11-05-2025

9610ZJA801237240036 JA

PHYSICS

SECTION-I (i)

1) A projectile passes two points A and B at same height after 3 s and 6 s of its projection. Horizontal
separation between the points A and B is 150 m. The horizontal range is closest to:-

(A) 180 m
(B) 240 m
(C) 350 m
(D) 450 m

2) Two masses m and are connected at the two ends of a massless rigid rod of length l. The rod is
suspended by a thin wire of torsional constant k at the centre of mass of the rod-mass system(see
figure). Because of torsional constant k, the restoring torque is τ=kθ for angular displacement 0. If
the rod is rota ted by θ0 and released, the tension in it when it passes through its mean position will

be:

(A)

(B)

(C)

(D)

3) A block of mass m is connected with two ideal pulley and a massless spring of force constant k as
shown in fig. The block is slightly displaced from its equilibrium position, its time period of
oscillation is

(A)

(B)

(C)

(D)

4) A hemispherical network of radius a is made by using a conducting wire of resistance per unit
length 'r'. The equivalent resistance across OP is.

(A)

(B)

(C)

(D)

5) A very long straight conductor and an isosceles triangular conductor lie in a plane and are
separated from each other as shown in figure. If a = 10 cm, h = 10 cm and b = 20 cm then the
coefficient of mutual inductance of system will be :

(A) 2 × 10–8 ln 2
(B) 2 × 10–8 (1 – ln 2)
(C) 4 × 10–8 ln 2
(D) 4 × 10–8 (1 – ln 2)

6) A uniform elastic string has length a1 when tension T1 and length a2 when tension is T2. The
amount of work done in stretching it from its natural length to a length (a1 + a2) is :

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) An X–ray tube is operating at 50 kV and 20mA. The target material of the tube has a mass of 1.0
kg and specific heat 495 J kg–1 °C–1. One percent of the supplied electric power is converted into
X–rays and entire remaining energy goes into heating the target. Then

(A) the average rate of rise of temperature of the target would be 2°C/sec
(B) the minimum wavelength of the X–rays emitted is about 0.25 × 10–10 m
(C) a suitable target material must have a low melting temperature
(D) a suitable target material must have low thermal conductivity

2) A metallic rod of length 1 m is rigidly clamped at its mid-point. Longitudinal stationary waves are
set up in the rod in such a way that there are two nodes on either side of the mid-point. The
amplitude of an antinode is 2 × 10–6m. Write the equation of motion at a point 2 cm from the mid-
point and those of the constituent waves in the rod. (Yong's modulus = 2 × 1011 N/m2, density = 800
kg/m3).
(A) Equation of motion of a point 2 cm from mid point is y = 2 × 10–6 cos (2.6 π) sin (25000 πt) m
(B) Constituent wave can be y = 10–6 sin (25000 πt – 5πx) m
(C) Constituent wave can be y = 10–6 sin (25000 πt + 5πx) m
(D) Wavelength of constituent waves is 30 cm.

3) A particle of mass m collides elastically with the pan of mass M = 2m of a spring balance. The
spring balance is arranged vertically with the lower end of spring fixed to ground and with the pan
fixed to the spring as shown in the figure. Pan is in equilibrium before collision. Spring constant is K
and speed of the particle before collision is v0. Choose the correct options.

Maximum further compression in the spring after the collision is

(A)

Maximum height attained by the particle from the point of collision after collision is
(B)

(C)
Minimum kinetic energy of the particle after collision is

(D)
Minimum kinetic energy of the particle after collision is

4) Time varying magnetic field is exist in cylindrical region as shown in figure. is increasing with
respect to time. Choose incorrect options. Given ab is conducting rod and voltmeter is ideal with
negligible size.

(A) Potential difference exist between a and b and voltmeter reading will not be zero.
(B) Potential difference does not exist between a and b and voltmeter reading will not be zero.
(C) Potential difference exist between a and b and voltmeter reading will be zero.
(D) Potential difference does not exist between a and b and voltmeter reading will not be zero.

5) A graph of the electric potential V (z) vs z is shown in the figure below. Which of the following
statements about the z-component of the electric field Ez is/are TRUE?

(A) Ez > 0 for –3m < z < 0

(B) Ez < 0 for –3m < z < 0
(C) Ez > 0 for 0 < z < 3m
(D) Ez < 0 for 0 < z < 3m

6) In the figure shown, X-rays are produced when 35 KeV electrons fall on a 'Mo' target. The
accelerating potential is maintained at 35 keV but a instead of 'Mo' target, 'Ag' target (Z = 47) is
placed. The K, L & M atomic X-ray levels for silver are 25.51, 3.56 & 0.53 KeV. Then for 'Ag' target

(approx values are given) choose the correct option(s) :

(A) λmin = 35.5 pm
(B) = 56.63 pm
(C) = 44.76 pm
(D) none

SECTION-II

1) A bullet of mass 0.01 kg strikes a block of mass 0.09 kg and gets embedded in it. The block then
slide along the surface and comes to rest at point B. The coefficient of friction varies as μ(x)=0.1x
along the surface where AB = 1 m and x is measured from point A. Find the velocity (in m/s) with

which the bullet hits the block.

2) A person of surface area 1.75 m2 is lying out in the sunlight to get sun bath. If the intensity of the
incident sunlight is 7 × 102 W/m2, at what rate must heat be lost (in watt) by the person in order to
maintain a constant body temperature ? (Assume the effective area of skin exposed to the Sun is
40% of the total surface area and that internal metabolic processes contribute another 90W for an
inactive person.) emissivity of the body is 0.6.

3) A solid cylinder C and a hollow pipe P of same diameter are in contact when they are released
from rest as shown in the figure on a long incline plane. Cylinder C and pipe P roll without slipping.
Determine the clear gap (in m) between them after 4 seconds.

4) The loss of pressure when a fluid flows through a pipe is given by P = k ρa ℓ Vb dc μ where d and ℓ
are diameter and length of the pipe respectively, ρ and μ are the mass density and coefficient of
viscosity of the fluid, V is the mean velocity of flow through the pipe and k is a numerical constant.
Write the value of (a + b – c).

5) A straight conducting wire MN of length 4m is rotated in a uniform magnetic field Tesla

about point O with angular speed ω = 10 rad/s as shown in the figure. The axis of rotation is
parallel to . Find the potential difference (in volt) between point M and point N.
6) A uniform rod of mass m and length ℓ can rotate freely on a smooth horizontal plane about a
vertical axis hinged at point H. A point mass having same mass m coming with an initial speed u
perpendicular to the rod, strikes the rod and sticks to it at a distance of 3ℓ/4 from hinge point. The

angular velocity of the rod just after collision is . Find the value of n.

CHEMISTRY

SECTION-I (i)

1) An electron of H-atom in 4th excited state makes transition to ground level , then total spectral
lines emitted will be -

(A) 6
(B) 15
(C) 10
(D) 3

2) Calculate the temporary and permanent hardness of water sample having the following
constituents per litre respectively.
Ca(HCO3)2 = 162 mg, MgCl2 = 95 mg
NaCl = 585 mg, Mg(HCO3)2 = 73 mg
CaSO4= 136 mg

(A) 200 ppm, 150 ppm

(B) 100 ppm, 150 ppm
(C) 150 ppm, 200 ppm
(D) 150 ppm, 150 ppm

3) The difference between heat of reaction at constant pressure and constant volume for the
reaction
2C6H6(l) + 15O2 (g) → 12CO2(g) + 6H2O (l) at 25°C in kJ mol–1 is :-

(A) –7.43
(B) +3.72
(C) –3.72
(D) +7.43

4) An ideal gas undergoes isothermal compression from 5 m3 to 1 m3 against a constant external

pressure of 4 Nm–2. Heat released in this process is used to increase the temperature of 1 mole of Al.
If molar heat capacity of Al is 24 J mol–1 K–1, the temperature of Al increases by

(A)
K

(B)
K
(C) 1 K
(D) 2 K

5) Correct magnetic behaviour of following s-block compounds/p-block compounds.

(A) Na2O2 : Paramagnetic

(B) KO2 : Paramagnetic
(C) : Diamagnetic
(D) BaO : Paramagnetic

6) Which of the following is correct order of Zeff :

(A) I– > I > I+

(B) Mg2+ > Na+ > F–
(C) P5+ < P3+
(D) Li > Be >B

SECTION-I (ii)

1)

If 270.0 g of water is electrolysed during an experiment performed by miss Abhilasha with 75%
current efficiency then

(A) 168 L of O2 (g) will be evolved at anode at 1 atm & 273 K

(B) Total 504 L gases will be produced at 1 atm & 273 K.
(C) 336 L of H2(g) will be evolved at anode at 1 atm & 273 K
(D) 45 F electricity will be consumed

2) Which of the following reaction produces PH3 :

(A) Ca3P2 + H2O →

(B) P4 + NaOH →
(C) PH4I +KOH →
(D) H3PO2

3) A organic compound having molecular formula C3H4, react with sodium metal to give a colourless
and odourless gas. Select the correct statements about organic compound.

(A) It gives Bromine water test

(B) It reacts with Bayer's reagent
(C) It reacts with Tollen's reagent
(D) It reacts with Ammonical cuprous chloride

4) In which of the following reactions gemdihalide is obtained as a major product :

(A)
Pot. fumerate X1 (Major product)

(B)
B X2 (Major product)

(C)
(Major product)

(D) (Major product)

5) Consider the following statements about sucrose.

(A) Hydrolysis of surcose with dilute acid yields an equimolar mixture of D-glucose and D-fructose
(B) Acid hydrolysis of sucrose is accompained by a change in optical rotation.
(C) In sucrose, the glycosidic linkage is between C-1 of glucose and C-2 of fructose.
(D) Aqueous solution of sucrose exhibits mutarotation.

6) In the reaction scheme shown below Q, R and S are the major products.

The correct
structure of

(A)

S is

(B)

Q is
(C)

R is

(D)

S is

SECTION-II

1) A 448 L vessel contains O2(g) & CO2(g) in 2 : 3 mole ratio at 1 atm & 0°C. Calculate the number of
moles of CO2(g) present in the vessel. Fill your answer as sum of digits (excluding decimal
places) till you get the single digit answer.

2) Total number of oxyacids in which, the underlined all atoms is/are in it's maximum oxidation state
?
H4P2O7, H2S2O6, H2S3O6, H2S2O8, H4P2O8, H2S2O5,

3) Calculate |ΔG| (in bar-L) when a definite mass of a monoatomic ideal gas at 1 bar & 27°C is
expanded adiabatically against vacuum from 10 L to 20 L (ln 2 = 0.7)

4) The molar conductivity of a solution of a weak acid HX (0.01 M) is 10 times smaller than the molar
conductivity of a solution of a weak acid HY (0.1 M). If , the difference in their pKa values,
pKa(HX) – pKa(HY), is (consider degree of ionization of both acids to be <<1).

5) The formation constant of complex is 1.0 × 10(n×5)

Given : and
The value of ‘n’ is

(∴ given , T = 298 K , R = 8.31 J/K.mol)

6)

How many reactions involve syn addition ?

(a) (b) (c) (d)

(e) (f) (g)

 (h)

MATHEMATICS

SECTION-I (i)

1) The value of is equal to :

(A)

(B)

(C)

(D)

2) Let for a sequence then is equal to (where [.] represent greatest

integer function) :

(A) 16
(B) 17
(C) 18
(D) 15

3) Minimum value of expression |sin x + cos x + tan x + cot x + sec x + cosec x| is :

(A)
(B)
(C)
(D) 2

4) If , then (a – 1)2 is

(A) 0
(B) 2
(C) 5
(D) 8

5) Number of points of discontinuity of the function ƒ(x) = sgn(x2 – x + 1) + [x2 – x + 1] in x ∈ [0, 3]

([.] denotes greatest integer function, sgn {.} denotes signum function) -

(A) 7
(B) 6
(C) 14
(D) 8

6) If probability that 2335547211α be resolved as product of two factors such that their highest

common factor is 1 or 5 or 7 is , then α is

(A) 1
(B) 3
(C) 5
(D) 8

SECTION-I (ii)

1) A parabola touches x-axis and y-axis at (1, 0) and (0, 1) respectively then :

(A) Equation of parabola is

Coordinates of focus parabola is
(B)

(C) Equation of directrix of parabola is x + y = 0

(D) Length of latus rectum of parabola is 2

2) Let for n ∈ N then :

(A)
(B)

(C)

(D)

3) then

(A) S > 7500

(B) S < 7510
(C) S < 5000
(D) S > 5010

4) Which of the following is/are correct :

(A) The total number of solutions of the equation xyz = 10800, where x . y, z ∈ Z is 3600
(B) The total number of solutions of the equation xyz = 10800, where x. y, z ∈ N is 900
28
(C) Number of zeroes at the end of C16 is 1
28
(D) Number of zeroes at the end of C16 is 0

5) Let f(x) = 2x3 – 3x2 – 12x + 8 then subsets of solution set of the inequality 2(f(x))3 – 3(f(x))2 –
12f(x) + 8) > f(2x – 7) is :

(A) (1, 2)

(B)

(C) (2, ∞)
(D) (3, ∞)

6) If and z does not lie in third quadrant, then-

(A)
(B)

(C)

(D)

SECTION-II

1) Let A be the set of all integral solution of the inequality x2 – |x| – 2 ≤ 0 and ,
(where a, b, c ∈ A) be two non zero vectors such that is orthogonal to then
number of such possible vector is :

2) Number of solutions of the equation , in [0, 2π) is, where {.} denotes
fractional part function :

3) Coefficient of x99 in is :

4) Find the least positive integral value of 'm' such that (2nCn)1/n < m ∀ n ∈ N :

5) Let ‘α’ and ‘β’ are the roots of quadratic then the value of

is equal to :
6) If A and B are non-singular matrices of order three such that and |B2
adj(A)| = p2 – 3, then p is
 ANSWER KEYS

PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. D D D C D B

SECTION-I (ii)

Q. 7 8 9 10 11 12
A. A,B A,B,D A,B,D A,B,D B,C A,B,C

SECTION-II

Q. 13 14 15 16 17 18
A. 10.00 384.00 8.00 3.00 4.80 43.00

CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. C C A B B B

SECTION-I (ii)

Q. 25 26 27 28 29 30
A. A,B A,B,C,D A,B,C,D A,D A,B,C B,D

SECTION-II

Q. 31 32 33 34 35 36
A. 3.00 2.00 7.00 3.00 6.00 6.00

MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. D A A B D C

SECTION-I (ii)

Q. 43 44 45 46 47 48
A. A,B,C A,C A,B,D A,B,C A,B,D B,C
 SECTION-II

Q. 49 50 51 52 53 54
A. 18.00 8.00 1.00 4.00 155.00 2.00
 SOLUTIONS

PHYSICS

1)

tf = 3 + 6 = 9s
Δt = 3s
ux = = 50 m/s
Range = 50 × 9 = 450 m

2)

Ω = ωθ0 = average velocity

T = mΩ2r1
3)

4)

In the given circuit A, B, C and D are the same potential by symmentry

5)

∴ 4 × 10–8 [1 – ln2]

6) Let ℓ is natural length and K is spring force constant

T1 = K (a1 - ℓ) ......(i)
T2 = K (a2 - ℓ) ......(ii)
From (i) and (ii)

The amount of work done

7) Average rate of rise of temperature = 2°C/sec

The minimum wavelength of the X-rays emitted = 0.248Å

8) The situation is shown in figure.

From figure, we can calculate the wavelength as

λ = 0.4m = 40 cm
Velocity of longitudinal waves in the rod can be given as

= 5000 m/s

Now
Assuming left end of the rod as origin, the equation of stationary waves is given by

or ... (i)
Where amplitude at any instant t is given by

At x = 0, R = 2, A = 2 × 10–6m
Thus, equation (i) can be written as
y = 2 × 10–6 cos (5 π x) sin (25000 πt) ... (ii)
At a point 2 cm from mid-point to the right
x = 50 + 2 = 52 cm = 0.52 m
y = 2 × 10–6 cos (5π × 0.52) sin (25000 πt)
or y = 2 × 10–6 cos (2.6π) sin (25000 πt) ... (iii)
This is the required equation of stationary waves in the rod.
Now we can write the equations of constituents waves in the rod as
y1 = 1 × 10–6 sin (25000 πt – 5 πx) and y2 = 1 × 10–6 sin (25000 πt + 5 πx)

9) JBC JAC
v1 + v2 = V0/2

2mv2 – mv1 = m ⇒ v1 = v2 =

Maximum compression =

Maximum height =

Minimum kinetic energy =

10) Conceptual

11) For values of –3m < z < 0, the derivative dV(z)/dz > 0, and Ez = –dV(z)/dz < 0.
For values of 0 < z < 3, the derivative dV(z)/dz < 0, Ez = –dV(z)/dz > 0.

12) (A)

(B)
where EK = 25.51 & EL = 3.56

(C)

13) (1 – y)m(1 + y)n

⇒ n – m = 10 &
⇒ m + n = 80

14)
 0.6 × 7 × 102 × 1.75 × 0.4 + 90 = = 384 W

15) ;

; × 1 × 16 = 8 m

16) P = kPaℓVbdcµ ⇒ [P] = [P]a [ℓ] [V]b [d]c [µ]

⇒ ML–1T–2 = (ML–3)a(L)(LT–1)b(L)c(ML–1T–1)
a+1=1⇒a=0
–b – 1 = –2 ⇒ b = 1
–3a + 1 + b + c –1 = –1
⇒ b + c = –1 ⇒ c = –2

17)

18)

Angular Momentum about hinge

Li = Lf

mu =

w=

CHEMISTRY

19) Spectral lines = = 10

20)

Mole of Ca(HCO3)2 = mole

Mole of Mg(HCO3)2 = = 5 ×10–4 = 0.5 × 10–3 mole

Mole of CaCO3 = 1.5 × 10–3 mole

Mass of CaCO3 = 1.5 × 10–3 × 100
= 0.150 gm

Temporary hardness (ppm) = ppm

Mole of MgCl2 = mole

Mole of CaSO4 = mole

Mole of CaCO3 = 2 × 10–3 mole

Mass of CaCO3 = 2 × 10–3 × 100 = 0.20 g

Permanent hardness (ppm) = ppm

21) ∆H = ∆U + ∆ngRT
∆H = Heat given at constant pressure
∆U = Heat given at constant volume
∆H – ∆U = ∆ngRT
∆ng = the difference between the number of gaseous moles of products and number of gaseous
moles in the reactant
2C6H6 (l) + 15O2 (g) → 12CO2 (g) + 6H2O(l)
∆ng = –3
∆H – ∆U = –3 × 8.314 × 298 J
= –7.432 kJ

22)

We know that,
w = –Pext(Vf – Vi)
w = –4 Nm–2(1 – 5)m3
w = 16 Nm ⇒ 16 J
For isothermal compression,
ΔU = q + w
⇒ q = –w = –16 J (ΔU = 0 for isothermal process)
From calorimetry,
Heat given = n C ΔT

So, 16 =

∴ Change in temperature, ΔT = K
23)

24)

zeff ∝ +ve charge on ion

25)

Moles of mole
Electrolysis of water

By 15 mole H2O 15 mole H2 & 7.5 mole O2 product

at cathode – produced = 15 × 22.4 = 336
at Anode – produced = 7.5 × 22.4 = 168
Total value of gas produced = 504
⇒ For 15 mole H2O 30 F electricity will be required with 100% efficiency.
with 75% efficiency, electricity required

Q = 40 F

26)

Ca3P2 + 6H2O → 2PH3 + 3Ca(OH)2

P4 + 3NaOH + 3H2O → PH3 + 3NaH2PO2
PH4I + KOH → PH3 + H2O + KI
H3PO2 PH3 + H3PO4

27)

28)
29) (A) On Acid hydrolysis, sucrose gives equimolar mixture of D–glucose and D–fructose.
(B) Acid hydrolysis of sucrose is accompained by a change in optical rotation.
(C) In glucose, the glucosidic linkage is present in between C–1 of glucose and C–2 of fructose.
(D) Sucrose doesn’t exhibit mutarotation because its glycoside bond is b/w the anomeric
carbon of glucose and the anomeric carbon of fructose

30)
31) At 1 atm pressure and 273 K 1mole of gas occupy 22.4 L volume.

Total moles of gas present =

5x = 20 , x = 4

32)
Ans. 2 (H4P2O7 and H2S2O8)

33)

q = 0; w = 0; ΔU = 0 so T is constant

ΔG = nRT ln

= P1V1 ln

= 1 × 10 ln
= –10 × 0.7 = –7 bar.L
|ΔG| = 7 bar.L

34)
Given
So

∴ Ka = Cα2

pKa(HX) – pKa(HY) = 3

35) Hg2+ + 2e– → Hg

Hg + 4I– →
____________________________________
 Hg2+ + 4I– → ΔG° =
From

-2F × 0.9 = -2.303 RT log Kf

Kf = 1.0 × 1030
n × 5 = 30
So n = 6

36)

(c,d,e,f,g,h) in these reactions involve syn addition

MATHEMATICS

37)

38)

⇒
similarly

39)

=
 Let S + C –1 = t

,
y is minimum when

40)
(apply Queen Theorem)

41) sgn(x2 – x + 1) = sgn

for x ∈ [0, 3], x2 – x + 1

[x2 – x + 1] is discontinuous where x2 – x + 1
= 1, 2, 3, 4, 5, 6, 7
but x2 – x + 1 = 1 ⇒ x = 0, 1
∴ Discontinuous at 8 points.

42) Total ways ⇒

factors having HCF 1 ⇒ 25–1 = 16
factors having HCF 5 ⇒ 24–1.2 = 16
factors having HCF 7 ⇒ 24–1.1 = 8
Probability ⇒
⇒α=5

43) Let S(h, k) is focus of parabola then using property of parabola

....(1)

Similarly ....(2)
Using (1) and (2)

44)

⇒
Hence

45)
S = sum of area of all shaded rectangles
 Parallely

⇒ x < 7510

46) if x, y, z
if any 2 of them are negative

Total solutions = 3600

47) f(f(x)) > f(2x – 7)

f′(x) = 6x2 – 6x – 12 = 6(x – 2) (x + 1)
Case I Case II
x ∈ (–1, 2)
f(x) < 2x – 7 f(x) > 2x – 7
3 2
⇒ 2x – 3x – 14x + 15 < 0 ⇒ (2x + 5) (x – 3) (x – 1) > 0

⇒ (x – 1) [2x2 – x – 15] < 0

⇒ (2x + 5) (x – 3) (x – 1) < 0
⇒ x ∈ (1, 2)

48) Put z = x + iy
⇒ x2 – y2 + 2ixy – 2iy = 4i

⇒
Case (1) if x = y then x2 – x – 2 = 0
⇒ x = –1,2

⇒
Case (2) if x = –y, then x2 – x + 2 = 0
⇒ x∈ϕ

49) A = {–2, –1, 0, 1, 2}

⇒ a+b+c=0
50) Draw graph of both the functions.

51) Coefficient of x–6 in

6 → (0, 6), (1, 5), (2, 4), (1, 2, 3)
So, required coefficent –6 + 5 + 8 – 6 = 1

52)

also
hence, m = 4

53)

= 125 – 3× (–2) (5)

= 125 + 30 = 155

54) adj(AB) = |AB|2 = (p – 1)2

|B2adjA| = |B2||A|2 = |AB|2
⇒ (p – 1)2 = p2 – 3 ⇒ p = 2