10-08-2025

1001CJA101022250025 JA

PART-1 : PHYSICS

SECTION-I

1) The diagram shown depicts three different states 1, 2 & 3 for an ideal gas. It is also known that
temperatures at states (1) & (2) are same and state (3) is at mid point. Then:

(A) 1→ 2 is an isothermal expansion process.

(B) 1 → 3 is an expansion process and is accompanied by cooling.
(C) 3 → 2 is an expansion process accompanied by cooling.
(D) internal energy must increase in process 1 → 3.

2) Two large thin conducting plates with small gap in between are placed in a uniform electric field
E (perpendicular to the plates). Area of each plate is A and charges +Q and –Q are given to these
plates as shown in the figure. If points R,S and T as shown in the figure are three points in space,

then the

(A) field at point R is E

(B) field at point S is E

(C)
field at point T is

(D)
field at point S is
3) For a satellite to orbit around the earth, which of the following must be true?

(A) It must be above the equator at some time.

(B) It cannot pass over the poles at any time.
(C) Its height above the surface cannot exceed 36,000 km.
(D) Its period of rotation must be > where R is radius of earth.

4) In the figure shown :-

(A) currents in R4 and R5 are equal.

(B) currents in R2 and R3 are equal.
(C) current in R1 is equal to the sum of currents in R3, R4 and R5.
(D) current in R1 is equal to the sum of currents in R2, R4 and R5.

5) A parallel plate capacitor has a dielectric slab of dielectric constant K between its plates that
covers 1/3 of the area of its plates, as shown in the figure. The total capacitance of the capacitor is C
while that of the portion with dielectric in between is C1. When the capacitor is charged, the plate
area covered by the dielectric gets charge Q1 and the rest of the area gets charge Q2. Choose the

correct option/options, ignoring edge effects.

(A)

(B)

(C)

(D)

6) A star shaped loop (with ℓ = length of each section) carries current i. Magnetic field at the centre
of the loop is :-

(A)

(B)

(C)

(D)

7) Two circular coils P and Q are fixed coaxially and carry currents I1 and I2 respectively :-

(A) if I2 = 0 and P moves towards Q, a current in the same direction as I1 is induced in Q.

(B) if I1 = 0 and Q moves towards P, a current in the opposite direction to that of I2 is induced in P.
(C) when I1 ≠ 0 and I2 ≠ 0 are in the same direction then the two coils tend to move apart.
(D) when I1 ≠ 0 and I2 ≠ 0 are in opposite directions then the coils tends to move apart.

8) At a certain moment, the photograph of a string on which a harmonic wave is travelling to the
right is shown. Then, which of the following is/are true regarding the velocities of the points P, Q

and R on the string?

(A) vP is upwards
(B) vQ = – vR
(C) | vP | > | vQ | = | vR |
(D) vQ = vR

SECTION-II
1) A thermodynamic system is taken from an initial state i with internal energy Ui = 100 J to the final
state f along two different paths iaf and ibf, as schematically shown in the figure. The work done by
the system along the paths af, ib and bf are Waf = 200 J, Wib = 50 J and Wbf = 100 J respectively. The
heat supplied to the system along the path iaf, ib and bf are Qiaf, Qib and Qbf respectively. If the
internal energy of the system in the state b is Ub = 200 J and Qiaf = 500 J, the ratio Qbf/Qib is :-

2) A particle performing linear SHM with time period T is at x = moving towards positive

extreme. The time after which it will first come to rest is . Find N.

3) A ray is incident on combination of two right angular prisms placed in air of refractive indices as

shown in the figure. The angle of incidence is 45°. The total angle of deviation in degree is . Find

n.

4) In the figure, if ray does not emerge from side AC then maximum value of θ is π/n radian. Then n

is :-

5) A non-uniform electric field in x-direction is increasing uniformly from 2N/C at x = 1m to 8 N/C

at x = 7m. The center of cube is at x = 2m. If the charge enclosed inside a small cube of side length
10 cm is 8.85 × 10–5n C, the value of n will be.

6) A capacitor stores 60mC charge when connected across a battery. When the gap between the
plates is filled with a dielectric, a charge of 120mC flows through the battery. The dielectric constant
of the material inserted is :-

7) The equivalent capacitance between points A and B in below shown figure will be _____µF.

8) A current of 25 A flows through an overhead power cable from the North to South direction. The
magnitude of magnetic field at a point 5 m below the cable is where n is :-

9) In a coil of area 10 cm2 and 10 turns, the magnetic field is directed perpendicular to the plane and
is changing at the rate of 108 gauss/second. The resistance of the coil is 20 ohm. The current (in A)
in the coil will be :-

10) A plane progressive wave of frequency 50 Hz, travelling along positive x-axis is represented as y
= (5 × 10–5 m) sin (100 πt) at x = 0, wave speed is 300 m/s. Maximum difference in displacements at
x = 0 and x = –3 m at any instant is Δy (in mm). Write 10Δy in OMR sheet.

PART-2 : CHEMISTRY

SECTION-I

1) Which of the following can give NaHSO3 test?

(A) CH3CHO

(B)

(C)

(D)

2) Correct method of preparation for alcohols from the following is

(A) Ozonolysis of alkene.

(B) Reaction of Ketone with RMgBr followed by hydrolysis.
(C) Hydroboration-oxidation of alkene.
(D) Reaction of alkyl halide with aqueous NaOH.

3) Which of the following reagents/ reactions will convert 'P' to 'Q'?

(A) Oxidation by PCC

(B) Ozonolysis by O3 / Zn / H2O
+
(C) Oxidation by H /KMnO4/Δ
(D) Oxidation by MnO2

4) Which of the following reaction(s) is/are correctly matched with their major product?

(A)

(B)

(C)

(D)

5) Which of the following option(s) is/are correct ?

[Given : log 3 = 0.48]

pH of 0.1 molar aqueous solution of phosphoric acid is nearly 2.

(A)
[ ]
In a solution having 0.1 M acetic acid and 0.1 M HCl there is very small contribution of common
(B)
ion from acetic acid.
A mixture is formed by adding 20 ml, 0.1 M HA (Ka = 2 × 10–6) and 20 ml, 0.2 M HB (Ka = 4 ×
(C) 10–5). Then pH of final mixture is 2.69.
[Given : log (4.1) = 0.62)]
(D) pH of 10–8 Molar HCl solution is nearly 8

6) The reversible expansion of an ideal gas under adiabatic and isothermal conditions is shown in the
figure. Which of the following statement(s) is (are) correct ?

(A) T1 = T2
(B) T3 > T1
(C) wisothermal > wadiabatic
(D) ΔUisothermal > ΔUadiabatic

7) Froth floatation :

(A) is physical method which is based on adsorption phenomenon

is a method to concentrate the ore depending on the difference in wettability of gangue and the
(B)
ore
(C) is used for the sulphide ores
(D) is a method in which impurities sink to the bottom

8) Which of the following compounds are tetrahedral but NOT sp3 hybridised?

(A) K2MnO4
(B) Ni(CO)4
(C) CrO2Cl2
2–
(D) [HgI4]

SECTION-II

1)
Find out the value of (x–y) in given reaction.

2) From the compounds given below, number of compounds which give positive Fehling's test is____.
(i) CH3–CHO (ii) HCHO (iii) Ph–CHO (iv)

(v) CH3–COOH (vi) (vii) (viii) Ph–COOH

3) The dissociation constant of a substituted benzoic acid at 25°C is 1.0 × 10–4. The pH of 0.01 M
solution of its sodium salt is ? [Neglect self-ionisation of water for given solution]

4) The pH of a solution obtained by mixing 50 mL of 1 M HCl and 30 mL of 1 M NaOH is x × 10–4.

The value of x is __________.
[Given : log 2.5 = 0.3979]

5) Standard Gibbs energy of formation (ΔG°f) for n-pentane (g) and isopentane (g) are 85.04 and
82.84 kcal mol–1, respectively. The mole percent of n-pentane (g) in the equilibrium mixture of these
two gases at 1000 K and 0.50 bar pressure is ______ %.
[Given : ln2 = 0.7, ln3 = 1.1, ln5 = 1.6]

6) 1.22 g of an organic acid is separately dissolved in 100 g of benzene (Kb = 2.6 K kg mol–1) and 100
g of acetone (Kb = 1.7 K kg mol–1). The acid is known to dimerize in benzene but remain as a
monomer in acetone. The boiling point of the solution in acetone increases by 0.17°C.
The increase in boiling point of solution in benzene in °C is x × 10–2. The value of x is _______.
[Atomic mass : C = 12.0, H = 1.0, O= 16.0]

7) The number of the paramagnetic and inner orbital complex in the following is ___.
[Ni(CO)4], [Ni(CN)4]2–, [Co(H2O)6]3+, [Cu(NH3)4]2+, [Cr(NH3)6]3+, [Fe(CN)6]3–

8) No. of enantiomeric pair of [Ma2bcde] complex = P

No. of geometrical isomers for [PdCl3Br(SCN)(NO2)]2– = Q
No. of unpaired electron in non axial d-orbital of [Co(H2O)6]3+ = R
Sum of P + Q + R is :

9) Pyrolusite, Rutile, Chromite, Bauxite, Kernite, Limonite, Chalcopyrite, Cerrusite.

Total number of transition metal oxide ores are :-

10) Calculate species in which shape with respect to underlined atom is tetrahedral.

B2H6 , Al2Cl6 , (BeH2)2 , N(SiH3)3 , NaBH4 , B3N3H6 , (BeH2)n , , C2F6 , SF4 , CF4

PART-3 : MATHEMATICS

SECTION-I
1) Let , where y′(0) = 3 & y(0) = 1, then y(1) is equal to

(A) 2
(B) 3
(C) 4
(D) 5

2) The curve (y – a)2 = bx – bc – 2, where a, b, c are consecutive integers, passes through (2c, 2a). If
tangent to the curve at a point P passes through (2, 0), then the normal at P may pass through

(A)

(B)

(C)

(D)

3) If touches the ellipse (n, m, a & b are positive real numbers), then -

(A)

(B)

(C)

(D)

4) Let A = , then which of the following is not correct - (where tr(A) represents sum
of diagonal elements of matrix A)

(A) tr(A) = 7
(B) tr(A) = 77
(C) tr(A) = 17
(D) tr(A) = 5

5) If 2 ≤ a < 3, then the value of cos–1 cos[a] + cosec–1 cosec[a] + cot–1 cot[a], (where [.] denotes
greatest integer less than equal to x) is equal to
(A) 2 – π
(B) 2 + π
(C) π
(D) 6

6) If where a, b ∈ R then the value of a & b can be -

(A)

(B)

(C)

(D)

7) If A denotes the area between the curve 2{y} = [x] + 1 for 0 ≤ y < 1 and the x-axis between x2 – x
≤ 0, then A is less than or equal to (where {.} and [.] are the fractional part and greatest integer
functions respectively) -

(A)

(B)

(C)

(D)

8) is

(A)

(B)

(C)

(D) ℓn 2

SECTION-II

1) Let y = cosecx – cotx such that , then 1000λ is equal to

2) If if the curve passes through origin & (x1, π), where 6 < x1 < 7, then is
equal to

3) The chord of the hyperbola x2 – y2 = 25, touches the parabola y2 = 20x. If the locus of middle point
of the chords can be expressed as x3 = y2 (x – a), then a2 is

4) The value of is equal to (where [.] denotes greatest integer function)

5) If , then f(1) + f ′ (1) is

6) Let y = , then is equal to

7) The area of the region enclosed between the curves y + 4 = x2 and is 2k, then the
value of k is

8) If the slope of tangent to the curve y = ax2 – bx at x = 1 is equal to 3 where a ∈ [5, 10], then
number of possible integral value of b is -

9) Suppose P(x) is polynomial function and P(x) – P′(x) = x2 + 2x + 1 for all x. Then P(5) is -

10) Let g : R → {4} be a function given by g(x) = x3(f '(t) – 2) + x2 f "(t) + 4x(f(0) + 6) + 4 and h(x) is

defined as . If number of integers in the range of h(x) is N then

find the value of .

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8
A. C,D A,D A,D A,B,C,D A,D C B,D C,D

SECTION-II

Q. 9 10 11 12 13 14 15 16 17 18
A. 2 6 4 4 3 3 6 1 5 1

PART-2 : CHEMISTRY

SECTION-I

Q. 19 20 21 22 23 24 25 26
A. A,B,C B,C,D B,C B,C,D A,B,C A,D A,B,C,D A,C

SECTION-II

Q. 27 28 29 30 31 32 33 34 35 36
A. 4 4 8 6021 25 13 3 10 4 7

PART-3 : MATHEMATICS

SECTION-I

Q. 37 38 39 40 41 42 43 44
A. D A,D A,B A,B,C,D B A,B,C,D A,B,C A

SECTION-II

Q. 45 46 47 48 49 50 51 52 53 54
A. 500 2 25 2 0 0 8 11 50 3
 SOLUTIONS

PART-1 : PHYSICS

1)

Correct Answer is (C,D)

2)

3)

Correct Answer is (A,D)

4)

Use rules of combination of resistances and distribution of currents.

5) C =

C1 =

Ans. (D)

E1 = E2 =

⇒ Ans. (A)

Q1 = C1V =

Q2 = C2V =

6)
7)

(B) When Q is brought towards P, north and south poles, will be induced at P as shown in the
figure which is as a result of current in P is opposite direction as current in Q.
(D) Not due to induction effect but because of magnetic force between them, if the currents
are in opposite direction in the loops, the loops will repel each other.

8)
vP → ↓, vQ → vR → , vQ = vR
∵ [ cos(–θ) = cosθ]
vP > vQ [speed max. at y = 0]

9) Qiaf = Wiaf + ΔUiaf

500 = 200 + ΔUiaf
ΔUiaf = 300
Uf = 400
Qib = Wib + ΔUib
= 50 + 100
Qib = 150
Qbf = Wbf + ΔUbf
= 100 + 200
Qbf = 300

= 2 ans

10)
11)
1 sin 45° = sin r1

r1 = 30°
r1 + r2 = 60°
r2 = 30
1 sin e = sin 30

e = 60°
δ = i + e – A = 45 + 60 – 60 = 45°
n=4

12) r = 75 – C = 75 – 45 = 30

θ = 45°

13)

Electric field is increasing uniformly according to |E| = 1 + x

total flux = +E2A – E1A

= [(1 + x2) – (1 + x1)]A

= (x2 – x1)A = (10 cm) (100 cm2) = 10–3m3
Qenc = 10–3 ∈0 = 8.85 × 10–15 C

14) As the potential difference is constant hence we can say that

Q1 = 60 μC = V × C ...(1)
Now there is already 60 μC on the capacitor.
More 120 μC charge flows from battery.
Hence net charge on capacitor is
Q2 = 180 μC = V × KC ...(2)
 (2) / (1) ⇒ 3 = K

15) Two capacitors are short circuited

Finally equivalent capacitance

16) Magnitude of the magnetic field is given by

17) (1 Gauss = 10 –4T)

i= = = 5A

18)

The phase difference between the point at x = 0 and x = 3m and is π

Maximum displacement between two particle at x = 0, and x = 3m is 2A.
2A = 0.1mm

PART-2 : CHEMISTRY

19) The correct answer is option (A,B,C)

20) The correct answer is option (B,C,D)

21) The correct answer is option (B,C)

22)

The correct answer is option (B,C,D)

23)

The correct answer is option (A), (B) & (C)

24) (A) [T1 = T2]

(Isothermal path)
(B) T3 < T2 (= T1)
Final temperature (for same volume expansion.
from same initial state) of adiabatic expansion is less than
isothermal expansion
i.e. T1 = T2 (Isothermal expansion)
T3 < T1 (Adiabatic expansion)
(C) Area under P.V. curve [A] for
Aisothermal > AAdiabatic
wisothermal < wadiabatic [w = –A expansion]
(D) ΔU = nCvm ΔT (ideal gas)
ΔTIsothermal = 0
ΔTAdiabatic < 0 (T3 < T1)
So ΔUIsothermal > ΔUAdiabatic

25) Froth floatation method is a physical method depending on adsorption of potassium ethyl
xanthate which prevents the wettability of or particle. It is used only for the concentration of
sulphide ores where ore particles come into frothwhile impurities sink down.

26)

K2MnO4 :- d3s hybridized and tetrahedral geometry

Ni(CO)4 :- sp3 hybridized and tetrahedral geometry
CrO2Cl2 :- d3s hybridized and tetrahedral geometry
[HgI4]2– :- sp3 hybridized and tetrahedral geometry

27) The correct answer is 4.00

28)

(i), (ii), (vi), (vii)

29) pH = 7 + pKa + logC

= 7 + [4 – 2]
= 8.00

30)

HCl + NaOH → NaCl + H2O

Millimoles 50 30 -
20 x 30
+ –1
[H ]finally = = 2.5 × 10
pH = 1 – log (2.5) = 0.6021
= 6021 × 10–4

31) n-pentane (g) ⇌ isopentane (g)

(A) (B)
ΔfG°1000 = ΔfG°B – ΔfG°A = 82.84 – 85.04 = –2.2 kcal mol–1
Now, ΔrG° = – RT ln K°P

or, –2.2 × 103 = – 2 × 1000 × ln

or,
As the equilibrium is independent from pressure change, the ratio at 1.0 bar and 0.5 bar will
remain same.
Hence, mole percent of n-pentane (A) = 25%.

32) With benzene as solvent

ΔTb = i Kb m

… (1)
With Acetone as solvent
ΔTb = i Kb m

0.17 = … (2)
(1) / (2)

ΔTb = 13 × 10–2
⇒ x = 13

0
33) Ni(CO)4 ⇒ [Ar] 3d84s2 ⇒ 3d104s
C. NO = 4 sp3 Converted d10
Diamagnetic - Tetrahedral
[Ni(CN)4]2– ⇒ Ni(+2) ⇒ [Ar] 3d8, C. NO = 4
CN– ⇒ SFL, Square planar, dsp2
Diamagnetic
 [Co(H2O)6]3+ – ⇒ Co(+3) → [Ar] 3d6
H2O → Strong field ligand when Co is in +3. Diamagnetic, inner orbital complex, d2sp3
[Cu(NH3)4]2+ ⇒ Co(+3) ⇒ [Ar] 3d6
H2O ⇒ strong field ligand when CO is in +3.
Diamagnetic, inner orbital complex, d2sp3
[Cu(NH3)4]2+ ⇒ Cu(+2) → [Ar] 3d9
NH3 ⇒ SFL. square planar complex, dsp2 paramagnetic-inner orbital complex
[Cr(NH3)6]3+ ⇒ Cr(+3) → [Ar] 3d3
NH3 ⇒ SFL, inner orbital complex
paramagnetic, d2sp3
[Fe(CN)6]3– ⇒ Fe(+3) → [Ar] 3d5
CN– ⇒ SFL, inner orbital complex paramagnetic .

34) P = 6, Q = 4, R = 0

35) Pyrolusite MnO2

Rutile TiO2
Chromite FeCr2O4
Limonite FeO(OH)

36) B2H6 , Al2Cl6 , N(SiH3)3 , NaBH4 , (BeH2)n , C2F6 , CF4

PART-3 : MATHEMATICS

37)
integrating, we get ℓny′ = ℓn(x2 + 1) + ℓnc
⇒ y′ = c(x2 + 1)
y′(0) = 3 ⇒ c = 3
y′ = 3(x2 + 1)
⇒ y = x3 + 3x + 1 ⇒ y(1) = 5

38) a2 = bc – 2
Case I :
a = b – 1, c = b + 1 ⇒ b = 1, a = 0, c = 2
y2 = x – 4
we know that focus is mid-point of line segment joining points where tangent and normal at a
point cut the axis of parabola.
(2, 0) lies on axis.
Case-II :
a = b + 1, c = b – 1
⇒ a = 0, b = –1, c = –2
y2 = –x – 4
39) ....(1)
but any tangent to the ellipse is
....(2)
comparing (1) & (2)

40) tr(A) = 2

41) ∵ 2 ≤ a < 3 ⇒ [a] = 2

∴ cos–1cos2 + cosec–1 cosec2 + cot–1 cot2
=2+π–2+2=π+2

42) (1)∞ form; use

⇒ 4ab = –6 ⇒

43) 2{y} = [x] + 1 ....(1)

∵ 0 ≤ y < 1 ⇒ {y} = y
∴ (1) ⇒ 2y = [x] + 1
0 ≤ [x] + 1 < 2
–1 ≤ [x] < 1
but [x] is an integer
⇒ [x] = –1 ⇒ –1 ≤ x < 0
[x] = 0 ⇒ 0 ≤ x < 1
when x ∈ [–1, 0) ⇒ y = 0

when x ∈ [0, 1) ⇒ ∴ Area =

44) Putting t = tanθ

45) y = cosecx – cotx

 = –cosecx cotx + cosec2x

= cosecx(cosecx – cotx)
y1 = y cosec x ⇒ y1sinx = y
y2sinx + y1cosx = y1 ⇒ y2sinx = y1(1 – cosx)

y2sinx =

y2 = ⇒ y2 = ysec2

⇒ ⇒ 1000λ = 500

46) (tany + ysec2y)dy = ex(sinx + cosx)dx

ytany = exsinx + C
(0, 0) gives C = 0
ytany = exsinx

⇒ sinx1 = 0 ⇒ x1 = 2π

47) Assume (h, k) be the middle point of chord

∴ Its equation is

hx – ky = h2 – k2 ⇒

Now using , we get

⇒ x3 = y2(x – 5)
∴ a2 = 25

48)

=
———————————

⇒
⇒S=2
49)
f ′ (1) = 2f(1)
f ′ (1) + f(1) = 3f(1) & f(1) = 0

50)

⇒ (1 + x2)y′ = y
⇒ (1 + x2)y″ + 2xy′ = y′
⇒ (1 + x2)y″ + (2x – 1)y′ = 0

51)
Area 2

= 16

52)

∵ 5 ≤ a ≤ 10

⇒ ⇒ 10 ≤ 3 + b ≤ 20
⇒ 7 ≤ b ≤ 17

53) Difference between polynomial & its derivative is of degree 2

⇒ P(x) = x2 + ax + b
∴ P(x) – P′(x) = x2 + 2x + 1
(x2 + ax + b) – (2x + a) = x2 + 2x + 1
x2 + (a – 2)x + b – a = x2 + 2x + 1
⇒a–2=2 b–a=1
a=4 b=5
2
P(x) = x + 4x + 5

54) Since g(x) is a constant function equal to 4.

Hence g(x) = 4 ⇒ x3(f '(t) – 2) + x2f "(t) + 4x(f(0) + 6) + 4 = 4 ∀ x
⇒ x3(f '(t) – 2) + x2 f "(t) + 4x(f(0) + 6) = 0 ∀ x
Hence (f '(t) – 2) = 0, f "(t) = 0 and (f(0) + 6) = 0
∴ f(t) = 2t – 6

Range of h(x) is [0, 56] i.e., N = 57