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ES2149756T3 - Revestimientos de polvo a base de pvdf. - Google Patents

Revestimientos de polvo a base de pvdf.

Info

Publication number
ES2149756T3
ES2149756T3 ES91120960T ES91120960T ES2149756T3 ES 2149756 T3 ES2149756 T3 ES 2149756T3 ES 91120960 T ES91120960 T ES 91120960T ES 91120960 T ES91120960 T ES 91120960T ES 2149756 T3 ES2149756 T3 ES 2149756T3
Authority
ES
Spain
Prior art keywords
based powder
powder coatings
pvdf
pvdf based
substrate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES91120960T
Other languages
English (en)
Inventor
Willem Sietses
Tjalling Meinoud Plantenga
Jean-Paul Dekerk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TotalEnergies Onetech Belgium SA
Original Assignee
Fina Research SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=10603524&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2149756(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Fina Research SA filed Critical Fina Research SA
Application granted granted Critical
Publication of ES2149756T3 publication Critical patent/ES2149756T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B13/00—Conditioning or physical treatment of the material to be shaped
    • B29B13/10—Conditioning or physical treatment of the material to be shaped by grinding, e.g. by triturating; by sieving; by filtering
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/08—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface
    • B05D5/083—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain an anti-friction or anti-adhesive surface involving the use of fluoropolymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B9/00—Making granules
    • B29B9/02—Making granules by dividing preformed material
    • B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16—Homopolymers or copolymers or vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16—Homopolymers or copolymers of vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10—Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12—Homopolymers or copolymers of methyl methacrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2401/00—Form of the coating product, e.g. solution, water dispersion, powders or the like
    • B05D2401/30—Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant
    • B05D2401/32—Form of the coating product, e.g. solution, water dispersion, powders or the like the coating being applied in other forms than involving eliminable solvent, diluent or dispersant applied as powders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2506/00—Halogenated polymers
    • B05D2506/10—Fluorinated polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10—Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12—Homopolymers or copolymers of methyl methacrylate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
    • Y10T428/2991—Coated
    • Y10T428/2998—Coated including synthetic resin or polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31511—Of epoxy ether
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Paints Or Removers (AREA)
  • Laminated Bodies (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Dental Preparations (AREA)
  • Manufacturing Of Micro-Capsules (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

SE HA DESCUBIERTO UN REVESTIMIENTO EN POLVO DE BASE PVDF PIGMENTADO, QUE INCLUYE UNA RESINA PVDF CON UNA RESINA TERMOPLASTICA COMPATIBLE, PREFERENTEMENTE PMMA, EN UNA ESCALA DE PESO DE 80:20 A 40:60, PIGMENTOS, Y OPCIONALMENTE UNA PEQUEÑA CANTIDAD DE ESTIMULADOR DEL FLUJO. TAMBIEN HA SIDO DESCUBIERTO UN PROCESO PARA REVESTIR UN SUSTRATO, CONDENSANDO LAS FASES DE (A) APLICACION DE DICHO REVESTIMIENTO EN POLVO EN UN SUSTRATO Y (B) SOMETIENDO A UN TRATAMIENTO DE CALENTAMIENTO.
ES91120960T 1986-09-01 1987-08-26 Revestimientos de polvo a base de pvdf. Expired - Lifetime ES2149756T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB8621109A GB2194539B (en) 1986-09-01 1986-09-01 Pvdf-based powder coatings

Publications (1)

Publication Number Publication Date
ES2149756T3 true ES2149756T3 (es) 2000-11-16

Family

ID=10603524

Family Applications (2)

Application Number Title Priority Date Filing Date
ES91120960T Expired - Lifetime ES2149756T3 (es) 1986-09-01 1987-08-26 Revestimientos de polvo a base de pvdf.
ES198787870118T Expired - Lifetime ES2032868T3 (es) 1986-09-01 1987-08-26 Recubrimientos en polvo a base de fluoruro de polivinilideno.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES198787870118T Expired - Lifetime ES2032868T3 (es) 1986-09-01 1987-08-26 Recubrimientos en polvo a base de fluoruro de polivinilideno.

Country Status (7)

Country Link
US (1) US4770939A (es)
EP (2) EP0259290B1 (es)
AT (1) ATE195093T1 (es)
DE (2) DE3779841T2 (es)
ES (2) ES2149756T3 (es)
GB (1) GB2194539B (es)
GR (1) GR3004956T3 (es)

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US5030394A (en) * 1988-11-08 1991-07-09 Labofina, S.A. PVdF-based powder coatings
US5177150A (en) * 1990-05-10 1993-01-05 Elf Atochem North America, Inc. Powder coatings of vinylidene fluoride/hexafluoropylene copolymers
US5932657A (en) * 1990-06-21 1999-08-03 Fina Research, S. A. Powder primer of thermosetting binder and PVdF-compatible thermoplastic
GB9125894D0 (en) * 1991-12-05 1992-02-05 Evode Ind Coatings Ltd Fluoropolymer-containing powders
NZ245901A (en) * 1992-06-02 1994-07-26 Atochem North America Elf Pigmented blend for powder coatings containing a vdf/tfe/hfp terpolymer
TW290579B (es) * 1993-12-23 1996-11-11 Fina Research
US6037412A (en) * 1994-07-21 2000-03-14 Fina Research, S.A. Preparing powder primer of thermoset binder and PVdF-compatible thermoplastic
JP3941128B2 (ja) * 1995-12-18 2007-07-04 ダイキン工業株式会社 粉体塗料用組成物
US5827608A (en) * 1996-10-28 1998-10-27 Minnesota Mining And Manufacturing Company Method of forming a thermoplastic layer on a flexible two-dimensional substrate and powder for preparing same
CA2264590A1 (en) * 1997-07-17 1999-01-28 Xavier F. Drujon Fluoropolymer powder coatings from modified thermoplastic vinylidene fluoride based resins
US6063855A (en) * 1998-01-02 2000-05-16 Pecsok; Roger L. Process for the manufacture of vinylidene fluoride powder coatings
DE69918607T2 (de) 1998-03-05 2005-07-21 Solvay Solexis, Inc., Wilmington Witterungsbeständige Beschichtungszusammensetzungen aus Polyvinylidenfluorid,die Polymethylmethacrylat enthalten
CA2321978A1 (en) 1998-03-11 1999-09-16 Ernest M. Rinehart Method of forming a thermoplastic layer on a layer of adhesive
DE69921718T2 (de) 1998-04-01 2005-12-22 Solvay Solexis, Inc., Wilmington Verträgliche Mischungen aus Polyvinylidenfluorid und aromatischem Polyimid
DE69930520T2 (de) 1998-07-27 2006-11-09 E.I. Dupont De Nemours And Co., Wilmington Mischmetallneutralisierte Copolymerharze und Verwendung zu Metall-Pulverbeschichtungen
US6340720B1 (en) 2000-02-14 2002-01-22 Ausimont Usa, Inc. Process for making polyvinylidene fluoride power coatings and coating formulations
US7247313B2 (en) 2001-06-27 2007-07-24 Advanced Cardiovascular Systems, Inc. Polyacrylates coatings for implantable medical devices
US6596790B2 (en) 2001-09-25 2003-07-22 Solvay Solexis, Inc. Precipitation process for making polyvinylidene fluoride powder coatings and coatings made by the process
EP1348490B1 (en) * 2002-03-21 2006-07-12 Bagetti Process for the preparation and application of a protective coating composition, as well as objects coated with such composition
US7217426B1 (en) 2002-06-21 2007-05-15 Advanced Cardiovascular Systems, Inc. Coatings containing polycationic peptides for cardiovascular therapy
US7396539B1 (en) 2002-06-21 2008-07-08 Advanced Cardiovascular Systems, Inc. Stent coatings with engineered drug release rate
US7005137B1 (en) 2002-06-21 2006-02-28 Advanceed Cardiovascular Systems, Inc. Coating for implantable medical devices
US7491233B1 (en) 2002-07-19 2009-02-17 Advanced Cardiovascular Systems Inc. Purified polymers for coatings of implantable medical devices
US8791171B2 (en) 2003-05-01 2014-07-29 Abbott Cardiovascular Systems Inc. Biodegradable coatings for implantable medical devices
US7563454B1 (en) 2003-05-01 2009-07-21 Advanced Cardiovascular Systems, Inc. Coatings for implantable medical devices
CA2527936A1 (en) * 2003-06-06 2004-12-16 Akzo Nobel Coatings International B.V. Non-stick powder coating
US7244443B2 (en) 2004-08-31 2007-07-17 Advanced Cardiovascular Systems, Inc. Polymers of fluorinated monomers and hydrophilic monomers
DE102004056788B4 (de) * 2004-11-24 2009-01-29 Eisenmann Anlagenbau Gmbh & Co. Kg Verfahren und Anlage zum Beschichten von Gegenständen
US7625973B2 (en) * 2005-02-24 2009-12-01 Ppg Industries Ohio, Inc. Methods for preparing fluoropolymer powder coatings
CA2607442A1 (en) 2005-05-06 2006-11-16 Akzo Nobel Coatings International B.V. Powder coating base coat
US20070054052A1 (en) * 2005-06-01 2007-03-08 Gregory Alaimo Fluoropolymer coating compositions for threaded fasteners
US7498511B1 (en) 2005-11-22 2009-03-03 Securus, Inc. Pipe hanger
US7621487B2 (en) 2005-12-21 2009-11-24 Securus, Inc. Twist-lock base for pipe holders
US7838582B2 (en) * 2006-02-03 2010-11-23 Ppg Industries Ohio, Inc. Hyperdispersant for use in fluorocarbon coating compositions
US7956144B2 (en) * 2006-02-03 2011-06-07 Ppg Industries Ohio, Inc. Acrylic resin for use in fluorocarbon coating compositions and method of forming the same
US20090012235A1 (en) * 2006-02-03 2009-01-08 Basf Corporation Dispersant for use in a fluorocarbon coating composition
KR101170034B1 (ko) * 2006-06-27 2012-07-31 파나소닉 주식회사 메타크릴 수지 조성물 및 그의 성형품
US9028859B2 (en) 2006-07-07 2015-05-12 Advanced Cardiovascular Systems, Inc. Phase-separated block copolymer coatings for implantable medical devices
ATE522574T1 (de) * 2006-10-13 2011-09-15 3M Innovative Properties Co Pulverbeschichtung von fluorpolymerzusammensetzungen mit aromatischen monohydroxy-materalien
WO2010043665A1 (en) * 2008-10-16 2010-04-22 Solvay Solexis S.P.A. Opaque fluoropolymer composition comprising white pigments for photovoltaic elements of solar cells
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US8722791B2 (en) * 2009-11-30 2014-05-13 Denki Kagaku Kogyo Kabushiki Kaisha Polyvinylidene fluoride resin composition, film, back sheet, and solar cell module
US8760040B2 (en) * 2011-04-01 2014-06-24 Korea Institute Of Science And Technology Polymer blend composition and tunable actuators using the same
CN103874716B (zh) 2011-08-17 2017-04-05 索尔维特殊聚合物意大利有限公司 研磨方法
US9385374B2 (en) 2014-04-01 2016-07-05 Ppg Industries Ohio, Inc. Electrode binder composition for lithium ion electrical storage devices
US20150280239A1 (en) 2014-04-01 2015-10-01 Ppg Industries Ohio, Inc. Aqueous binder composition for lithium ion electrical storage devices
WO2016002724A1 (ja) * 2014-07-01 2016-01-07 旭硝子株式会社 粉体塗料用組成物、粉体塗料および塗装物品
CN105368184A (zh) * 2015-11-25 2016-03-02 安徽圣德建材科技有限公司 一种抗菌性聚偏氟乙烯粉末涂料
US11130871B2 (en) * 2016-06-29 2021-09-28 Awi Licensing Llc High performance coatings for building panels
FR3060594B1 (fr) * 2016-12-20 2019-03-15 Arkema France Revetement en poudre a base de polymere fluore
WO2018190371A1 (ja) * 2017-04-14 2018-10-18 ダイキン工業株式会社 樹脂組成物及び成形体
FR3076832B1 (fr) * 2018-01-15 2019-12-06 Arkema France Poudre de polymere fluore a fenetre de frittage elargie par traitement thermique et son utilisation dans le frittage laser
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CN115588820A (zh) * 2022-10-28 2023-01-10 江苏厚生新能源科技有限公司 一种高电解液浸润性的低成本锂电池隔膜及其制备方法
JP2025037538A (ja) 2023-09-06 2025-03-18 石川ガスケット株式会社 プライマー塗料組成物、及びガスケット

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Also Published As

Publication number Publication date
GB8621109D0 (en) 1986-10-08
ES2032868T3 (es) 1993-03-01
EP0483887A2 (en) 1992-05-06
ATE195093T1 (de) 2000-08-15
EP0259290B1 (en) 1992-06-17
GB2194539A (en) 1988-03-09
EP0483887A3 (en) 1993-09-08
EP0259290A3 (en) 1990-02-21
GR3004956T3 (es) 1993-04-28
DE3752320T2 (de) 2001-02-08
US4770939A (en) 1988-09-13
DE3779841D1 (de) 1992-07-23
EP0483887B1 (en) 2000-08-02
EP0259290A2 (en) 1988-03-09
GB2194539B (en) 1990-08-01
DE3779841T2 (de) 1992-12-24
DE3752320D1 (de) 2000-09-07

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