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D Block

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yuvrajaulakh1995
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21 views9 pages

D Block

Notes

Uploaded by

yuvrajaulakh1995
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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> D-BLock | & NARS ASRS Dd. bhck s— > 4) Eleetseonife_Con fy: Roflor Panoidic Table % » fag nefte Pecopertiek- - %» 3) Mefateee B Mefatlec Bond aia !- PT and CB D 4) Metall, Radios: pr (4 and f) o 5) m4, pt enti of alomifation »_ oy a ae > §) Donizahon Energy :-P T., 9 Der pamadeed een -4) fash Ex DL24EZ Elo IIe IF IZ 16 le 920 2 25 26 Fx4345 68 Zio 134 Is; "big 24, 98 2% 28Cdeann) al au oe 94 a5, 36, 3% > 9) Vora ble Oxidation Stale» dbfock clemente shew ) inte O.hadue do lowensryy. difforend ‘ eee : bbe AS and (n-Vd_ Scanned with CamScanner | Thus oder of ovidising Sime ng Hh Vos mod, >Wwo, and Mn Oy >To, >Re % @Electsode ‘ Beeotiaks— —m 2s me pes Eten? Stondand ovidation fotenrtich ~ pf? tedy pe ; , S45, Eat? Stand ~ Reduction potential, ary E°=+tve 5 neachen 24 feasible xf B°s-ve 3 SKeackon is non Fpontoneous ae of Ene? eS Hus Mt? Uf mone’ Fable than M and spsatetoc pitied neclhasAeedacinp agent ibcanniee ae Scanned with CamScanner Af Twesdesenies one Chee trek ay, valwendueto | a — . +2. 3 SP Elyapegrt MS Mh OMe mane sede (3) and Cracts ag a seducing, agent. i Evan pene 5 thus Mints mone Shable Hon Mn? n and Myt? acte af a seducing agent, FORMATION OF INTERSTITIAL COMPOUNDS. ‘Transition metals form interstitial compounds with elements such as hydrogen, boron, carbon and nitrogen. The small atoms of these non-metallic elements (H, B, C, N, etc.) get trapped in vacant spaces of the lattices Of the transition metal atoms as shown below. e.g. TIC, FegH, TH, 25, VHy ayy Mn,N ete Properties : = (1) They are generally non-stoichiometric compound. (2) Neither typically ionic nor typically covalent (3) Harder than pure metal.” (4) High melting point than pure metal (8) They retiin metallic conductivity (6) ; They are chemically inert I ‘Trapped atoms in ‘Transition metal atoms [r=phed atoms Figure showing formation of interstitial compounds Scanned with CamScanner @) CATALYTIC PROPERTIES Lock metals or thelr compound act ay catalyst In many reaction de 0: (Possibility of sartable oxklation state AW Presence of free valencles over metal surface (adsorption power) (W) Presence of vacant dtorbital ‘e.gt ron (l) catalyses the wactlon between lodide andl per sulphate fons. 8 Mehwme Cre geaaeeeroed 6. Alloys of steel @ am stecl Cr (2-49) | wo) tee! Ni-596) | od Stainless steel Cr (12-1494) & NI (2-410) Cr forms oxidle layer & Protects iron From Rusting | ‘ oe (3690) Ar Aol hich ts forme! by mixing a metal with Ha, Fe, CO, NI do not form the to le ference tn se ‘Atoms of metal M Atoms of different metal | Alloy formation ® Compounds of d- block _ Badly lrsesssy ” i —m n@ + Kom + 0, — 6, > Ki Mn % +t Or ky Co3-+0, ———> kon 0, + Co MTR ken oxid +t k ree ee ee "Me . Hot cs @) Caeid med.) ca ka tnd, Sipraaeek, Keng + Mn, + Ky Co, Scanned with CamScanner Mn, fide with Kol, Ma ay Gxnee Mn 9, eects. pn OF Gaeen on on Pas ple -2 Mn?? + Sa + Ho (cevaten) Ao Pro pentic’ :— ® rfhetd Hot !~ KMRop——A—> 0, Cad and (Ve tOiaeHermapr @ Kemopmacts a5 Aserg OA Snvacidies meussahwond - Atocang hy bohic. median donor pte tings end itin kMn Oy Cocidified) Mn Oy + Soy te HE +t ies py kMno, Neutral ot es s weakly ack) +4 +6 oy 7 os ae SO, Soy Boo, * Worf ther 17 fe + - ° “Sgt - cl Ch 3% ‘$ at re Fet? Bx/xz™ c oy te 4 Bx/z $2 / Tr wae, (Shc) Scanned with CamScanner . 6 Porassrum DICHROMATE 3 kuCt2 Gy Bre 101 1. ae fe, a, + F229, +9 Fed. Cr, 0, + NGO, + Op > Nag OG (reside) 2 Chnomate axe) (pies Bina, & 0, + Ha $e, > No, er, 0, t Na, SG) + Ho (yettos) é Noer,a, + KC > ky Cr, 0, + Nac] 6 2 pheg ryt (01 KE: atin gt fe Oy aissivanz eet we Sg pad 2) TARasTCLNARNO.A in acidic Medium woncogceanitfed) Kors, a, (acidic) Ws s i SO, SO, 2 Nor Nox Fet* fet? anf Boo/Fo G tou Clg Ces0 H Dray ken Daiver Test) Capt 9 ‘gxeen) 9 Ghoomylaellosidemtest :~ vetinef,chonichetedhasecenaden chlorides Sc Agel 3 PECL § PECL, Stach He oY, 3 snc, 3 3 since CHycl Sete. donot yime this test, Bobppnananane.- ae se Scanned with CamScanner Salt, . . / _ wean > ae BOP ances Ce » oO ff Oo 3 IK! » Oo 2 so #_F - BLOCK SO Thner ‘Mantition clement S — Lanthanosds 1 ce®S—p 74 + DB PD Actinoids + TRY Lxl?? ) TEP = DY Eleclsent Gm fig t~ DOD Mognete fropertios:— > @ Nesdpriumeisnmos+ spose loxamagnest'c S : ’ > @ Ov.idation, SaIH4'~ Motta, ey ? CemTERcasaD yale. H BO AKa Wb by D Sem 6es Te Y, Ae Bhowr 2 2 2 cottareperetmniterymeremerenindiamalttccotieney — > RRs Lekntendencytamerqusnenan Coane) 2 @ Colour asotemdfnlanthonaideemshancingeun paisedines arc 2 2 Scanned with CamScanner tot speciesarhensngentif 2m fyssabsioamnciishanerHaeaRere ok peicsienterasclcaaalparmnmer feat mepe ® Eek sap ae Natures — ceerineieei cath Bimibanctooohbsrinium 6 Lantana id Contraction ;— periodic Tabbe IF Some Treposctontt Reaction? of Lonthansidd :— ¥ C95%) z Scanned with CamScanner ousahows, keep assbyiNpransatugy (uniele) 2 (+6 06 by U ) a P ° Tonisafion Enery y of eo achinides, ane Cowes > than early fanthanoides ; . Yo Aut actinide metals are Ai hy electoopasibve Like > fantroneids and act ax Alscong seducing agers. Y° They have high mp and B.p. They do not folloe ) regular Gredation of mPand BP Pe ahomec ne ) *@ Actinide eonlsaction > Lathanoid confxacton due to ) poor Shield of sf yo Most of. the fonthanoid and actinides ane cobusied, ints Daishech ; Pow: ff. is tiachon Actinides : Lanthanide’ 4 ayFYTO;s an Cestain: (elementr some elemenks 2. they tye Jess tenden 3. They howe Al xonger to a frremasion a tendeney towards Gornp len formokion “3. Except Promethcum aan . . ane non sKneachve Stadio active a ar Ox. side: praxemmemmmmemmansmamiags but scoemetsmNeny, > . > > A, Oxides and hydrorides of 4 Oxeh and by drowsder Janthenide? axe Legs of actinides che mone basic boxsac, Scanned with CamScanner

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