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EA201300546A1 - Способ получения полимеров пропилена со сверхвысокой скоростью течения расплава - Google Patents

Способ получения полимеров пропилена со сверхвысокой скоростью течения расплава

Info

Publication number
EA201300546A1
EA201300546A1 EA201300546A EA201300546A EA201300546A1 EA 201300546 A1 EA201300546 A1 EA 201300546A1 EA 201300546 A EA201300546 A EA 201300546A EA 201300546 A EA201300546 A EA 201300546A EA 201300546 A1 EA201300546 A1 EA 201300546A1
Authority
EA
Eurasian Patent Office
Prior art keywords
polymerization
copolymer
homo
reactor
catalyzing
Prior art date
Application number
EA201300546A
Other languages
English (en)
Other versions
EA023164B1 (ru
Inventor
Юха Паавилайнен
Паули Лескинен
Original Assignee
Бореалис Аг
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Бореалис Аг filed Critical Бореалис Аг
Publication of EA201300546A1 publication Critical patent/EA201300546A1/ru
Publication of EA023164B1 publication Critical patent/EA023164B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/12—Polypropene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Предложен способ получения гомо- или сополимера пропилена с MFR(230°С; 2,16 кг; ISO 1133) в пределах от 800 до 3000 г/10 мин, включающий стадии: a) полимеризации пропилена и необязательно этилена и/или сомономера C-Cальфа-олефина в суспензионном реакторе в присутствии катализирующей полимеризацию системы с получением в качестве продукта суспензионного реактора первого компонента гомо- или сополимера с MFR(230°С; 2,16 кг; ISO 1133) в пределах от 1000 до 4000 г/10 мин; b) перемещение продукта суспензионного реактора в газофазный реактор; c) дальнейшую полимеризацию пропилена и необязательно этилена и/или сомономера C-Cальфа-олефина в присутствии указанного продукта суспензионного реактора и катализирующей полимеризацию системы; d) необязательно удаление совместно полученного гомо- или сополимера для дальнейшей технологической обработки указанная катализирующая полимеризацию система включает: (i) прокатализатор Циглера-Натта, (ii) металлоорганический сокатализатор и (iii) внешний донор, представленный формулой (I)где Rи Rмогут быть одинаковыми или отличаться и представлены углеводородной группой, имеющей от 1 до 12 атомов углерода, и применение таких полученных полимеров для аэродинамического распыления расплавов.
EA201300546A 2010-11-12 2011-11-08 Способ получения полимеров пропилена со сверхвысокой скоростью течения расплава EA023164B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP20100191004 EP2452960B1 (en) 2010-11-12 2010-11-12 Process for preparing propylene polymers with an ultra high melt flow rate
PCT/EP2011/069616 WO2012062737A1 (en) 2010-11-12 2011-11-08 Process for preparing propylene polymers with an ultra high melt flow rate

Publications (2)

Publication Number Publication Date
EA201300546A1 true EA201300546A1 (ru) 2013-11-29
EA023164B1 EA023164B1 (ru) 2016-04-29

Family

ID=43920847

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201300546A EA023164B1 (ru) 2010-11-12 2011-11-08 Способ получения полимеров пропилена со сверхвысокой скоростью течения расплава

Country Status (4)

Country Link
EP (1) EP2452960B1 (ru)
CN (1) CN103201302B (ru)
EA (1) EA023164B1 (ru)
WO (1) WO2012062737A1 (ru)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2676763C1 (ru) * 2014-12-15 2019-01-11 Бореалис Аг Нетканые мельтблауны без дробинок и с улучшенными барьерными свойствами

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2749580B1 (en) * 2012-12-28 2016-09-14 Borealis AG Process for producing copolymers of propylene
US9096729B2 (en) 2013-02-06 2015-08-04 Exxonmobil Chemical Patents Inc. Polymerization activators for supported Ziegler-Natta catalysts
CN110612314B (zh) * 2017-05-18 2023-05-30 博里利斯股份公司 具有优异光学性能的多相聚烯烃组合物
CN112384588B (zh) * 2018-07-18 2023-06-16 巴塞尔聚烯烃意大利有限公司 聚烯烃基热熔粘合剂组合物
CN110760130A (zh) * 2018-07-27 2020-02-07 合肥杰事杰新材料股份有限公司 一种低气味聚丙烯材料及其制备方法
EP4210947A4 (en) * 2020-09-09 2024-06-19 W. R. Grace & Co.-Conn POLYPROPYLENE POLYMER WITH ULTRA-HIGH HOT FLOW INDEX
TWI762127B (zh) * 2020-12-29 2022-04-21 臺灣塑膠工業股份有限公司 聚丙烯與其製作方法及熔噴纖維布
WO2022260891A1 (en) * 2021-06-11 2022-12-15 Exxonmobil Chemical Patents Inc. Processes for making polypropylene random copolymers and products made therefrom

Family Cites Families (83)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3242150A (en) 1960-03-31 1966-03-22 Phillips Petroleum Co Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone
US3405109A (en) 1960-10-03 1968-10-08 Phillips Petroleum Co Polymerization process
US3324093A (en) 1963-10-21 1967-06-06 Phillips Petroleum Co Loop reactor
US3374211A (en) 1964-07-27 1968-03-19 Phillips Petroleum Co Solids recovery from a flowing stream
JPS5330681A (en) 1976-09-02 1978-03-23 Mitsui Petrochem Ind Ltd Preparation of polyalpha-olefin
US4347160A (en) 1980-06-27 1982-08-31 Stauffer Chemical Company Titanium halide catalyst system
JPS57153005A (en) 1981-03-19 1982-09-21 Ube Ind Ltd Polymerization of alpha-olefin
US4532311A (en) 1981-03-26 1985-07-30 Union Carbide Corporation Process for reducing sheeting during polymerization of alpha-olefins
US4530912A (en) 1981-06-04 1985-07-23 Chemplex Company Polymerization catalyst and method
US4621952A (en) 1981-07-28 1986-11-11 Union Carbide Corporation Fluidized bed discharge process
DE3271544D1 (en) 1981-08-07 1986-07-10 Ici Plc Supported transition metal composition
US4382019A (en) 1981-09-10 1983-05-03 Stauffer Chemical Company Purified catalyst support
IT1190682B (it) 1982-02-12 1988-02-24 Montedison Spa Catalizzatori per la polimerizzazione di olefine
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4560671A (en) 1983-07-01 1985-12-24 Union Carbide Corporation Olefin polymerization catalysts adapted for gas phase processes
JPS6079540U (ja) 1983-11-08 1985-06-03 三井造船株式会社 気相流動層反応器のガス分散板支持装置
US4933149A (en) 1984-08-24 1990-06-12 Union Carbide Chemicals And Plastics Company Inc. Fluidized bed polymerization reactors
AU576409B2 (en) 1984-12-31 1988-08-25 Mobil Oil Corporation Fluidized bed olefin polymerization process
US4582816A (en) 1985-02-21 1986-04-15 Phillips Petroleum Company Catalysts, method of preparation and polymerization processes therewith
FI80055C (fi) 1986-06-09 1990-04-10 Neste Oy Foerfarande foer framstaellning av katalytkomponenter foer polymerisation av olefiner.
FR2599991B1 (fr) 1986-06-16 1993-04-02 Bp Chimie Sa Evacuation de produits presents dans un reacteur de polymerisation d'alpha-olefines en lit fluidise
US4855370A (en) 1986-10-01 1989-08-08 Union Carbide Corporation Method for reducing sheeting during polymerization of alpha-olefins
US5026795A (en) 1987-02-24 1991-06-25 Phillips Petroleum Co Process for preventing fouling in a gas phase polymerization reactor
US4803251A (en) 1987-11-04 1989-02-07 Union Carbide Corporation Method for reducing sheeting during polymerization of alpha-olefins
AU636487B2 (en) 1990-06-18 1993-04-29 Kimberly-Clark Worldwide, Inc. A nonwoven web with improved barrier properties
US5565175A (en) 1990-10-01 1996-10-15 Phillips Petroleum Company Apparatus and method for producing ethylene polymer
FI89929C (fi) 1990-12-28 1993-12-10 Neste Oy Foerfarande foer homo- eller sampolymerisering av eten
FI86867C (fi) 1990-12-28 1992-10-26 Neste Oy Flerstegsprocess foer framstaellning av polyeten
EP0499759A1 (en) 1991-02-21 1992-08-26 Bp Chemicals S.N.C. Process for monitoring flow in a pneumatic conveying system
FI88048C (fi) 1991-05-09 1993-03-25 Neste Oy Grovkornig polyolefin, dess framstaellningsmetod och en i metoden anvaend katalysator
FI88047C (fi) 1991-05-09 1993-03-25 Neste Oy Pao tvenne elektrondonorer baserad katalysator foer polymerisation av olefiner
FI88049C (fi) 1991-05-09 1993-03-25 Neste Oy Polyolefin med stora porer, foerfarande foer dess framstaellning och en i foerfarandet anvaend katalysator
FI90247C (fi) 1991-05-31 1994-01-10 Borealis As Menetelmä polymerointikatalyytin aktiivisten ja tasakokoisten kantajahiukkasten valmistamiseksi
FI91967C (fi) 1991-11-29 1994-09-12 Borealis Polymers Oy Menetelmä olefiinipolymerointikatalyyttien valmistamiseksi
FI90248C (fi) 1991-11-29 1994-01-10 Borealis As Menetelmä hiukkasmaisen kantajan valmistamiseksi olefiinipolymerointikatalyyttiä varten
IT1262933B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Processo per la polimerizzazione in fase gas di alfa-olefine
FI95715C (fi) 1992-03-24 1996-03-11 Neste Oy Suihkukiteyttämällä valmistetun polymerointikatalyyttikantajan valmistus
DE69317485T2 (de) 1992-07-16 1998-07-09 Bp Chem Int Ltd Polymerisationsverfahren
CA2110140A1 (en) 1992-11-30 1994-05-31 Hiroyuki Koura Gas distributor for use in gas phase polymerization apparatus
JP3077940B2 (ja) 1993-04-26 2000-08-21 エクソン・ケミカル・パテンツ・インク 流動層重合法のための安定な操作条件を決定する方法
ATE260305T1 (de) 1993-04-26 2004-03-15 Exxonmobil Chem Patents Inc Verfahren zur polymerisation von monomeren in wirbelschichtbetten
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
FI96745C (fi) 1993-07-05 1996-08-26 Borealis Polymers Oy Menetelmä olefiinien polymeroimiseksi leijupetipolymerointireaktorissa
FI96867C (fi) 1993-12-27 1996-09-10 Borealis Polymers Oy Leijupetireaktori
JP3497029B2 (ja) 1994-12-28 2004-02-16 三井化学株式会社 気相重合装置用ガス分散板
IT1275573B (it) 1995-07-20 1997-08-07 Spherilene Spa Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine
FI102070B (fi) 1996-03-29 1998-10-15 Borealis As Uusi kompleksiyhdiste, sen valmistus ja käyttö
FI963707A0 (fi) 1996-09-19 1996-09-19 Borealis Polymers Oy Foerfarande foer polymerisering av alfa-olefiner, vid polymerisering anvaendbar katalysator och foerfarande foer framstaellning av densamma
US6057407A (en) * 1997-01-08 2000-05-02 Bp Amoco Corporation High melt flow propylene polymer produced by gas-phase polymerization
FI111846B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto polypropeeniseosten valmistamiseksi
FI111845B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä propeenin homopolymeerien ja iskulujuudeltaan modifioitujen polymeerien valmistamiseksi
FI111848B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi
FI111847B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä propeenin kopolymeerien valmistamiseksi
US6239235B1 (en) 1997-07-15 2001-05-29 Phillips Petroleum Company High solids slurry polymerization
FI974175L (fi) 1997-11-07 1999-05-08 Borealis As Menetelmä polypropeenin valmistamiseksi
FI980342A0 (fi) 1997-11-07 1998-02-13 Borealis As Polymerroer och -roerkopplingar
EP0926165B1 (en) 1997-12-23 2002-02-27 Borealis Technology Oy Catalyst component comprising magnesium, titanium, a halogen and a electron donor, its preparation and use
FI982388A7 (fi) 1998-11-04 2000-05-05 Borealis Polymers Oy Menetelmä staattisen sähkön eliminoimiseksi
FI111953B (fi) 1998-11-12 2003-10-15 Borealis Tech Oy Menetelmä ja laite polymerointireaktoreiden tyhjentämiseksi
FI991015A0 (fi) 1999-05-04 1999-05-04 Borealis As Menetelmä alfa-olefiinipolymeerien valmistamiseksi
FI991057A0 (fi) 1999-05-07 1999-05-07 Borealis As Korkean jäykkyyden propeenipolymeerit ja menetelmä niiden valmistamiseksi
US6617405B1 (en) 1999-07-14 2003-09-09 Union Carbide Chemicals & Plastics Technology Corporation Process for the preparation of polyethylene
FI111955B (fi) 1999-12-27 2003-10-15 Borealis Tech Oy Propeenipolymeerit, joilla on erittäin korkea sulavirta
DE60120141T2 (de) 2001-06-20 2007-03-29 Borealis Technology Oy Herstellung einer Olefinpolymerisationskatalysatorkomponente
DE60120389T2 (de) 2001-06-20 2007-06-14 Borealis Technology Oy Herstellung eines Katalysatorbestandteils zur Olefinpolymerisation
EP1310295B1 (en) 2001-10-30 2007-07-18 Borealis Technology Oy Polymerisation reactor
WO2004016662A1 (ja) 2002-08-19 2004-02-26 Ube Industries, Ltd. α−オレフィンの重合又は共重合に用いられるα−オレフィンの重合又は重合用触媒、その触媒成分及びその触媒を用いたα−オレフィン重合方法
EP1403292B1 (en) 2002-09-30 2016-04-13 Borealis Polymers Oy Process for preparing an olefin polymerisation catalyst component with improved high temperature activity
ES2296888T3 (es) 2002-10-30 2008-05-01 Borealis Technology Oy Proceso y aparato para la produccion de polimeros de olefinas.
EP1484343A1 (en) 2003-06-06 2004-12-08 Universiteit Twente Process for the catalytic polymerization of olefins, a reactor system and its use in the same process
ATE541868T1 (de) 2003-06-20 2012-02-15 Borealis Polymers Oy Verfahren zur herstellung eines katalysators für die olefinpolymerisation
EP1577003A1 (en) 2004-03-15 2005-09-21 Borealis Technology Oy Method and apparatus for producing polymers
ATE329941T1 (de) 2004-04-29 2006-07-15 Borealis Tech Oy Verfahren zur herstellung von polyethylen
CN1993384B (zh) 2004-07-28 2010-11-03 三井化学株式会社 烯烃聚合用催化剂和使用该催化剂的聚合方法
JP2008510872A (ja) 2004-08-23 2008-04-10 エクソンモービル・ケミカル・パテンツ・インク 重合プロセス用装置
EP1717269A1 (en) 2005-04-28 2006-11-02 Borealis Technology Oy Alpha-olefin homo-or copolymer compositions
RU2412207C2 (ru) 2005-05-13 2011-02-20 Базелль Полиолефин Италия С.Р.Л. Способ газофазной полимеризации олефинов
CN1923861B (zh) 2005-09-02 2012-01-18 北方技术股份有限公司 在烯烃聚合催化剂存在下的烯烃聚合方法
EP1860125B1 (en) 2006-05-22 2011-05-11 Borealis Technology Oy A process to produce polyolefins with extra low impurity content
ES2594859T3 (es) 2006-05-31 2016-12-23 Borealis Technology Oy Catalizador con componente de Al-alcoxilo
EP1862480B1 (en) 2006-05-31 2016-07-27 Borealis Technology Oy Process for preparing an olefin polymerisation catalyst component with improved high temperature activity
EP1939227B1 (en) 2006-12-28 2013-10-30 Borealis Technology Oy Catalyst preparation with phosphorous compound
US20110086970A1 (en) * 2008-06-16 2011-04-14 Borealis Ag Thermoplastic polyolefins with high flowability and excellent surface quality produced by a multistage process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2676763C1 (ru) * 2014-12-15 2019-01-11 Бореалис Аг Нетканые мельтблауны без дробинок и с улучшенными барьерными свойствами
US10870937B2 (en) 2014-12-15 2020-12-22 Borealis Ag Melt-blown webs without shots and with improved barrier properties

Also Published As

Publication number Publication date
EP2452960B1 (en) 2015-01-07
WO2012062737A1 (en) 2012-05-18
EA023164B1 (ru) 2016-04-29
CN103201302A (zh) 2013-07-10
EP2452960A1 (en) 2012-05-16
CN103201302B (zh) 2015-02-18

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