[go: up one dir, main page]

KR870006093A - α-올레핀 중합용 고체촉매성분 및 그 제조방법 - Google Patents

α-올레핀 중합용 고체촉매성분 및 그 제조방법 Download PDF

Info

Publication number
KR870006093A
KR870006093A KR860010404A KR860010404A KR870006093A KR 870006093 A KR870006093 A KR 870006093A KR 860010404 A KR860010404 A KR 860010404A KR 860010404 A KR860010404 A KR 860010404A KR 870006093 A KR870006093 A KR 870006093A
Authority
KR
South Korea
Prior art keywords
reaction
olefin polymerization
catalyst component
solid catalyst
manufacturing
Prior art date
Application number
KR860010404A
Other languages
English (en)
Other versions
KR910004484B1 (ko
Inventor
히로시 시미즈
아끼히로 사이또오
도시히로 우와이
마사미 다찌바나
Original Assignee
노기 사다오
짓소 가부시끼가이샤
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 노기 사다오, 짓소 가부시끼가이샤 filed Critical 노기 사다오
Publication of KR870006093A publication Critical patent/KR870006093A/ko
Application granted granted Critical
Publication of KR910004484B1 publication Critical patent/KR910004484B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/908—Containing catalyst of specified particle size
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/909—Polymerization characterized by particle size of product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

내용 없음

Description

α－올레핀 중합용 고체 촉매성분 및 그 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음
본 발명에 따른 α－올레핀 중합용 촉매를 사용하여 프로필렌을 중합시켜 수득된 중합체 입자의 절단면의 확대도(현미경 사진을 스켓치한 것)
1 : 절단면
2 : 속이 빈 부분
3 : 외면

Claims (4)

  1. 4염화티탄에 대해, 교반소요동력 250kw/m3이하의 교반하에서 유기알루미늄 화합물(A )과 전자공여체(B1)의 반응 생성물(Ⅰ)을, 0 내지 70℃에서 1 내지 10시간 첨가하여 반응시켜 수득된 고체 생성물(Ⅱ)에, 다시 전자공여체(B2) 및 전자수용체(E)를 반응시켜 고체 생성물(Ⅲ)으로 하는 것을 특징으로 하는 α－올레핀 중합용 고체 촉매성분의 제조방법.
  2. 제1항에 있어서, 불활성 용매로 희석된 4염화티탄을 사용하는 제조방법.
  3. 제1항에 있어서, 반응 생성물(Ⅰ)의 첨가가 끝난 후의 반응혼합물을 첨가시의 온도 및 교반조건하에서 0.5 내지 3시간 유지한 후, 다시 50 내지 90℃에서 5분 내지 3시간 교반하는 제조방법.
  4. 제1항에 있어서, 유기알루미늄 화합물(A) 1몰에 대해, 1 내지 4몰의 전자공여체를 0.5 내지 3ℓ의 불활성 용매의 존재하에 －10 내지 50℃에서 30초 내지 5시간 반응시켜 수득한 반응생성물(Ⅰ)을 사용하는 제조방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019860010404A 1985-12-05 1986-12-05 α-올레핀 중합용 고체 촉매성분 및 그 제조방법 KR910004484B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP60273649A JPS62209104A (ja) 1985-12-05 1985-12-05 α−オレフイン重合用固体触媒成分及びその製造方法
JP273649 1985-12-05

Publications (2)

Publication Number Publication Date
KR870006093A true KR870006093A (ko) 1987-07-09
KR910004484B1 KR910004484B1 (ko) 1991-06-29

Family

ID=17530627

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019860010404A KR910004484B1 (ko) 1985-12-05 1986-12-05 α-올레핀 중합용 고체 촉매성분 및 그 제조방법

Country Status (12)

Country Link
US (1) US4724225A (ko)
EP (1) EP0229413B1 (ko)
JP (1) JPS62209104A (ko)
KR (1) KR910004484B1 (ko)
CN (1) CN1010782B (ko)
AU (1) AU594990B2 (ko)
BR (1) BR8606106A (ko)
CA (1) CA1283396C (ko)
CS (1) CS269990B2 (ko)
DE (1) DE3678134D1 (ko)
HU (1) HU204861B (ko)
MX (1) MX168632B (ko)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2591602B1 (fr) * 1985-12-18 1988-02-26 Atochem Procede de traitement de catalyseurs spheriques de polymerisation des olefines. application du catalyseur obtenu a la polymerisation des olefines.
US5231119A (en) * 1990-04-27 1993-07-27 Himont Incorporated Crystalline olefin polymers and copolymers in the form of spherical particles at high porosity
JP3016880B2 (ja) * 1991-02-01 2000-03-06 三菱化学株式会社 フィルム成形用高結晶性ポリプロピレン
ATE291059T1 (de) 1992-11-13 2005-04-15 Cryovac Inc Wärmeschrumpfbare, durch single-site-katalyse hergestellte copolymere enthaltende folien.
JP3471099B2 (ja) * 1994-11-25 2003-11-25 昭和電工株式会社 オレフィン重合用触媒担体の製造方法
US6533988B2 (en) 1995-05-02 2003-03-18 Borealis Technology Oy Rotational moulding process of ethylene polymers or copolymers having a controlled particle size and morphology
CZ34998A3 (cs) * 1997-02-17 1999-08-11 Pcd Polymere Gesellschaft M. B. H. Způsob přípravy pevného nosiče pro katalyzátory polymerace olefinů
JP2004509201A (ja) 2000-09-15 2004-03-25 バセルテック　ユーエスエイ　インコーポレイテッド オレフィンポリマーに対する添加物の押出成形されていない分散体および濃縮物
CN113845613B (zh) * 2021-09-29 2023-01-06 天津华聚化工科技有限公司 一种高纯度超高分子量聚乙烯树脂及其生产工艺
CN115260490B (zh) * 2022-08-18 2023-07-25 井冈山大学 一种电子给体-受体二维共轭有机框架材料及其制备方法和应用

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS591723B2 (ja) * 1980-01-17 1984-01-13 チッソ株式会社 α−オレフイン重合体を製造する方法
JPS5928573B2 (ja) * 1980-02-05 1984-07-13 チッソ株式会社 α−オレフイン重合体の製造方法
JPS6023764B2 (ja) * 1980-02-27 1985-06-10 チッソ株式会社 α−オレフイン重合体を製造する方法
CA1185400A (en) * 1981-07-23 1985-04-09 Akihiro Sato PROCESS FOR PRODUCING .alpha.-OLEFIN POLYMERS
JPS5817104A (ja) * 1981-07-23 1983-02-01 Chisso Corp α−オレフイン重合体の製造方法
JPS5823806A (ja) * 1981-08-04 1983-02-12 Chisso Corp α−オレフイン重合体を製造する方法
JPH0672166B2 (ja) * 1984-07-06 1994-09-14 チッソ株式会社 α―オレフィン重合用固体触媒成分およびその製造法

Also Published As

Publication number Publication date
HU204861B (en) 1992-02-28
CN1010782B (zh) 1990-12-12
BR8606106A (pt) 1987-09-15
AU594990B2 (en) 1990-03-22
EP0229413A1 (en) 1987-07-22
KR910004484B1 (ko) 1991-06-29
HUT44585A (en) 1988-03-28
CA1283396C (en) 1991-04-23
CS269990B2 (en) 1990-05-14
CN86108794A (zh) 1987-07-29
EP0229413B1 (en) 1991-03-13
JPS62209104A (ja) 1987-09-14
US4724225A (en) 1988-02-09
DE3678134D1 (de) 1991-04-18
AU6575686A (en) 1987-06-11
MX168632B (es) 1993-06-02
CS895586A2 (en) 1989-09-12

Similar Documents

Publication Publication Date Title
KR870006093A (ko) α-올레핀 중합용 고체촉매성분 및 그 제조방법
ES544034A0 (es) Procedimiento para la preparacion de estabilizantes a base de silicio para polimeros organicos particularmente homopolimeros o copolimeros de etileno, propileno o butadieno.
DE69414667D1 (de) Verfahren zur herstellung von olefinpolymeren und mittels dieses verfahrens gefertigte produkte
ATE384747T1 (de) Verfahren zur herstellung von verzweigten ethylen-propylen copolymeren
KR880000500A (ko) 교차결합고무 제품의 제조방법
AU559240B2 (en) Polymerisation catalyst
EP0274536A4 (en) Polyolefin composition for injection molding.
KR850005868A (ko) 트리펜디옥사진 비닐 설폰의 제조방법
FR2364961A1 (fr) Procede de preparation de bitumes-polymeres
AU612871B2 (en) A process for the preparation of surfactants having improved physical properties
KR880013988A (ko) 올레핀 중합촉매 성분의 제조
ES2059358T3 (es) Procedimiento de polimerizacion anionica.
Wang et al. In situ epoxidation of ethylene propylene diene rubber by performic acid
EP0270930A3 (en) Substantially pure enzyme-antibody conjugate preparations
KR850003142A (ko) 난백화, 고 용융점 탄성 에틸렌 프로필렌 공중합체의 제조 방법
AU6857487A (en) Process for the preparation of hydroxylamines and products thereby obtained
KR880001615A (ko) 5,6-치환-2,4-퀴나졸인디아민 및 신규의 중간 생성물을 제조하는 향상된 방법
Fujio et al. Effects of sulfur on the peroxide cure of EPDM and divinylbenzene compounds
KR840006197A (ko) N-포르밀-l-아스파르트산 무수물의 제조방법
KR860001131A (ko) α-올레핀 중합용 고체촉매성분의 제조방법
ES484220A1 (es) Un procedimiento para la fabricacion de un articulo confor- mado de polimero reticulado.
EP0333878A4 (en) PROCESS FOR PRODUCING A STYRENIC POLYMER.
KR860001005B1 (ko) 수지 에멀죤 방수제의 제법
KR870009991A (ko) N-(술포닐메틸) 포름아미드의 제조방법
UST989005I4 (en) Nickel organic compositions to improve dyeability of polymers

Legal Events

Date Code Title Description
PA0109 Patent application

Patent event code: PA01091R01D

Comment text: Patent Application

Patent event date: 19861205

PG1501 Laying open of application
A201 Request for examination
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 19880107

Comment text: Request for Examination of Application

Patent event code: PA02011R01I

Patent event date: 19861205

Comment text: Patent Application

G160 Decision to publish patent application
PG1605 Publication of application before grant of patent

Comment text: Decision on Publication of Application

Patent event code: PG16051S01I

Patent event date: 19910603

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

Patent event code: PE07011S01D

Comment text: Decision to Grant Registration

Patent event date: 19910924

GRNT Written decision to grant
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 19911202

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 19911202

End annual number: 3

Start annual number: 1

PR1001 Payment of annual fee

Payment date: 19940427

Start annual number: 4

End annual number: 4

PR1001 Payment of annual fee

Payment date: 19950517

Start annual number: 5

End annual number: 5

FPAY Annual fee payment

Payment date: 19960605

Year of fee payment: 6

PR1001 Payment of annual fee

Payment date: 19960605

Start annual number: 6

End annual number: 6

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee