3;S → 1,2,4
(D) P → 2,3,4;Q → 3,5;R → 1,3;S → 2,4

2)

List-I List-II
+ –
(P) H (aq) + OH (aq) → H2O(ℓ) (1) ΔH° > 0

(Q) 2NH3(g) → N2(g) + 3H2(g) (2) ΔH° < 0

(R) C(graphite) → C(diamond) (3) Example of phase transition.

(S) H2O(g) → H2O(ℓ) (4) ΔS° > 0

(5) W < 0
(A) P → 1;Q → 1,4,5;R → 1,3;S → 2,3
(B) P → 2;Q → 2,4,5;R → 1,3;S → 2,3
(C) P → 2;Q → 1,4,5;R → 2,3;S → 2,3
(D) P → 2;Q → 1,4,5;R → 1,3;S → 2,3

3)

List-I List-II

(P) C(graphite) + O2(g) → CO2(g) (1) ΔH°formation

(Q) C(graphite) → C(gas) (2) ΔH°combustion

– –
(R) HCN(aq) + OH (aq) → CN (aq) + H2O(ℓ) (3) ΔH°atomization

(S) S(Rhombic) → S(Monoclinic) (4) ΔH°neutralization

(5) ΔH°transition
(A) P → 1,2;Q → 3,5;R → 4;S → 3
(B) P → 1,5;Q → 1,3,5;R → 3;S → 5
(C) P → 1,2;Q → 1,3,5;R → 4;S → 1,5
(D) P → 2,5;Q → 1,3,5;R → 4;S → 5
4)

List-II
List-I
(Molar heat capacity
(Ideal gas and process, K = constant)
at moderate temperature)

(P) NH3 gas and PV2 = K (1)

(Q) CO2 gas and TV3 = K (2)

(R) Ar gas and PT = K (3) 2R

(S) SO2 gas V = KT2 (4) 4R

(5) 5R
(A) P → 5;Q → 2;R → 3;S → 1
(B) P → 3;Q → 1;R → 2;S → 5
(C) P → 4;Q → 2;R → 3;S → 1
(D) P → 3;Q → 1;R → 5;S → 4

SECTION-II

1) From the TS diagram of a reversible Carnot engine : In

order to illuminate 10,000 bulbs of 40 W power each, calculate the number of cycle per second in
above must go through.

2) A real gas is subjected to an adiabatic process from (2 bar, 40 L, 300 K) to (4 bar, 30 L, 300 K)
against a constant pressure of 4 bar. The enthalpy change for the process (in Joule) is :

3) 0.5 mole each of two ideal gas A (CV = R) and B (CV = R) are taken in a container and expanded
reversibly and adiabatically from V = 1 litre to V = 4 litre starting from initial temperature T = 300
K.
|ΔH| for the process (in cal/mol) is.

4) Carbon mono oxide (CO) and oxygen O2 react according to : 2CO(g) + O2(g) → 2CO2(g) Assuming
that the reaction takes place and goes to completion, let P is the partial pressure of O2 after the

valve is opened in the apparatus represented in the accompanying figure, then find the value of in
atm–1. Also assume that the temperature is fixed at 300 K.

5) Suppose the inhaled air has partial pressure of water vapour of 7 mm Hg and exhaled air is nearly
saturated at body temperature (310 K) with water vapour. The mass of water lost per day by a
person (in gram) assuming that the normal man breaths 10,000 litre per day. Saturated vapour
pressure of water at 310 K is 45 mm Hg. (R = 0.08 L-atm/k-mole)
(Answer to the nearest integer)

6) Calculate magnitude of proton affinity of NH3(g) in kJ mol–1 from the following data :
ΔHdissociation H2 = 218 kJ mole–1
ΔHdissociation Cl2 = 124 kJ mole–1
of NH3(g) = –46 kJ mole–1
of NH4Cl(s) = –314 kJ mole–1
Ionization energy of H = 1310 kJ mole–1
Electron gain enthalpy of Cl(g) = –348 kJ mole–1
Lattice energy of NH4Cl(s) = –683 kJ mol–1.

PART-3 : MATHEMATICS

SECTION-I (i)

1) The number of rational roots of the equation, is

(A) 0
(B) 1
(C) 2
(D) 3

2) Let f(x) = x2 – bx + c, where b is an odd positive integer. Also f(x) = 0 have two prime numbers as
roots and b + c = 35. Then minimum value of f(x) is

(A)

(B)

(C)

(D) data is not sufficient

3) The product of real values of x such that is

(A)

(B)

(C)

(D)

4) Let a1 = 1, a2 = 1 + a1, a3 = 1 + a1a2, ..., an + 1 = 1 + a1a2 ... an, then upto ∞ is

equal to

(A) 1
(B) 2
(C) 3

(D)

SECTION-I (ii)

1) If A1, A2, A3 ; G1, G2, G3 and H1, H2, H3 are arithmetic, geometric and harmonic means between two
positive numbers a and b (a < b) then which of the following is/are true

(A) 2G1G3 = H2(A1 + A3)

2
(B) A2H2 = G2
2
(C) A2G2 = H2
(D) 2G1A1 = H1(A1 + A3)

2) If α, β, γ ∈ R and satisfy the relations α2 + 2β2 + 3α = 1 + γ2 and 2α2 + 4β2 = 2γ2 + 5β then,

(A)
minimum value of α2 + β2 is

(B)
minimum value of α2 + β2 is

(C)
minimum value of α2 + β2 – 2α + 1 is

(D)
minimum value of α2 + β2 – 2α + 1 is

3) Let and be two real sequences such that an = and bn = , then

(A) ap + ap + 1 + ap + 2 ... ∞ is never finite for any p

(B) bp + bp + 1 + bp + 2 ... ∞ is not finite for any p
(C) either all or none of the terms in an are zero
(D) either all or none of the terms in bn are zero

SECTION-I (iii)

1) Let a, b, c and d are four distinct real numbers satisfying the system of equations a + b = 8, ab +
c + d = 23, ad + bc = 28 and cd = 12.
Match each entry in List-I to the correct entry in List-II.

List-I List-II

(P) (2c + 2d – 15)2 = (1) 1

(Q) ((4ab + 4cd) – 110)2 = (2) 4

(R) (3) 6

(S) (2ab – 31)2 + 1 = (4) 2

(5) 3
The correct options is
(A) P → 1;Q → 3;R → 4;S → 2
(B) P → 1;Q → 2;R → 3;S → 4
(C) P → 2;Q → 1;R → 3;S → 4
(D) P → 2;Q → 1;R → 4;S → 3

2) Match each entry in List-I to the correct entry in List-II.

List-I List-II

If a2 – 4a – 3 = 0, then the value of

(P) (1) 3
=

The number of value (s) of x satisfying the equation

(Q) (2) 2
is

The number of value (s) of x satisfying the equation

(R) (3) 4
3x + l – |3x – 1| = 2log5|6 – x| is

If the sum of the first 2n terms of the A.P 2, 5, 8, ..., is

(S) equal to the sum of the first n terms of the A.P., 57, 59, (4) 11
61, ..., then n equals

(5) 8
The correct option is
(A) P → 3;Q → 1;R → 2;S → 4
(B) P → 3;Q → 3;R → 4;S → 2
(C) P → 3;Q → 3;R → 2;S → 4
(D) P → 2;Q → 4;R → 3;S → 1

3) Let f(x) = 3x2 – 7x + 2 and g(x) = x2 – 5x + 6, x ∈ R

List-I List-II

If the sum of roots of equation f(sinx) = 0, x ∈ (0, 6π) is

(P) (1) 4
equal to kπ, then value of k is

The average of maximum & minimum values of expression f

(Q) (2) 7
(sin x)+ f (cos x) is

The possible value of x satisfying the

(R) (3) 8
equation is

If the sum of values of θ, θ ∈ (0, 2π) satisfying the equation

(S) (4) 15
f(cosθ) g(cosecθ) = 0 is equal to kπ, then the value of k is

(5) 17
The correct option is
(A) P → 2;Q → 4;R → 3;S → 1
(B) P → 4;Q → 2;R → 3;S → 1
(C) P → 4;Q → 2;R → 1;S → 3
(D) P → 4;Q → 3;R → 2;S → 1

4) Match each entry in List-I to the correct entry in List-II.

List-I List-II

If a, b, c are positive real numbers such that

(P) (1) 1210
2 2 2 2
49(4a + 9b + c ) = 36(a + b + c) then

Let {a1, a2, ...} be a sequence such that a1 = 1 and

(Q) (2) 270
an – an – 1 = n2 ∀ n ≥ 2 then is equal to

(R) (3) 229

If then 1088 a =

(S) If Sn = to n term then is (4) 1681

equal to

(5) 1409
The correct option is
(A) P → 3;Q → 1;R → 4;S → 2
(B) P → 3;Q → 1;R → 2;S → 4
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 3;Q → 2;R → 1;S → 4
 SECTION-II

1) The number of integral solutions of the inequation is

2) If log245175 = a, log1715875 = b, then the value of is _____

3) Given (2 + 6 + 10 + 14 + ... + 2a) + (2 + 6 + 10 + 14 + ... + 2b) = (2 + 6 + 10 + 14 + ... + 2c),

where a + b + c = 21 and a > 6. Then a – b is equal to _________ .

4) Let p(x) = x5 + x2 + 1 = 0 have roots x1, x2, x3, x4 & x5 and g(x) = x2 – 2, then the value of g(x1) g(x2)
g(x3) g(x4) g(x5) – 30g(x1x2x3x4x5) is

5) Roots of equation x3 + 3x2 + 2x + 1 = 0 are α, β, γ and roots of equation ax3 + bx2 + cx + d = 0

are α2 + β2, β2 + γ2, γ2 + α2, then is equal to

6) If the real numbers α, β satisfy the equation α3 – 3α2 + 5α – 17 = 0; β3 – 3β2 + 5β + 11 = 0, then (α

+ β) is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. D C A D

SECTION-I (ii)

Q. 5 6 7
A. A,D A,C A,B,D

SECTION-I (iii)

Q. 8 9 10 11
A. C C D A

SECTION-II

Q. 12 13 14 15 16 17
A. 1 60 33 69 17 2400

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20 21
A. A B B B

SECTION-I (ii)

Q. 22 23 24
A. B,D A,D A,B,C

SECTION-I (iii)

Q. 25 26 27 28
A. D D C B

SECTION-II

Q. 29 30 31 32 33 34
A. 5 8000 900 6 363 718

PART-3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37 38
A. A C D B

SECTION-I (ii)

Q. 39 40 41
A. A,B A,C C,D

SECTION-I (iii)

Q. 42 43 44 45
A. B C B B

SECTION-II

Q. 46 47 48 49 50 51
A. 3 5 2 7 4 2
 SOLUTIONS

PART-1 : PHYSICS

1)

3)

4) Q = ΔU + W
ΔU = Q – W
ΔU1 = 0
ΔU2 = 70J
ΔU3 = –55J
ΔU4 = 60J

5) Q12 = 350 × 2 = 700 J

Q23 = 0

QCycle = = 50 J
W12 = Q12 = 700 J

Q12 = ΔU + W =

V2 = 0.208 m3

6) ΔUgas = 0

Q = ΔU + W

Qsolid = ΔU + W = mSΔT = 0
7)

Δr = 0.32 × 10–4 mm

= 1.08 × 10–6 m3

8)

10) T + B = mg
T = (ρ – ρ0)Vg
(P) T = (ρ – ρ0)V(g + a)
p = hρgeff + ρ0
(S)

11)

12)

PV1/3 = const.

TV–2/3 = const.

300 × 22 = T
T = 1200 K ⇒ H = nCΔT

= 32π × 10–3 J

13)

300 – 3T – T + 24 – =0
324 = 4.5T
14)

mg – B = 6πηrv

= 6π × 10–3 × 10–2 × 25

= 3300 × 10–5 = 33 mN

15)
2Tcos 30° = mg
8 × 10–12 × 2 cm = A × 4 cm
A = 4 × 10–12 m2
1.00 × 108 × 4 × 10–12 = T

m = 6.93 × 10–5 kg = 69.3 mg

16)
V = V1 × 323/5 = 8V1
 17) ;
R2 >> R1

= 25 × 4 × 4 × 6 = 2400 J/s

PART-2 : CHEMISTRY

18)

At 0°C for H2, Z > 1.

19)

For gases, thermal energy > > Molecular attraction.

20) = 5 JK–1 < ΔS ⇒ Process is irreversible.

21)

ΔG°f, Sn (white) = 0.

23)

Also,
So 'A' and 'D' are correct.

24)

(A) In adiabatic free expansion, q = 0, w = 0, ΔU = 0 ⇒ T = constant.

(B) q = (–)ve. PV7/5 = constant ⇒ x =

Cm = Cv,m + = –R < 0.
∵ q<0
⇒ nCmΔT < 0 ⇒ ΔT > 0 (∵ Cm < 0).

(C) Clausius inequality is :

For cyclic process, ΔS = 0 ⇒ .

(D) Only reversible adiabatic process is iso-entropic process.

25)
(P) P = low, T < TB
∴ Z< 1 or PV≠nRT
Gas is more compressible with respect to an ideal gas.
∵ T > Tc , so gas cannot be liquefied at any pressure at given temperature.
(Vm)real < (Vm)ideal
(Q) P = very high, T = TB
∴ Z > 1 or PV≠nRT
∵ T > Tc , so gas cannot be liquefied at any pressure at given temperature.
(Vm)real > (Vm)ideal
(R) P = low, T = TB
∴ Z > 1 or PV= nRT
∵ T > Tc , so gas cannot be liquefied at any pressure at given temperature.

26)

(P) For neutralisation reaction : ΔH° < 0

(Q) For decomposition reaction, ΔH° > 0, also ΔS° > 0.
∵ Δng > 0
(R) Energy of graphite < diamond
entropy of graphite > diamond.
(S) Condensation is exothermic.

28)

29)

W/Cycle = (500 – 400) (1000 – 200) = 80000 J

Required work per sec. = 40 × 10000 J/sec.

∴ No. of cycle/sec = = 5 cycle/sec.

30)

q = 0, ΔU = W = –4(30 – 40) = 40 bar L = 4000 J

ΔH = ΔU + (P2V2 – P1V1)
or, ΔH = 4000 + (4 × 30 – 2 × 40) × 100
= 4000 + 4000 = 8000 J.

31)

n = 1, Cv,m = R, reversible adiabatic ⇒ q = 0.

V1 = 1 L, V2 = 4 L, γ = 2

T1V1γ–1 = T2V2γ–1 ⇒ T2 = T1 = 300

or, T2 = 75 K.
ΔH = n CPm ΔT = 1 × 2R × (–225) = –900 cal.

32)
 2CO + O2 → 2CO2

= atm

33)

= 362.90 gm.

34)

–46 + 109 + 1310 + x + 62 – 348 – 683 = –314

or, x = –718 kJ mol–1
Ans. = 718.

PART-3 : MATHEMATICS

35)

Divide the numerator & denominator by x and take y = x +

36)

Let α, β be roots of x2 – bx + c = 0
Then α + β = b
⇒ one of the roots is '2' (since α, β are primes and b is odd positive integer)
∴ f(2) = 0 ⇒ 2b – c = 4 and b + c = 35
∴ b = 13, c = 22

Minimum value =

37)

If t = log2x, the given relation becomes

 ⇒ (t – 1) (t4 + 2t3 + t2 + 2t + 1) = 0

⇒ t = 1, t2 + 2t + 1 +

or

∴t+ = ∈ R – (–2, 2)

The sum of its roots is t1 + t2 =

The product of the value of x is

38)

Let

= .........

Finally
∴

39)

, ,

, ,

, ,

40)

Eliminate γ2 ⇒ 6α + 5β = 2 ≤
Also [6(α – 1) + 5β]2 = 16 ≤ (36 + 25) ((α – 1)2 + β2)

41)

Let an = 0 ⇒ an + 1 = an + 2 = ... ∞ are zero

⇒ an – 1 is zero hence all are zero
Also let bn = 0 ⇒ bn – 1 = 0 also let bm be the first non-zero term
⇒ bm – 1 ≠ 0 which is not true
Clearly can be taken as
So infinite sum exists
For an however if (a1 + a2 ... an) exists we can find n such that an + 1 + an + 2 ... ∞ < 1
Then an = ... < an (an + 1 + an + 2 + ...) < an which is not possible

42) (x2 + ax + c) (x2 + bx + d)

= x4 + (a + b)x3 + (c + d + ab)x2 + (ad + bc)x + cd
= x4 + 8x3 + 23x2 + 28x + 12
= (x + 1)(x + 2)2(x + 3)

43)

(P) Given a2 – 4a + 1 = 4 ⇒ a2 + 1 = 4(1 + a)

y=

(Q) taking log|x – 3|

⇒ log|x – 3| = 0 or ⇒ x = 4, 2 or x = 11 and x = 3
(R) critical pts x = 0, 6
Case–I : x ≥ 6 3x + 1 – (3x – 1) = 2log5(6 – x) ⇒ x = 11
Case–II : 0 ≤ x ≤ 6 3x + 1 – (3x – 1) = 2log5(6 – x) ⇒ x = 1
Case–III : x < 0 ⇒ 3x + 1 + 3x – 1 = 2log5(6 – x) ⇒ 3x – log5(6 – x) ⇒ no solution

(S) (4 + (2n – 1)3) = (114 + (n – 1)2) ⇒ n = 11

44)

(P) f(sin x) = 0
(3sinx – 1) (sinx – 2) = 0 (sin x ≠ 2)

sinx = ⇒ x = θ, π – θ, 2π + θ, 3π – θ, 4π + θ, 5π – θ
⇒ sum = 15π Ans.
(Q) f(sinx) + f(cosx) = 3 – 7(sinx + cosx) + 4
(sin x + cos x) ≤ 7 +
Average = 7 Ans.

(R) ⇒ x = 3 ⇒ log2x = 3 ⇒ x = 8
(S) (3cosθ – 1) (cosθ – 2) (cosecθ – 2) (cosecθ – 3) = 0

cosθ = ⇒ θ = θ1, 2π – θ1
cosecθ = 2 ⇒ θ = θ2, π – θ2
cosecθ = 3 ⇒ θ = θ3, π – θ2
⇒ sum = 4π

45)

(P) (3(2a) + 2(3b) + 6(c))2 < [32 + 22 + 62]. [4a2 + 9b2 + c2]
(Q) ai = 12 + 22 + ... i2 =

(R)

Let Un =

Now,

(S)

46)

Df = (–5, 4)

Case (i) and solving x ∈ (3, 4)

Case (ii) and solving x ∈ (–3, 1)

∴ solution set x ∈ (–3, 1) ∪ (3, 4)
∴ x = –2, –1, 0 ∈ z ⇒ no. of integers = 3

47)

175 = 52.7.245 = 5.72.875 = 537.1715 = 5.73

Let α = log5, β = log7

48)

2(1 + 3 + 5 + 7 + ... + a) + 2(1 + 3 + 5 + 7 +.... + b)

= 2(1 + 3 + 5 + 7 + ..... + c)

⇒ (a + 1)2 + (b + 1)2 = (c + 1)2

∵ a > 6 and a + b + c = 21
∴ a = 7, b = 5, c = 9
∴a–b=2

49)

50)

Put x = to get a cubic equation

Whose roots are α2, β2, γ2 then replace t by 5 – y to get y3 – 10y2 + 23y + 11 = 0

51)

Average value of –17 and 11 is –3

Let f(x) = x3 – 3x2 + 5x – 3
⇒ (x – 1)3 + 2(x – 1)
The graph of f(x) is odd w.r.t to x = 1
The if the root of x3 – 3x2 + 5x – 17 = 0 is α = 1 + x1
Then the root of x3 – 3x2 + 5x + 11 = 0 is β = 1 – x1
So, α + β = 2