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KR940005226A - 항균화합물의 제조방법 - Google Patents

항균화합물의 제조방법 Download PDF

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Publication number
KR940005226A
KR940005226A KR1019930008587A KR930008587A KR940005226A KR 940005226 A KR940005226 A KR 940005226A KR 1019930008587 A KR1019930008587 A KR 1019930008587A KR 930008587 A KR930008587 A KR 930008587A KR 940005226 A KR940005226 A KR 940005226A
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KR
South Korea
Prior art keywords
ions
metal
valence
silver
phosphate
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KR1019930008587A
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English (en)
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KR100252367B1 (en
Inventor
스이찌 오스미
고지 스기우라
히데끼 가또
Original Assignee
가메따니 도시아끼
도아고세이가가꾸고오교 가부시끼가이샤
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Publication of KR940005226A publication Critical patent/KR940005226A/ko
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Publication of KR100252367B1 publication Critical patent/KR100252367B1/ko

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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
    • A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B25/00—Phosphorus; Compounds thereof
    • C01B25/16—Oxyacids of phosphorus; Salts thereof
    • C01B25/26—Phosphates
    • C01B25/45—Phosphates containing plural metal, or metal and ammonium
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
    • A01N59/26—Phosphorus; Compounds thereof

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Inorganic Chemistry (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

은, 구리, 아연, 주석, 수은, 납, 철, 코발트, 니켈, 망간, 비소, 안티몬, 비스무스. 바륨. 카드윰 및 크롬으로 부터 선택된 하나 이상의 금속을 하기 일반식 (2)로 나타내는 인산염상에 담지시켜 하기 일반식 (1)로 나타내는 항균 화합물을 제조하는 방법에 있어서. 이러한 인산염이 습식법애 의하여 합성되고 수소 이온을 담지시키는 단계 및 500 내지 1300℃에서 연소하는 단계를 사용함을 특징으로 하는 제조방법 :
M1 aHbA1 cM2 2(PO4)3· nH20 (1)
A2 dM2 2(PO4)3· nH2O (2)
상기식에서, M1은 은, 구리, 아연, 주석, 수은, 납, 철, 코발트, 니켈, 망간, 비소 안티몬, 비스무스, 바륨, 카드윰 및 크롬으로부터 선택된 하나 이상의 금속이온이고, A1은 알칼리 금속이온 및 알칼리 토금속이온으로부터 선택된 하나 이상의 금속이온이고, M2는 4가 금속이고, n은 0≤n≤6을 만족시키는 수이고, a 및 b는 양수이며 c는 0 또는 양수이고, a,b 및 c는 ka+b+mc=1 (여기서, k는 M1의 원자가이고 m은 A1의 원자가이다)을 만족시키며, A2는 알칼리 금속이온, 알칼리 토금속이온 및 암모늄 이온으로부터 선택된 하나 이상의 이온이고, d는 1/m1(여기서, m1은 A1의 원자가이다)이다.

Description

항균화합물의 제조방법
내용없음

Claims (3)

  1. 은, 구리, 아연, 주석, 수은, 납, 철, 코발트 니켈, 망간, 비소 안티몬, 바륨, 카드뮴 및 크롬으로 부터 선택된 하나 이상의 금속을 하기 일반식(2)로 나타내는 인산염상에 담지시켜 하기 일반식(1)로 나타내는 항균 화합물을 제조하는 방법에 있어서, 이러한 인산염이 습식법에 의하여 합성되고 수소이온을 담지시키는 단계 및 500 내지 1300℃에서 연소하는 단계를 사용함을 특징으로 하는 제조방법:
    M1 aHbA1 cM2 2(PO4)3·nH2O (1)
    A2 dM2 2(PO4)3·nH2O (2)
    상기식에서, M1은 은, 구리, 아연, 주석, 수은, 납, 철, 코발트, 니켈, 망간, 비소, 안티몬, 비스무스, 바륨, 카드뮴 및 크롬으로부터 선택된 하나 이상의 금속이온이고, A1은 알칼리 금속이온 및 알칼리 토금속이온으로부터 선택된 하나 이상의 금속 이온이며, M2는 4가 금속이고, n은 0≤n≤6을 만족시키는 수이고, a 및 b는 양수이며 c는 0 또는 양수이고, a,b 및 c는 ka＋b＋mc＝1(여기서, k는 M1의 원자가이고 m은 A1의 원자가이다)을 만족시키며, A2는 알칼리 금속이온, 알칼리 토금속이온 및 암모늄 이온으로부터 선택된 하나 이상의 이온이고, d는 1/m1(여기서, m1은 A2의 원자가이다)이다.
  2. 제1항에 있어서, 인산염이 3차원 망상 구조를 가지며, A2가 나트륨이온이고 M2가 지르코늄 또는 티타늄인 일반식(2)로 나타내는 결정질화합물인 방법.
  3. 제1항에 있어서, 항균 화합물이 3차원 망상구조를 가지며, M1이 은이온이고, a가 0.01 내지 0.5이고, A1이 나트륨이온이며, M2가 지르코늄 또는 일반식(1)로 나타내는 결정질 화합물인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930008587A 1992-05-21 1993-05-19 Process for producing antimicrobial compounds KR100252367B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP92-154356 1992-05-21
JP15435692 1992-05-21
JP15569692 1992-05-22

Publications (2)

Publication Number Publication Date
KR940005226A true KR940005226A (ko) 1994-03-21
KR100252367B1 KR100252367B1 (en) 2000-04-15

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Country Status (7)

Country Link
US (1) US5441717A (ko)
JP (1) JP3448896B2 (ko)
KR (1) KR100252367B1 (ko)
DE (1) DE4317122B4 (ko)
FR (1) FR2691326B1 (ko)
GB (1) GB2267085B (ko)
TW (1) TW226965B (ko)

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Also Published As

Publication number Publication date
US5441717A (en) 1995-08-15
JP3448896B2 (ja) 2003-09-22
GB9310437D0 (en) 1993-07-07
DE4317122B4 (de) 2005-06-02
GB2267085B (en) 1995-06-07
JPH0640829A (ja) 1994-02-15
TW226965B (ko) 1994-07-21
KR100252367B1 (en) 2000-04-15
GB2267085A (en) 1993-11-24
FR2691326A1 (fr) 1993-11-26
DE4317122A1 (de) 1993-11-25
FR2691326B1 (fr) 1994-08-05

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