ES2533072T3 - Procedimiento para la preparación de compuestos complejos de manganeso puenteados del triazaciclononano - Google Patents
Procedimiento para la preparación de compuestos complejos de manganeso puenteados del triazaciclononano Download PDFInfo
- Publication number
- ES2533072T3 ES2533072T3 ES10760913.3T ES10760913T ES2533072T3 ES 2533072 T3 ES2533072 T3 ES 2533072T3 ES 10760913 T ES10760913 T ES 10760913T ES 2533072 T3 ES2533072 T3 ES 2533072T3
- Authority
- ES
- Spain
- Prior art keywords
- manganese
- ion
- divalent
- metal
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000011572 manganese Substances 0.000 title abstract description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title abstract 4
- 150000001875 compounds Chemical class 0.000 title abstract 4
- 229910052748 manganese Inorganic materials 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- 150000003839 salts Chemical class 0.000 abstract description 7
- 239000003446 ligand Substances 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract 6
- 239000002184 metal Substances 0.000 abstract 6
- 230000003647 oxidation Effects 0.000 abstract 4
- 238000007254 oxidation reaction Methods 0.000 abstract 4
- 150000002500 ions Chemical class 0.000 abstract 3
- 150000002739 metals Chemical class 0.000 abstract 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 2
- -1 hexafluorophosphate Chemical compound 0.000 abstract 2
- 150000004679 hydroxides Chemical class 0.000 abstract 2
- 229910000000 metal hydroxide Inorganic materials 0.000 abstract 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract 2
- 150000004706 metal oxides Chemical class 0.000 abstract 2
- 239000011541 reaction mixture Substances 0.000 abstract 2
- 238000000926 separation method Methods 0.000 abstract 2
- 239000000126 substance Substances 0.000 abstract 2
- WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- 229910001413 alkali metal ion Inorganic materials 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 229910052742 iron Chemical group 0.000 abstract 1
- 159000000014 iron salts Chemical class 0.000 abstract 1
- 150000002696 manganese Chemical class 0.000 abstract 1
- 150000002697 manganese compounds Chemical class 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 abstract 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 229910021135 KPF6 Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F13/00—Compounds containing elements of Groups 7 or 17 of the Periodic Table
- C07F13/005—Compounds without a metal-carbon linkage
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
- B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
- B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
- B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
- B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0213—Complexes without C-metal linkages
- B01J2531/0216—Bi- or polynuclear complexes, i.e. comprising two or more metal coordination centres, without metal-metal bonds, e.g. Cp(Lx)Zr-imidazole-Zr(Lx)Cp
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
Abstract
Procedimiento para la preparación de unos compuestos complejos de manganeso de la fórmula general (1) en la que M está seleccionado entre manganeso y hierro en el escalón de oxidación III o IV, siendo por lo menos uno de los M un manganeso en el escalón de oxidación III o IV, los X independientemente unos de otros, son una especie química coordinante o puenteadora, que está seleccionada entre H2O, O2 2-, O2 -, O2-, OH-, HO2 -, SH-, S2-, SO, Cl-, N3-, SCN-, N3 -, RCOO-, NH2 - y NR3, siendo R un radical que está seleccionado entre H, alquilo y arilo, L es el 1,4,7-trimetil-1,4,7-triazaciclononano, z es un número entero de -4 a + 4, Y es un ion de signo contrario mono- o multivalente, tomado del conjunto formado por los de hexafluorofosfato, perclorato o tetrafenilborato, que conduce a la neutralidad de cargas eléctricas del compuesto complejo, y q es un número entero de 1 hasta 4; caracterizado por las siguientes etapas del procedimiento: a) una conversión química de una o varias sales de metales divalentes, estando seleccionada la una o las varias sales de metales divalentes entre unas sales de manganeso y hierro divalentes, y por lo menos una sal de un metal divalente es una sal de manganeso divalente, con el ligando L en el seno de agua como disolvente para la formación de un compuesto de coordinación a partir de la una o las varias sales de metales divalentes y del ligando L, b) una oxidación del compuesto de coordinación procedente de la etapa a) con un agente oxidante, siendo mantenido al mismo tiempo un valor del pH de 11 a 14, para la transformación del metal M desde el escalón de valencia dos al escalón de valencia tres y/o cuatro, c) una disminución del valor del pH de la mezcla de reacción hasta un valor del pH de 4 a 9, de manera preferida de 5 a 8, y separación de los óxidos o hidróxidos metálicos del metal M que eventualmente se han formado y d) una adición de una sal de la fórmula MezYq, en la que Me representa un ion de un metal alcalino, un ion de amonio o un ion de alcanolamonio, e Y, z y q tienen los significados indicados, en el caso de un valor del pH de 4 a 9 y de manera preferida de 5 a 8, y siendo incorporada en la mezcla de reacción y convertida químicamente la sal de un ion de signo contrario MezYq, tan sólo después de la etapa de oxidación y de la separación de los óxidos e hidróxidos metálicos que se han formado.
Description
E10760913
17-03-2015
manganeso, a un pH de 7,5 se añade una solución caliente de 4,6 g de KPF6 en agua. Después de un tratamiento se aíslan 12,7 g de unos cristales de color verduzco del [Mn(IV)Mn(lll) (µ-O)3 (4,7-Me4-DTNE)] 2 PF6 *H2O. En el producto no se puede detectar ninguna sal de ligando ni nada de dióxido de manganeso (límite de medición < 0,1 % en peso).
8
Claims (1)
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imagen1 imagen2
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP09290713 | 2009-09-18 | ||
| EP09290713 | 2009-09-18 | ||
| PCT/EP2010/005569 WO2011032666A1 (de) | 2009-09-18 | 2010-09-10 | Verfahren zur herstellung von verbrückten mangan-komplexen des triazacyclononans |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2533072T3 true ES2533072T3 (es) | 2015-04-07 |
Family
ID=41682826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES10760913.3T Active ES2533072T3 (es) | 2009-09-18 | 2010-09-10 | Procedimiento para la preparación de compuestos complejos de manganeso puenteados del triazaciclononano |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9012630B2 (es) |
| EP (1) | EP2477740B1 (es) |
| JP (1) | JP5688413B2 (es) |
| CN (1) | CN102510774B (es) |
| ES (1) | ES2533072T3 (es) |
| PL (1) | PL2477740T3 (es) |
| WO (1) | WO2011032666A1 (es) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2103604A1 (de) | 2008-03-17 | 2009-09-23 | Evonik Degussa GmbH | Verfahren zur Herstellung von Epichlorhydrin |
| EP2550283B1 (en) | 2010-03-03 | 2016-05-11 | Catexel Limited | Preparation of bleaching catalysts |
| US10144005B2 (en) | 2011-09-08 | 2018-12-04 | Richard William Kemp | Catalysts |
| US9624119B2 (en) | 2014-06-13 | 2017-04-18 | Ecolab Usa Inc. | Enhanced catalyst stability in activated peroxygen and/or alkaline detergent formulations |
| CN107652436B (zh) * | 2016-07-23 | 2020-12-11 | 金华职业技术学院 | 一种不同价双核锰(ii、iii)一维双带状配位聚合物及其制备方法 |
| US20220396595A1 (en) * | 2019-10-17 | 2022-12-15 | Rhodia Operations | A metal complex and use thereof |
| CN110963558A (zh) * | 2019-11-29 | 2020-04-07 | 常熟市化创化学技术有限公司 | 类芬顿试剂及其在有机废水处理中的应用 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE69125310T2 (de) | 1990-05-21 | 1997-07-03 | Unilever Nv | Bleichmittelaktivierung |
| US5274147A (en) | 1991-07-11 | 1993-12-28 | Lever Brothers Company, Division Of Conopco, Inc. | Process for preparing manganese complexes |
| GB9118242D0 (en) | 1991-08-23 | 1991-10-09 | Unilever Plc | Machine dishwashing composition |
| US5153161A (en) * | 1991-11-26 | 1992-10-06 | Lever Brothers Company, Division Of Conopco, Inc. | Synthesis of manganese oxidation catalyst |
| US5256779A (en) | 1992-06-18 | 1993-10-26 | Lever Brothers Company, Division Of Conopco, Inc. | Synthesis of manganese oxidation catalyst |
| US5329024A (en) | 1993-03-30 | 1994-07-12 | National Starch And Chemical Investment Holding Corporation | Epoxidation of olefins via certain manganese complexes |
| US5385893A (en) * | 1993-05-06 | 1995-01-31 | The Dow Chemical Company | Tricyclopolyazamacrocyclophosphonic acids, complexes and derivatives thereof, for use as contrast agents |
| AU2524495A (en) * | 1994-05-09 | 1995-11-29 | Unilever Plc | Bleach catalyst composition |
| WO1996006154A1 (en) | 1994-08-19 | 1996-02-29 | Unilever N.V. | Detergent bleach composition |
| CA2197998A1 (en) | 1994-08-19 | 1996-02-29 | Paulus Pieter De Wit | Liquid-crystalline polyethers |
| DE19620241A1 (de) | 1996-05-20 | 1997-11-27 | Patt R Prof Dr | Verfahren zum Delignifizieren von Zellstoffen und Verwendung eines Katalysators |
| KR20010108326A (ko) * | 1999-03-08 | 2001-12-07 | 에프. 아. 프라저, 에른스트 알테르 (에. 알테르), 한스 페터 비틀린 (하. 페. 비틀린), 피. 랍 보프, 브이. 스펜글러, 페. 아에글러 | 살렌 리간드의 망간 착화합물 및 이의 용도 |
| GB9930422D0 (en) | 1999-12-22 | 2000-02-16 | Unilever Plc | Bleach catalysts |
| DE10051317A1 (de) | 2000-10-17 | 2002-04-18 | Degussa | Übergangsmetallkomplexe mit Polydentaten Liganden zur Verstärkung der Bleich- und Delignifizierungswirkung von Persauerstoffverbindungen |
| JP2004523617A (ja) * | 2001-01-26 | 2004-08-05 | チバ スペシャルティ ケミカルズ ホールディング インコーポレーテッド | サルジミン型マンガン錯体の水溶性顆粒又は粒子の調製方法 |
| WO2002088063A1 (en) | 2001-04-27 | 2002-11-07 | Lonza Ag | Process for the production of ketones |
| MXPA05000483A (es) * | 2002-07-11 | 2005-03-23 | Ciba Sc Holding Ag | Uso de compuestos complejos de metal como catalizadores de oxidacion. |
| CN101331260B (zh) | 2005-10-12 | 2012-05-30 | 荷兰联合利华有限公司 | 底物的漂白 |
| CA2670743C (en) | 2007-01-16 | 2015-12-15 | Unilever Plc | Bleaching of substrates |
-
2010
- 2010-09-10 CN CN201080041259.0A patent/CN102510774B/zh active Active
- 2010-09-10 WO PCT/EP2010/005569 patent/WO2011032666A1/de active Application Filing
- 2010-09-10 ES ES10760913.3T patent/ES2533072T3/es active Active
- 2010-09-10 EP EP10760913.3A patent/EP2477740B1/de active Active
- 2010-09-10 PL PL10760913T patent/PL2477740T3/pl unknown
- 2010-09-10 US US13/394,968 patent/US9012630B2/en active Active
- 2010-09-10 JP JP2012529144A patent/JP5688413B2/ja active Active
Also Published As
| Publication number | Publication date |
|---|---|
| WO2011032666A1 (de) | 2011-03-24 |
| EP2477740A1 (de) | 2012-07-25 |
| US9012630B2 (en) | 2015-04-21 |
| PL2477740T3 (pl) | 2015-06-30 |
| JP5688413B2 (ja) | 2015-03-25 |
| CN102510774A (zh) | 2012-06-20 |
| US20120202990A1 (en) | 2012-08-09 |
| CN102510774B (zh) | 2014-07-23 |
| JP2013505206A (ja) | 2013-02-14 |
| EP2477740B1 (de) | 2015-01-21 |
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