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KR850007105A - 전해전극 및 그 제조공정 - Google Patents

전해전극 및 그 제조공정 Download PDF

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Publication number
KR850007105A
KR850007105A KR1019850001328A KR850001328A KR850007105A KR 850007105 A KR850007105 A KR 850007105A KR 1019850001328 A KR1019850001328 A KR 1019850001328A KR 850001328 A KR850001328 A KR 850001328A KR 850007105 A KR850007105 A KR 850007105A
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South Korea
Prior art keywords
electrode
metal
intermediate layer
group
weight
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KR1019850001328A
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English (en)
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KR890003861B1 (ko
Inventor
히로시(외 3) 아사노
Original Assignee
나까가와 세이지
페르멜렉 덴꼬꾸 가부시끼 가이샤
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Publication of KR850007105A publication Critical patent/KR850007105A/ko
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Publication of KR890003861B1 publication Critical patent/KR890003861B1/ko

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/091Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
    • C25B11/093Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds at least one noble metal or noble metal oxide and at least one non-noble metal oxide
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • C25C7/02Electrodes; Connections thereof
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25BELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/055Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material
    • C25B11/057Electrodes formed of electrocatalysts on a substrate or carrier characterised by the substrate or carrier material consisting of a single element or compound
    • C25B11/061Metal or alloy
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/64Carriers or collectors
    • H01M4/66Selection of materials
    • H01M4/661Metal or alloys, e.g. alloy coatings
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)

Abstract

내용 없음

Description

전해전극 및 그 제조공정
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (9)

  1. 전해전극에 있어서, (a) 전기적 도전금속의 전극기판과; (b) 전극활성물질이 전극코팅과; (c) 전극기판(a)과 전극코팅(b) 사이에 제공된 중간층을 구비하여, 상기 중간층은 (i) 티타늄과 주석을 구성하는 그룹으로부터 선택된 최소 하나 이상의 산화물을 구비하며, 상기 각각은 원자가 4를 가지며, 금속중량으로 중량의 약 60 내지 95% 정도이고, (ii) 알루미늄, 갈륨, 철, 코발트, 니켈 및 탈륨을 구성하는 그룹으로부터 선택된 최소한 하나 이상의 산화물을 구비하며, 각각은 원자가 2 내지 3을 가지며, 금속중량으로 중량이 약 5 내지 40%인 것을 특징으로 하는 전해전극.
  2. 제1항의 전극에 있어서, 상기 기판물질(a)은 티타늄, 탄탈륨, 니오비움 또는 지르코늄 또는 상기의 합금인 것을 특징으로 하는 전해전극.
  3. 제1항의 전극에 있어서, 상기 중간층(c)은 (i) TiO2또는 SnO2와, (ii) Al2O3, Ga2O3, FeO, Fe2O3, CoO, Co2O3, NiO와 Tl2O3의 그룹중에서 선택된 최소한 하나 이상의 성분의 전기적 혼합산화물인 것을 특징으로 하는 전해전극.
  4. 제1항의 전극에 있어서, 상기 전극 활성물질은 플라티늄 그룹 금속 또는 상기 금속의 산화물인 것을 특징으로 하는 전해전극.
  5. 전해전극 제조공정에 있어서, (1) 코팅된 전극기판을 제공하기 위해 (i) Ti 또는 Sn의 염과 (ii) Al, Ga, Fe, Co, Ni 및 Tl로 구성된 그륨에서 선택된 최소 하나의 금속염을 포함하는 용액으로 전기적 도전 금속의 전극기판을 코팅하는 단계와; (2) 상기 (1)단계의 상기 용액으로 코팅된 전극기판을 산화조건에서 가열하여, 상기 기판상에 혼합산화물의 중간층을 형성하는 단계를 구비하며; 상기 혼합산화물은, (i) 금속중량으로 60 내지 약 95% 중량에 해당하는 양으로 Ti와 Sn의 그룹에서 선택된 하나이상의 산화물과,(ii) 금속중량으로 약 5 내지 40% 중량에 해당하는 양으로 Al, Ga, Fe, Co, Ni 및 Tl의 그룹에서 선택된 하나 이상의 산화물로 구비되어 있고, (3) 상기 전극활성물질의 층으로 상기 중간층을 연속적으로 코팅하는 단계를 구비하는 것을 특징으로 하는 전해전극 제조공정.
  6. 제5항의 공정에 있어서, 상기 전극활성물질을 사용한 중간층의 코팅은 열분해에 의해 수행되는 것을 특징으로 하는 전해전극 제조공정.
  7. 제5항의 공정에 있어서, 상기 중간층은 약 350°내지 600°C의 산화조건에서 코팅된 전극기판을 가열하여 형성된 것을 특징으로 하는 전해전극 제조공정.
  8. 제5항의 공정에 있어서, 상기 전극물질은 티타늄, 탄탈륨, 니오비움, 또는 지르코늄 또는 상기 금속의 합금중 하나인 것을 특징으로 하는 전해전극 제조공정.
  9. 제5항의 공정에 있어서, 상기 전극활성 물질은 플라티늄 그룹 금속 또는 상기 금속의 산화물을 포함하는 것을 특징으로 하는 전해전극 제조공정.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019850001328A 1984-03-02 1985-03-02 전해 전극 및 그 제조 공정 KR890003861B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP38733 1984-03-02
JP59038733A JPS60184690A (ja) 1984-03-02 1984-03-02 耐久性を有する電極及びその製造方法

Publications (2)

Publication Number Publication Date
KR850007105A true KR850007105A (ko) 1985-10-30
KR890003861B1 KR890003861B1 (ko) 1989-10-05

Family

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KR1019850001328A KR890003861B1 (ko) 1984-03-02 1985-03-02 전해 전극 및 그 제조 공정

Country Status (12)

Country Link
US (1) US4584084A (ko)
JP (1) JPS60184690A (ko)
KR (1) KR890003861B1 (ko)
AU (1) AU566717B2 (ko)
DE (1) DE3507071C2 (ko)
FR (1) FR2560610B1 (ko)
GB (1) GB2155953B (ko)
IT (1) IT1181757B (ko)
MY (1) MY101998A (ko)
NL (1) NL187694C (ko)
SE (1) SE456915B (ko)
SG (1) SG25788G (ko)

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KR20020005480A (ko) * 2000-07-07 2002-01-17 조셉 제이. 스위니 애노드 코팅 장치 및 방법

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JPS62284095A (ja) * 1986-06-02 1987-12-09 Permelec Electrode Ltd 耐久性を有する電解用電極及びその製造方法
US5156726A (en) * 1987-03-24 1992-10-20 Tdk Corporation Oxygen-generating electrode and method for the preparation thereof
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KR100196094B1 (ko) * 1992-03-11 1999-06-15 사토 히로시 산소발생전극
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FR2788377B1 (fr) * 1999-01-11 2001-04-13 Europ Accumulateurs Element bipolaire a couche de protection et accumulateur au plomb comportant un tel element
JP3407130B2 (ja) * 1999-12-01 2003-05-19 エヌイーシートーキン株式会社 電極、二次電池及びその製造方法
US6572758B2 (en) 2001-02-06 2003-06-03 United States Filter Corporation Electrode coating and method of use and preparation thereof
US6660307B2 (en) 2001-04-16 2003-12-09 United States Filter Corporation Process for generating stabilized bromine compounds
WO2005072946A1 (en) * 2004-01-23 2005-08-11 Arkema Inc. Transparent conductive oxide films having enhanced electron concentration/mobility and method of making same
FR2870639B1 (fr) * 2004-05-19 2006-11-10 Electricite De France Support type collecteur de courant et son utilisation en tant qu'electrode de batterie
ITMI20061974A1 (it) * 2006-10-16 2008-04-17 Industrie De Nora Spa Anodo per elettrolisi
US8221599B2 (en) * 2009-04-03 2012-07-17 The Board Of Trustees Of The Leland Stanford Junior University Corrosion-resistant anodes, devices including the anodes, and methods of using the anodes
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Publication number Priority date Publication date Assignee Title
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Also Published As

Publication number Publication date
DE3507071A1 (de) 1985-10-03
MY101998A (en) 1992-02-29
SG25788G (en) 1988-07-15
SE456915B (sv) 1988-11-14
FR2560610A1 (fr) 1985-09-06
AU3940985A (en) 1985-09-05
KR890003861B1 (ko) 1989-10-05
GB2155953B (en) 1987-10-21
IT8547746A1 (it) 1986-08-28
GB2155953A (en) 1985-10-02
SE8501025D0 (sv) 1985-03-01
FR2560610B1 (fr) 1987-07-10
IT8547746A0 (it) 1985-02-28
JPS60184690A (ja) 1985-09-20
NL8500558A (nl) 1985-10-01
IT1181757B (it) 1987-09-30
US4584084A (en) 1986-04-22
DE3507071C2 (de) 1987-04-02
SE8501025L (sv) 1985-10-14
AU566717B2 (en) 1987-10-29
JPS6320312B2 (ko) 1988-04-27
GB8504993D0 (en) 1985-03-27
NL187694C (nl) 1991-12-16

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