25-06-2025

7101CJA101021250007 JM

PHYSICS

SECTION-I

1) Two insulating plates are both uniformly charged in such a way that the potential difference
between them is V2 – V1 = 20 V. (i.e., plate 2 is at a higher potential). The plates are separated by d
= 0.1 m and can be treated as infinitely large. An electron is released from rest on the inner surface
of plate 1. What is its speed when it hits plate 2 ?
(e = 1.6 × 10–19 C, m0 = 9.11 × 10–31 kg)

(A) 2.65 × 106 m/s

(B) 7.02 × 1012 m/s
(C) 1.87 × 106 m/s
(D) 32 × 10–19 m/s

2) A battery is used to charge a parallel plate capacitor till the potential difference between the
plates becomes equal to the electromotive force of the battery. The ratio of the energy stored in the
capacitor and the work done by the battery will be-

(A) 1
(B) 2
(C) 1/4
(D) 1/2

3) A parallel plate capacitor is made of two circular plates separated by a distance of 5 mm and with
a dielectric of dielectric constant 2.2 between them. When the electric field in the dielectric is 3 ×
104 V/m, the charge density of the positive plate will be close to :

(A) 3 × 104 C/m2

(B) 6 × 104 C/m2
(C) 6 × 10–7 C/m2
(D) 3 × 10–7 C/m2

4) A network of uncharged capacitors and resistance is shown. Current through the battery

immediately after key K is closed and after a long time interval is:-
(A)

(B)

(C)
R,

(D)

5)

For the section AB of a circuit shown in figure C1 = 1µF, C2 = 2µF, E = 10 V and the potential
difference VA – VB = –10 volt. Then, the charge on capacitor C1 is-

(A) 0 µC

(B)
µC

(C)
µC
(D) None of these

6) When two isolated conductors A and B are connected by a conducting wire positive charge will

flow from :-

(A) A to B
(B) B to A
(C) will not flow
(D) can not say

7) What is the equivalent capacitance between points A and B. Each plate has area. A (one side) and

negligible thickness. Given

(A)
(B)
(C)
(D)

8) In the given figure initially all switches are open and the capacitor has charge q. At t = 0, switch
S0 is closed along with S1 or S2 or both. The values of currents I1 & I2 at t = 0 as shown in figure. (R

= 1Ω). If the S and S1 both are closed and q = 1 μC

(A) I1 < 2I2

(B) I1 = 1A
(C) I1 > 1A
(D) I2 = 1A

9) The energy density in a parallel plate capacitor is given as 2.2 × 10–10 J/m3. The value of the
electric field in the region between the plates is :-

(A) 7 NC–1
(B) 3.6 NC–1
(C) 72 NC–1
(D) 8.4 NC–1

10) Two spherical conductors of capacitance 3.0 µF and 5.0 µF are charged to potentials of 300 volt
and 500 volt. The two are connected for redistribution of charges. Then the final potential is :-

(A) 300 volt

(B) 500 volt
(C) 425 volt
(D) 400 volt

11) Find heat produced in the capacitors on closing the switch S :-

(A) 0.0002 J
(B) .0005 J
(C) 0.00075 J
(D) Zero

12) Two mutually perpendicular insulated long conducting wires carrying equal currents I, intersect

at origin. Then the resultant magnetic P(2m, 3m) will be :-

(A)

(B)

(C)

(D) 0

13)

An infinite long cable is carrying current I along negative z-axis through origin. The magnetic field at
a point (a, b, 0) is :-

(A)

(B)

(C)

(D)

14) Figure shows a square loop with edge length 'a' meter. The resistance of wire ABC is 'r' Ω and

that of ADC is '2r' Ω. Magnetic field at the centre of the loop is :-

(A)

(B)

(C)
(D)

15) Figure shows a regular hexagon made of uniform wire. If a battery is connected across the ends
AB, magnetic field at O is B0. If the same battery is connected across A and C, the magnetic field at

O will be

(A) Equal to B0
(B) Greater than B0
(C) Less than B0
(D) May be less or greater than B0

16) Find the ratio of magnetic field at the centre of a current carrying conductor bent in the form of

an arc subtending angle α1 & α2 at the centre.

(A) 1
(B) 2
(C) 4
(D) 5

17)

Magnetic field due to semi infinite length wire at point 'P'

(A)

(B)
(C)

(D)

18) Two infinitely long wires P and Q separated by a distance of 10 cm in air, carry currents I and 2I
in opposite directions as shown in figure. The resultant magnetic field due to currents in these wires

will be zero at :-

(A) Point A
(B) Point B
(C) Point C
(D) None of the points A, B, C

19) In the given figure net magnetic field at O will be:-

(A)

(B)

(C)

(D)

20) AB and CD are long straight conductor, distance d apart, carrying a current I. The magnetic field

at the midpoint of BC is :-

(A)

(B)

(C)

(D)
 SECTION-II

1) A and B are two concentric circular conductors of centre O and carrying currents i1 and i2 as
shown in the diagram. If ratio of their radii is 1 : 2 and ratio of the magnetic fields at O due to A and

B is 1 : 3, then the value of will be

2) The total equivalent capacitance of the series parallel combination of capacitors across A and B

shown in figure is in μF:

3) Find the potential difference (in V) between the points a and b of the circuit.

4) The charge accumulated on the capacitor connected in the following circuit is _______ μC.

(Given : C = 150 μF)

5) In the given figure, the charge stored in 6μF capacitor, when points A and B are joined by a
connecting wire is _______μC.

CHEMISTRY

SECTION-I

1) A 250 mL sample of a 0.2 M Cr3+ is electrolysed with a current of 96.5 amp; if the remaining
3+
concentration of Cr ion is 0.1 M, the duration of electrolysis is : (Atomic wt. of Cr = 52) Assume
volume of solution remains constant during electrolysis :-

(A) 75 sec
(B) 150 sec
(C) 225 sec
(D) 25 sec

2) Electrolysis of hot aqueous solution of NaCl gives NaClO4, i.e., sodium perchlorate,
NaCl + 4H2O → NaClO4 + 4H2
How many faraday are required to obtain 1000 g of sodium perchlorate :-

(A) 66
(B) 40.3
(C) 18.3
(D) 31.6

3) The density of Cu is 8.94 g cm–3. The quantity of electricity needed to plate an area 10 cm × 10 cm
to a thickness of 10–2 cm using CuSO4 solution would be
MW. of Cu 63.5g/mol

(A) 13586 C
(B) 27172 C
(C) 40758 C
(D) 20348 C

4) Four moles of electrons were transferred from anode to cathode in an experiment on electrolysis
of water. The total volume of the two gases (dry and at STP) produced will be approximately (in
litres) :-
(A) 22.4
(B) 44.8
(C) 67.2
(D) 89.4

5) The Eº in the given diagram is :-

(A) 0.5
(B) 0.6
(C) 0.7
(D) 0.8

6) Value of Λm∞ for SrCl2 in water at 25º from the following data :
Conc. (mol/lt) 0.25 1
Λm (Ω cm mol ) 260 250
–1 2 –1

(A) 270
(B) 260
(C) 250
(D) 255

7) In the concentration cell,

Pt(H2) (H2) Pt
(pKa of HA = 4)
Cell potential will be :-

(A) 0.03 V
(B) 0.06 V
(C) – 0.06 V
(D) – 0.03 V

8) The ionization constant of a weak electrolyte is 25 × 10–6 while the equivalent conductance of its
0.01 M solution is 19.6 S cm2 eq–1. The equivalent conductance of the electrolyte at infinite dilution
(in S cm2 eq–1) will be :-

(A) 250
(B) 196
(C) 392
(D) 384

9) When 9.65 ampere current was passed for 1.0 hour into nitrobenzene in acidic medium, the
amount of p-aminophenol produced is :-

(A) 10.9 g
(B) 98.1 g
(C) 109.0 g
(D) 9.81 g

10) The standard reduction potential value of the metals A, B and C are 0.68, –2.50 and 0.50 V
respectively. The order of their reducing power is :

(A) A > B > C

(B) A > C > B
(C) C > B > A
(D) B > C > A

11) Which of the following major product is formed in the following reaction ?

(A)

(B)

(C)

(D)

12)
Which of the following solvents is most suitable for this reaction ?

(A) H2O
(B) EtOH
(C) Et2O
(D) None of these

13) The organic compound (P) of the reaction

(A)

(B)

(C)

(D)

14) The following reaction is described as

(A) SN1 reaction with racemisation

(B) Intramolecular SN2 reaction with Walden inversion
(C) Intramolecular SN2 reaction with retention of configuration
(D) Intramolecular SN1 reaction with racemisation

15) Arrange the following compounds in decreasing order of their reactivity for hydrolysis reaction.

(I) (II)

(III) (IV)
(A) I > II > III > IV
(B) IV > II > I > III
(C) III > IV > II > I
(D) IV > III > II > I

16) In the given following halides SN1 reaction reactivity order is :

(A) (i) > (ii) > (iii) > (iv) > (v)
(B) (iii) > (ii) > (i) > (iv) > (v)
(C) (v) > (ii) > (i) > (iv) > (iii)
(D) (iii) > (i) > (iv) > (ii) > (v)

17) Predict major product of the following reaction?

(A)

(B)

(C)

(D)

18) Given,
(A)

(B)

(C)

(D)

19)

Consider the following nucleophiles

when attached to sp3-hybridized carbon, their leaving group ability in nucleophilic substitution
reactions decreases in the order :-
(A) I > II > III > IV
(B) I > II > IV > III
(C) IV > I > II > III
(D) IV > III > II > I

20) Ethylidene chloride can be prepared by the reaction of HCl and

(A) Ethane
(B) Ethylene
(C) Acetylene
(D) Ethylene glycol

SECTION-II
1)
Give total number of elimination products including stereoisomers.

2) The total number of alkenes possible by dehydrobromination of 3 – bromo – 3 cyclo pentyl hexane
using alcoholic KOH is

3)
How many transition states will be formed in above reaction ?

4) The standard oxidation potential of Ni/Ni2+ electrode is 0.236 V. If this is combined with a
hydrogen electrode in acid solution, at what pH of the solution will the measured e.m.f. be

zero? (Assume [Ni2+] = 1 M) (Take = 0.059)

5) The conductivity of pure water in a conductivity cell with electrodes of cross-sectional area 4 cm2
and 2 cm apart is 8 × 10–7 S cm–1.
The value of current that would flow through the cell under an applied potential difference of 1 volt
is 1.6 × 10–X amp. The correct value of X is:

MATHS

SECTION-I

1) The value of is equal to

(A) 32 + 16
(B) 16 + 16
(C) 32 + 32
(D) 32 - 16

2) Range of the function f (x) = tan–1 is

where [*] is the greatest integer function.
(A)

(B)

(C)

(D)

3) If , then value of can be-

(A) 0

(B)

(C)

(D)

4) If we consider only the principle values of the inverse trigonometric functions then the value of

is

(A)

(B)

(C)

(D)

5) The value of cot–1 , where < x < π, is:

(A)

(B)

(C)

(D)

6) The complete solution set of the inequality [cot–1x]2 – 6 [cot–1 x] + 9 ≤ 0, where [.] denotes greatest
integer function, is
(A) (–∞, cot 3]
(B) [cot 3, cot 2]
(C) [cot 3, ∞)
(D) (–∞, cot 2]

7) The value of is

(A)

(B)

(C)

(D)

8) The set of values of x, satisfying the equation tan2(sin–1x) > 1 is -

(A) [–1,1]

(B)

(C)

(D)

9)

A value of is :

(A)

(B)

(C)

(D)

10) Let , where a is a constant such that then the

value of a is :

(A) 2
(B) 3
(C) 5
(D) –5

11) is equal to -

(A)

(B)

(C)

(D)

12)

Let ƒ(x) = xcosx, then

is
(where [.] represents greatest integer function)

(A) 2015
(B) 4030

(C)

(D) 0

13)

If and , then is

(A)
(B) e2
(C) 1
(D)

14) Which of the following is the graph of the function :-

(A)
(B)

(C)

(D)

15) If = 2, then a and b are:

(A) 1, 3
(B) 1, –1
(C) 2, –3
(D) 2, 3

16)

(A) 0

(B)

(C) 1
(D) ln2

17) The value of is

(A)

(B)

(C) 0
(D) None of these

18) The value of is

(A) 1
(B) 2
(C) 2020
(D) 0

19) is equal to ({.} fractional part function)

(A)

(B)

(C)

(D) π – 3

20) If f (x) is a strictly increasing and positive valued function in R and then the

value of is

(A) ln 2
(B) log2e
(C) 0
(D) 1

SECTION-II

1) Evaluate the given limit :

2) The number of real solutions of the equation sin–1

lying in the interval is ____

(Here, the inverse trigonometric functions sin–1 x and cos–1 x assume value in and [0, π],
respectively.)

0 0
3) Let and α ,β are are respective values of α, β for which
x + y is maximum. If maximum value of x + y is , then α0 + β0 + γ0 is

4) Let f : [0, 4π] → [0, π] be defined by f(x) = cos–1 (cos x). The number of points xϵ[0, 4π] satisfying

the equation f(x) = is :

5)

If ƒ (x) =

& g(x) = , then find the

 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A D C A C B B B A C D C B A A A C A B B

SECTION-II

Q. 21 22 23 24 25
A. 6 4 17 400 36

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A A B C B A B C D D D C B B B C B D B C

SECTION-II

Q. 46 47 48 49 50
A. 3 5 4 4 6

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A C A D B A A C A B A D A A B B A D C D

SECTION-II

Q. 71 72 73 74 75
A. 2 2 9 3 1
 SOLUTIONS

PHYSICS

1)
ΔV = 20V

eΔV = meV2

⇒ e(20) = × meV2

⇒ V2 =
⇒ V = 2.65 × 106 m/s

2)
ωb = qv

for capacitor

& energy stored in capacitor =

So,

3)

E= = 3 × 104
σ = (Kε0) 3 × 104
σ = 2.2 × 8.85 × 10–12 × 3 × 104
σ = 5.84 × 10–7 ≈ 6 × 10–7

4)

Immediately after switch is closed

So current through battery =

And after long time current =

5)

VA + – 10 + = VB

6) Charge always flows from higher potential body to lower potential body Hence, VA = =

3V ⇒ VB = = 4V
As VB > VA

7)

Equivalent capacitance is as shown

⇒ ⇒

8)
By nodal analysis
x+x–1+x–2=0
x = 1 V, I2 = 0, I1 = 1A

9)

10)
VC = 425 volt

11)

Heat produced = Wb – ΔV
= zero

12)

13)
 0

14) B = (sin45° + sin45°) × 2

– (sin45° + sin45°)

15)

B0 = Zero

16)

Magnetic field at the centre of arc abc and adc wire of circuit loop

and

∴ angle =

17)
18) Conceptual.

19)
Magnetic field at 0 due to
Part (1) : B1 = 0

Part (2) : B2 = (along –Z-axis)

Part (3) : B3 = (along –Y-axis)

Part (4) : B4 = (along +Z-axis)

Part (5) : B5 = (along –Y-axis)

B2–B4 = (along –Z-axis)

B3+B5 = (along –Y-axis)

Hence net magnetic field

Bnet =

20) The field at the midpoint of BC due to AB is and the same is due to CD.

Therefore the total field is .

21)

⇒
⇒

22)

23)

q = 21µC

va – vb = 17 V

24)
 Now,

10 – VB = 1 × 6
VB = 4V

VA – VB =

So, a = CΔV

a=
a = 400 μC

25) At steady state, capacitor behaves as an open circuit and current flows in circuit as shown
in the diagram.

=6V
VA = 3 V
So, potential difference across 6μF is 6 V.
Hence Q =
= 6 × 6 × 10–6 C
= 36 μC

CHEMISTRY

26) 0.2 M 0.1 M

M= M= =4
0.2 = =4 = x = 0.05

= x = 0.05
w = zit
w = mw × moles w = mw × moles
w1 = 52 × 0.05 w1 = 52 × 0.25

(52 × 0.05 – 52 × 0.025) =

52 × 0.025 =
0.025 × 3 × 1000 = t
t = 75 sec

27) NaCl + 4H2O → NaClO4 + 4H2↑

–1 +1
8 mol e– = 8F
Mw = 122.5 g
122.5 g → 8F

1g→

1000 g → × 1000 = 66

28)

8.94 g cm–3 =
Q = 27172 C

29) 2H2O + electrical → 1O2 + 2H2

3 mole of electron
∴ 1 mol O2 and 2 mol hydrogen
total = 3 mol of electron

n=

3= , V = 67.2 L

30) (1) ClO3– → ClO– , DGº1 = –4F (0.54)

(1) ClO– → Cl– , DGº2 = –2F (0.71)
– –
(1) ClO3 → Cl , DGº3 = –6F (Eº)

–6Eº = –4 × 0.54 – 2 × 0.71

Eº = 0.6

31) (always for all condition)

 ∵ > 260
then check option is 270

32)
Buffer Buffer
Solution Solution

=4
=5 [H+] = 10–4 M
[H+] = 10–5 M

Anode : H2 → H+ + e–
10–5 M

Cathode : H+ + e– → H2
10–4 M
________________________________

H2 + H+ → H+ + H2
10–4 10–5

= 0 – 0.06 log 10–1

E = 0.06 V

33) Kα =
∝ ≤ S + then Ka = Cα2

= = α2
a = 0.05

α=
= 392

34)

Eq. (p-aminophenol) =
M = 9.81 g

35) SRP↑ Reducing ↓

power

36)

37) Given reaction is SN2, so polar aprotic solvent like'Et2O' is most suitable.

38)
39)

40) Hydrolysis will proceed by SN1 mechanism.

Rate of SN1 reaction depends on the stability of carbocation formed.
Comparing (I) and (II)
Benzyl cation is generally stable but in (II) the carbocation is also stabilised by +I group of
CH2CH3.
Comparing (III) and (IV)
(III) will be less reactive-anti aromatic.
(IV) Will be more reactive as its carbocation is the most stable.

41) The rate of SN1 depends on stability of carbocation intermediate.

* The stability of carbocation increases with +M/+I groups and decreases with -M/-I groups.
42)

43)

44) Leaving group ability stability of conjugated acid

45) Ethylidene chloride can be prepared as :

46)

47)
 48)

49) Here we are provided with standard oxidation potential of nickel electrode and we all
know that reduction potential of hydrogen electrode is always zero so first the standard
electrode potential of the cell is equal the oxidation potential of nickel electrode. Here it we
are also with e.m.f of the cell (zero) so substitute the values of different term in Nernst
equation and calculate the concentration of hydrogen ion. From the concentration one can
easily find out the pH as using the following expression
pH= –logH+
Ni → Ni2+ + 2e⁻; = 0.236V
2H+ + 2e⁻ → H2; =0
∴ = 0.236 + 0.0 = 0.236 V

∴ Ecell =

0 = 0.236 + log10[H+]2
or –log H+ = 4
∴ pH = 4

50)

MATHS

51) = tan + cot + tan + cot

= = =
Þ Req. = 16(2 + ) = 32 + 16

52) 2 – | x | 0 or |x| 2 –2 x 2

because of x 0
Hence x can only be integer
x – 2, –1, 1, 2
 f (1) = 2 ; f (2) =

53)

sinθ + cosθ = 2n + 1
⇒ sinθ + cosθ = 1,–1

⇒ sin(θ + 45º) = ±
θ + 45º = nπ + (–1)n.(±45º)
θ = 0º, 90º,180º,360º,270º
but θ = 90º, 270 not in domain
θ = 0, 180º

54) = =

55)

by rationalisation

56) [cot–1x] = t, t2 – 6t + 9 ≤ 0
(t – 3)2 ≤ 0 → t = 3
[cot–1x] = 3 → 3 ≤ cot–1x < π

∴ x ∈ (–∞, cot3]

57) tan–1 = tan–1

= tan–1 (n + 1) – tan–1 n

so,
= tan–1 51 – tan–1 1

cot = cot (tan–1 51 – tan–1 1)

= = = =

58)

Ans. (C)

59)

60)

⇒–
⇒a=3

61)

Let x2012 = t then t → 0 as x→0

∴ Given limit =

(use standard limit )

62)

63)

64)

65)
⇒ 1 – a = 0 and a – b = 2
⇒ a = 1 and b = –1

66)
67)

68) Let f(x) =

and g(x) =

f(x) =

g(x) = —→ –∞
g(x)
⇒ (f(x))

= =0

69)

70)

Ans. (D)
1

71)
Let
Then,
Now, we get

=
=
We know that,

=
By multiplying and dividing by 2, we get

= =2

72) Ans. (2)

To have real solutions

∴ x = 0 and let

Hence two solutions exist.

73)

⇒ Maximum value of x, at α = 1, x = sin–11 + =π

Maximum value of y, at β = 1,

Maximum value of
at α = 1, β = 1
⇒ α0 = 1, β0 = 1, γ0 = 7

74)

Ans. (3)
75)

{sin x = t}