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FR2870251B1 - Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention - Google Patents

Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention

Info

Publication number
FR2870251B1
FR2870251B1 FR0405120A FR0405120A FR2870251B1 FR 2870251 B1 FR2870251 B1 FR 2870251B1 FR 0405120 A FR0405120 A FR 0405120A FR 0405120 A FR0405120 A FR 0405120A FR 2870251 B1 FR2870251 B1 FR 2870251B1
Authority
FR
France
Prior art keywords
obtaining
carbon nanotubes
methods
composite materials
materials based
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0405120A
Other languages
English (en)
Other versions
FR2870251A1 (fr
Inventor
Olivier Guerret
Piecourt Christelle Guerret
Laurent Billon
Vitaliy Datsyuk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Arkema SA
Original Assignee
Centre National de la Recherche Scientifique CNRS
Arkema SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0405120A priority Critical patent/FR2870251B1/fr
Application filed by Centre National de la Recherche Scientifique CNRS, Arkema SA filed Critical Centre National de la Recherche Scientifique CNRS
Priority to EP05748178A priority patent/EP1751232B1/fr
Priority to KR1020067023546A priority patent/KR20070034469A/ko
Priority to CNA2005800151250A priority patent/CN1984954A/zh
Priority to EP10180899A priority patent/EP2275487B1/fr
Priority to JP2007512095A priority patent/JP2007537313A/ja
Priority to CA002566702A priority patent/CA2566702A1/fr
Priority to EP10180902A priority patent/EP2277947A3/fr
Priority to PCT/EP2005/005135 priority patent/WO2005108485A2/fr
Priority to ES05748178T priority patent/ES2374556T3/es
Priority to AT05748178T priority patent/ATE529477T1/de
Priority to US11/579,839 priority patent/US20070232748A1/en
Priority to AT10180899T priority patent/ATE531763T1/de
Priority to TW094115235A priority patent/TW200609284A/zh
Publication of FR2870251A1 publication Critical patent/FR2870251A1/fr
Application granted granted Critical
Publication of FR2870251B1 publication Critical patent/FR2870251B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/26—Thermosensitive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Paints Or Removers (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

La présente invention décrit un matériau composite à base de matrice polymère dans laquelle sont dispersés des nanotubes de carbone ainsi qu'un procédé d'obtention d'un tel matériau.Le procédé de l'invention est basé sur l'utilisation comme compatibilisant d'un copolymère à blocs obtenu par la polymérisation radicalaire contrôlée et présentant au moins un bloc portant des fonctions acides et/ou anhydrides.Un tel compatibilisant permet le contrôle et l'optimisation des interactions inter faciales et l'obtention ainsi d'un matériau composite stable et présentant des bonnes propriétés d'usage.
FR0405120A 2004-05-11 2004-05-11 Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention Expired - Fee Related FR2870251B1 (fr)

Priority Applications (14)

Application Number Priority Date Filing Date Title
FR0405120A FR2870251B1 (fr) 2004-05-11 2004-05-11 Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention
AT05748178T ATE529477T1 (de) 2004-05-11 2005-05-10 Verbundwerkstoffe auf basis von kohlenstoffnanoröhren und polymermatrizes und herstellungsverfahren dafür
CNA2005800151250A CN1984954A (zh) 2004-05-11 2005-05-10 基于碳纳米管和聚合物基质的复合材料以及获得该材料的方法
EP10180899A EP2275487B1 (fr) 2004-05-11 2005-05-10 Matériaux composites basés sur des nanotubes de carbone et des matrices polymériques, et procédés de production de ces matériaux
JP2007512095A JP2007537313A (ja) 2004-05-11 2005-05-10 カーボンナノチューブとポリマーマトリックスとをベースにした複合材料と、その製造方法
CA002566702A CA2566702A1 (fr) 2004-05-11 2005-05-10 Materiaux composites bases sur des nanotubes de carbone et des matrices polymeriques, et procedes de production de ces materiaux
EP10180902A EP2277947A3 (fr) 2004-05-11 2005-05-10 Matériaux composites basés sur des nanotubes de carbone et des matrices polymériques, et procédés de production de ces matériaux
PCT/EP2005/005135 WO2005108485A2 (fr) 2004-05-11 2005-05-10 Materiaux composites bases sur des nanotubes de carbone et des matrices polymeriques, et procedes de production de ces materiaux
EP05748178A EP1751232B1 (fr) 2004-05-11 2005-05-10 Materiaux composites bases sur des nanotubes de carbone et des matrices polymeriques, et procedes de production de ces materiaux
KR1020067023546A KR20070034469A (ko) 2004-05-11 2005-05-10 탄소 나노튜브 및 중합체 매트릭스 기재 복합 재료 및 그의수득 방법
US11/579,839 US20070232748A1 (en) 2004-05-11 2005-05-10 Composite Materials Based on Carbon Nanotubes and Polymer Matrices and Processes for Obtaining Same
AT10180899T ATE531763T1 (de) 2004-05-11 2005-05-10 Verbundmaterialien auf der basis von kohlenstoffnanoröhren und polymermatrizen und deren herstellungsverfahren
ES05748178T ES2374556T3 (es) 2004-05-11 2005-05-10 Materiales compuestos basados en nanotubos de carbono y matrices poliméricas y procesos para obtener los mismos.
TW094115235A TW200609284A (en) 2004-05-11 2005-05-11 Composite materials based on carbon nanotubes and polymer matrices and processes for obtaining same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0405120A FR2870251B1 (fr) 2004-05-11 2004-05-11 Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention

Publications (2)

Publication Number Publication Date
FR2870251A1 FR2870251A1 (fr) 2005-11-18
FR2870251B1 true FR2870251B1 (fr) 2010-09-17

Family

ID=34946446

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0405120A Expired - Fee Related FR2870251B1 (fr) 2004-05-11 2004-05-11 Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention

Country Status (11)

Country Link
US (1) US20070232748A1 (fr)
EP (3) EP2275487B1 (fr)
JP (1) JP2007537313A (fr)
KR (1) KR20070034469A (fr)
CN (1) CN1984954A (fr)
AT (2) ATE529477T1 (fr)
CA (1) CA2566702A1 (fr)
ES (1) ES2374556T3 (fr)
FR (1) FR2870251B1 (fr)
TW (1) TW200609284A (fr)
WO (1) WO2005108485A2 (fr)

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Also Published As

Publication number Publication date
KR20070034469A (ko) 2007-03-28
EP2277947A2 (fr) 2011-01-26
ATE529477T1 (de) 2011-11-15
EP2277947A3 (fr) 2011-03-09
WO2005108485A3 (fr) 2006-03-16
EP1751232A2 (fr) 2007-02-14
TW200609284A (en) 2006-03-16
EP2275487B1 (fr) 2011-11-02
US20070232748A1 (en) 2007-10-04
ATE531763T1 (de) 2011-11-15
FR2870251A1 (fr) 2005-11-18
EP2275487A3 (fr) 2011-03-09
EP1751232B1 (fr) 2011-10-19
WO2005108485A2 (fr) 2005-11-17
JP2007537313A (ja) 2007-12-20
CA2566702A1 (fr) 2005-11-17
ES2374556T3 (es) 2012-02-17
EP2275487A2 (fr) 2011-01-19
CN1984954A (zh) 2007-06-20

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