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KR970042568A - 사이클로올레핀 공중합체의 제조방법 - Google Patents

사이클로올레핀 공중합체의 제조방법 Download PDF

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Publication number
KR970042568A
KR970042568A KR1019960064752A KR19960064752A KR970042568A KR 970042568 A KR970042568 A KR 970042568A KR 1019960064752 A KR1019960064752 A KR 1019960064752A KR 19960064752 A KR19960064752 A KR 19960064752A KR 970042568 A KR970042568 A KR 970042568A
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formula
cycloolefin copolymer
different
same
hydrogen atom
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KR100480532B1 (ko
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미카엘 리델
토마스 벨러
알렉산드라 야콥스
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원본미기재
훽스트 아크티엔게젤샤프트
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
    • C08F4/6428—Component covered by group C08F4/64 with an organo-aluminium compound with an aluminoxane, i.e. a compound containing an Al-O-Al- group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 화학식 1의 메탈로센 화합물을 하나 이상 포함하는 촉매의 존재하에 하나 이상의 사이클릭 올레핀과 하나 이상의 비사이클릭 올레핀을 중합시켜 사이클로올레핀 공중합체를 제조하는 방법에 관한 것이다.
화학식 1
상기 화학식에서, L 및 L'는 π-리간드이고, T는 L과 L' 사이의 가교결합 그룹이며, M은 4가 전이 금속이고, m은 1 또는 2이며, R1, R2, R3및 R4는 각각 독립적으로 동일하거나 상이하며 각각 수소원자 또는 C1-C20- 탄화수소 라디칼이다.

Description

사이클로올레핀 공중합체의 제조방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (7)

  1. 화학식 1의 메탈로센 화합물을 하나 이상 포함하는 촉매의 존재하에 하나 이상의 사이클릭 올레핀과 하나 이상의 비사이클릭 올레핀을 중합시켜 사이클로올레핀 공중합체를 제조하는 방법.
    화학식 1
    상기 화학식 1에서, L 및 L'는 각각 π-리간드이고, T는 L과 L' 사이의 가교결합 그룹이며, M은 4가 전이 금속이고, m은 1 또는 2이며, R1, R2, R3및 R4는 각각 독립적으로 동일하거나 상이하며 각각 수소원자 또는 C1-C20- 탄화수소 라디칼이다.
  2. 제1항에 있어서, 촉매가 하나 이상의 조촉매를 추가로 포함하는 방법.
  3. 제1항 또는 제2항에 있어서, 화학식 1의 메탈로센 화합물에서 L 및 L'가 동일하거나 상이하고 각각 치환되지 않거나 치환된 사이클로펜타디에틸 그룹인 방법.
  4. 제1항 내지 제3항 중 어느 한 항에 있어서, 메탈로센 화합물이 화학식 2의 화합물인 방법
    화학식 2
    상기 화학식 2에서, Cp는 치환되지 않거나, 치환된 사이클로펜타디에닐 그룹이고, Ind는 치환되지 않거나 치환된 인데닐이며, M은 4가 전이 금속이고, R1, R2, R3및 R4는 서로 독립적으로 동일하거나 상이하며 각각 수소원자 또는 C1-C|20- 탄화수소 라디칼이고, R5및 R6는 서로 독립적으로 동일하거나 상이하며, 각각 수소원자 또는 C1-C30- 탄화수소 라디칼이고, m은 1 또는 2이며, k 및 1은, m이 1인 경우에는 1이고 m이 2인 경우에 0이다.
  5. 제1항 내지 제4항 중의 어느 한 항에 따르는 방법으로 제조할 수 있는 사이클로올레핀 공중합체.
  6. 제5항에 따르는 사이클로올레핀 공중합체를 하나 이상 포함하는 성형품.
  7. 사이클로올레핀 공중합체를 제조하기 위한, 화학식 1의 메탈로센 화합물의 용도.
    화학식 1
    상기 화학식 1에서, L 및 L'는 π-리간드이고, T는 L과 L' 사이의 가교결합 그룹이며, M은 4가 전이 금속이고, m은 1 또는 2이며, R1, R2, R3및 R4는 각각 독립적으로 동일하거나 상이하며 각각 수소원자 또는 C1-C20- 탄화수소 라디칼이다.
KR1019960064752A 1995-12-13 1996-12-12 사이클로올레핀공중합체의제조방법 Expired - Fee Related KR100480532B1 (ko)

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Application Number Priority Date Filing Date Title
DE19546500A DE19546500A1 (de) 1995-12-13 1995-12-13 Verfahren zur Herstellung eines Cycloolefincopolymeren
DE19546500.8 1995-12-13

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KR970042568A true KR970042568A (ko) 1997-07-24
KR100480532B1 KR100480532B1 (ko) 2005-07-07

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US (2) US5869586A (ko)
EP (1) EP0779306B1 (ko)
JP (1) JPH09176223A (ko)
KR (1) KR100480532B1 (ko)
CN (1) CN1089771C (ko)
CA (1) CA2192771C (ko)
DE (2) DE19546500A1 (ko)
TW (1) TW356473B (ko)

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CA2192771A1 (en) 1997-06-14
CN1089771C (zh) 2002-08-28
US6020444A (en) 2000-02-01
DE19546500A1 (de) 1997-06-19
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