01-06-2025

1752CJA101021250014 JA

PART-1 : PHYSICS

SECTION–I (i)

1) Magnitude of electric field and potential at corner (D) of a rhombus ABCD in case (i) and case (ii)
are respectively E1, V1 and E2, V2 :-

(A) E2 = E1; V2 = V1
(B) E2 = E1; V2 = 0
(C) E2 = ; V2 = 0
(D) E2 = ; V2 = V1

2) Figure shows a wire, hinged at A and B, and given the shape of half ring of radius R, the assembly
is now free to rotate about an axis passing through AB in a uniform electric field E as shown in the
figure. Linear charge density of wire is λ1 and linear mass density is λ2. If assembly is slightly
disturbed from unstable equilibrium position, then find maximum angular velocity of ring during

ensuing motion.

(A)

(B)

(C)

(D)
3) Inside a spherical uncharged conducting shell centered at O, a point charge ‘q’ is kept such
that OA = d. The radius of the inner and outer surface of the shell is ‘r’ and R. The potential of point

B is :-

(A)

(B)

(C)

(D)

4) A wire, which passes through the hole in a small bead, is bent in the form of quarter of a circle.
The wire is fixed vertically on ground as shown in the figure. The bead is released from near the top
of the wire and it slides along the wire without friction. As the bead moves from A to B, the force it

applies on the wire is

(A)
Radially outwards from θ = 0° to θ = and thereafter radially inwards.

(B)
Radially inwards from θ = 0° to θ = and thereafter radially outwards.

(C)
Radially outwards from θ = 0° to θ = and thereafter radially inwards.

(D)
Radially inwards from θ = 0° to θ = and thereafter radially outwards.

SECTION–I (ii)

1) Three concentric conducting spherical shells have radii r, 2r and 3r respectively. In the state
shown charges are q1, q2 and q3 are present on innermost, middle and outermost shells respectively.

Then select correct alternative(s).

(A) q1 + q3 = – q2

(B)

(C)

(D)

2) A spherical conductor of radius 2R has a spherical cavity of radius . The cavity does not enclose
the centre of sphere. Charges Q1 and Q2 are placed as shown in figure. Q2 is at the center of cavity.

An additional charge Q3 is given to the sphere.

(A)
The potential of the sphere is

(B) The potential inside the cavity at a distance from the center of cavity is

The value of potential outside the sphere at a distance r from the center of sphere is
(C)
where r’ is the distance from Q1

(D)
The charge that will flow into ground if the sphere is grounded is

3) A dipole of dipole moment p is placed at a distance 2R from the centre of a neutral conducting
sphere of radius R. The direction of dipole is towards the centre of the sphere. A tangent is drawn
from the dipole to the sphere which meets the sphere at point A.

(A)
The potential at point A is .
(B)
The potential at point A is
The potential at point A due to induced charges is
(C)

(D)
The potential at point A due to dipole is .

4) Three metallic plates out of which middle is given charge Q as shown in the figure. The area of

each plate is same.

(A)
The charge appearing on the outer surface of extreme left plate is .

(B)
The charge appearing on the right surface of middle plate is .
(C) Each of the facing surfaces will bet equal and opposite.
(D) The charge on surface with separation 'd' is more than that on other two charge surfaces.

5) A charged particle (+q) is moving simple harmonically on the x-axis with its mean position at
origin. Amplitude of the particle is A and its angular frequency is ω. Then choose the correct

option(s) :

(A) The magnitude of magnetic field at (2A, 0) will change periodically with period 2π/ω.
The maximum magnitude of the magnetic field at (0, A) is
(B)
 The magnetic field at (A, A) at the moment the particle passes through , will be
(C)

(D) The magnitudes of magnetic field at (0, A) and (0, –A) will be same at any time.

6) A point charge +Q is placed just outside an imaginary hemispherical surface of radius R as shown

in the figure. Which of the following statements is/are correct ?

(A) The circumference of the flat surface is an equipotential

The electric flux passing through the curved surface of the hemisphere is
(B)

(C)
Total flux through the curved and the flat surfaces is
(D) The component of the electric field normal to the flat surface is constant over the surface.

7) A student skates up a ramp that makes an angle 30° with the horizontal. He/she starts (as shown
in the figure) at the bottom of the ramp with speed v0 and wants to turn around over a semicircular
path xyz of radius R during which he/she reaches a maximum height h (at point y) from the ground
as shown in the figure. Assume that the energy loss is negligible and the force required for this turn
at the highest point is provided by his/her weight only. Then (g is the acceleration due to gravity)

(A)

(B)

(C) the centripetal force required at points x and z is zero

(D) the centripetal force required is maximum at points x and z

8) A car of mass M is travelling on a horizontal circular path of radius r. At an instant its speed is v
and tangential acceleration is a :

(A) The acceleration of the car is towards the centre of the path
 The magnitude of the frictional force on the car is greater than
(B)

(C) The friction coefficient between the ground and the car is not less than a/g.

(D)
The friction coefficient between the ground and the car is μ = tan–1

SECTION–II

1) Four uniformly charged wires of length a are arranged to form a square. Linear charge density of

each wire is as shown. Electric field intensity at centre of square is then value of n

2) An infinitely long solid cylinder of radius R has a uniform volume charge density ρ. It has a
spherical cavity of radius R/2 with its centre on the axis of the cylinder, as shown in the figure. The
magnitude of the electric field at the point P, which is at a distance 2R from the axis of the cylinder,

is given by the expression . The value of k is :-

3) A closed circular tube of average radius 15 cm, whose inner walls are rough, is kept in vertical
plane. A block of mass 1 kg just fit inside the tube. The speed of block is 22 m/s, when it is
introduced at the top of tube. After completing five oscillations, the block stops at the bottom region
of tube. The work done by the tube on the block is ______ J. [Given g = 10 m/s2]
4) A point charge +q is placed on the axis of a closed cylinder of radius R and height as shown.

If electric flux coming out from the curved surface of cylinder is , then calculate x.

5) Figure shows two conducting thin concentric shells of radii r and 3r. The outer shell carries
charge q = 6 C. Inner shell is neutral. Find the charge (in C) that will flow from inner sphere to the

earth after the switch S is closed.

6) As shown in the figure. a configuration of two equal point charges (q0 = +2µ C) is placed on an
inclined plane. Mass of each point charge is 20 g. Assume that there is no friction between charge
and plane. For the system of two point charges to be in equilibrium (at rest) the height h = x × 10–3
m
The value of x is ____.

(Take )

PART-2 : CHEMISTRY

SECTION–I (i)

1) Which of the following compound can exhibit optical isomerism?

(A)
(B)

(C)

(D) CH3–CH=C=CH2

2)

Which of the following represent correct stability order of :

(I) (II)

(III) (IV)
(A) II > I > IV > III
(B) II > III > IV > I
(C) II > IV > III > I
(D) II > IV > I > III

3) Find total number of H replaced by deuterium when below compound is kept in solution
for long time

(A) 6
(B) 8
(C) 9
(D) 3

4)

The greater the energy of a photon, the :-

(A) longer the wavelength and the higher the frequency.

(B) longer the wavelength and the lower the frequency.
(C) shorter the wavelength and the higher the frequency.
(D) shorter the wavelength and the lower the frequency.
 SECTION–I (ii)

1) Select the correct graph for Bohr atom -

(A)

(B)

(C)

(D)

2) Which of the following is the nodal plane of dxy orbital ?

(A) XY
(B) YZ
(C) ZX
(D) All

3)

Which of the following represent D-form

(A)

(B)

(C)

(D)

4)

Which amongst the following can show geometrical isomerism ?

(A)

(B)

(C)

(D)

5) In which case 2nd structure is less stable than 1st structure.

(A)
(B)

(C)

(D)

6)

Which compound give tautomerisation ?

(A)

(B)

(C)

(D)

7) The number of isomeric pairs with correct relationship specified are :

(A)

and Position isomers

(B)
and Metamers

(C)

and Functional isomers

(D)
and Chain isomers

8) Which of the following are correctly matched ?

(A) Geometrical Isomers

&

(B) Positional Isomers

&

(C) Identical
&

(D) Functional isomers

&

(A) A
(B) B
(C) C
(D) D

SECTION–II

1) Total number of orbitals that are to be filled completely before entering into the 6s subshell for
filling of electrons (Add the digits till you get a single digit integer)

2) A power source of 360 watt emits 50% of energy as light (λ = 331 nm). If photons are emitted out
by the source per second is x × 1020 then what is the value of x ? (Given : h = 6.62 × 10–34 Js, c = 3 ×
108 m/s)

3) Total number of geometrical isomers of the given compound

4)

Number of molecules with chiral centres are :

(i) (ii) (iii) (iv)

(v) (vi) (vii) (viii) Lactic acid

5)

How many structural isomers are possible for molecular formula C4H9Cl

6) How many of the following compounds will have tautomerism phenomenon ?

(i) (ii) (iii)

(iv) (v) (vi)

(vii) (viii) (ix)

(x)

PART-3 : MATHEMATICS

SECTION–I (i)

1) Let T2,T3,.........,Tn is a sequence of positive numbers such that

 and n ≥ 2. If , then T10 is -

(A) 51.5
(B) 50.5
(C) 90.5
(D) 100.5

2) ƒ : R R is defined as

ƒ (x) =
If ƒ (x) is one–one then the set of values of 'm' is -

(A)
(B)
(C)
(D)

3) Let ƒ : [2,∞) → [8,∞) be a function defined by .If ƒ(x) is

surjective then product of all values of α is -

(A)
(B)
(C) 2
(D) –2

4)

If an invertible function ƒ(x) satisfies x + |ƒ(x)| = 2ƒ(x), then ƒ–1(x) satisfies

(A) 3x + |ƒ–1(x)| = 2ƒ–1(x)

(B) x + |ƒ–1(x)| = 2ƒ–1(x)
(C) ƒ–1(x) – |x| = 2x
(D) 3x – |ƒ–1(x)| = 2ƒ–1(x)

SECTION–I (ii)

1) Let a1, a2, a3,… be an arithmetic progression with a1 = 7 and common difference 8. Let T1, T2, T3,…
be such that T1 = 3 and Tn+1 – Tn = an for n ≥ 1. Then, which of the following is/are TRUE ?

(A) T20 = 1604

(B)

(C) T30 = 3454

(D)

2) If first and (2n – 1)th terms of an A.P., G.P. and H.P. are equal and their nth terms are a, b, c
respectively where a, b, c are positive real numbers then -

(A) a + c = b/4
(B) a ≥ b ≥ c
(C) a + c = b
(D) b2 = ac

3) The sequence {bn} is a geometric progression with and b2 + b5 = 216. Then b1 is :

(A) 12

(B)

(C) 24

(D)

4) Let ƒ : {1,2,3,4,5} → {1,2,3,4,5} is such that ƒ(x) is a one-one function satisfying following
condition
ƒ(x) = x + 1 if and only if x is even (i.e. ƒ(3) ≠ 4, ƒ(4) = 5 etc). Then ƒ–1(2) can be-

(A) 1
(B) 3
(C) 5
(D) 2

5) Let ƒ(x) = and , then which of the

following is/are true -

(A) (ƒ + g) (1) = 9
(B) (ƒ – g) (3.5) =1
(C) (ƒ g) (0) = 24

(D)

6) Which of the following function(s) have the same domain and range ?

(A)

(B)

(C)
(D)

7) Graph of the curve y = ƒ(x) is drawn in x-y plane and applied the transformations then correct
option's is/are-

(A) if we replace x with (x – 1), then curve will be shifted in positive x direction by 1 unit
(B) if we replace x with (x – 1), then curve will be shifted in negative x direction by 1 unit
(C) if we replace y with (y – 1), then curve will be shifted in positive y direction by 1 unit
(D) if we replace y with (y – 1), then curve will be shifted in negative y direction by 1 unit

8) For the function ƒ(x) = |x + 3| – |x + 1| – |x – 1| + |x – 3|, identify correct option(s)

(A) Range of ƒ(x) is (–∞, 4]

(B) maximum value of ƒ(x) is 4
(C) ƒ(x) = 4 has infinite solutions
(D) ƒ(x) = 0 has infinite solutions

SECTION–II

1) The sum, is equal to ________.

2) If a, b, c, d are positive real numbers satisfying . If

least value of (abcd)1/4 is n, then is

3) Find number of solution of the equation [x] + 2{–x} = 3x

(Where [.] and {.} denote greatest integer and fractional part function respectively)

4) Let f(x) = and f(g(x)) = x. If is equal to λ, then sum of the digits of the λ
is?

5) Let ƒ : [1, ∞) ~ {2} → B, is an onto function then sum of all integers in set
B, is

6) The value of is :
 ANSWER KEYS

PART-1 : PHYSICS

SECTION–I (i)

Q. 1 2 3 4
A. B A B B

SECTION–I (ii)

Q. 5 6 7 8 9 10 11 12
A. A,B,C A,D A,C,D A,C B,C,D A,B A,D B,C

SECTION–II

Q. 13 14 15 16 17 18
A. 8 6 -245 7 2 300

PART-2 : CHEMISTRY

SECTION–I (i)

Q. 19 20 21 22
A. C C C C

SECTION–I (ii)

Q. 23 24 25 26 27 28 29 30
A. A,B,C B,C A,B,C,D B A,B,D B,C,D A,B,D A ,B ,C ,D

SECTION–II

Q. 31 32 33 34 35 36
A. 9 3 2 5 4 7

PART-3 : MATHEMATICS

SECTION–I (i)

Q. 37 38 39 40
A. C A D D

SECTION–I (ii)

Q. 41 42 43 44 45 46 47 48
A. B,C B,D A,B B,C A,B,C B,C A,C B,C,D
 SECTION–II

Q. 49 50 51 52 53 54
A. 504 4 3 6 6 6
 SOLUTIONS

PART-1 : PHYSICS

1)

AB = BC = CD = DA = BD = a (say)

Figure-1 Figure-2
in Fig. 1

in Fig. 2

V2 = 0
Electric field

So,

2)

Centre of charge of ring lies at its centre of mass.

Centre of charge moves by a distance "x" along electric field from 1 to 2.

Charge on ring (Q) = (λ1)πR
mass of ring (M) = (λ2)πR
Work on ring by field (w) = QEx {x = 2a}
λ1 = linear charge density

w = λ1πRE (2)
λ2 = linear mass density
w = 4λ1ER2π

kinetic energy of ring (K) =

I (moment of inertia) =
ω → angular velocity at final position
Since initially ring is at rest –
w = k (Work energy theorem)

4πλ1ER2 =

ω2 =

ω=

3)

4) Initial force on bead is outwards to balance mg. By IIIrd law force on wire is inwards. Force
is zero when

mgR – R cos θ =

5)

…(i)
 …(ii)
Solving (i) and (ii)

6) For (A), use the fact that potential at center of sphere, due to Q2 will be exactly cancelled by
charge –Q2 induced on the surface of the cavity. Hence (A).
Potential at any point at surface of cavity is equal to potential at the centre of sphere. This will
solve (B).
Potential outside the sphere cannot be found easily as the charge on the outer surface will be non-
uniform. Hence C is incorrect as the given answer for uniform Q2 + Q3.
(D) can be calculated by making the net potential at the center of sphere zero and finding new
charge on sphere.

7)
Potential at center and at any point on the sphere will be same

So, vA = vC =

vA due to dipole =

8)

Correct Answer : (A), (C)

9) (a) For (2A, 0), θ = 0° or 180°

∴ B = 0 permanent zero
(b) Magnetic field will be max at (0, A) when the particle passes through (0, 0)

Bmax = (c) sin θ =

 r=

V=ω =

B= =

= =
(d) same r, same θ

⇒ same B

10) Every point on circumference of flat surface is at equal distance from point charge
Hence circumference is equipotential.
Flux passing through curved surface = – flux passing through flat surface.

(dϕ)through the ring =

∴ Flux through curved surface =

Note : Flux through surface can be calculated using concept of solid angle.

Ω = 2π(1 – cosθ) = 2π
∴ Solid angle subtended =

ϕ for 4π solid angle =

∴ ϕ for solid angle = =

11) By the energy conservation (ME) between bottom point and point Y

… (i)
Now at point Y the centripetal force provided by the component of mg

∴ from (i)

At point x and z of circular path, the points are at same height but less then h. So the velocity
more than a point y.

So required centripetal is more.

12)

Correct Answer : (B), (C)

13)

Enet at O ⇒
14)
λℓ = ρ(πR2)ℓ
λ = ρ(πR2)
EP = E1 + E2

k=6

15)

ravg = 15 cm

wf + wg = ΔKE

wf + 10 × 0.3 = × 484
wf = –245 J
Official Ans. by NTA (+245)

16)

17) After earthing potential of Inner sphere is zero

Charge coming from earth = q
 VInner =
so charge move from sphere to earth = +2c

18) For equilibrium along the plane

= 300 mm

PART-2 : CHEMISTRY

19) Compound has non superimposable mirror image.

20) Bulky group at equitorial position increases stability.

II > IV > III > I

21)

Ans:- Option (C)

Concept :- Tautomerism :- Arises due to rapid oscillation of an atom usually hydrogen between
2 polyvalent atoms in a molecule. It is of 3 types:-
(i) Died tautomerism :- Iy the migration takes place in between adjacent atoms then system is
known as diad tautomerism.
(ii) Triad tautomerism :- If migration takes place between first atom to 3rd atom
(iii) space tautomerism :- If distance of migration is more than 3 atom then it is known as
space tautomerism
Condition :- Must have min. one
Hence total a replaceable hydrogens are there
Option (C) will correct

22)

23)

Correct Answer : (A), (B), (C)

24)

Correct Answer : (B), (C)

25)

Ans is (A,B,C,D)
(A)

(B)

(C)
the chiral centre which is above CH2OH the -OH group is in R.H.S therefore D-isomer.

(D)

26)

(B)

27)

Correct Answer : (A), (B), (D)

28)
 Correct Answer : (B), (C), (D)

29) Position isomers must have same chain length but different position of multiple bond or
functional gorup or substituents.
In metamerism carbon skelton must be changed at least across with 2-valencies.
Functional isomers must have different functional group.

30)

Correct Answer : (A), (B), (C), (D)

31)

Correct Answer : 9

32) Ans. (3)

33)

Only non-terminal double bond present outside ring will show G.I.

∴ No. of G.I. = 2

34)

Correct Answer : 5

35)

Correct Answer : 4

36) (i) , (ii) , (iii) , (iv) , (vi) , (vii) , (ix)

PART-3 : MATHEMATICS
 37)
put n=2
n=3

n=n

38)

For f to be one–one vertex must lie on or to the right of y–axis.

∴ for m = 0, f(x) = which is not one–one

39)

f : [2, ∞) → [8, ∞)

f(x) = x2 –
Given : f is surjective ⇒ one-one & onto.
Since given function is quadratic polynomial with leading coefficient equal to unity.
⇒ It takes minimum value at vertex .
& f(x) is onto ⇒ Range = Co-domain
Hence function has minimum value equal to 8 at x = 2.

x-coordinate of vertex =
= 8 = 4 + 2α2
2α2 = 4
α2 = 2
α2 – 2 = 0
Product of all values of α = –2

40)

Given x + |ƒ(x)| = 2ƒ(x) ...(1)

If ƒ(x) ≥ 0, then (1) ⇒ ƒ(x) = x
⇒ ƒ–1(x) = x is x ≥ 0 ...(3)

if ƒ(x) < 0, then (1) ⇒

⇒ ƒ–1(x) = 3x is x < 0 ...(4)
∴ Now option (4) satisfies both (3), (4)

41)

Correct Answer : (B), (C)

42) Let α be the first and β be the (2n – 1)th term of an A.P. G.P. and H.P., then α, a, β will be in
A.P. a, b, b will be in G.P. and α, c, β in H.P.
Hence a, b, c are respectively A.M., G.M. and H.M. of α and β.
Since A.M. ≥ G.M. ≥ H.M. ⇒ a ≥ b ≥ c

Again a = , b2 = αβ and c =
∴ b2 = ac

43)

ar + ar4 = 216 at r=2 at r=–2

14a = 216

44)

ƒ(2) = 3 ƒ(1) ≠ 2
ƒ(4) = 5 ƒ(3) ≠ 4
so there are total 3 possibilities
Case-I : ƒ={(1,1), (2,3), (3,2), (4,5), (5,4)}
Case-II : ƒ={(1,4), (2,3), (3,1), (4,5),(5,2)}
Case-III : ƒ = {(1,4), (2,3), (3,2), (4,5), (5,1)}
so ƒ–1(2) can be 3 or 5

45)

(A)
⇒ (ƒ + g)(1) = 9

(B) (ƒ – g)(x) =
⇒ (ƒ – g)(3.5) = 1
(C) (ƒ – g)(x) =
⇒ (ƒ – g)(0) = 24

(D)

46)

(A) [–1, 1] and [0, 1]

(B) (–∞, 0) (0, ∞) & (–∞, 0) (0, ∞)
(C) [0, ∞) and [0, ∞)
(D) (–∞, 4] and [0, ∞)(A) [–1, 1] and [0, 1]
(B) (–∞, 0) (0, ∞) & (–∞, 0) (0, ∞)
(C) [0, ∞) and [0, ∞)
(D) (–∞, 4] and [0, ∞)

47)

Correct Answer : (A), (C)

48)

x=3 x=1 x=1 x=3

f(x) = |x + 3| – |x + 1| – |x – 1| + |x – 3|
x>3
f(x) = x + 3 – x– 1 – x + 1 + x – 3 = 0
1<x<3
f(x) = x + 3 – x – 1 – x + 1 – x + 3 = 6 – 2x
1<x<1
f(x) = x + 3 – x – 1 + x – 1 + 3 = 4
3<x<–1
f(x) = x + 3 x + 1 + x – 1 – x + 3 = 2x + 6
x<–3
f(x) = – x – 3 + x + 1 + x – 1 – x + 3 = 0
Range [0,4]
f(x)max = 4
f(x) = 4 x ∈ [–1,1]
f(x) = 0 x ∈ (–∞,–3) ∪ (3,∞)

49)

= 504

50)
⇒ A+B+C+D=1
1 – A ≥ 3(BCD)1/3 ........(1)
(1 – B) ≥ 3(ACD)1/3 ........(2)
(1 – C) ≥ 3(ABD)1/3 ........(3)
1/3
(1 – D) ≥ 3(ABC) ........(4)
(1) × (2) × (3) × (4)
(1 – A)(1 – B)(1 – C)(1 – D) > 81 ABCD

51) Case-I : x ∈ I
x + 0 = 3x ⇒ 2x = 0 ⇒ x = 0
Case-II : x ∉ I
[x] + 2(1 – {x}) = 3[x] + 3{x}
2[x] + 5{x} = 2

⇒ [x] = –1, {x} = 4/5 ⇒ x = –1/5

or [x] = 0, {x} = 2/5 ⇒ x = 2/5
Hence 3 solutions.

52) Let y = ⇒ e2x – 1 = 2yex

Therefore, t2 – 2yt – 1 = 0, t = ex
⇒t=

⇒ x = log (Since ex > 0)

∴ f–1(x) = g(x) = log

= log e501 = 501.

53)

if x ∈ [1, 2), then y ∈ (2, 4]

if x ∈ [2, ∞), then y ∈ (–2, 0)
sum = 3 + 4 – 1 = 6 Ans.

54)

⇒ Tr =