EP0071671B1 - Acetylengas-Reaktor - Google Patents
Acetylengas-Reaktor Download PDFInfo
- Publication number
- EP0071671B1 EP0071671B1 EP81108804A EP81108804A EP0071671B1 EP 0071671 B1 EP0071671 B1 EP 0071671B1 EP 81108804 A EP81108804 A EP 81108804A EP 81108804 A EP81108804 A EP 81108804A EP 0071671 B1 EP0071671 B1 EP 0071671B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- reactor
- reaction vessel
- sump
- water
- carbide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 title description 8
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 title description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- 238000006243 chemical reaction Methods 0.000 claims abstract description 22
- 239000010802 sludge Substances 0.000 claims abstract description 18
- 239000005997 Calcium carbide Substances 0.000 claims abstract description 14
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000003860 storage Methods 0.000 claims abstract description 12
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims abstract description 4
- 235000011941 Tilia x europaea Nutrition 0.000 claims abstract description 4
- 239000004571 lime Substances 0.000 claims abstract description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims abstract description 3
- 239000000920 calcium hydroxide Substances 0.000 claims abstract description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims abstract description 3
- 239000000428 dust Substances 0.000 claims abstract description 3
- 238000010276 construction Methods 0.000 claims abstract 3
- 229940095643 calcium hydroxide Drugs 0.000 claims abstract 2
- 235000011116 calcium hydroxide Nutrition 0.000 claims abstract 2
- 230000001105 regulatory effect Effects 0.000 claims 1
- 239000008187 granular material Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 5
- 239000007921 spray Substances 0.000 description 4
- 238000007789 sealing Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000009420 retrofitting Methods 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10H—PRODUCTION OF ACETYLENE BY WET METHODS
- C10H1/00—Acetylene gas generators with dropwise, gravity, non-automatic water feed
Definitions
- the invention relates to an acetylene gas reactor which is also suitable for mobile use and preferably works with low pressure, in particular for feeding a motor vehicle engine, consisting of a calcium carbide storage container, a reaction vessel with a water supply device and a collecting container for the calcium hydroxide sludge or lime dust which is produced.
- acetylene gas developers which have hitherto become known are generally expensive because of their complicated structure and are very susceptible to faults, since the carbide granules have hitherto generally been passed through screw conveyors and the like under a sprinkler device. They are also generally only suitable for stationary, but not for mobile use. Especially if you want to use them to power a motor vehicle engine, they cannot work properly because of the vehicle vibrations that inevitably occur in motor vehicles and prevent the proper operation of screw conveyors and the like.
- a tubular sieve-shaped guide enclosed by the reaction vessel is arranged in a vertical orientation under the carbide container, which is surrounded by an annular jet nozzle arrangement for supplying the water required for the reaction and into a funnel arranged under the guide tubular collection container opens and that the reaction vessel encloses the carbide container, the jet nozzle arrangement, the water storage container and the collection container.
- the components arranged one above the other in vertical alignment i.e.
- the calcium carbide storage container located above, the sprinkling chamber underneath and the collecting container, which is arranged under the sprinkling chamber in a coaxial orientation, ensure a constant supply of the carbide granules and also a continuous removal of the hydroxide sludge after appropriate consumption.
- the reactor can be designed as a closed cylindrical unit, on the housing of which only connections have to be provided for filling in the carbide granules, for removing the generated gas, for filling up the water of reaction and for removing the hydroxide sludge.
- the jet nozzles are arranged in a ring around the carbide feed path of the reactor in such a way that they support the calcium carbide feed and contribute to self-cleaning of the feed path.
- the reactor according to the invention is enclosed by a cylindrical housing 1.
- the housing 1 When the reactor is in operation, the housing 1 is set up in such a way that its cylinder axis is essentially vertical.
- the upper end face 2 of the housing 1 is recessed in a dome shape and has a filling opening 3 in its center, which can be closed gas-tight with a screw plug 4 and an interposed sealing washer 5.
- a basket-shaped insert In the upper section of the housing 1 there is a basket-shaped insert which serves to hold the calcium carbide required for the reaction.
- the sealing plug 4 When the sealing plug 4 is open, the dome-shaped countersunk end face 2 facilitates the filling process.
- the plug 4 cannot protrude beyond the cylindrical contour of the housing 1.
- the insert 6 receiving the calcium carbide has a funnel-shaped base 7 which merges into a short pipe socket 8 in the middle part.
- a cylindrical screen basket 9 Connected to the pipe socket 8 is a cylindrical screen basket 9, which can consist of perforated sheet metal or of wire mesh. At the upper free end, the carbide granulate can enter the screen basket 9 and fill it up to the bottom of the screen basket, which is also designed as a screen.
- the sieve basket 9 is surrounded by a nozzle arrangement 10 to be described below, with which the water required for the reaction can be sprayed against the walls of the sieve basket and against the calcium carbide contained in the sieve basket.
- a collecting container 11 in the housing 1 which surrounds the strainer basket 9 in its upper, cylindrical section 12 which is open at the top.
- a substantially conical section 13 adjoining section 12 merges in the central region into a further cylindrical section, the diameter of which essentially corresponds to the diameter of the strainer basket 9 and serves as a sludge collecting pipe 14 in a manner to be described below.
- the sludge collecting pipe 14 is sealingly connected to a central opening 15 in the lower end face 16 of the housing 1.
- the lower end face 16 is also recessed in a dome shape and can be closed in the middle with a screw plug 17 and a sealing washer 18.
- the walls of the container are impermeable with off taking water outlet openings in the sludge collecting pipe 14 close to the transition to the conical section 13. These openings 19 are preferably relatively narrow slots which retain solid components but can allow the water to pass through.
- the lower part of the housing 1 between the cylindrical side walls, the lower end face 16 and the sludge collecting pipe 14 below the openings 19 forms the actual water storage space 20.
- a gas-tight filler neck 21 is used to fill up the water storage space 20, which is preferably slightly above the in the housing 1 normally provided water level flows.
- Another connection piece 22, which crosses the side wall of the housing 1, serves to feed the aforementioned nozzle arrangement 10.
- the nozzle arrangement 10 already mentioned consists of an annular tube 23 which surrounds the screen basket 9 concentrically.
- This ring pipe 23 is connected to a radial pipe 24, which also serves to secure the position of the ring pipe 23, with a connecting piece 25 in the side wall of the housing 1.
- the ring tube 23 On the inner circumference of the ring tube 23 there are several spray nozzles distributed over the circumference, via which the water required on the ring tube can be fed in the direction of the strainer basket.
- the spray nozzles 26 are directed so that they can irradiate a large part of the walls of the screen basket 9 and the calcium carbide contained therein. However, at least some of the nozzles 26 are preferably directed such that they support the passage of the calcium carbide particles from the insert 6 to the sludge collecting pipe 14.
- a water pump 27 is used, which is switched on with pipes 28 and 29 between the connecting pieces 22 and 25.
- This pump 27 is preferably a pump that is driven electrically from the on-board battery.
- the gas pressure prevailing in the entire housing 1 can also be used to convey the water from the reservoir 20 to the ring tube 23 or to support the conveyance.
- a pump 27 If a pump 27 is used, it is controlled by a sensor 30, which detects the gas pressure prevailing in the housing 1 via a connecting piece 31 and only switches on the pump 27 when a preset minimum pressure of, for example, 100 mb is not reached.
- the sensor 30 thus forms the switch-on device for the pump 27, which is connected to the on-board battery via the sensor 30.
- the developed acetylene gas is removed from the housing 1 via a gas outlet connection 32, which is connected via a pipeline 33 to a pressure reducing valve 34.
- the pressure reducing valve is adjustable in order to adjust the working pressure of the gas.
- a pipeline 35 leads from the pressure reducing valve 34 to the actual gas valve 36, which is connected to the mixer valve 38 via a pipeline 37.
- the mixer valve 38 receives the air required for combustion from an adjustable air valve 40 via a further pipeline 39.
- optimally combustible gas can be discharged with the help of the valves 36 and 40, with which the gas intake connection of the motor vehicle is then fed can.
- the calcium carbide of the insert 6 also fills the sieve basket 9, where the carbide particles can be supported on the sieve bottom.
- the sludge collecting tube 14 inside the water storage container is empty and sealed at the bottom with the screw plug 17.
- the sensor 30 If the sensor 30 now detects that there is too little or even no gas pressure inside the housing 1, it actuates the pump 27, so that the water pumped out of the water reservoir 20 via the spray nozzles 26 of the ring tube 23 against the carbide granules in the sieve basket 9 is sprayed. As a result of this spraying, acetylene gas develops, which steadily increases the pressure in the housing until the sensor 30 responds again and switches off the pump 27 when a maximum pressure is reached. The pump 27 is only switched on again when the sensor 30 detects an insufficient gas pressure.
- these particles disintegrate and can, if smaller than the mesh opening of the sieve basket, fall out downwards.
- the sludge collecting tube 14 is preferably dimensioned such that it can absorb the carbide residues from a complete filling of the insert 6. If the carbide supply is now used up and the sludge collecting pipe 14 is filled, 4 new calcium carbide granules can be filled in via the stopper and the carbide residues can be reduced Remove the opening of the screw plug 17 at the lower end of the housing 1. If the latter is lined with a cylindrical bag in the manner of vacuum cleaner bags after emptying the sludge collecting tube, the removal of the carbide residues is not only very easy, but also very clean.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Treatment Of Sludge (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Carbon And Carbon Compounds (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3131670A DE3131670C2 (de) | 1981-08-11 | 1981-08-11 | Acetylengas-Reaktor |
DE3131670 | 1981-08-11 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0071671A2 EP0071671A2 (de) | 1983-02-16 |
EP0071671A3 EP0071671A3 (en) | 1983-05-25 |
EP0071671B1 true EP0071671B1 (de) | 1985-05-02 |
Family
ID=6139047
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP81108804A Expired EP0071671B1 (de) | 1981-08-11 | 1981-10-23 | Acetylengas-Reaktor |
Country Status (18)
Country | Link |
---|---|
EP (1) | EP0071671B1 (hu) |
JP (1) | JPS5840389A (hu) |
AT (1) | ATE13071T1 (hu) |
AU (1) | AU544876B2 (hu) |
BR (1) | BR8107505A (hu) |
CA (1) | CA1188101A (hu) |
CS (1) | CS229925B2 (hu) |
DD (1) | DD202305A5 (hu) |
DE (1) | DE3131670C2 (hu) |
DK (1) | DK147601C (hu) |
HU (1) | HU185495B (hu) |
IN (1) | IN155504B (hu) |
MX (1) | MX159101A (hu) |
PH (1) | PH19767A (hu) |
PL (1) | PL129517B1 (hu) |
SU (1) | SU1158047A3 (hu) |
YU (1) | YU41382B (hu) |
ZA (1) | ZA8220B (hu) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7608070B2 (en) | 2004-09-30 | 2009-10-27 | Kimberly-Clark Worldwide, Inc. | Foam-based fasteners |
US7640637B2 (en) | 2005-11-01 | 2010-01-05 | Kimberly-Clark Worldwide, Inc. | Methods to modify the fibrous landing layer of a foam based fastener and products made from the same |
WO2021216288A1 (en) | 2020-04-10 | 2021-10-28 | The Procter & Gamble Company | Cleaning implement with a rheological solid composition |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3223923A1 (de) * | 1982-06-26 | 1983-12-29 | Wolfgang 2210 Itzehoe Priesemuth | Acetylengas-reaktor |
HUT68337A (en) * | 1993-01-29 | 1995-06-28 | Szilvasy | Process and apparatus for producing fuel-gas |
DE19718990C2 (de) * | 1997-05-05 | 2001-07-12 | Priesemuth W | Carbid-Ladung, enthaltend einen Grundkörper aus Calciumcarbid und eine Umhüllung |
US7629043B2 (en) | 2003-12-22 | 2009-12-08 | Kimberly-Clark Worldwide, Inc. | Multi purpose cleaning product including a foam and a web |
JP5101749B2 (ja) * | 2010-11-15 | 2012-12-19 | 電気化学工業株式会社 | アセチレン発生設備、アセチレン発生設備の制御方法及びアセチレンガスの製造方法 |
CN103272536B (zh) * | 2012-06-21 | 2016-05-04 | 北京化工大学 | 一种联产电石、煤气和焦油的复合床反应器及方法 |
CN116200212B (zh) * | 2023-05-06 | 2023-06-30 | 中国科学院过程工程研究所 | 一种利用撞击流进行干法电石渣处理的装置及方法 |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE261701C (hu) * | ||||
DE549555C (de) * | 1932-04-29 | Internationales Patent Und Tec | Acetylenentwickler | |
DE641178C (de) * | 1937-01-21 | Autogenwerk Sirius G M B H | Acetylenentwickler, in dem staubfoermiges und koerniges Karbid vergast wird | |
GB191515628A (en) * | 1915-11-05 | 1916-03-16 | Lewis Radmore | Improvements in and connected with Acetylene Gas Generators. |
DE723910C (de) * | 1937-07-24 | 1942-08-13 | Lonza Werke Elektrochemische F | Verfahren zum Erzeugen von Acetylen |
GB537224A (en) * | 1939-11-29 | 1941-06-13 | Edward Hector Lonsdale Hart | Improvements in acetylene generators |
-
1981
- 1981-08-11 DE DE3131670A patent/DE3131670C2/de not_active Expired
- 1981-10-23 AT AT81108804T patent/ATE13071T1/de not_active IP Right Cessation
- 1981-10-23 EP EP81108804A patent/EP0071671B1/de not_active Expired
- 1981-11-05 DD DD81234654A patent/DD202305A5/de not_active IP Right Cessation
- 1981-11-18 BR BR8107505A patent/BR8107505A/pt unknown
- 1981-12-10 AU AU78443/81A patent/AU544876B2/en not_active Ceased
- 1981-12-14 YU YU2914/81A patent/YU41382B/xx unknown
- 1981-12-15 DK DK554881A patent/DK147601C/da not_active IP Right Cessation
- 1981-12-23 CS CS819749A patent/CS229925B2/cs unknown
- 1981-12-25 SU SU813366199A patent/SU1158047A3/ru active
-
1982
- 1982-01-04 ZA ZA8220A patent/ZA8220B/xx unknown
- 1982-01-05 HU HU8215A patent/HU185495B/hu unknown
- 1982-02-05 IN IN141/CAL/82A patent/IN155504B/en unknown
- 1982-02-26 MX MX191595A patent/MX159101A/es unknown
- 1982-06-07 CA CA000404564A patent/CA1188101A/en not_active Expired
- 1982-06-16 PH PH27438A patent/PH19767A/en unknown
- 1982-08-10 PL PL1982237848A patent/PL129517B1/pl unknown
- 1982-08-10 JP JP57138042A patent/JPS5840389A/ja active Granted
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7608070B2 (en) | 2004-09-30 | 2009-10-27 | Kimberly-Clark Worldwide, Inc. | Foam-based fasteners |
US7640637B2 (en) | 2005-11-01 | 2010-01-05 | Kimberly-Clark Worldwide, Inc. | Methods to modify the fibrous landing layer of a foam based fastener and products made from the same |
WO2021216288A1 (en) | 2020-04-10 | 2021-10-28 | The Procter & Gamble Company | Cleaning implement with a rheological solid composition |
Also Published As
Publication number | Publication date |
---|---|
EP0071671A3 (en) | 1983-05-25 |
JPS5840389A (ja) | 1983-03-09 |
ZA8220B (en) | 1982-11-24 |
SU1158047A3 (en) | 1985-05-23 |
AU544876B2 (en) | 1985-06-20 |
JPS6366359B2 (hu) | 1988-12-20 |
PH19767A (en) | 1986-06-27 |
IN155504B (hu) | 1985-02-09 |
DD202305A5 (de) | 1983-09-07 |
YU41382B (en) | 1987-02-28 |
DK147601C (da) | 1985-04-22 |
DE3131670C2 (de) | 1984-08-23 |
MX159101A (es) | 1989-04-19 |
PL129517B1 (en) | 1984-05-31 |
DK147601B (da) | 1984-10-15 |
EP0071671A2 (de) | 1983-02-16 |
PL237848A1 (en) | 1983-03-14 |
BR8107505A (pt) | 1983-05-17 |
CA1188101A (en) | 1985-06-04 |
ATE13071T1 (de) | 1985-05-15 |
YU291481A (en) | 1983-09-30 |
AU7844381A (en) | 1983-02-17 |
CS229925B2 (en) | 1984-07-16 |
DK554881A (da) | 1983-02-12 |
DE3131670A1 (de) | 1983-03-10 |
HU185495B (en) | 1985-02-28 |
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