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KR960000935A - 사이클로올레핀 공중합체를 제조하는 방법 - Google Patents

사이클로올레핀 공중합체를 제조하는 방법 Download PDF

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Publication number
KR960000935A
KR960000935A KR1019950017248A KR19950017248A KR960000935A KR 960000935 A KR960000935 A KR 960000935A KR 1019950017248 A KR1019950017248 A KR 1019950017248A KR 19950017248 A KR19950017248 A KR 19950017248A KR 960000935 A KR960000935 A KR 960000935A
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group
same
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cycloolefin
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KR1019950017248A
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KR100386759B1 (ko
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벨러 토마스
오잔 프랑크
퀴버 프랑크
아울바흐 미카엘
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아울미히, 루츠
훽스트 아크티엔게젤샤프트
요시다 시게노리
미쓰이세키유가가쿠고교 가부시키가이샤
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F232/00—Copolymers of cyclic compounds containing no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F32/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system
    • C08F32/02—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having no condensed rings
    • C08F32/04—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic ring system having no condensed rings having one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

본 발명은 하나 이상의 공촉매 및 하나 이상의 일반식(I)의 메탈로센을 함유하는 촉매의 존재하에 하나 이상의 사이클로올레핀 및 하나 이상의 비환식 올레핀의 중합에 의해 사이클로올레핀 공중합체를 제조하는 방법에 관한 것이다.

Description

사이클로올레핀 공중합체를 제조하는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. 하나 이상의 공촉매 및 하나 이상의 일반식(I)의 메탈로센을 함유하는 촉매의 존재하에 하나 이상의 사이클로올레핀 및 하나 이상의 비환식 올레핀의 중합에 의해 사이클로올레핀 공중합체를 제조하는 방법.
    상기 식에서,M은 원소 주기율표의 IVb족, Vb족 또는 VIb족 금속이고, R1및 R2는 동일하거나 상이하며, 각각 C1-C10-알킬그룹, C6-C10-아릴그룹,
    C1-C10알콕시 그룹, C6-C10-아릴옥시 그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹, C8-C40-아릴알케닐 그룹,할로겐 원자 또는 트리플루오로설폰산 라디칼이고, R3및 R4는 동일하거나 상이하며, 각각 전이 금속과 샌드위치 구조를 형성할수 있는 일반식 또는 다환식 탄화수소 라디칼이고, R5및 R6은 동일하거나, 상이하며, 각각 수소원자, 할로겐원자, C1-C10-알킬그룹, C1-C10-알콕시 그룹, C6-C10-아릴그룹, C6-C10-아릴옥시그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹, C8-C40-아릴알케닐 그룹,C1-C10-할로알킬 그룹, -SiR7 3-, NR7 2-, -PR7 2-, -P(O)R7 2-, Si(OR7)7R2-, Si(OR7)2R7-, Si(OR7)3-, -AsR7 2- 또는 SR7-라디칼이고, 라디칼 R7은 동일하거나 상이하며, 각각 C1-C10알킬그룹,C1-C10알콕시 그룹,C6-C10-아릴 그룹, C6-C10-아릴옥시그룹, C2-C10-알케닐 그룹, C7-C40-아릴알킬 그룹, C7-C40-알킬아릴 그룹, C8-C40-아릴알케닐 그룹, 할로겐 원자 또는 트리플루오로메틸 설폰산 그룹이다.
  2. 제1항에 있어서, 일반식(I)의 메탈로센에서 M이 티탄, 지르코늄 또는 하프늄이고, R1및 R2가 동일하고 각각 C1-C10-알킬그룹 또는 할로겐 원자이고, R3및 R2가 동일하고 각각 치환된 사이클로펜타디에닐, 인데닐 또는 치환된 인데닐이고 R5및 R6이 동일하거나 상이하며, 각각 C1-C10-알킬그룹 또는 C6-C10-아릴그룹인 방법.
  3. 제1항 또는 제2항에 있어서, 공촉매가 알루민옥산의 방법.
  4. 제1항 내지 제3항 중 어느 한 항에 있어서, 하나 이상의 다환식 올렌핀 및 하나 이상의 비환식 올레핀이 중합되는 방법.
  5. 결정성 에틸렌 연쇄를 함유하지 않고, 인장강도가 50 내지 100MPa이며, 점도수가 100 내지 250㎤/g인, 하나 이상의 사이클로올레핀, 에틸렌및, 필요에 따라, 하나 이상의 탄소수 3이상인 비환식 올레핀의 반복단위를 함유하는 사이클로올레핀 공중합체.
  6. 제5항에 따른 사이클로올레핀 공중합체를 함유하는 성형제품.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019950017248A 1994-06-24 1995-06-24 사이클로올레핀공중합체의제조방법 KR100386759B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4422157A DE4422157A1 (de) 1994-06-24 1994-06-24 Verfahren zur Herstellung von Cycloolefincopolymeren
DEP4422157.6 1994-06-24

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KR960000935A true KR960000935A (ko) 1996-01-25
KR100386759B1 KR100386759B1 (ko) 2003-08-09

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US (1) US5698645A (ko)
EP (1) EP0688801B1 (ko)
JP (1) JP3703525B2 (ko)
KR (1) KR100386759B1 (ko)
CN (1) CN1116324C (ko)
CA (1) CA2152552C (ko)
DE (2) DE4422157A1 (ko)

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CA2152552A1 (en) 1995-12-25
JP3703525B2 (ja) 2005-10-05
EP0688801A1 (de) 1995-12-27
EP0688801B1 (de) 1997-12-29
CN1116324C (zh) 2003-07-30
JPH0812712A (ja) 1996-01-16
US5698645A (en) 1997-12-16
KR100386759B1 (ko) 2003-08-09
DE59501145D1 (de) 1998-02-05
CA2152552C (en) 2008-03-18
DE4422157A1 (de) 1996-01-04
CN1120551A (zh) 1996-04-17

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