KR880001846A - 니켈 합금 양극 - Google Patents
니켈 합금 양극 Download PDFInfo
- Publication number
- KR880001846A KR880001846A KR1019870008388A KR870008388A KR880001846A KR 880001846 A KR880001846 A KR 880001846A KR 1019870008388 A KR1019870008388 A KR 1019870008388A KR 870008388 A KR870008388 A KR 870008388A KR 880001846 A KR880001846 A KR 880001846A
- Authority
- KR
- South Korea
- Prior art keywords
- silver
- cell
- nickel
- molybdenum
- chromium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910000990 Ni alloy Inorganic materials 0.000 title 1
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 4
- 229910052709 silver Inorganic materials 0.000 claims 4
- 239000004332 silver Substances 0.000 claims 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims 3
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims 3
- 239000000956 alloy Substances 0.000 claims 3
- 229910045601 alloy Inorganic materials 0.000 claims 3
- 229910052804 chromium Inorganic materials 0.000 claims 3
- 239000011651 chromium Substances 0.000 claims 3
- 229910052750 molybdenum Inorganic materials 0.000 claims 3
- 239000011733 molybdenum Substances 0.000 claims 3
- 229910052759 nickel Inorganic materials 0.000 claims 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 239000000460 chlorine Substances 0.000 claims 2
- 229910052801 chlorine Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 238000000034 method Methods 0.000 claims 2
- 150000004045 organic chlorine compounds Chemical class 0.000 claims 2
- 239000002245 particle Substances 0.000 claims 2
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 claims 2
- GXFRQLQUKBSYQL-UHFFFAOYSA-N 3,4,5,6-tetrachloropyridine-2-carboxylic acid Chemical compound OC(=O)C1=NC(Cl)=C(Cl)C(Cl)=C1Cl GXFRQLQUKBSYQL-UHFFFAOYSA-N 0.000 claims 1
- TVMKSGXYTVKNRK-UHFFFAOYSA-N 3,5,6-trichloropyridine-2-carboxylic acid Chemical compound OC(=O)C1=NC(Cl)=C(Cl)C=C1Cl TVMKSGXYTVKNRK-UHFFFAOYSA-N 0.000 claims 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims 1
- 239000010941 cobalt Substances 0.000 claims 1
- 229910017052 cobalt Inorganic materials 0.000 claims 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims 1
- 238000006298 dechlorination reaction Methods 0.000 claims 1
- 238000005868 electrolysis reaction Methods 0.000 claims 1
- 229910052742 iron Inorganic materials 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 claims 1
- 239000011572 manganese Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229910001923 silver oxide Inorganic materials 0.000 claims 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
- 229910052721 tungsten Inorganic materials 0.000 claims 1
- 239000010937 tungsten Substances 0.000 claims 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/055—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
- C25B11/057—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
- C25B11/061—Metal or alloy
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
- C22C19/03—Alloys based on nickel or cobalt based on nickel
- C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
- C22C19/051—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
- C22C19/053—Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 30% but less than 40%
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/052—Electrodes comprising one or more electrocatalytic coatings on a substrate
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/25—Reduction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Magnetic Ceramics (AREA)
Abstract
Description
Claims (9)
- 전해셀에서 유기염소 화합물중의 염소를 선택적으로 수소로 치환시키는데 유용하고 필수적으로 니켈 40 내지 70%, 크롬 5내지 30%, 및 몰리브덴 3 내지 25%를 함유하는 합금의 표면을 갖는 양극.
- 제1항에 있어서, 합금이 니켈 50 내지 65%, 크롬 12 내지 20%, 및 몰리브덴 4 내지 20%를 함유하는 양극.
- 제2항에 있어서, 합금이 대략 니켈 55%, 크롬 16%, 몰리브덴 16%, 철 5%, 텅스텐 4%, 코발트 2.5% 및 망간 1%를 함유하는 양극.
- 유기염소 화합물 중의 염소를 선택적으로 수소로 치환시키는데 유용하고 제1항 내지 3항중 어느 한 항의 양극 적어도 하나를 포함하는 전해셀.
- 제4항에 있어서, 은 표면으로 된 음극을 추가로 포함하는 전해셀.
- 제5항에 있어서, 은이 수성 염기의 존재하에서 교질성, 함수산화은 입자를 전해적으로 환원시켜 생성된 미세결정질 층을 갖는 전해셀.
- 전기화학 셀중에서 테트라클로로피콜린 산 또는 3,5,6-트리클로로피콜린 산을 환원적으로 탈염소화 시켜 3.6-디클로로피콜린산을 제조하는 방법에 있어서, 제4항 내지 6항 중 어느 한 항의 전기화학 셀을 이용함을 특징으로 하는 방법.
- 제7항에 있어서, 셀이 은의 표면을 갖는 음극을 추가로 함유하는 방법.
- 제8항에 있어서, 은이 수성염기의 존재하에서 교질성, 함수 산화은 입자를 전기분해에 의해 환원시켜 생성된 미세결정질 층을 갖는 방법.※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US891,814 | 1986-07-31 | ||
US06/891,814 US4778576A (en) | 1986-07-31 | 1986-07-31 | Nickel alloy anodes for electrochemical dechlorination |
US891814 | 2001-06-26 |
Publications (2)
Publication Number | Publication Date |
---|---|
KR880001846A true KR880001846A (ko) | 1988-04-27 |
KR940010105B1 KR940010105B1 (ko) | 1994-10-21 |
Family
ID=25398864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
KR1019870008388A Expired - Fee Related KR940010105B1 (ko) | 1986-07-31 | 1987-07-31 | 전기 화학적 탈염소화 반응용 니켈 합금 양극 |
Country Status (15)
Country | Link |
---|---|
US (2) | US4778576A (ko) |
EP (1) | EP0254982B1 (ko) |
JP (1) | JP2592848B2 (ko) |
KR (1) | KR940010105B1 (ko) |
AT (1) | ATE69068T1 (ko) |
AU (1) | AU594485B2 (ko) |
BR (1) | BR8703924A (ko) |
CA (1) | CA1312039C (ko) |
DE (1) | DE3774201D1 (ko) |
DK (1) | DK168639B1 (ko) |
ES (1) | ES2025600T3 (ko) |
FI (1) | FI82489C (ko) |
HU (1) | HU201014B (ko) |
IL (1) | IL83358A (ko) |
NZ (1) | NZ221194A (ko) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6740291B2 (en) | 2002-05-15 | 2004-05-25 | Haynes International, Inc. | Ni-Cr-Mo alloys resistant to wet process phosphoric acid and chloride-induced localized attack |
US6764646B2 (en) * | 2002-06-13 | 2004-07-20 | Haynes International, Inc. | Ni-Cr-Mo-Cu alloys resistant to sulfuric acid and wet process phosphoric acid |
JP4695069B2 (ja) * | 2003-03-04 | 2011-06-08 | ダウ アグロサイエンシィズ エルエルシー | 6−クロロ−2−トリクロロメチルピリジンの気相塩素化による3,6−ジクロロ−2−トリクロロメチルピリジンの製造 |
AU2004236085B2 (en) * | 2003-05-09 | 2010-03-25 | Asahi Glass Company, Limited | Processes for producing 3-substituted 2-chloro-5-fluoropyridine or salt thereof |
KR100761369B1 (ko) | 2005-03-31 | 2007-09-27 | 주식회사 하이닉스반도체 | 온도변화 적응형 내부 전원 발생 장치 |
JP4773773B2 (ja) | 2005-08-25 | 2011-09-14 | 東京電波株式会社 | 超臨界アンモニア反応機器用耐食部材 |
CN100436648C (zh) * | 2005-12-16 | 2008-11-26 | 浙江工业大学 | 3,6-二氯吡啶甲酸的电解合成方法及设备 |
CA2705819C (en) * | 2007-11-16 | 2016-12-13 | Akzo Nobel N.V. | An electrode substrate composition |
CN103603006B (zh) * | 2013-09-29 | 2016-01-20 | 杭州赛龙化工有限公司 | 一种3,6-二氯吡啶甲酸的电解合成工艺 |
US9440923B2 (en) * | 2014-08-06 | 2016-09-13 | Dow Agrosciences Llc | Process for the preparation of 4,5,6-trichloropicolinic acid |
CN105018962B (zh) * | 2015-07-07 | 2018-01-12 | 浙江工业大学 | 一种氯代有机污染物电化学氢化脱氯的方法 |
KR102040020B1 (ko) * | 2018-08-29 | 2019-11-04 | 주식회사 영동테크 | 은과 구리의 고용체를 포함하는 금속 나노 분말 |
RU2715760C1 (ru) * | 2019-05-31 | 2020-03-03 | Общество с ограниченной ответственностью Управляющая компания "Алтайский завод прецизионных изделий" | Способ лазерной сварки прецизионных деталей осесимметричной формы |
CN110195240B (zh) * | 2019-06-03 | 2020-03-13 | 东莞理工学院 | 一种超声辅助四溴双酚a高效电化学氢化脱溴方法 |
CN113912533B (zh) * | 2021-11-23 | 2023-06-20 | 西安凯立新材料股份有限公司 | 一种制备3,6-二氯吡啶甲酸的方法 |
CN115928113B (zh) * | 2023-01-06 | 2025-03-04 | 山东京博农化科技股份有限公司 | 一种4-三氟甲基烟酸的制备方法 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US275524A (en) * | 1883-04-10 | Remedy for ague | ||
NL65441C (ko) * | 1939-10-16 | |||
US2755241A (en) * | 1952-07-28 | 1956-07-17 | Union Carbide & Carbon Corp | Electrowinning of manganese |
IT1066389B (it) * | 1976-01-30 | 1985-03-04 | Ford Motor Co | Cella o batteria elettrica secondaria con elettrodo a polisolfuro bagnabile |
US4242183A (en) * | 1979-04-13 | 1980-12-30 | The Dow Chemical Company | Highly active silver cathode, preparation of same and use to make 2,3,5-trichloropyridine |
US4217185A (en) * | 1979-07-02 | 1980-08-12 | The Dow Chemical Company | Electrolytic production of certain trichloropicolinic acids and/or 3,6-dichloropicolinic acid |
DE2946089A1 (de) * | 1979-11-15 | 1981-06-11 | Sachs Systemtechnik Gmbh, 8720 Schweinfurt | Vorrichtung zum reinigen von fluessigkeiten mittels anodischer oxydation |
JPS5857501B2 (ja) * | 1980-09-29 | 1983-12-20 | 三菱製鋼株式会社 | 電気メツキ用通電ロ−ル |
US4533454A (en) * | 1981-09-28 | 1985-08-06 | The Dow Chemical Company | Electrolytic cell comprising stainless steel anode, basic aqueous electrolyte and a cathode at which tetrachloro-2-picolinate ions can be selectively reduced in high yield to 3,6-dichloropicolinate ions |
US4460441A (en) * | 1982-08-31 | 1984-07-17 | The Dow Chemical Company | Expanded metal as more efficient form of silver cathode for electrolytic reduction of polychloropicolinate anions |
US4497697A (en) * | 1984-03-02 | 1985-02-05 | The Dow Chemical Company | Electrolytic preparation of 3,6-dichloropicolinic acid |
JPS6199651A (ja) * | 1984-10-22 | 1986-05-17 | Kubota Ltd | 通電ロ−ル用合金 |
-
1986
- 1986-07-31 US US06/891,814 patent/US4778576A/en not_active Expired - Lifetime
-
1987
- 1987-07-15 CA CA000542140A patent/CA1312039C/en not_active Expired - Fee Related
- 1987-07-16 DE DE8787110318T patent/DE3774201D1/de not_active Expired - Lifetime
- 1987-07-16 AT AT87110318T patent/ATE69068T1/de not_active IP Right Cessation
- 1987-07-16 ES ES198787110318T patent/ES2025600T3/es not_active Expired - Lifetime
- 1987-07-16 EP EP87110318A patent/EP0254982B1/en not_active Expired - Lifetime
- 1987-07-23 AU AU76045/87A patent/AU594485B2/en not_active Ceased
- 1987-07-23 JP JP62184647A patent/JP2592848B2/ja not_active Expired - Fee Related
- 1987-07-24 NZ NZ221194A patent/NZ221194A/xx unknown
- 1987-07-28 IL IL83358A patent/IL83358A/xx not_active IP Right Cessation
- 1987-07-30 HU HU873519A patent/HU201014B/hu not_active IP Right Cessation
- 1987-07-30 BR BR8703924A patent/BR8703924A/pt not_active IP Right Cessation
- 1987-07-31 FI FI873344A patent/FI82489C/fi not_active IP Right Cessation
- 1987-07-31 DK DK402187A patent/DK168639B1/da not_active IP Right Cessation
- 1987-07-31 KR KR1019870008388A patent/KR940010105B1/ko not_active Expired - Fee Related
-
1988
- 1988-01-05 US US07/141,021 patent/US4789449A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DK402187D0 (da) | 1987-07-31 |
ES2025600T3 (es) | 1992-04-01 |
EP0254982A2 (en) | 1988-02-03 |
BR8703924A (pt) | 1988-04-05 |
US4789449A (en) | 1988-12-06 |
ATE69068T1 (de) | 1991-11-15 |
EP0254982A3 (en) | 1988-08-31 |
IL83358A (en) | 1990-11-05 |
HU201014B (en) | 1990-09-28 |
AU7604587A (en) | 1988-02-04 |
DE3774201D1 (de) | 1991-12-05 |
JP2592848B2 (ja) | 1997-03-19 |
FI873344A0 (fi) | 1987-07-31 |
CA1312039C (en) | 1992-12-29 |
US4778576A (en) | 1988-10-18 |
JPS6342388A (ja) | 1988-02-23 |
DK402187A (da) | 1988-02-01 |
AU594485B2 (en) | 1990-03-08 |
DK168639B1 (da) | 1994-05-09 |
EP0254982B1 (en) | 1991-10-30 |
FI82489C (fi) | 1991-03-11 |
IL83358A0 (en) | 1987-12-31 |
FI873344L (fi) | 1988-02-01 |
FI82489B (fi) | 1990-11-30 |
HUT44236A (en) | 1988-02-29 |
KR940010105B1 (ko) | 1994-10-21 |
NZ221194A (en) | 1989-01-27 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PA0109 | Patent application |
Patent event code: PA01091R01D Comment text: Patent Application Patent event date: 19870731 |
|
PG1501 | Laying open of application | ||
A201 | Request for examination | ||
PA0201 | Request for examination |
Patent event code: PA02012R01D Patent event date: 19920729 Comment text: Request for Examination of Application Patent event code: PA02011R01I Patent event date: 19870731 Comment text: Patent Application |
|
G160 | Decision to publish patent application | ||
PG1605 | Publication of application before grant of patent |
Comment text: Decision on Publication of Application Patent event code: PG16051S01I Patent event date: 19940927 |
|
E701 | Decision to grant or registration of patent right | ||
PE0701 | Decision of registration |
Patent event code: PE07011S01D Comment text: Decision to Grant Registration Patent event date: 19950106 |
|
GRNT | Written decision to grant | ||
PR0701 | Registration of establishment |
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