Solution
Solution
9610ZJM800000030002 JM
PART 1 : PHYSICS
SECTION-I
1)
A particle is moving along x-axis, its “v2–t” graph is shown below. The acceleration at t = 1sec is :
(A) m/s2
(B)
m/s2
(C)
m/s2
(D) 2 m/s2
3) A projectile is given an initial velocity of , where is along the ground & is along the
2
vertical. If g = 10 m/s , the equation of its trajectory is :-
(A) y = 2x – 5x2
(B) 2y = 3x – 5x2
(C) 4y = 6x – 5x2
(D) 4y = 3x – 5x2
4) If a particle moves in a straight line according to the law x= t3 – 6t2 – 15t, the time interval during
which velocity is negative and acceleration is positive, is
(A) t < 2 and t > 5
(B) 2 < t < 5
(C) –1 < t < 5
(D) –1 < t < 2
6) If a particle is thrown vertically upward from point A which is 'h' distance from ground. Sign of
displacement, velocity, acceleration at 'C' is (take upward direction as negative) :-
7) Figure shows the velocity (v) of particle plotted again time 't'. For time interval t : [0, 2T], choose
INCORRECT option :
(A)
(B)
(C)
(D)
9) In the picture shown, a ball starting from rest rolls down a ramp AB, goes along at the horizontal
bottom BC, and then moves up on a smaller ramp CD, thereafter rolls on horizontal plane DE. Ignore
friction and air resistance . Which of the following figure shows variation in speed with time ?
(A)
(B)
(C)
(D)
10) If initial speed of particle is 2m/s. The speed of the particle at x = 6m will be :
(A) m/s
(B) m/s
(C) m/s
(D) 20 m/s
11) A 120 V toaster has a resistance of 12Ω. What must be the minimum rating of the fuse in the
electric circuit to which the toaster is connected ?
(A) 5 A
(B) 10 A
(C) 15 A
(D) 20 A
12) In the circuit shown below, find the decrease in power dissipated in 2Ω resistance after switch is
(A) 8.34 W
21.21 W
(B)
(C) 3.68 W
(D) 14.72 W
14) Rate of dissipation of joule heat in resistance per unit volume is (E is electric field, ρ resistivity):-
(A)
(B)
(C) E2ρ2
(D) None of these
15) A cylindrical resistance is connected across battery ε. Cylinder has uniform free electron density,
mid part of cylinder has larger radius as shown in figure. Then Vd (drift velocity) V/S (distance across
(A)
(B)
(C)
(D)
(A) 12 volt
(B) –8 volt
(C) 14 volt
(D) –20 volt
17) In a practical wheat stone bridge circuit as shown, when one more resistance of 100Ω is
connected in parallel with unknown resistance 'x', then ratio becomes ' 2 '. ℓ1 is balance length.
18) Three capacitors are connected as shown in the figure, where C1 = 3µF, C2 = 6µF, C3 = 2µF and
E = 10 V. Then the
(a) Energy drawn from the source is 4 × 10–4 J
(b) Energy drawn from the source is 2 × 10–4 J
(c) Heat generated in the system during charging is 2 × 10–4 J
(d) Charges on the three capacitors are equal
(A) 1 & 3
(B) 2 & 3
(C) 1, 3 & 4
(D) 1 only
19)
(A) R
(B) 5/8R
(C) R/2
(D) 2R
20) A slab of copper of thickness b is inserted in between the plates of parallel plate capacitor as
shown in figure. The separation between the plates is d if , then what is the ratio of
SECTION-II
1) Find heat produced in the circuit shown in figure on closing the switch S.
2) Two parallel plate of area A are separated by two different dielectrics as shown in figure. The net
3) Four identical rectangular plates with length ℓ = 2 cm and breadth b = 3/2 cm are arranged as
shown in figure. The equivalent capacitance between A and C is . The value of x is ___. (Round off
4) Ten identical capacitors are connected as shown. The capacitance of each capacitor is 30 μF. The
5) If charge on 3μF capacitor is 3μC. Find the charge on capacitor of capacitance C in μC.
PART 2 : CHEMISTRY
SECTION-I
1) An ideal solution is formed by mixing two volatile liquids A and B. XA and XB are the mole fractions
of A and B respectively in the solution and YA and YB are the mole fractions of A and B respectively in
the vapour phase. A plot of along y-axis against along x-axis gives a straight line. What is the
slope of the straight line?
(A)
(B)
(C)
(D)
2) An ideal solution was found to have a vapour pressure of 80 torr when the mole fraction of a non-
volatile solute was 0.2. What would be the vapour pressure of the pure solvent at the same
temperature?
(A) 64 torr
(B) 80 torr
(C) 100 torr
(D) 400 torr
The correct order of osmotic pressure for 0.01 M aqueous solution of each compound is BaCl2 >
(A)
KCl > CH3COOH > sucrose
(B) Isotonic solutions are those solutions which have the same osmotic pressure
Raoult's law states that the vapour pressure of a component over a solution is proportional to its
(C)
mole fraction in liquid state
Two sucrose solutions of same molality prepared in different solvents will have the same
(D)
freezing point depression
4) The boiling point of an aqueous solution of a non volatile solute is 100.15 °C. What is the freezing
point of an aqueous solution obtained by diluting the above solution with an equal volume of water ?
The values of Kb and Kf for water are 0.5 and 1.8 K molality–1 :
(A) –0.54 °C
(B) –0.512 °C
(C) –0.27 °C
(D) –1.86 °C
5) What is the freezing point depression constant of a solvent, 50 g of which contain 1 g non-volatile
solute (molar mass 256 g mol–1) and the decrease in freezing point is 0.40 K ?
6) The vapour pressure of ethanol and methanol are 42.0 mm and 88.5 mm Hg respectively. An ideal
solution is formed at the same temperature by mixing 46.0 g of ethanol with 16.0 g of methanol. The
mole fraction of methanol in the vapour is :
(A) 0.467
(B) 0.502
(C) 0.513
(D) 0.556
7) What would be the maximum number of emission lines for atomic hydrogen that you would expect
to see with naked eye if the only electronic energy levels involved are those as shown in figure :-
(A) 15
(B) 10
(C) 6
(D) 4
8) What is the ratio of the De-Broglie wave lengths for electrons accelerated through 200 volts
and 50 volts :-
(A) 1 : 2
(B) 2 : 1
(C) 3 : 10
(D) 10 : 3
9) (i) 26Fe54 , 26Fe56, 26Fe57, 26Fe58 (a) Isotopes
(ii) 1H3, 2He3 (b) Isotones
76 77
(iii) 32Ge , 33As (c) Isodiaphers
235 231
(iv) 92U , 90Th (d) Isobars
(v) 1H1, 1D2, 1T3
Match the above correct terms:-
(A) [(i), - a], [(ii) - d], [(iii) - b], [(iv) - c], [(v) - a]
(B) [(i) - a] [(ii) - d], [(iii) - d] [(iv) - c] [v - a]
(C) [v -a] [(iv) - c]. [(iii) - d] [(ii) - b] [(i) - a]
(D) None of them
10) For H atom, the energy required for the removal of electron from various sub-shells is given as
(A) a and b
(B) b and c
(C) b and d
(D) a and d
12)
(A) 5 × 10–3
(B) 6 × 10–3
(C) 7 × 10–3
(D) None of these
14) A conductance cell was filled with a 0.02 M KCl solution which has a specific conductance of
2.768 × 10–3 ohm–1 cm–1. If its resistance is 82.4 ohm at 25°C, the cell constant is :-
(A) 0.059 V
(B) 0.0295 V
(C) 0.118 V
(D) – 0.118 V
(A) The second ionization energy of sulphur is greater than that of chlorine
(B) The third ionization energy of phosphorus is greater than that of magnesium
(C) The first ionization energy of aluminium is less than as that of gallium
(D) The second ionization energy for boron is greater than that of carbon
19) Which is mismatched regarding the position of the element as given below ?
SECTION-II
2) Number of pairs for which size of 1st element is bigger than 2nd.
[Li+, Mg2+] [Ne, Ar] [Be, B] [O2–, F–]
[Cl–, Cl] [F–, H–] [Na+, Mg+2]
3) The magnitude of potential energy of electron in nth excited state of He+ ion is times the kinetic
energy of electron in the first excited state of Li2+ ion. Find "n"
4) What is the sum of van’t Hoff factor for Ca(NO3)2 and K4[Fe(CN)6] if they are 60% and 70%
dissociated respectively?
5) Calculate Ecell for following
[Given ]
Fill your answer by multiplying it with 100.
PART 3 : MATHEMATICS
SECTION-I
(A) 1
(B)
(C) 0
(D)
(A)
(B) 5
(C)
(D) 7
(A) 0
(B) 1
(C) 2
(D) 3
4)
(A) x ∈ (–1, 0)
(B) x ∈ (0, 1)
(C) x ∈ (–1, 1)
(D) x ∈ ϕ
6) Let f(x) = x2 – 2ax + a – 2 and g(x) = . If the complete set of real values of 'a'
for which ∀ x ∈ R is (k1, k2), then the value of (10k1 + 3k2) is equal to
[Note : [k] denotes greatest integer less than or equal to k.]
(A) 35
(B) 27
(C) 20
(D) 8
(A)
(B) π
(C)
(D) None
(A)
(B)
(C)
(D)
9) The value of is
(A)
(B)
(C)
(D)
(A)
(B)
(C)
(D)
11) If x > 1, y > 1 and logxy + logyx2 = 4 and x > y, then logxy is
(A) 2
(B)
(C)
(D)
12) Let f(x) = min{tan–1x, cot–1x} and . If α, β (where α < β) be the integers in the
range of g(x), then the value of
cos–1(cos α) + sin–1(sin β) is
(A) 3 – π
(B) π
(C) 1
(D) π – 3
13) Which of the following values of ‘x’ will satisfy the inequality
(A)
(B)
(C)
(D)
(A) 0
(B) 1
(C) 2
(D) none of these
15) Number of integers ≤ 8 satisfying the inequality is
(A) 5
(B) 6
(C) 7
(D) 8
(A) 0
(B) 1
(C) 3
(D) infinite
(A)
(B)
(C) [1, 2]
(D) (-2, 2)
(A)
(B)
(C)
(D)
19) If x & y are positive integers such that log2(xy) = 4 + ƒ1 & log2(x/y) = 2 + ƒ2, where ƒ1, ƒ2 ∈ [0, 1),
then number of integers for x is
(A) 8
(B) 9
(C) 10
(D) 11
20) Let f(x) be even periodic function with period '3' such that . The
number of solutions of the equation in [–3,100] is
(A) 68
(B) 69
(C) 102
(D) 103
SECTION-II
2) If range of the function f(x) = tan–1(3x2 + (k – 1)x + 3) is for x ∈ R, then find the sum of all
possible real value(s) of k ?
3) The number of solutions of the equation 1 + x2 + 2x sin(cos–1y) = 0 is equal to 'k' and ordered
pairs (x,y) which satisfy the equation are (ai,bi) for i = 1,2,3,...k then value of is
4)
What is the value of
= 1 is
ANSWER KEYS
PART 1 : PHYSICS
SECTION-I
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B C B D C D A A C B D D B A B B C C B
SECTION-II
Q. 21 22 23 24 25
A. 0 4 2 6 9
PART 2 : CHEMISTRY
SECTION-I
Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A C D C A C D A A C C D A B C B C D D A
SECTION-II
Q. 46 47 48 49 50
A. 3 5 5 6 3
PART 3 : MATHEMATICS
SECTION-I
Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C A C C C C B B B D C C D C C A A B A D
SECTION-II
Q. 71 72 73 74 75
A. 2 2 0 0 9
SOLUTIONS
PART 1 : PHYSICS
1)
va = 1
v at t = 1 sec is
m/sec2
2)
3)
vx = 2
vy = 3
x = 2t
y = 3t –
y=
4y = 6x – 5x2
4)
⇒ required interval
2<t<5
5)
x = t + 1 and y =
Now average velocity.
Its magnitude is
= 5/4 m/s
6)
Because downward direction is considered positive so by sign convention x > 0, v > 0, a > 0.
7)
Theoretical
8) t = t1 + t2
9) Velocity increases down the incline, then becomes constant in BC as there is no friction,
decreases in CD up the incline and again becomes constant in DE.
10) Area = 8 + 6 + 4 = 18
∴
⇒v= m/s
11)
0
12) i =
P0 = 50 W
iT =
I2 = 7 × = 4.2 A
P = 4.22 × 2 = 35.28 W.ΔP = 14.72 W
13)
Theoretical
14)
= ρJ2 = E2/ρ
15) i = JA
J = neVd
i = AneVd
i = constant
AVd = Constant
16)
⇒ VD = 0
∴ VE = –4 × 2 = –8 volt
17)
∴ wheat stone bridge is in balanced condition
so
∴ = 2 ⇒ x = 100 W
18)
19)
Wheatstone bridge
20) Copper slab is conducting material. Hence the effective width of capacitor in second case
will become (d – t). (here d is width of capacitor and t is thickness of the slab).
, , given ⇒
21)
70 = 7 × Vf
Vf = 10V
Heat
= =0
22)
23)
24)
PART 2 : CHEMISTRY
26) ⇒
YA =
y = C + m.x
27) = xsolute
Po – 80 = 0.2 Po
Po = 100 torr
29) ΔTb = Kb × m
0.15 = 0.5 × m
m = 0.3
∵ due to dilution
m1v1 = m2v2
0.3 × v = m2 × 2V
m2 = 0.15
ΔTf = Kf × m2
= 1.8 × 0.15
= 0.27°C
so F.P. of solution = –0.27°C
30)
31) Ethanol Methanol
(P) (B)
YB = ?
YB =
YB = = 0.513
33)
V1 = 200
V2 = 50
If we are concern about e– then mass and charge (e) are same
so ⇒ =1:2
36)
A. Question Explanation:
The question asks you to identify which of the given metal displacement reactions are
spontaneous, based on the reactivity series of metals.
C. Solution -
A. Reactivity Series of Metals: A list of metals arranged in order of their reactivity. A more
reactive metal can displace a less reactive metal from its salt solution.
B. Displacement Reaction: A reaction in which a more reactive metal displaces a less reactive
metal from its salt solution.
C. Electrochemical Series: The electrochemical series is a more precise list, but for this
question, a general understanding of metal reactivity is sufficient.
D. General reactivity order from most to least reactive. K, Na, Ca, Mg, Al, Zn, Fe, Pb, H, Cu, Ag,
Au.
D. Final Answer:
A. (a) Copper can displace iron from FeSO4 solution: Copper is less reactive than iron, so
this is incorrect.
B. (b) Iron can displace copper from CuSO4 solution: Iron is more reactive than copper, so
this is correct.
C. (c) Silver can displace copper from CuSO4 solution: Silver is less reactive than copper, so
this is incorrect.
D. (d) Iron can displace silver from AgNO3 solution: Iron is more reactive than silver, so this
is correct.
37)
At 300 K
E = E° –
E = 0.29 –
39) k=
2.768 × 10–3 =
40) Anode :
Cathode :
________________________________
________________________________
= 0.118 volt
41) (i)
(ii)
(iii)
(size almost same due to transition contraction)
Al < Ga (IE)
(iv)
42) General outermost shell e– configuration of d-block is ns1–2 (n–1)d1-10
45)
Acidic character of non–metallic oxides increases along a period (from left to right) of periodic
table.
Cl2O7 > SO3 > P4O10
47)
1, 3, 4 , 5 , 7
2 × 13.6 ×
(n + 1)2 = 36
n+1=6⇒n=5
49)
50) Concentration =0
= 0.03
PART 3 : MATHEMATICS
sin–1 (1 – x) = + 2sin–1x
2sinÝx = –cos–1 (1 – x) ..(1)
Domain is x ∈ [0, 1]
sin–1x = θ, θ ∈
x = sinθ ..(2)
By (1) and (2)
2θ = –cos–1 (1 – sinθ)
cos–1 (1 – sinθ) = –2θ, –2θ ∈ [–π, 0]
Only possible when –2θ = 0.
⇒ θ=0 ⇒ x = 0.
52) ⇒
⇒ (log2x + log2(x – 1))(log2(x – 1) – log2x) + (log2x)2 = 4
⇒ (log2(x – 1))2 – (log2x)2 + (log2x)2 = 4
(log2(x – 1))2 = 4
log2(x – 1) = 2, –2
53)
x = 25 & cosy = 1 x = 25 & y = 0 or y = 2π
54)
log is defined when
Case – I when
no solution
Case – II
55) =2+
∴ 2< ≤4
sin–1 <π–3
⇒ π– <π–3
⇒ 2+
⇒ >1
⇒ 2 > 1 + x2
⇒ x2 < 1
⇒ x ∈ (–1, 1)
As, sin–1
∴ = – 2, – 1, 0, 1.
Range of g(x) = {0, 1, 2, 3} for <0∀x∈R
⇒ f(0) < 0 and f(3) < 0
Now, f(0) < 0 ⇒ a – 2 < 0 ⇒ a < 2
and f(3) < 0 ⇒ 9– 6a + a – 2 < 0
a>
∴ a∈ .
Hence, k1 = , k2 = 2
∴ (10k1 + 3k2) = 14 + 6 = 20. Ans.
57) =
=
=π
58) We have,
and
59) =
60)
Let
As
tan–1 x + tan–1y = if xy ≤ 1
a2 – 4a + 2 = 0
∵x>y ∴ logxy < 1
a<1
Hence
62)
Range of g(x) is
⇒ α = –2 & β = –1
⇒ cos–1cos(–2) + sin–1(sin(–1)) = 1
63)
From we get
Furthermore,
64)
and logsecx(sec2x – tan2x) = logsecx(1) = 0
65)
2(x – 1)5 ≥ x
If x ≤ 0, the RHS is greater than LHS.
So those integers don't satisfy the inequality
if both numbers x and x – 1 are greater than 1 then inequality holds true
but RHS is also a multiple of 2 so
x ≥ 1 and x – 1 ≥ 1
⇒x≥2
66)
68)
Let tan–1x = α and tan–1y = β then, a tan α + b sec α = c and a tan β + b sec β = c
Obviously a tanθ + b secθ = c has roots tan α and tan β
⇒ (a2 – b2) tan2θ – 2 ac tan θ + c2 – b2 = 0
So
2log2x = 6 + ƒ1 + ƒ2 or x = 23 + ƒ
23 < x < 24
⇒ Number of x = 8
70)
for one period : [–3,0] number of solution is '3'
so for [–3,99], number of solution = 34 × 3
for [99, 100], number of solution = 1
73) sin(cos–1y) =
as
So, sin(cos–1y) = ±1
& x = ±1
75)
Put log2x = t
⇒ |t–2| + |t – 1| =1