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D - Block Elements

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121 views39 pages

D - Block Elements

Uploaded by

prashant90224
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Se ae us By leftaatioa | ghia _clefenabion excluctes Zr CAS 9 Be travisition elements — in 2+ ——= TCO. ‘ Re fez ad 2h 4 the foorbt tals To Canfégunalten wf Tiete—abopos. z: | = Pond ane Gd! 4d’, SA Zhe fa nut = SArd_properties xp transitéan slamends. — @ Or Teansrrrad Fy ener oe ee EA D_Flust Trans? ton Serta or 3A — Series; Of Caxrespomds a say Of cf — SUB Shee [a ~ cep or bee Lattice Jn Their A Be en eee i3 ae = _Treanhstton Chunk have reltval _41 EAE banizaPion energy and have eet 4 elected fe Geir Ober mush Shel! + As Oo G Kesults metaliie bonds are formed. Fhe —)ppatyed of -e/e feong also result 7 Prrreie Bon op eae bands > Yreater Fo no of of -eleFrond, 0S; epgex ie The efalltc ++ boating aa ns = Cr, No amd p) have Maximum no of . unpatred of —clechrons omd therefor ety have) metals. m= Wherad Zn CeJ_ om eye not fpard due fo Me abserce of iealeed electrrond j 4 : ae Mereury 1s digutd ab orclinar« | sem el. take becqude of Meta — High FE of 49. efleProng are nat Vs — ie barxtict pi tne ia _metallie bancling._ AD © Arese Volvr Ayo Qlewsery oe Tranks*#00 Clement hove ton) odomic L Volume ond Algh dens? {y- or Elements Se) Ti vier N]n | Fe Co Nie (2a Ab Vol Cem’) haa F243) 71 EF |EE[ 7/72 | = Dense gferd) oO 7 on FT FFL Bl EF he | Explarofion:- Atomic Vol? of FE cre Low 6 ecaure eleckrons are being. Lregreively Site} tn trner CnDd-abiply’ Tus frtvenkes nudleay Charge fs Poors ‘ 1 ig Sereened onzd Sa ena ade he efeSzons 175re os free: j his tresrtys tr Lov) Volime. oma Ag h? ens ifg- = HOES oare laments tH Wa Texte densi#eeg Dodium (lx) J 22: 6a (ems oa 2S mitiy COS) 22:57 37 tms. EEE oy radius in & nae Sentbeg aPeerBases ee ve righ? bub > Ses Areveasegs Shea ht ty Tn a ah: Atomic radius _fheam eft te_right as 2¢ Pp scree sed Whereas Ge eee ——- GbE padius HF Trea zs fEon retels are Afferent In Aifferen’ oxtloF? tr. Sates. c mb (On eral he Po ta decd decweades’ 7 Lncreasing in oxidation ‘at « = his Ta ponte Size af MIT cotirns are &matler han those of Mr. @ Porlen& Wp EATS Bar Leng FRENDS. Fhe frantsttion metals howe Nery Pe wilting privd ond batting Pletm Sheonges ep __ ahsins Ff Gesl elements are _reeap ts _ St ie Aigh prethngy ond eating P AF Tr ist Garksi fom Serkeo adi mefals + hove melting points abaye (000 C- 7 In ind and SrJI trantsi Por Saries aso x22? Ka ond Ag ale metals Pave melting points abo ye /O00C + | > 1) had fe 29k cof, wel ing fA ~ & F4o0%e anon y fa A-bloK_e/erxm &, Be Cas. ond He Are Fa franlsifien Serle, TE increases phle fr agp oz Go iP _o% gel, Aer PP decreas. Reason ZF Tie ine Teeny. ln-2e fs Lue to increase for Ruclear Charge swith increasing in atomic numbers in q Senieo fig increas fa pe ts Mery low): Nore ;— LE of 54 - elements are higher a Compitred to Those f 3A ond 4a -Sereg | plemnie oe i, Beeanoe We whialdin ore wee plectroons fn GA-elerenh PORE this effective P2UCeay ChI79-2 actin of on = He cuter mst Valence ele bray 10) Oxt Darton STATS ________ “Transition element exhibit Varta ble — Va leneye Or axtfoPian Sfo0HEd. nd : : os she trantsihon efinnte hove Tbeér | Valence electron tn fore Lifferent Sets Gf crbrlaly fe Dd an ns+ Since here fs very title Aiffs ir. e €77¢, fepe. orbitals, Gop 5 ene ele bond formation: = 42, S, HG, 3d ?45¢ 42) +3 GES) +e 3d 54s? #2, #8, th, Fb, 7 Bd eAs> t2 F544, 6 aes BE FE 48, FF ow BABYS +2, F3, FH * @ Cu BIH St 2 1) Zn 3 Mgt te J ——> Vaoe/z0v% Benzene +0 ppene @ ______ Many af fhe tre | Cay Minds are Uoed Ys Siffercet Chemical Le Some example es 4 Spnrals fe ammania by SlaberS paocesd » | 2 Behyaegenal em SAE to ald fe = w. Be Contact process of Manufackor of Soq ets 4 Manufactor of by Fes03, +Cr 03 bosch process ae? cl 7 ee Deaqaon's peat ZF Cudch 6 Manufactors of nas by- please Ostwald Preess. ee Mana, ‘acher &f vegelable ghee > NP &_Mehy —__ hp Omd Co 7 Zins; Cind, Benzene to oe es 2 anhganssle "Ot —— Vee soo te Pb alte ned fram => tigso4 NaphThalene am fo: Sythe tee Petrol from > Torn oxalate Conte C Berg tua proces) I Acetalletyele fan acstyline Bpseg 2 Acefic ack from acefaldleby de = - See. ge V2. 0g Ba _ Sy ntbeas F yasotine 7 Co-Th 4 polyhene 7” ylene Tela ona} krekalrn yf ahurinium. ____ CZiegler— ata Cat) see SET =” A Va } . Ieoge: alker, $y tegnation F a os a = lstKinson cof) Secs > Pa C WaEber'§ process) 0 =| i peas aa ¥e | sr i, £—oH I Se Sun —_oxalp¥ Dost of He Cranks tiem metal Compo undd Ctente er Co ~valent) are Csfoured bets Ip the Soltd Ske aorley ao 7 «49° Solukian i Canfrash to Fe Corps OF S- ond P—hlock 2femen ss: | ___ -Resongs s— ae Aa | Fhe 2etbion Coley tp lhe ___Pranist Hon metal fond or Thedr Corapds 8 cue fo absaption 7 Some madéiatton fram Visible tepht, which (8 uoed fr ee cn ‘electron firom one af ___ Mie of= Erbitel to fe anclfer+ > The franks lon, ae fed. tors hone ntemplete f— Suk Shel Moreover, when anfeng a tiporadd approach ta branisifey, jnetel tins. “tetr of—ab3 lols alo reed Rermain Aepnerats he all fs of at | do nol hase Sone 7 er, Aa cl oréitet © vt hove Some en 5 CRG They syplee nto tio sets xf ey 2G One Sak Sonsisting of Lowey Sner¢g erbilode CA, 14g2 ome A2x). Pipi 2h Consisting af Eyher —E2LES OV OILAS Copy? = 4/22). Ths is Fate, fp Cres tak Sikes Se oe i Py BiiGcr a sss PEK Rg eae —— =4 Vapenemig ipsa] 4 a Lorb}tals jn * bai es —___ 45 tronisihon e/ements Aare Pa #lig =a bfinlt, Pramottin Ff an eleckin from Lower doorbitals to Apher l-cvéttaly ig Pussthle» a | > Fhe ener eguired for (hbs promolin _| falls in fhe visi fegian. So When Whe kispt falls 07 fins “Compounds Ti 4 orb a parti'culay Coloyy of Mz Hadtatim far Gia_prom tion of d-elelnms ond Ke temanin are enjtted. Fhe Colour 2 Cempoun ha TLS ern: é s She promote d-efe i om. one te v d-ad ~ brranks?Hond. @ 3) Colour of the tone of I5t Treanisi tion Sen'es: Soe as oS oe Se | E [oras) confhy | [Notfumpatees) [epleur) a ~pusple. geet ddt ik vst Bd> 2 Green Vt CR —_3q3 3 Viole | SE et At Zh Wolof Fest Ti! Peal Gules pnt dd € a Pink, Fer _ 3dé 4 Gineen i Co2t SAF 3 PPni “= a wiper Jd & 2 Greeen et 8AT 4 Blue CH Zi. Bd lt oO Colour (248 . a a €_Car, t82: efemenh in_bihich petol fons have e2 Ther ica of-erbttals or ol-orbitale fully filled d=bréltals are Colurless ae Ffere 29 no- A-SI trantsttien possible. je bashes of Magnetta proper es, ¥ Compounds are cfusstfied inde fire _—— __ pass - = _ D Diamagnetee — aa | = — se as OO fara magnetic MAG NETEC i— Fhe Compounds whose Cons betuent particles Ao not Contatn any unpeér electrons ond ave repelled by _ wregne tie SSPE ave Cater in Blamepnetic - a 2) PRRAMPANETES 3 Fi a The Substances LIhAICh contain unpatrey efeccone fn (netr ar bileks are Caked 2 fzamagietic: —2 ETT Magnetic Moment, ue Vntota) Phen n= ne of Unpokr electing By = Bohr a Ds 5 ad® 3 N= o y= Tree) 62 He VAD ary VEG) 6M Gace as (ea) ele i aloe a = Vata) 6 = N24 6 j 2464 yh ghe substances Which are soiree 3 1h ayracted by rragnettc fief] are Med a ferromagnetic Scebs lances: -_. . Ghese Substames Shevs perroanent ————=nagnettzm even tn Fie absence Fe a ae mee of Magnetic a Fe lef « Fhe Substances hich Show twelativel, wi (ess paramaynestese are Called an ont ferromagy ne D185» Expi- Mine, , Wnz0a, Feo ete: _ Eesesenpneatize = = The Substanced Whih are expected fo howe Lage parame etisim Aue to tnequk no of om lotion of mag netic gromertt In opposite lire tion Are caked ferrimagnetic. Exp ? Fe 64 - Dee ea to, form Camplen. Cam panes Oat Saar “gustan melod fone fama Cage We “no ef complen compels: See” S\ ee erat lor, PAHS farm raples because Ff fhe Sellovriig Feasons — . D_ Sirall Size ond Aigh charge clensiby (i) of fhe bons Zranaiflor, 72ePUS- 7 ] D Presence CZ Oxides; RA % paw Srankstiton metal COM Shot iy» Merafore ot pee Xe? ze Yon dererent px footer Vain Pable Sor al fore a5 and eg D102 Mbor Wn» C1021 Moor pres. D) Agile oxides oss 1G, fet OF ; 2) baste oxides: ii Sey 032 THO) TOF 5 X07 eg UND _ Feo, Fez,as, Fegag» ©0201 Nid, Mee — © Araphatente opts Tia, Va37 C7293 7 Cr 0p ng 0 4 "Unb , Co. 4) Mixed ori dese— g Féz04 [5 an examples of mexefontde fa. which ontfattm sf tron are 2: ond 43. Actually tf is a mbextuve of Mp3 «5 amintire F fino & Feo and Fe303. In Ge Same oa a See. Pel = Expr Za a FeC Fe,)04 muestra hy obeides— Seemsttinn alerenents am des HbOL Compeumd = ess elenae —}- nt Soments HAAS re xy ge NiO ee Grup euro oan VetAL Pwiteddas tor [ ree ie compound and CaUed od Inperay | noak'ny Cund x2 Collad AL 7 F at ig Ep Exe= 1) pip SSaTidy Dprte2 —> Tity zi R Sa Ose en NCR) 7 Av +02 => ¥205 rs 2) ENDUST REAL RET HOD 7 t @ arakion af Sokkus ee cAromate © i Fae Oat FE Nee Gt FI ENG Cbg - 2 Pe zagf Slop ® Conversion of Sodium Chremoti TO 50 Lium A&ch tom ohh — Ba, C04 + HeS0y > NGstaoz t+ NYSe, thy a (J Conversion af Sokiam Lechrmek to porasstum Lichro m2 t— Nan C.07 +#KY —> ke, Crez tNacd chromate 7 to 2? Actesn of Alka? — tIhen en alxal? 2 added €a an Orange Red Solution of Aichromate, Bell ar sora. Kesutt Mie? fee frmoakin of Shromele. Ko C0207 t2ZKOH 72k, Cr0g +b 0 Orange Golo y 2 = 6707 2H — ZETOF +6 a : ZCrd3 4oR® 24 Cx07 FO 2— _PH=4, CHF tf Ky C87 ff eS0g 7b ey os Err ae (Sibg Jg 0 Die (S04) 3 PIs 2) £-é622i-_. 2 . Cree tt lesog tT zZ F ; Ko Crp TK S69 EOD Cs05)3 tZBTTHO BER Seg E Ko Cr 7 FS og F SN GS63——> byS0g PCB CS0z)9+ BNGS0g FAO 3s Y QE 362 to" S04 3 ome a5 ko Crrox t teSb4 t IS09—F KS0gt_. Cio 0 D 60> C707? [hos Sh PPE FD 19) BN 09 +O 077 BAT ING RPE GID a ze Ze ie Ty 25203 FOF FF PYF D FS0q TISHEA YG 12) 35n27 f C07 ZAP SS ZSn Ty Oey PF ___ klerides on , Aeving = sore Ke C: orange —red Semes UF Ketne7 FF OF FANGS FCS 04 — Sis 20% 2 2: angered Fos oh Bs ge FirBugh Naew Solution Po Nace Selution Yello C43 Coo sae ed 6 ccetate Giles Thick ae Pht C PbC%O4) A Cropth #9 Nach 7 Nas Cro-4 FENAST 2h Necro F & tos), PE—> Pb Crag Lt 2 Ch CaON Ss spelled ppt tor ay 27 6 Cr B97 on fee adreel 24 [ere (02) 04] Foy ent a4 REACTHON WITH Hy 504 — a) ko Ciso7 + Ha50g > 2Cro3 + Sdy p1b0 Red crystale, tng? iy Ke S04 # Cr. C504) 35 Gio + 300] REAsTegn BELEN al Ke CBOF TIGHT PEK +3 Crh PT FBOT3 Uy 6) Keo C07 PatoTy eee aT i420 paras tum ChloveCh wrk. aa oe opt ACE 7 Se eco LE pain oe _—— imag PaNiga Lo Cade F2KY Hmomyy > Formation Of of chomp alam , KC oF F MypSo4 $0 Ss KoS04 + Coes) oy eo Kn.504 Fr C04 yt Hes = Ky S04) Cy(Su)y2thi at ied ee a | eh ol! a um). Lt Ge ar E x 0 ib) es = peo A 2D. (chromate eons. CR ee _ Gt Lis pofasstune Sat) G/ p Permosnpanis acid (Fi Ine4). a ee Ce Pee paren chon — wae 2 a 2p 80g - f2eo meske ee F 2 bei04 aay oR EE HS 2 py aesing cag © CO, 03 Ino: 50/2 a) aka Nny + 2 ea FY C2 > 2 Knog ty t ARKH Coa ) 2k tng F ds —> 2KMneg + 2Kep 0) 2h Mney £03 tbo —> Z2KMUn0g + 2KoH +0) Ofer practs se 2 Noo tH KON +0, BALI 2K Mnogt2hoa a) 8 Uny FS Kept Kdos ae Bh May FKUO fF Bia [ ———— Step-n D2 Ano, + ch 2 2KMN G4 “2K ot DNS M05 F204 tes => DKateg PZ kin ey btn 0, F Ip Hy g i] Ay oxidation riiiy © Zong 2 N04 + £37 tad 2K Mn bgp 2KGH +o OOF & & Viokt Coloured Cngstltine F01ep, QO Melting point = 275° WD ois partial Soluble in Cale Paler buP Sully soluble o72 oft rater = 70h bz - SS) paw AOF7A/ Op) Ltaet OH? 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