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ES2097833T3 - Sistemas catalizadores solubles para la obtencion de polialqu-1-enos con elevados pesos moleculares. - Google Patents

Sistemas catalizadores solubles para la obtencion de polialqu-1-enos con elevados pesos moleculares.

Info

Publication number
ES2097833T3
ES2097833T3 ES92108888T ES92108888T ES2097833T3 ES 2097833 T3 ES2097833 T3 ES 2097833T3 ES 92108888 T ES92108888 T ES 92108888T ES 92108888 T ES92108888 T ES 92108888T ES 2097833 T3 ES2097833 T3 ES 2097833T3
Authority
ES
Spain
Prior art keywords
polialqu
enso
obtaining
high molecular
molecular weights
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92108888T
Other languages
English (en)
Inventor
Eberhard Karl
Werner Dr Roell
Hans Prof Dr Brintzinger
Bernhard Dr Rieger
Udo Stehling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=6434172&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=ES2097833(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by BASF SE filed Critical BASF SE
Application granted granted Critical
Publication of ES2097833T3 publication Critical patent/ES2097833T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/63912Component covered by group C08F4/62 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/639Component covered by group C08F4/62 containing a transition metal-carbon bond
    • C08F4/6392Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/63922Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/63927Component covered by group C08F4/62 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)

Abstract

SISTEMA DE CATALIZADORES PARA LA POLIMERIZACION DE C2 ASTA C10 A) UN COMPLEJO METALOCENICO DE LA FORMULA GENERAL I EN LA QUE LOS SUSTITUYENTES TIENEN EL SIGUIENTE SIGNIFICADO: M TITANIO, CIRCONIO, HAFNIO, VANADIO, NIOBIO, TANTALO X HALOGENO O C1 ASTA C8 NIO, Z C1 C6 HASTA C10 R1 Y R2 SON IGUALES O DISTINTOS, R3 HASTA R6, HIDROGENO, C1 HASTA C8 OS, O EN DONDE DOS RESTOS VECINOS, R3 Y R4 ASI COMO R5 Y R6 EQUIVALEN RESPECTIVAMENTE A SISTEMAS DE ANILLOS DEL HIDROCARBUROS QUE PRESENTAN 4 HASTA 15 ATOMOS DE C, Y N 0, 1 O 2, B) ASI COMO UN COMPUESTO DE ALUMOXANO DE CADENA ABIERTA O CICLICO DE LA FORMULA GENERAL II O III EN DONDE R7 EQUIVALE A UN GRUPO C1 C4 AS DE CATALIZADORES DE LA INVENCION SON APROPIADOS ESPECIALMENTE PARA LA PRODUCCION DE POLIALQU MOLARES.
ES92108888T 1991-06-18 1992-05-27 Sistemas catalizadores solubles para la obtencion de polialqu-1-enos con elevados pesos moleculares. Expired - Lifetime ES2097833T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE4120009A DE4120009A1 (de) 1991-06-18 1991-06-18 Loesliche katalysatorsysteme zur herstellung von polyalk-1-enen mit hohen molmassen

Publications (1)

Publication Number Publication Date
ES2097833T3 true ES2097833T3 (es) 1997-04-16

Family

ID=6434172

Family Applications (2)

Application Number Title Priority Date Filing Date
ES92108888T Expired - Lifetime ES2097833T3 (es) 1991-06-18 1992-05-27 Sistemas catalizadores solubles para la obtencion de polialqu-1-enos con elevados pesos moleculares.
ES95115772T Expired - Lifetime ES2116027T3 (es) 1991-06-18 1992-05-27 Polialqu-1-enos con pesos moleculares elevados.

Family Applications After (1)

Application Number Title Priority Date Filing Date
ES95115772T Expired - Lifetime ES2116027T3 (es) 1991-06-18 1992-05-27 Polialqu-1-enos con pesos moleculares elevados.

Country Status (5)

Country Link
US (3) US5296434A (es)
EP (2) EP0692499B1 (es)
JP (2) JP2675236B2 (es)
DE (3) DE4120009A1 (es)
ES (2) ES2097833T3 (es)

Families Citing this family (196)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0485821B1 (de) 1990-11-12 1996-06-12 Hoechst Aktiengesellschaft Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
USRE39532E1 (en) 1990-11-12 2007-03-27 Basell Polyolefine Gmbh Metallocenes containing ligands of 2-substituted indenyl derivatives, process for their preparation, and their use as catalysts
US5830821A (en) * 1991-11-30 1998-11-03 Targor Gmbh Process for olefin preparation using metallocenes having benzo-fused indenyl derivatives as ligands
TW318184B (es) * 1991-11-30 1997-10-21 Hoechst Ag
TW309523B (es) * 1991-11-30 1997-07-01 Hoechst Ag
ZA929213B (en) * 1991-11-30 1993-05-24 Hoechst Ag Metallocenes having benzo-fusen indenyl derivatives as ligands, processes for their preparation and their use as catalysts.
US5932669A (en) * 1991-11-30 1999-08-03 Targor Gmbh Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
US6143854A (en) * 1993-08-06 2000-11-07 Exxon Chemical Patents, Inc. Polymerization catalysts, their production and use
TW294669B (es) * 1992-06-27 1997-01-01 Hoechst Ag
JPH072936A (ja) * 1992-07-10 1995-01-06 Fina Technol Inc アイソタクチツクポリオレフイン製造のための方法及び触媒
DE59308494D1 (de) * 1992-08-03 1998-06-10 Targor Gmbh Verfahren zur Herstellung eines Olefinpolymers unter Verwendung von Metallocenen mit speziell substituierten Indenylliganden
USRE39156E1 (en) 1992-08-15 2006-07-04 Basell Polyolefine Gmbh Process for the preparation of polyolefins
US5372980A (en) * 1993-06-03 1994-12-13 Polysar Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers
US5459117A (en) * 1993-08-27 1995-10-17 Ewen; John A. Doubly-conformationally locked, stereorigid catalysts for the preparation of tactiospecific polymers
US5631202A (en) 1993-09-24 1997-05-20 Montell Technology Company B.V. Stereospecific metallocene catalysts with stereolocking α-CP substituents
DE4333128A1 (de) * 1993-09-29 1995-03-30 Hoechst Ag Verfahren zur Herstellung von Polyolefinen
DE4344688A1 (de) * 1993-12-27 1995-06-29 Hoechst Ag Metallocenverbindung
DE4406963A1 (de) * 1994-03-03 1995-09-07 Basf Ag Metallocenkomplexe mit heterofunktionellen Gruppen am Cyclopentadienylsystem
IT1269931B (it) * 1994-03-29 1997-04-16 Spherilene Srl Componenti e catalizzatori per la polimerizzazione di olefine
IT1273420B (it) * 1994-04-06 1997-07-08 Spherilene Srl Composti metallocenici, procedimento per la preparazione e loro utilizzo in catalizzatori per la polimerizzazione delle olefine
US5468440B1 (en) * 1994-05-06 1997-04-08 Exxon Chemical Patents Inc Process of making oriented film or structure
DE4416894A1 (de) * 1994-05-13 1995-11-16 Witco Gmbh Verfahren zur Synthese von Mono- und Dimethylmetallocenen und deren Lösungen speziell für den Einsatz zur Polymerisation von Olefinen
US5571619A (en) * 1994-05-24 1996-11-05 Exxon Chemical Patents, Inc. Fibers and oriented films of polypropylene higher α-olefin copolymers
EP0760744A1 (en) * 1994-05-24 1997-03-12 Exxon Chemical Patents Inc. Fibers and fabrics incorporating lower melting propylene polymers
DE4436113A1 (de) * 1994-10-10 1996-04-11 Hoechst Ag Metallocenverbindung
US5625015A (en) 1994-11-23 1997-04-29 Exxon Chemical Patents Inc. Method for making supported catalyst systems and catalyst systems therefrom
WO1996023751A1 (de) * 1995-02-01 1996-08-08 Basf Aktiengesellschaft Verfahren zur herstellung von olefin-oligomeren
US6399533B2 (en) * 1995-05-25 2002-06-04 Basell Technology Company Bv Compounds and catalysts for the polymerization of olefins
DE19519884A1 (de) * 1995-05-31 1996-12-05 Basf Ag Verfahren zur Herstellung von verbrückten Metallocenkomplexen
DE19525178A1 (de) * 1995-07-11 1997-01-16 Basf Ag Verfahren zur Umwandlung der achiralen meso-Form eines ansa-Metallkomplexes in die chirale rac.-Form
US6403772B1 (en) * 1995-09-11 2002-06-11 Montell Technology Company, Bv Open-pentadienyl metallocenes, precursors thereof and polymerization catalysts therefrom
US6787618B1 (en) 1995-12-01 2004-09-07 Basell Polypropylen Gmbh Metallocene compound and high molecular weight copolymers of propylene and olefins having two or four to thirty-two carbon atoms
US5679814A (en) * 1995-12-11 1997-10-21 Albemarle Corporation Purification of metallocenes
FI104826B (fi) * 1996-01-30 2000-04-14 Borealis As Heteroatomilla substituoituja metalloseeniyhdisteitä olefiinipolymerointikatalyytti-systeemejä varten ja menetelmä niiden valmistamiseksi
US6225426B1 (en) * 1996-04-10 2001-05-01 Uniroyal Chemical Company, Inc. Process for producing polyolefin elastomer employing a metallocene catalyst
EP0834519B1 (en) * 1996-04-22 2002-03-06 Japan Polyolefins Co., Ltd. Catalyst for polyolefin production and process for producing polyolefin
DE19615953A1 (de) * 1996-04-22 1997-10-23 Basf Ag Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums
WO1997048735A1 (en) 1996-06-17 1997-12-24 Exxon Chemical Patents Inc. Mixed transition metal catalyst systems for olefin polymerization
US5710299A (en) * 1996-06-27 1998-01-20 Albemarle Corporation Production of bridged metallocene complexes and intermediates therefor
US6759499B1 (en) 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
DE19635503A1 (de) 1996-09-02 1998-03-05 Basf Ag Weißbrucharme, zähmodifizierte Propylenpolymerisate
US5760262A (en) * 1996-09-17 1998-06-02 Albemarle Corporation Enhanced production of bridged hafnocenes
US5936108A (en) * 1996-10-17 1999-08-10 Albemarle Corporation Metallocene synthesis
US5780660A (en) * 1996-11-07 1998-07-14 Albemarle Corporation Zirconocene ismerization process
US6329541B1 (en) * 1997-01-08 2001-12-11 Phillips Petroleum Company Organo omega-alkenyl cyclopentacarbyl silane-bridged metallocene compounds
KR100564499B1 (ko) 1997-02-07 2006-03-29 엑손모빌 케미칼 패턴츠 인코포레이티드 분지된 올레핀 공중합체로부터 제조된 열가소성 엘라스토머 조성물
KR100503523B1 (ko) 1997-02-07 2005-07-25 엑손모빌 케미칼 패턴츠 인코포레이티드 비닐-함유 거대단량체의 제조방법
US6160072A (en) * 1997-05-02 2000-12-12 Ewen; John A. Process for polymerizing tactioselective polyolefins in condensed phase using titanocenes
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US7232871B2 (en) * 1997-08-12 2007-06-19 Exxonmobil Chemical Patents Inc. Propylene ethylene polymers and production process
US7026404B2 (en) * 1997-08-12 2006-04-11 Exxonmobil Chemical Patents Inc. Articles made from blends made from propylene ethylene polymers
US6921794B2 (en) * 1997-08-12 2005-07-26 Exxonmobil Chemical Patents Inc. Blends made from propylene ethylene polymers
US6635715B1 (en) * 1997-08-12 2003-10-21 Sudhin Datta Thermoplastic polymer blends of isotactic polypropylene and alpha-olefin/propylene copolymers
US5905162A (en) * 1997-08-12 1999-05-18 Albemarle Corporation Enhanced production of bridged hafnocenes
DE69810781T2 (de) 1997-08-15 2003-09-25 Chisso Corp., Osaka Polydisperses propylenpolymer und verfahren zu dessen herstellung
US6197910B1 (en) 1997-12-10 2001-03-06 Exxon Chemical Patents, Inc. Propylene polymers incorporating macromers
US6184327B1 (en) 1997-12-10 2001-02-06 Exxon Chemical Patents, Inc. Elastomeric propylene polymers
US6117962A (en) * 1997-12-10 2000-09-12 Exxon Chemical Patents Inc. Vinyl-containing stereospecific polypropylene macromers
DE19757540A1 (de) * 1997-12-23 1999-06-24 Hoechst Ag Geträgertes Katalysatorsystem zur Polymerisation von Olefinen
DE69918100T2 (de) 1998-05-13 2005-07-07 Exxonmobil Chemical Patents Inc., Baytown Propylenhomopolymere und herstellungsverfahren
US6784269B2 (en) 1998-05-13 2004-08-31 Exxonmobil Chemical Patents Inc. Polypropylene compositions methods of making the same
US6306960B1 (en) 1998-05-13 2001-10-23 Exxonmobil Chemical Patents Inc. Articles formed from foamable polypropylene polymer
JP2002519497A (ja) * 1998-07-01 2002-07-02 エクソンモービル・ケミカル・パテンツ・インク 結晶性プロピレンポリマーと結晶化可能プロピレンポリマーとを含んでなる弾性ブレンド
CA2341167A1 (en) 1998-08-26 2000-03-09 Exxon Chemical Patents Inc. Branched polypropylene compositions
US5965759A (en) * 1998-09-23 1999-10-12 Albemarle Corporation Catalytic process for isomerizing metallocenes
US6667424B1 (en) * 1998-10-02 2003-12-23 Kimberly-Clark Worldwide, Inc. Absorbent articles with nits and free-flowing particles
US6562192B1 (en) 1998-10-02 2003-05-13 Kimberly-Clark Worldwide, Inc. Absorbent articles with absorbent free-flowing particles and methods for producing the same
US6503233B1 (en) 1998-10-02 2003-01-07 Kimberly-Clark Worldwide, Inc. Absorbent article having good body fit under dynamic conditions
US6673982B1 (en) * 1998-10-02 2004-01-06 Kimberly-Clark Worldwide, Inc. Absorbent article with center fill performance
US6225427B1 (en) 1998-10-15 2001-05-01 Uniroyal Chemical Company, Inc. Olefin polymerization process employing metallocene catalyst provided by cocatalyst activation of a metallocene procatalyst
DE19857292A1 (de) 1998-12-11 2000-06-15 Targor Gmbh Talkumverstärkte Polypropylen-Formmasse mit hoher Schlagzähigkeit
US6376011B1 (en) 1999-04-16 2002-04-23 Kimberly-Clark Worldwide, Inc. Process for preparing superabsorbent-containing composites
US6387495B1 (en) 1999-04-16 2002-05-14 Kimberly-Clark Worldwide, Inc. Superabsorbent-containing composites
US6409883B1 (en) * 1999-04-16 2002-06-25 Kimberly-Clark Worldwide, Inc. Methods of making fiber bundles and fibrous structures
US6174930B1 (en) 1999-04-16 2001-01-16 Exxon Chemical Patents, Inc. Foamable polypropylene polymer
US6339134B1 (en) 1999-05-06 2002-01-15 Univation Technologies, Llc Polymerization process for producing easier processing polymers
US6750284B1 (en) 1999-05-13 2004-06-15 Exxonmobil Chemical Patents Inc. Thermoplastic filled membranes of propylene copolymers
WO2000070134A1 (en) 1999-05-13 2000-11-23 Exxon Chemical Patents Inc. Elastic fibers and articles made therefrom, including crystalline and crystallizable polymers of propylene
US6500563B1 (en) 1999-05-13 2002-12-31 Exxonmobil Chemical Patents Inc. Elastic films including crystalline polymer and crystallizable polymers of propylene
EP1074557A3 (de) * 1999-07-31 2003-02-26 Basell Polyolefine GmbH Übergangsmetallverbindung, Ligandensystem, Katalysatorsystem und seine Verwendung zur Polymerisation von Olefinen
BR0014148A (pt) 1999-09-01 2002-05-07 Exxon Chemical Patents Inc Filmes respiráveis e método para sua produção
US6476164B1 (en) 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Carbenium cationic complexes suitable for polymerization catalysts
US6475946B1 (en) * 1999-10-22 2002-11-05 Exxonmobil Chemical Patents Inc. Olefin polymerization catalysis with aryl substituted carbenium cationic complexes
WO2001032758A1 (en) 1999-11-04 2001-05-10 Exxon Chemical Patents Inc. Propylene copolymer foams and their use
US6822057B2 (en) * 1999-12-09 2004-11-23 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
US6489480B2 (en) 1999-12-09 2002-12-03 Exxonmobil Chemical Patents Inc. Group-15 cationic compounds for olefin polymerization catalysts
CN1407995A (zh) * 1999-12-10 2003-04-02 埃克森化学专利公司 丙烯-二烯共聚的聚合物
US6809168B2 (en) * 1999-12-10 2004-10-26 Exxonmobil Chemical Patents Inc. Articles formed from propylene diene copolymers
US6977287B2 (en) * 1999-12-10 2005-12-20 Exxonmobil Chemical Patents Inc. Propylene diene copolymers
US6281306B1 (en) 1999-12-16 2001-08-28 Univation Technologies, Llc Method of polymerization
US6590055B2 (en) 1999-12-20 2003-07-08 Exxonmobil Chemical Patents Inc. Electrical devices from polymer resins prepared with ionic catalysts
CA2395532A1 (en) 1999-12-22 2001-06-28 A. G. Karandinos Polypropylene-based adhesive compositions
US6809209B2 (en) 2000-04-07 2004-10-26 Exxonmobil Chemical Patents Inc. Nitrogen-containing group-13 anionic compounds for olefin polymerization
US6252098B1 (en) 2000-06-05 2001-06-26 Albemarle Corporation Enhanced synthesis of racemic metallocenes
US6703458B2 (en) 2000-12-22 2004-03-09 Basell Polyolefine Gmbh Catalyst components for the polymerization of olefins
JP5156167B2 (ja) * 2001-04-12 2013-03-06 エクソンモービル・ケミカル・パテンツ・インク プロピレン−エチレンポリマー及び製造法
CA2447769C (en) * 2001-06-13 2011-07-26 Energy & Environmental International, L.C. Bulk polymerization reactors and methods for polymerization
EP1406761B1 (en) 2001-06-20 2016-11-02 ExxonMobil Chemical Patents Inc. Polyolefins made by catalyst comprising a noncoordinating anion and articles comprising them
CA2450570A1 (en) * 2001-06-22 2003-01-03 Exxonmobil Chemical Patents, Inc. Metallocene-produced very low density polyethylenes or linear lowdensity polyethylenes as impact modifiers
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
US6824650B2 (en) * 2001-12-18 2004-11-30 Kimberly-Clark Worldwide, Inc. Fibrous materials treated with a polyvinylamine polymer
US7214633B2 (en) * 2001-12-18 2007-05-08 Kimberly-Clark Worldwide, Inc. Polyvinylamine treatments to improve dyeing of cellulosic materials
WO2003083003A1 (en) * 2002-03-22 2003-10-09 Exxonmobil Chemical Patents Inc. Adhesives
US20030236365A1 (en) * 2002-06-24 2003-12-25 Fina Technology, Inc. Polyolefin production with a high performance support for a metallocene catalyst system
US7572859B2 (en) 2002-06-26 2009-08-11 Basell Polyolefine Italia S.R.L. Impact-resistant polyolefin compositions
CA2487517A1 (en) 2002-06-26 2004-01-08 Basell Poliolefine Italia S.P.A. Impact-resistant polyolefin compositions
US20040052690A1 (en) * 2002-09-12 2004-03-18 Eaton Gerald B. Polymerization reactant injection system
US7223822B2 (en) 2002-10-15 2007-05-29 Exxonmobil Chemical Patents Inc. Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom
BR0315341B1 (pt) 2002-10-15 2014-02-18 Adesivos compreendendo poliolefina.
WO2004037871A1 (en) * 2002-10-24 2004-05-06 Exxonmobil Chemical Patents Inc. Branched crystalline polypropylene
AU2003277350A1 (en) * 2002-10-24 2004-05-13 Exxonmobil Chemical Patents Inc. Branched crystalline polypropylene
US7195806B2 (en) * 2003-01-17 2007-03-27 Fina Technology, Inc. High gloss polyethylene articles
EP1611169B1 (en) * 2003-03-21 2010-06-02 Dow Global Technologies Inc. Morphology controlled olefin polymerization process
US8349929B2 (en) * 2003-08-25 2013-01-08 Dow Global Technologies Llc Coating composition and articles made therefrom
US8158711B2 (en) * 2003-08-25 2012-04-17 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
TW200517426A (en) 2003-08-25 2005-06-01 Dow Global Technologies Inc Aqueous dispersion, its production method, and its use
US7763676B2 (en) 2003-08-25 2010-07-27 Dow Global Technologies Inc. Aqueous polymer dispersions and products from those dispersions
US9169406B2 (en) 2003-08-25 2015-10-27 Dow Global Technologies Llc Coating compositions
US8722787B2 (en) 2003-08-25 2014-05-13 Dow Global Technologies Llc Coating composition and articles made therefrom
US8357749B2 (en) * 2003-08-25 2013-01-22 Dow Global Technologies Llc Coating composition and articles made therefrom
US8779053B2 (en) 2003-08-25 2014-07-15 Dow Global Technologies Llc Coating compositions
US7803865B2 (en) * 2003-08-25 2010-09-28 Dow Global Technologies Inc. Aqueous dispersion, its production method, and its use
US7947776B2 (en) 2003-08-25 2011-05-24 Dow Global Technologies Llc Aqueous dispersion, its production method, and its use
US8946329B2 (en) 2003-08-25 2015-02-03 Dow Global Technologies Llc Coating compositions
JP2005099712A (ja) * 2003-08-28 2005-04-14 Sharp Corp 表示装置の駆動回路および表示装置
WO2005044911A1 (en) 2003-11-06 2005-05-19 Basell Poliolefine Italia S.R.L. Polypropylene composition
US7985811B2 (en) * 2004-01-02 2011-07-26 Univation Technologies, Llc Method for controlling sheeting in gas phase reactors
US20070073012A1 (en) * 2005-09-28 2007-03-29 Pannell Richard B Method for seed bed treatment before a polymerization reaction
US20050148742A1 (en) * 2004-01-02 2005-07-07 Hagerty Robert O. Method for controlling sheeting in gas phase reactors
US20050234198A1 (en) * 2004-04-20 2005-10-20 Fina Technology, Inc. Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system
JP4920587B2 (ja) 2004-06-08 2012-04-18 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 剛性、衝撃強さおよび破断点伸び率の良好なバランスならびに低い熱収縮を有するポリオレフィン組成物
CA2473378A1 (en) * 2004-07-08 2006-01-08 Nova Chemicals Corporation Novel borate activator
EP1805229A1 (en) * 2004-10-28 2007-07-11 Dow Gloval Technologies Inc. Method of controlling a polymerization reactor
US7169864B2 (en) * 2004-12-01 2007-01-30 Novolen Technology Holdings, C.V. Metallocene catalysts, their synthesis and their use for the polymerization of olefins
US7232869B2 (en) * 2005-05-17 2007-06-19 Novolen Technology Holdings, C.V. Catalyst composition for olefin polymerization
WO2007002177A1 (en) 2005-06-24 2007-01-04 Exxonmobil Chemical Patents Inc. Plasticized functionalized propylene copolymer adhesive composition
CN101248133B (zh) 2005-06-24 2012-11-21 埃克森美孚化学专利公司 官能化丙烯共聚物粘合剂组合物
US7598329B2 (en) * 2005-11-04 2009-10-06 Ticona Gmbh Process for manufacturing ultra high molecular weight polymers using novel bridged metallocene catalysts
US8034886B2 (en) * 2005-11-04 2011-10-11 Ticona Gmbh Process for manufacturing high to ultra high molecular weight polymers using novel bridged metallocene catalysts
US7709577B2 (en) 2005-12-07 2010-05-04 Exxonmobil Chemical Patents Inc. Process of making polymer blends
EP1803747A1 (en) 2005-12-30 2007-07-04 Borealis Technology Oy Surface-modified polymerization catalysts for the preparation of low-gel polyolefin films
EP1847555A1 (en) * 2006-04-18 2007-10-24 Borealis Technology Oy Multi-branched Polypropylene
US8188170B2 (en) 2006-06-20 2012-05-29 Chemtura Corporation Polymers with low gel content and enhanced gas-fading
US7601255B2 (en) 2006-09-06 2009-10-13 Chemtura Corporation Process for removal of residual catalyst components
US7256240B1 (en) 2006-12-22 2007-08-14 Exxonmobil Chemical Patents Inc. Process of making polymer blends
CN101679699B (zh) 2007-04-09 2012-07-04 埃克森美孚化学专利公司 柔软的非均相全同立构聚丙烯组合物
US20090053959A1 (en) * 2007-08-21 2009-02-26 Sudhin Datta Soft and Elastic Nonwoven Polypropylene Compositions
US7928162B2 (en) 2007-09-13 2011-04-19 Exxonmobil Research And Engineering Company In-line process for producing plasticized polymers and plasticized polymer blends
TW200932762A (en) 2007-10-22 2009-08-01 Univation Tech Llc Polyethylene compositions having improved properties
US7906588B2 (en) * 2007-10-26 2011-03-15 Exxonmobil Chemical Patents Inc. Soft heterogeneous isotactic polypropylene compositions
CN101939343B (zh) 2007-12-18 2013-10-02 尤尼威蒂恩技术有限责任公司 聚合期间控制双峰催化剂活性的方法
CN101959665B (zh) 2008-02-29 2014-10-01 巴塞尔聚烯烃意大利有限责任公司 聚烯烃组合物
US8580902B2 (en) 2008-08-01 2013-11-12 Exxonmobil Chemical Patents Inc. Catalyst system, process for olefin polymerization, and polymer compositions produced therefrom
CN102731694B (zh) 2008-08-01 2015-04-01 埃克森美孚化学专利公司 催化剂体系和用于烯烃聚合的方法
EP2172490A1 (en) 2008-10-03 2010-04-07 Ineos Europe Limited Controlled polymerisation process
US8378042B2 (en) 2009-04-28 2013-02-19 Exxonmobil Chemical Patents Inc. Finishing process for amorphous polymers
US20120028865A1 (en) 2010-07-28 2012-02-02 Sudhin Datta Viscosity Modifiers Comprising Blends of Ethylene-Based Copolymers
US9127151B2 (en) 2009-04-28 2015-09-08 Exxonmobil Chemical Patents Inc. Polymer compositions having improved properties as viscosity index improvers and use thereof in lubricating oils
DE102009020090A1 (de) 2009-05-06 2010-11-11 Lanxess Deutschland Gmbh Reduktion des Einflusses der Wasseraufnahme auf die elektrische Leitfähigkeit von elektrisch leitfähigen Polyamid-Formmassen
US8067652B2 (en) 2009-08-13 2011-11-29 Chemtura Corporation Processes for controlling the viscosity of polyalphaolefins
EP2357035A1 (en) 2010-01-13 2011-08-17 Ineos Europe Limited Polymer powder storage and/or transport and/or degassing vessels
EP2526133B1 (en) * 2010-01-22 2015-04-22 ExxonMobil Chemical Patents Inc. Ethylene copolymers, methods for their production, and use
US8378048B2 (en) 2010-01-27 2013-02-19 Exxonmobil Chemical Patents Inc. Copolymers, compositions thereof, and methods for making them
EP2539123A1 (en) 2010-02-22 2013-01-02 Ineos Commercial Services UK Limited Improved polyolefin manufacturing process
EP2383298A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
EP2383301A1 (en) 2010-04-30 2011-11-02 Ineos Europe Limited Polymerization process
US20130137331A1 (en) 2010-06-15 2013-05-30 Galen C. Richeson Nonwoven Fabrics Made From Polymer Blends And Methods For Making Same
KR101442434B1 (ko) 2010-07-28 2014-09-17 엑손모빌 케미칼 패턴츠 인코포레이티드 에틸렌계 공중합체의 블렌드를 포함하는 점도 개질제
EP2598572B1 (en) 2010-07-28 2020-03-18 ExxonMobil Chemical Patents Inc. Ethylene based copolymer compositions as viscosity modifiers and methods for making them
CN103025819B (zh) 2010-07-28 2015-07-22 埃克森美孚化学专利公司 含乙烯-基共聚物的共混物的粘度改性剂
CN103328518B (zh) 2010-11-29 2016-07-06 英力士销售(英国)有限公司 聚合控制方法
US9643900B2 (en) 2011-03-25 2017-05-09 Dow Global Technologies Llc Hyperbranched ethylene-based oils and greases
US9469791B2 (en) 2011-04-28 2016-10-18 Adherent Laboratories, Inc. Polyolefin based hot melt adhesive composition
US8383740B1 (en) 2011-08-12 2013-02-26 Ineos Usa Llc Horizontal agitator
EP2573091A1 (en) 2011-09-23 2013-03-27 Lummus Novolen Technology Gmbh Process for recycling of free ligand from their corresponding metallocene complexes
RU2608615C2 (ru) 2011-10-17 2017-01-23 Инеос Юроуп Аг Регулирование процесса дегазации полимеров
US10316176B2 (en) 2012-02-03 2019-06-11 Exxonmobil Chemical Patents Inc. Polymer compositions and methods of making them
CN109135034A (zh) 2012-02-03 2019-01-04 埃克森美孚化学专利公司 可用于油料改性剂的聚合物组合物的制备方法
US9139794B2 (en) 2012-02-03 2015-09-22 Exxonmobil Chemical Patents Inc. Process for the production of polymeric compositions useful as oil modifiers
US9012578B2 (en) 2012-04-19 2015-04-21 Exxonmobil Chemical Patents Inc. Blocky ethylene propylene copolymers and methods for making them
EP2925823B1 (en) 2012-12-28 2021-01-20 Dow Global Technologies LLC A coating composition and articles made therefrom
KR102146702B1 (ko) 2012-12-28 2020-08-21 다우 글로벌 테크놀로지스 엘엘씨 코팅 조성물
US9963648B2 (en) 2013-06-28 2018-05-08 Dow Global Technologies Llc Process for the preparation of branched polyolefins for lubricant applications
KR102173912B1 (ko) 2013-06-28 2020-11-05 다우 글로벌 테크놀로지스 엘엘씨 초분지된 에틸렌계 올리고머
WO2014209711A1 (en) 2013-06-28 2014-12-31 Dow Global Technologies Llc Process for the preparation of lightly-branched hydrophobes and the corresponding surfactants and applications thereof
EP3114149B1 (en) 2014-03-06 2019-09-18 Saudi Basic Industries Corporation Catalyst comprising a metallocene complex and a co-catalyst
WO2015161241A1 (en) 2014-04-18 2015-10-22 IFS Industries Inc. Low density and high performance packaging hot melt
CN107001504B (zh) 2014-11-25 2020-07-17 尤尼威蒂恩技术有限责任公司 控制聚烯烃熔融指数的方法
CN107849080B (zh) 2015-05-27 2020-10-30 Sabic环球技术有限责任公司 包含金属茂络合物和助催化剂的催化剂
CN108473520B (zh) 2016-01-05 2021-07-23 Sabic环球技术有限责任公司 包含金属茂络合物和助催化剂的催化剂
WO2019103800A1 (en) 2017-11-21 2019-05-31 Exxonmobil Chemical Patents Inc. Bimodal copolymer compositions useful as oil modifiers
US12163104B2 (en) 2017-12-13 2024-12-10 Chevron Oronite Company Llc Bimodal copolymer compositions useful as oil modifiers and lubricating oils comprising the same
US11993699B2 (en) 2018-09-14 2024-05-28 Fina Technology, Inc. Polyethylene and controlled rheology polypropylene polymer blends and methods of use
MX2021006769A (es) 2019-02-20 2021-07-15 Fina Technology Composiciones de polimero con baja distorsion.
MX2023011768A (es) 2021-04-26 2023-10-10 Fina Technology Laminas de polimero delgadas catalizadas en un solo sitio.
EP4330294A1 (en) 2021-04-30 2024-03-06 ExxonMobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor

Family Cites Families (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) * 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
DE3443087A1 (de) * 1984-11-27 1986-05-28 Hoechst Ag, 6230 Frankfurt Verfahren zur herstellung von polyolefinen
US4874880A (en) * 1987-03-10 1989-10-17 Chisso Corporation Bis(di-, tri- or tetra-substituted-cyclopentadienyl)-zirconium dihalides
EP0284708B1 (en) * 1987-04-03 1996-01-31 Fina Technology, Inc. Metallocene catalyst systems for olefin polymerization having a silicon hydrocarbyl bridge.
US4794096A (en) * 1987-04-03 1988-12-27 Fina Technology, Inc. Hafnium metallocene catalyst for the polymerization of olefins
GB8716950D0 (en) * 1987-07-17 1987-08-26 Ici Plc Polymers & catalyst components
US4931417A (en) * 1987-11-09 1990-06-05 Chisso Corporation Transition-metal compound having a bis-substituted-cyclopentadienyl ligand of bridged structure
DE3808268A1 (de) * 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US5017714A (en) * 1988-03-21 1991-05-21 Exxon Chemical Patents Inc. Silicon-bridged transition metal compounds
US5001205A (en) * 1988-06-16 1991-03-19 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
DE3826074A1 (de) * 1988-07-30 1990-02-01 Hoechst Ag Propylen-isoblockpolymer und verfahren zu seiner herstellung
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
DE4005947A1 (de) * 1990-02-26 1991-08-29 Basf Ag Loesliche katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen
JPH03294687A (ja) * 1990-04-09 1991-12-25 Sanden Corp 容量可変型圧縮機の容量制御方法
DE59107973D1 (de) * 1990-11-12 1996-08-08 Hoechst Ag Verfahren zur Herstellung eines hochmolekularen Olefinpolymers
US5243001A (en) * 1990-11-12 1993-09-07 Hoechst Aktiengesellschaft Process for the preparation of a high molecular weight olefin polymer
EP0485823B1 (de) * 1990-11-12 1995-03-08 Hoechst Aktiengesellschaft 2-Substituierte Bisindenylmetallocene, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren bei der Olefinpolymerisation

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US5296434A (en) 1994-03-22
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JP2675236B2 (ja) 1997-11-12
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JPH05209014A (ja) 1993-08-20
EP0519237B1 (de) 1997-02-12
US6096912A (en) 2000-08-01
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