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KR950011347A - 열처리 변환가능의 피복유리 및 그를 변환하는 방법 - Google Patents

열처리 변환가능의 피복유리 및 그를 변환하는 방법 Download PDF

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KR950011347A
KR950011347A KR1019940025446A KR19940025446A KR950011347A KR 950011347 A KR950011347 A KR 950011347A KR 1019940025446 A KR1019940025446 A KR 1019940025446A KR 19940025446 A KR19940025446 A KR 19940025446A KR 950011347 A KR950011347 A KR 950011347A
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layer
glass
nickel
sputter
heat
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KR970008986B1 (ko
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더블류. 하티그 클라우스
제이. 링글 필립
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존 제이. 가스파로빅
가디안 인더스트리즈 코퍼레이션
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3607—Coatings of the type glass/inorganic compound/metal
    • C—CHEMISTRY; METALLURGY
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    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3626—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer one layer at least containing a nitride, oxynitride, boronitride or carbonitride
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    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
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    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
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    • C03C17/3652—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the coating stack containing at least one sacrificial layer to protect the metal from oxidation
    • C—CHEMISTRY; METALLURGY
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    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3657—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating having optical properties
    • C03C17/366—Low-emissivity or solar control coatings
    • C—CHEMISTRY; METALLURGY
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    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
    • C03C17/36—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal
    • C03C17/3602—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer
    • C03C17/3681—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating being a metal the metal being present as a layer the multilayer coating being used in glazing, e.g. windows or windscreens
    • C—CHEMISTRY; METALLURGY
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    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00—Coatings on glass
    • C03C2217/70—Properties of coatings
    • C03C2217/78—Coatings specially designed to be durable, e.g. scratch-resistant
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12542—More than one such component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12576—Boride, carbide or nitride component
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
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    • Y10T428/12—All metal or with adjacent metals
    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12535—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.] with additional, spatially distinct nonmetal component
    • Y10T428/12597—Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
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    • Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
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Abstract

유리 기판에 층 조직을 스퍼터 피복함에 의하여, 열처리 후 약 76% 이상의 가시 투과율과, 약 0.16 이하의 반구형 방사율(Eh) 및 약 0.12 이하의 정상 방사율(En)을 나타내고 Si3n4의 언더코트와 오버코트, 은 층, 및 은 층의 대향 측의 둘의 니켈 또는 니크롬 층을 포함하며, 하측의 니켈 토대의 층이 타의 니켈 토대의 층의 약 세배 두꺼운 고성능의, 내구력이 있는 스퍼터 피복의, 열처리 가능의 유리가 형성된다. 하측의 니켈 토대의 증대된 두께는 피복 유리 품목을, 열처리 가능하고, 또 열처리 "저 E"의 양자가 되게 한다. 이는 층 구성요소의 타의 기지의 유리들과 열처리 방식의 대신으로 어울리게 한다. 채용된 층 조직은, 비록 또다른 유리에 걸맞지 않을지라도, 스퍼터 피복 작업에 대해 표적의 변화없이 일군의 층 구성요소의 타의 부재들의 피복과, 현존하는 코팅기 표적들의 능률적인 이용, 그리고 생산 중 최소의 조작상의 변화를 포함하게 한다..

Description

열처리 변환가능의 피복유리 및 그를 변환하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
제1도는 본 발명의 실시에 채용되어도 좋은(또 제2도의 선행기술의 실시에 달리 채용되는) 에어코 기계장치(Airco apparatus)의 개략도이다,
제2도는 선행기술 에어코 피복 유리품 층 체계의 부분 측단면도이다,
제3도는 본 발명의 실시양태의 부분 측단면도이다.

Claims (34)

  1. 열처리 가능 피복의 유리 품목으로서, a) 약 350Å-450Å의 두께를 가진 Si3N4의 제1의 층; b) 약 20Å이상의 두께를 가진 니켈 또는 니크롬의 제1의 층; c) 약 50Å-120Å의 두께를 가진 은의 층; d) 적어도 약 7Å의 두께를 가진 니켈 또는 니크롬의 제2의 층; e) 약 450Å-550Å의 두께를 가진 Si3N4의 제2의 층; 을 유리로부터 외향으로 함유하는 스퍼터 피복의 층 조직을 가지며 상기 피복의 유피 품목이, 상기 유리가 투명유리이고 약 2.5mm-3.5mm의 두께를 가지는 경우 열처리 후 하기의 특성를 가지는 유리 품목.
    투과율(C 광원 10° 관측) 약 76%-78%
    시트 저항(Rs) 약 12 옴/sq 미만
    방사율, 정상(En) 약 0.12 미만
    방사율, 반구형(Eh) 약 0.16 미만
  2. 제1항에 있어서, 상기 정상 방사율(En)이 열처리 전에는 약 0.15 이하고 열처리 후에는 약 0.11 이하이며; 상기 반구형 방사율(Eh)이 열처리 전에는 약 0.18 미만이고 열처리 후에는 약 0.14 미만인 열처리 가능 피복의 유리품목.
  3. 제1항에 있어서, 제1의 Si3N4층의 두께가 약 375Å이고 제2의 Si3N4층의 두께가 약 500Å인 열처리 가능 피복의 유리품목.
  4. 제3항에 있어서, 은 층의 두께가 약 75Å인 열처리 가능 피복의 유리품목.
  5. 제1항에 있어서, 제1의 스퍼터 피복의 니켈 또는 니크롬 층의 두께가 제2의 니켈 또는 니크롬 층의 두께의 약 3배 큰 열처리 가능 피복의 유리품목.
  6. 제5항에 있어서, 제1의 니켈 또는 니크롬 층이 약 20-50Å 두껍고 제2의 니켈 또는 니크롬 층이 약 7-15Å 두꺼운 열처리 가능 피복의 유리품목.
  7. 제1항에 있어서, 상기 층 조직이 상기 다섯 층으로 본래 이루어져 있고, 또 상기 스퍼터 피복의 품목이 내구적이며 내화학적인 열처리 가능 피복의 유리품목.
  8. 적어도 하나의 태양 관리 특징에 있어서나, 각기 열처리된 그들의 가능성과 불가능성에 있어서나, 또는 양자에 있어, 사실상 서로 다른 적어도 둘의 스퍼터 피복의 유리 품목을 연속하여 산출하는 방법으로서, 각 유리 품목상의 상기 스퍼터 피복이 복수의 스퍼터 피복의 층을 함유함으로써 Si3N4및 니켈/크롬 성분으로 이루어지는 스퍼터 피복 조직을 형성하게 되며, a) 제1의 유리 품목에 제1의 층을 산출하도록 복수의 분위기 지대 설비 내에 복수의 표적을 가진 코팅기를 마련하여, 사실상 상기 표적들과 지대들의 모두를 상기 제1의 층을 산출함에 이용하고, b) 단계 (a)에 있어 마련한 것과 같은 설비를 이용하여 상기 제1의 유리 품목에 제2의 층 조직을 스퍼터 피복하며; c) 그 다음, 제2의 유리 품목에 제2의 층 조직을 산출하도록 설비를 마련하게, 상기 복수의 표적의 어느 것에 부가하거나 대응함이 없이 그리고 상기 분위기 지대의 크기를 확대하거나 축소함이 없이 단계 (a)의 설비를 변경함으로써 기 제2의 층 조직을 산출함에 사실상 상기 표적들과 지대들의 모두를 사용하며, 또 d) 단계 (c)에 있어 마련한 것과 같은 설비를 이용하여 상기 제2의 유리 품목에 제2의 층 조직을 스퍼터 피복하는, 단계들로 이루어지는 연속 산출법.
  9. 제8항에 있어서, 상기 스퍼터 코팅기가 약 30 이하의 표적들과 약 6 이하의 부위기 지대들을 포함하는 연속 산출법.
  10. 제8항에 있어서, 상기 스퍼터 피복의 유리 품목들 중의 하나만이 열처리 가능하며 그러나 그것을 열처리한 후의 상기 스퍼터 피복의 유리 품목들 양자는 가시 투과율, 색상, 및 방사율에 의해 규정되는 한에서 사실상 동일한 태양 관리 특징을 가지는, 연속 산출법.
  11. 제10항에 있어서, 상기 열처리 가능의 스퍼터 피복의 유리 품목이 열처리되기 전에는 그 것이 가시 투과율, 색상, 및 방사율에 의해 규정되는 한에서 사실상 다른 태양 관리 특징을 가지는, 연속 생출법.
  12. 제11항에 있어서, 상기 열처리 가능 스퍼터 피복의 유리 품목이 a) 약 350Å-450Å의 두께를 가진 Si3N4의 제1의 층; b) 약 20Å 이상의 두께를 가진 니켈 또는 니크롬의 제1의 층; c) 약 50Å-120Å의 두께를 가진 은의 층; d) 적어도 약 7Å의 두께를 가진 니켈 또는 니크롬의 제2의 층; e) 약 450Å-550Å의 두께를 가진 Si3N4의 제2의 층; 을 유리로부터 외향으로 함유하는 스퍼터 피복의 층 조직을 그에 가지며, 상기 피복의 유리 품목이, 상기 유리가 투명유리이고 약 2.5mm-3.5mm의 두께를 가지는 경우 열처리 후 하기의 특성을 가지는, 연속 산출법.
    투과율(C 광원 10° 관측) 약 76%-78%
    시트 저항(Rs) 약 12 옴/sq 미만
    방사율, 정상(En) 약 0.12 미만
    방사율, 반구형(Eh) 약 0.16 미만
  13. 제12항에 있어서, 상기 열처리 가능 스퍼터 피복의 유리 품목이, 상기 유리가 투명하며 약 2.5mm-3.5mm의 두께를 가지는 경우 열처리 전 하기의 특성을 가지는, 연속 산출법.
    투과율(C 광원 10° 관측) 약 70%-73%
    시트 저항(Rs) 약 15 옴/sq 미만
    방사율, 정상(En) 약 0.16 미만
    방사율, 반구형(Eh) 약 0.20 미만
  14. 제13항에 있어서, 상기 제1의 스퍼터 피복의 유리 품목이, 비 열처리가능하며 유리로부터 외향으로 Si3N4/Ni : Cr/Ag/Ni : Cr/Si3N4의 스퍼터 피복의 층으로 본래 이루어진 스퍼터 피복의 층 조직을 그에 가지고 있고; 또 상기 유리가 투명하며 약 2.5mm-3.5mm의 두께를 가지는 경우, 상기 제1의 유리 품목이 하기의 특성을 가지는, 연속 산출법.
    투과율(C 광원 10° 관측) 약 76% 이상
    시트 저항(Rs) 약 12 옴/sq 미만
    방사율, 정상(En) 약 0.12 미만
    방사율, 반구형(Eh) 약 0.16 미만
  15. 제14항에 있어서, 상기 스퍼터 피복의 유리 품목이 내화학성이며 내구력이 있는 연속 산출법.
  16. 제10항에 있어서, 상기 열처리 가능의 스퍼터 피복의 유리 품목을 상기 층 조직을 그에 스퍼터 피복한 후 열처리하는 단계를 더 포함하고, 상기 열처리는 상기 열처리 가능의 스퍼터 피복의 유리 품목을 약 1150°F-1450°F의 온도에서 약 5분 이상의 시간 동안 가열하기와 또 상기 유리 품목을 불리기에 충분한 온도에 한 동안 상기 유리 품목을 냉각하기를 포함하는, 연속 산출법.
  17. 제10항에 있어서, 상기 열처리 가능의 스퍼터 피복의 유리 품목을 상기 층 조직을 그에 스퍼터 피복한 후 열처리하는 단계를 더 포함하고, 상기 열처리는 상기 열처리 가능의 유리 품목을 상기 유리 품목이 만곡할 수 있게 만드는 충분한 기간의 시간 동안 가열하기와 그 다음 그의 만곡할 수 있는 상태일 동안에 희망하는 모양에 만곡하기를 포함하는, 연속 산출법.
  18. 열처리된 얇고, 단단하며, 유리 기판에 태양 관리 층 조직을 형성하는 방법으로서, 그 단계들이 a) 질소 함유 분위기에서 Si3N4의 언더코트 층을 스퍼터 피복하고; b) 불활성 가스 분위기에서 니켈 또는 니크롬의 제1의 층을 스퍼터 피복하며, 니켈 또는 니크롬의 상기 제1의 층은 적어도 약 20Å 두껍고; c) 불활성 가스 분위기에서 은의층을 스퍼터 피복하고; d) 불활성 가스 분위기에서 니켈 또는 니크롬의 제2의 층을 스퍼터 피복하며, 니켈 또는 니크롬의 상기 제1의 층은 적어도 약 7-15Å 두껍고; e) 질소 함유 분위기에서 Si3N4의 오버코트 층을 스퍼터 피복하며; 그 다음 상기 피복의 유리를 열처리하는 것을 포함하며; 상기 열처리한, 스퍼터 피복의 유리가 상기 유리 기판이 투명하며 약 2.5-3.5mm의 두께를 가지는 경우, 상기 열처리 후 하기의 특징을 가지는, 형성방법.
    투과율(C 광원 10° 관측) 약 76%-78%
    시트 저항(Rs) 약 12 옴/sq 미만
    방사율, 정상(En) 약 0.12 미만
    방사율, 반구형(Eh) 약 0.16 미만
  19. 제18항에 있어서, 상기 열처리가 불리기, 만곡하기 또는 열강화로부터 선택되는, 유리 기판에 태양 관리층 조직을 형성하는 방법.
  20. 제19항에 있어서, 상기 열처리의 단계가 피복의 유리를, 약 1150°F-1450°F의 온도에 그것을 가열하고 그 다음 그것을 냉각함에 의하여 불리기로 이루어져 있고, 가열과 냉각 단계는 상기 유리를 불리기에 충분한 동안의 시간인, 유리 기판에 태양 관리 층 조직을 형성하는 방법.
  21. 제19항에 있어서, 피복의 유리가 상기 열처리 가능의 유리 품목을 만곡할 수 있게 만드는 온도에서 충분한 동안의 시간동안 가열되며, 그 다음 상기 유리를 그의 만곡할 수 있는 상태일 동안에 희망하는 모양에 만곡하는, 유리 기판에 태양 관리 층 조직을 형성하는 방법.
  22. 제18항에 있어서, 상기 스퍼터 피복이 상호 격리된 복수의 재대에서 단행되며 스퍼터 피복에 의한 Si3N4의 언더코트 및 오버코트 충돌을 형성하는 단계들이, 약 80% N2와 20% Ar을 본래 함유하는 분위기를 가지는, 적어도 둘의 분리 지대에서 단행되며, 니켈 또는 니크롬 층들과 은의 층을 형성하는 단게드이 동일 지대에서 단행되고 상기 스퍼터 피복이 본래 a) 사실상 100% Ar; 및 약 95% Ar과 약 5% O2중의 하나로 본래 이루어지는 분위기의 상기 동일 지대에서 단행되는, 유리 기판에 태양 관리 층 조직을 형성하는 방법.
  23. 제18항에 있어서, 상기 언더코트 Si3N4층이 약 350-450Å 두껍고 상기 오버코트 Si3N4층이 약 450-550Å 두꺼운, 유리 기판에 태양 관리 층 조직을 형성하는 방법.
  24. 제23항에 있어서, 상기 언더코트 Si3N4층이 약 375Å 두께에 스퍼터 피복되며 상기 오버코트 Si3N4층이 약 500Å 두께에 스퍼터 피복되는, 유리 기판에 태양 관리 층 조직을 형성하는 방법.
  25. 제18항에 있어서, 단지 하나의 은 층이 있고, 상기 은 층이 약 50-120Å 두께를 가지며 니켈 또는 니크롬의 상기 제1의 층이 상기 제2의 니켈 또는 니크롬 층의 두께의 약 세배의 두께를 가지는, 유리 기판에 태양 관리 층 조직을 형성하는 방법.
  26. 제18항에 있어서, 상기 제1의 니켈 또는 니크롬 층이 약 20-50Å 두껍고 상기 제2의 니켈 또는 니크롬 층이 약 7-15Å 두꺼운, 유리 기판에 태양 관리 층 조직을 형성하는 방법.
  27. 제18항에 있어서, 피복의 유리가, 상기 열처리 후, 약 11 옴/sq 이하의 시트 저항(Rs)과 약 0.11 이하의 정상 방사율을 가지는, 유리 기판에 태양 관리 층 조직을 형성하는 방법.
  28. 열처리 가능의, 스퍼터 피복의 유리 품목의 적어도 하나의 태양 관리 특성을 상기 피복의 유리 품목을 열처리함에 의하여 미리 선택한 수준에 변환하는 방법으로서, 그 단계들이 a) 유리 기판에 기판으로부터 외향으로 (i) 제1의 Si3N4층; (ii) 제1의 니켈 또는 니크롬 층; (iii) 은 층 (iv) 제2의 니켈 또는 니크롬 층; 및 (v) 제2의 Si3N4층; 을 유리 기판에 스퍼터 피복함에 의하여 열처리 가능의 피복 유리를 산출하기와; b) 상기 피복의 유리 품목을 열처리함으로써 가시 투과율, 방사율 또는 색상으로부터 선택된 적어도 하나의 태양 관리 특징을 증대하게 변경하는 것을 포함하며; 또 상기 결과의 피복의 유리 품목이 상기의 열처리 후 그리고 기판이 투명 유리이며 약 2.5-3.5mm 두꺼운 경우 하기의 특징을 가지는, 태양 관리 특성을 변환하는 방법.
    투과율(C 광원 10° 관측) 약 76% 이상
    시트 저항(Rs) 약 12 옴/sq 미만
    방사율, 정상(En) 약 0.12 미만
    방사율, 반구형(Eh) 약 0.16 미만
  29. 제28항에 있어서, 열처리 전의 상기 스퍼터 피복의 유리가 상기 기판이 투명 유리이며 약 2.5mm-3.5mm의 두께를 가지는 경우 하기의 특징을 가지는, 태양 관리 특성을 변환하는 방법.
    투과율(C 광원 10° 관측) 약 70-73%
    시트 저항(Rs) 약 15.0 옴/sq 미만
    방사율, 정상(En) 약 0.16 미만
    방사율, 반구형(Eh) 약 0.20 미만
  30. 제29항에 있어서, 상기 열처리 후의 상기 En이 약 0.11 미만이고 열처리 전의 상기 En이 약 0.14 이며 상기 열처리 후의 상기 반 구형 방사율(Eh)이 약 0.11 미만이고 상기 열처리 전이 약 0.17인, 태양 관리 특성을 변환하는 방법.
  31. 제29항에 있어서, 상기 열처리 단계가 상기 스퍼터 피복의 유리 품목을 불리기를 포함하는, 태양 관리 특성을 변환하는 방법.
  32. 제29항에 있어서, 상기 제1의 니켈 또는 니크롬 층이 약 20-50Å 두껍고 상기 제2의 니켈 또는 니크롬 층이 약 7-15Å 두꺼운, 태양 관리 특성을 변환하는 방법.
  33. 제32항에 있어서, 상기 은 층이 약 75Å 두껍고 상기 제1의 Si3N4층이 약 350-450Å 두꺼우며 상기 제2의 Si3N4층이 약 450-550Å 두꺼운, 태양 관리 특성을 변환하는 방법.
  34. 제32항에 있어서, 상기 제1의 니켈 또는 니크롬 층이 약 45Å 두껍고 상기 제2의 니켈 또는 니크롬 층이 약 15Å 둬운, 태양 관리 특성을 변환하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019940025446A 1993-10-05 1994-10-05 열처리 변환가능의 피복유리 및 그를 변환하는 방법(heat-treament convertible coated glass and method of converting same) KR970008986B1 (ko)

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US08/131,696 1993-10-05
US08/131,696 US5376455A (en) 1993-10-05 1993-10-05 Heat-treatment convertible coated glass and method of converting same
US8/131,696 1993-10-05

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KR950011347A true KR950011347A (ko) 1995-05-15
KR970008986B1 KR970008986B1 (ko) 1997-06-03

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TW302350B (ko) 1997-04-11
AU677859B2 (en) 1997-05-08
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US5584902A (en) 1996-12-17
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US5376455A (en) 1994-12-27
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EP0646551A1 (en) 1995-04-05
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